JPH02113082A - Water-soluble cutting and grinding composition - Google Patents
Water-soluble cutting and grinding compositionInfo
- Publication number
- JPH02113082A JPH02113082A JP63265026A JP26502688A JPH02113082A JP H02113082 A JPH02113082 A JP H02113082A JP 63265026 A JP63265026 A JP 63265026A JP 26502688 A JP26502688 A JP 26502688A JP H02113082 A JPH02113082 A JP H02113082A
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- grinding
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- carboxylic acid
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Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は水溶性切削、研削用組成物に関し、さらに詳し
くはステンレス等のベルト研削に使用する水溶性切削、
研削用組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a water-soluble cutting and grinding composition, and more specifically to a water-soluble cutting and grinding composition used for belt grinding of stainless steel and the like.
The present invention relates to a grinding composition.
一般にステンレス鋼板や綱帯を製造するに際しては、そ
の製造工程中、熱間圧延後のコイル粗研摩工程、および
調質圧延に引き続くコイル仕上研摩工程が行われ、これ
等工程に於いては、従来鉱物油を主体とするベルト研削
油が使用されて来た。Generally, when manufacturing stainless steel sheets and steel strips, during the manufacturing process, a coil rough polishing process after hot rolling, and a coil finish polishing process following skin pass rolling are performed. Belt grinding oils based on mineral oil have been used.
この従来のベルト研削油は研削中に火花が多発し、火災
の危険があり、またミストが発生し作業環境を著しく悪
くする難点があり、特に前者のコイル粗研摩工程ではコ
イル板表面が粗くまた研削取代が大きいためにこの難点
が極めて重大な問題となっていた。This conventional belt grinding oil generates many sparks during grinding, which poses a risk of fire, and also generates mist, which significantly worsens the working environment.Especially in the former coil rough polishing process, the surface of the coil plate is rough and Since the grinding allowance is large, this difficulty has become an extremely serious problem.
これに対し、水溶性研削油は火災およびミストの問題は
ないが、研削性が低く、研削ベルトの早期交換が必要と
なり、製造コストの増大を来たし、このため従来は、水
溶性研削油は殆んど用いられず、専ら鉱物油を主体とす
る研削油いわゆるニート油が使用されてきた。On the other hand, water-soluble grinding oils do not cause the problems of fire and mist, but they have poor grinding properties and require early replacement of the grinding belt, which increases manufacturing costs.For this reason, conventionally, water-soluble grinding oils Grinding oil mainly composed of mineral oil, so-called neat oil, has been used exclusively.
本発明が解決しようとする課題は、上記従来のニート油
の欠点を解決することである。The problem to be solved by the present invention is to solve the above-mentioned drawbacks of conventional neat oil.
本発明者は上記課題を解決するために鋭意検討した結果
、遂に下記に示す特定の成分を特定量含有する組成物が
上記課題を解決出来ること、即ち水溶性でありながら研
削性能が優れ、研削ベルトの早期交換を必要としない優
れた水溶性切削、研削用組成物となり得ることを見出し
た。尚水溶性であるため火災の危険がなく、しかもミス
トの発生のないことは勿論である。As a result of intensive studies to solve the above problems, the present inventors have finally discovered that a composition containing a specific amount of the specific components shown below can solve the above problems, that is, it is water-soluble, has excellent grinding performance, and has excellent grinding performance. It has been found that the present invention can be used as an excellent water-soluble cutting and grinding composition that does not require early belt replacement. Since it is water-soluble, there is no danger of fire, and it goes without saying that it does not generate mist.
即ち本発明は（Ａ）（イ）炭素数１２〜１８の脂肪族ア
ルコール
（ロ）炭素数１２〜１８の脂肪酸アミド、及び
（ハ）グリセリンのエチレンオキサイドプロピレンオキ
サイド付加物であって、
その分子量が１０００〜１００００の範囲にあるもの
から選ばれた少なくとも１種３〜５０
重量部
（Ｂ）（ニ）炭素数１１〜２２の不飽和カルボン酸、又
は
（ホ）上記（ニ）のカルボン酸に、炭素数１１〜２２の
飽和又は不飽和脂肪族
カルボン酸と炭素数１〜２２の飽和
又は不飽和脂肪族アルコールとのエ
ステル（但し、カルボン酸又はアル
コールの少なくとも一方が不飽和脂
肪族基を有する）の少なくとも１種
を酸価が２０ ｍｇＫＯＨ／ｇ以上となる様に混合した
混合物、
にその３〜２５重量％の硫黄を付加した有機硫黄化合物
の少なくとも１種１〜３０重量部、及び
（Ｃ） アルカノールアミン１〜３０重量部を主成分
として成ることを特徴とする水溶性切削、研削用組成物
に係るものである。That is, the present invention is an ethylene oxide propylene oxide adduct of (A) (a) an aliphatic alcohol having 12 to 18 carbon atoms, (b) a fatty acid amide having 12 to 18 carbon atoms, and (c) glycerin, the molecular weight of which is 3 to 50 parts by weight of at least one selected from those in the range of 1,000 to 10,000; Ester of a saturated or unsaturated aliphatic carboxylic acid having 11 to 22 carbon atoms and a saturated or unsaturated aliphatic alcohol having 1 to 22 carbon atoms (provided that at least one of the carboxylic acid or the alcohol has an unsaturated aliphatic group) A mixture of at least one of the following to have an acid value of 20 mgKOH/g or more, 1 to 30 parts by weight of at least one organic sulfur compound to which 3 to 25% by weight of sulfur is added; This invention relates to a water-soluble cutting and grinding composition characterized by containing 1 to 30 parts by weight of alkanolamine as a main component.
本発明の組成物は基本的には、上記（Ａ）、（Ｂ）及び
（Ｃ）の成分を含有して成るものであり、これ等（八）
〜（Ｃ）の各成分を上記特定量含有せしめることにより
、はじめて優れた切削、研削特性を発揮し、惹いては研
削ベルトの早期交換が不要となる。また水溶性であるた
めに火災の危険がなく、ミストも発生しない。この際上
記（Ａ）〜（Ｃ）の各成分のうちどれ１つが欠けても上
記優れた効果は発揮されず、更には上記３成分を上記特
定割合で併用しなければ上記優れた効果が損なわれる傾
向が生じる。The composition of the present invention basically contains the above components (A), (B) and (C), and these (8)
By containing each of the components (C) in the above-mentioned specific amounts, excellent cutting and grinding properties are exhibited for the first time, and early replacement of the grinding belt becomes unnecessary. Furthermore, since it is water-soluble, there is no danger of fire and no mist is generated. In this case, even if any one of the above components (A) to (C) is missing, the above excellent effect will not be exhibited, and furthermore, the above excellent effect will be impaired unless the above three components are used together in the above specific ratio. There is a tendency to
先ず本発明の（Ａ）成分から説明する。First, component (A) of the present invention will be explained.
本発明に於いて使用する脂肪族アルコールは炭素数１２
〜１日のものを使用し飽和ばかりでなく不飽和脂肪族ア
ルコールをも包含する。また１価アルコールばかりでな
く、多価アルコールも使用することが出来、更にはＯＨ
基等適宜な置換基が置換したものも使用出来、たとえば
オキソアルコール等も使用することが出来る。好ましい
具体例は、例えばラウリルアルコール、オレイルアルコ
ール、ステアリルアルコール、オキソアルコール、トリ
メチロールプロパン等である。The aliphatic alcohol used in the present invention has 12 carbon atoms.
~1 day is used and includes not only saturated but also unsaturated aliphatic alcohols. In addition, not only monohydric alcohols but also polyhydric alcohols can be used, and even OH
Those substituted with appropriate substituents such as groups can also be used, and for example, oxo alcohols and the like can also be used. Preferred specific examples include lauryl alcohol, oleyl alcohol, stearyl alcohol, oxo alcohol, trimethylolpropane, and the like.
脂肪族アミドは炭素数１２〜１８のものであって、その
脂肪族基としては飽和ばかりでなく不飽和のものでも良
い。またアミドとしては１級アミドばかりでなく、２〜
３級アミドも包含され、更にはＯＨ基等が置換していて
も良い。好ましい具体例として例えばラウリルアミド、
オレイルアミド、ステアリルアミド、オキソアルコール
アミド等を使用することができる。The aliphatic amide has 12 to 18 carbon atoms, and the aliphatic group may be unsaturated as well as saturated. In addition, amides include not only primary amides, but also 2- to
Tertiary amides are also included, and further, OH groups and the like may be substituted. Preferred specific examples include laurylamide,
Oleylamide, stearylamide, oxoalcoholamide, etc. can be used.
この炭素数１２〜１８の脂肪族アルコール又は（及び）
脂肪族アミドは主に研削性を賦与するための成分であり
、いずれに於いても炭素数が１２に達しないと研削性が
不足し、また炭素数が１８より大きくなると流動性が低
下する傾向がある。This aliphatic alcohol having 12 to 18 carbon atoms or (and)
Aliphatic amide is a component that mainly imparts grindability, and in any case, if the number of carbon atoms does not reach 12, grindability is insufficient, and if the number of carbon atoms exceeds 18, fluidity tends to decrease. There is.
次にグリセリンのエチレンオキシドプロピレンオキシド
（以下ＥＯＰＯと略記する）付加物について説明するが
、この付加物もやはり主に研削性を賦与するために使用
される成分であり、その分子量は１０００〜１００００
の範囲のものを使用する。分子量が１０００に達しない
と研削性が不足し、１００００より多くなると溶解性が
低下する。またエチレンオキシドとプロピレンオキシド
の割合はエチレンオキシドが３０〜９０重量％好ましく
は４０〜６０重量％であってエチレンオキシドが３０重
量％未満では溶解性が不足し、９０重量％以上では研削
性が不足する。Next, the ethylene oxide propylene oxide (hereinafter abbreviated as EOPO) adduct of glycerin will be explained. This adduct is also a component mainly used to impart grindability, and its molecular weight is 1,000 to 10,000.
Use a range of . If the molecular weight does not reach 1,000, grindability is insufficient, and if it exceeds 10,000, solubility decreases. The ratio of ethylene oxide to propylene oxide is 30 to 90% by weight, preferably 40 to 60% by weight; if ethylene oxide is less than 30% by weight, the solubility will be insufficient, and if it is 90% by weight or more, the grindability will be insufficient.
本発明に於いてはこの（Ａ）成分としては上記（イ）〜
（ハ）の各成分の１種または２種以上が併用され、その
使用量は３〜５０重量部好ましくは５〜４０重量部であ
る。３重量部に達しないと研削性が不足し、５０重量部
より多くなると溶解性が低下する。In the present invention, the component (A) includes the above (a) to
One or more of the components (c) are used in combination, and the amount used is 3 to 50 parts by weight, preferably 5 to 40 parts by weight. If the amount is less than 3 parts by weight, the grindability will be insufficient, and if it is more than 50 parts by weight, the solubility will decrease.
次いで（Ｂ）成分について説明する。Next, component (B) will be explained.
この（Ｂ）成分は主に極圧性を付与することにより研削
性能を向上せしめる目的で使用され、その使用量は１〜
３０重量部である。この際１重量部未満では研削性が不
足し、３０重量部より多いと溶解性が低下する。This component (B) is mainly used for the purpose of improving grinding performance by imparting extreme pressure properties, and the amount used is 1 to 1.
It is 30 parts by weight. In this case, if it is less than 1 part by weight, the grindability is insufficient, and if it is more than 30 parts by weight, the solubility is decreased.
この（Ｂ）成分を大別すると１つは炭素数１１〜２２の
不飽和カルボン酸に３〜２５％の硫黄を付加せしめた反
応生成物であり、他の１つは上記のカルボン酸に、炭素
数１１〜２２の飽和又は不飽和脂肪族カルボン酸と炭素
数１〜２２の飽和又は不飽和脂肪族アルコールとのエス
テル（但しカルボン酸又はアルコールの少なくとも一方
が不飽和脂肪族基を有する）の少なくとも１種を酸価が
２０■ＫＯＨ／ｇ以上となる様に混合した混合物に、そ
の３〜２５重量％の硫黄を付加した反応生成物である。Roughly dividing this component (B), one is a reaction product in which 3 to 25% of sulfur is added to an unsaturated carboxylic acid having 11 to 22 carbon atoms, and the other is a reaction product in which 3 to 25% of sulfur is added to the above carboxylic acid. An ester of a saturated or unsaturated aliphatic carboxylic acid having 11 to 22 carbon atoms and a saturated or unsaturated aliphatic alcohol having 1 to 22 carbon atoms (provided that at least one of the carboxylic acid or the alcohol has an unsaturated aliphatic group) It is a reaction product obtained by adding 3 to 25% by weight of sulfur to a mixture of at least one substance having an acid value of 20 ■KOH/g or more.
尚３〜２５重量％とは硫黄付加物中の硫黄の量が３〜２
５重量％であることを示す。ここで使用する炭素数１１
〜２２の不飽和脂肪族カルボン酸としては一塩基酸ばか
りでなく多塩基酸も使用され、また置換基たとえばＯＨ
基その他の基が置換していても良い。好ましい具体例と
してたとえばウンデシレン酸、オレイン酸、エルシン酸
、リノール酸、リルン酸、エレオステアリン酸、ワシル
イン酸、エライジン酸、リンデル酸、アラキドン酸等が
例示できる。Note that 3 to 25% by weight means that the amount of sulfur in the sulfur adduct is 3 to 2% by weight.
It shows that it is 5% by weight. The carbon number used here is 11.
As the unsaturated aliphatic carboxylic acids of ~22, not only monobasic acids but also polybasic acids are used, and substituents such as OH
It may be substituted with other groups. Preferred specific examples include undecylenic acid, oleic acid, erucic acid, linoleic acid, linuric acid, eleostearic acid, wasillic acid, elaidic acid, lindelic acid, and arachidonic acid.
また上記エステルを構成する一成分である炭素数１１〜
２２の飽和又は不飽和脂肪族カルボン酸としては、不飽
和脂肪族カルボン酸は上記と同様のものが使用され、ま
た飽和脂肪族カルボン酸とじては一塩基酸ばかりでなく
、多塩基酸も使用出来、また必要に応じＯＲ基等適宜な
置換基が置換していても良い１代表的な具体例としては
、ラウリン酸、トリデシル酸、ミリスチン酸、ペンタデ
シル酸、パルミチン酸、ステアリン酸、ノンデシル酸、
ベヘン酸、エイコサノイック酸等が例示できる。Also, one component constituting the above-mentioned ester has 11 to 11 carbon atoms.
As the saturated or unsaturated aliphatic carboxylic acids in 22, the same unsaturated aliphatic carboxylic acids as mentioned above are used, and as the saturated aliphatic carboxylic acids, not only monobasic acids but also polybasic acids are used. Representative examples include lauric acid, tridecylic acid, myristic acid, pentadecyl acid, palmitic acid, stearic acid, nondecylic acid,
Examples include behenic acid and eicosanoic acid.
上記エステルの他の一成分たる飽和または不飽和アルコ
ールとしてはその炭素数が１〜２２の１価または多価ア
ルコールが使用される。好ましい具体例としてはたとえ
ばメチルアルコール、エチルアルコール、ブチルアルコ
ール、ヘキシルアルコール、オクチルアノール、ラウリ
ルアルコール、オレイルアルコール、ステアリルアルコ
ール、オキソアルコール等が例示できる。As the saturated or unsaturated alcohol which is another component of the above ester, a monohydric or polyhydric alcohol having 1 to 22 carbon atoms is used. Preferred examples include methyl alcohol, ethyl alcohol, butyl alcohol, hexyl alcohol, octyl anol, lauryl alcohol, oleyl alcohol, stearyl alcohol, and oxo alcohol.
上記エステルとしては特に上記カルボン酸またはアルコ
ールの少なくともいずれか一方が不飽和脂肪族基である
ことが必須である。この際いずれもが飽和脂肪族基の場
合には硫黄が反応しないため、目的の添加剤にならない
ので好ましくない。In the above-mentioned ester, it is particularly essential that at least one of the above-mentioned carboxylic acid or alcohol is an unsaturated aliphatic group. In this case, if both groups are saturated aliphatic groups, the sulfur will not react with the group, and the target additive will not be used, which is not preferable.
このエステルは上記炭素数１１〜２２の不飽和脂肪族カ
ルボン酸に、得られる混合物の酸価が２０■ＫＯＨ／ｇ
以上となるように混合される。この際の酸価が上記値に
達しないと水溶性が低下する。This ester is added to the unsaturated aliphatic carboxylic acid having 11 to 22 carbon atoms, and the resulting mixture has an acid value of 20 KOH/g.
They are mixed so that the above results are achieved. If the acid value at this time does not reach the above value, the water solubility will decrease.
本発明に於ける（Ｂ）成分は上記不飽和脂肪族カルボン
酸、または上記混合物に３〜２５重量％の硫黄を付加せ
しめた反応物であり、この反応は以下の様にして行われ
る。即ちこの硫黄付加反応は無溶媒、反応温度９０〜１
２０°Ｃ１反応時間３０分〜２時間の条件下、該カルボ
ン酸または混合物に対し、硫黄付加量が３〜２５好まし
くは５〜２０重量％になる様に反応させる。ここで硫黄
付加量が３重量％に達しないと研削性が不足し、２５重
量％より多（なると臭気が大となるので好ましくない。Component (B) in the present invention is a reaction product obtained by adding 3 to 25% by weight of sulfur to the above-mentioned unsaturated aliphatic carboxylic acid or the above-mentioned mixture, and this reaction is carried out as follows. That is, this sulfur addition reaction is carried out without solvent and at a reaction temperature of 90 to 1
The carboxylic acid or the mixture is reacted at 20 DEG C. for a reaction time of 30 minutes to 2 hours so that the amount of sulfur added is 3 to 25% by weight, preferably 5 to 20% by weight. If the amount of sulfur added does not reach 3% by weight, the grindability will be insufficient, and if the amount is more than 25% by weight, the odor will become large, which is not preferable.
本発明に於いて使用する（Ｃ）成分たるアルカノールア
ミンは主に（Ｂ）成分と反応してアミン塩とし水に可溶
なものとする目的で使用され、その使用量は１〜３０重
量部である。この際１重量部未満では、（Ｂ）成分の溶
解性が低下する傾向が生じ、３０重量部より多くなると
添加効果が少なくなる傾向が生ずる。アルカノールアミ
ンは具体的には、たとえばモノエタノールアミン、ジェ
タノールアミン、トリエタノールアミン、Ｎ、Ｎジメチ
ルエタノールアミン、Ｎ、Ｎジエチルエタノールアミン
、Ｎ、Ｎジイソプロピルエタノールアミン、Ｎ−（βア
ミノエチル）エタノールアミン、Ｎ−メチルメタノール
アミン、Ｎ−Ｎ−ビス（β−アミノエチル）エタノール
アミン等が例示できる。The alkanolamine as component (C) used in the present invention is mainly used for the purpose of reacting with component (B) to form an amine salt which is soluble in water, and the amount used is 1 to 30 parts by weight. It is. In this case, if it is less than 1 part by weight, the solubility of component (B) tends to decrease, and if it exceeds 30 parts by weight, the effect of addition tends to decrease. Alkanolamines include, for example, monoethanolamine, jetanolamine, triethanolamine, N,N dimethylethanolamine, N,N diethylethanolamine, N,N diisopropylethanolamine, and N-(β-aminoethyl)ethanol. Examples include amine, N-methylmethanolamine, and N-N-bis(β-aminoethyl)ethanolamine.
本発明水溶性切削、研削組成物は上記（Ａ）（Ｂ）及び
（Ｃ）成分が必須であるが、この他に必要に応じて塩素
系または硫黄系極圧添加剤例えば塩素化脂肪酸、塩素化
油脂、塩素化パラフィン、硫黄化脂肪酸等が、またその
他油脂も配合することが出来る。またその他この種組成
物に従来から使用されて来た各種の添加剤を配合するこ
とが出来る。In the water-soluble cutting and grinding composition of the present invention, the above components (A), (B), and (C) are essential, but in addition to these, chlorine-based or sulfur-based extreme pressure additives such as chlorinated fatty acids, chlorine, etc. Chemical oils and fats, chlorinated paraffins, sulfurized fatty acids, and other oils and fats can also be blended. In addition, various other additives conventionally used in this type of composition can be blended.
本発明組成物はこれを使用するに際しては適宜水で希釈
して使用するが、使用状態に於いてその組成物濃度が２
０〜５０重景％程度になるように水に溶解させることが
好ましい。When using the composition of the present invention, it is diluted with water as appropriate.
It is preferable to dissolve it in water to a concentration of about 0 to 50%.
（実施例）
次に本発明の詳細な説明するため、実施例をあげて詳述
する。(Examples) Next, in order to explain the present invention in detail, examples will be given and described in detail.
実施例１〜５
第１表に示す所定の成分を所定Ｎ（重量部）混合して組
成物を調製した。Examples 1 to 5 Compositions were prepared by mixing predetermined components shown in Table 1 in predetermined N (parts by weight).
比較例
鉱油９２．１重量部、ウールグリース５．６重量部及び
ジンクジチオフォスフェート２．３重量部を混合して組
成物を得た。Comparative Example A composition was obtained by mixing 92.1 parts by weight of mineral oil, 5.6 parts by weight of wool grease, and 2.3 parts by weight of zinc dithiophosphate.
実施例および比較例の各組成物を下記条件にてベルト研
削試験を行った。その結果を第１図に示す。但し第１図
中イ〜ホは順番に実施例１〜５の組成物を表し、また点
線で示したへは比較例の組成物を表す。A belt grinding test was conducted on each of the compositions of Examples and Comparative Examples under the following conditions. The results are shown in FIG. However, in FIG. 1, I to H represent the compositions of Examples 1 to 5 in order, and the dotted line represents the composition of the comparative example.
ベルト研削試験条件
試験機：南式千面研磨機
材料送り速度：１２ｍ／分
ベルト速度： １２００ｍ／分
ベルト寸法： １００ Ｘ２１００ｒＩＲベルト種：ク
ロスベルト＃６０（氷塊工業製＾Ａ−ＥＲ５）研削圧：
２０ｋｇ１５０埴（Ｗ）
研削圧＃：５００ＩＴ１１＋＋
被研削材：５ＵＳ３０４１０（ｔ）Ｘ５０（Ｗ） ｘ５
００（ｆ） ｒｔｒｍコンタクトロール： ２５０ｍ
ｍ （φ） 、７０ｄｕｒ。Belt grinding test conditions Test machine: Southern type thousand-sided grinder Material feed speed: 12 m/min Belt speed: 1200 m/min Belt dimensions: 100
20kg150 clay (W) Grinding pressure #: 500IT11++ Material to be ground: 5US30410 (t) x 50 (W) x5
00(f) rtrm contact roll: 250m
m (φ), 70 dur.
但し第１表中の次の記載は以下のことを表す。However, the following description in Table 1 represents the following.
ＤＥＡ ニジエタノールアミン ＴＥＡ ：）リエタノールアミン ＴＩＰＡ ニトリイソプロピルアミンDEA Nidiethanolamine TEA :) Reethanolamine TIPA Nitriisopropylamine
第１図は各組成物のベルト研削試験の結果を示す。 FIG. 1 shows the results of the belt grinding test for each composition.
Claims (2)
ル、 （ロ）炭素数１２〜１８の脂肪酸アミド、 及び （ハ）グリセリンのエチレンオキサイドプ ロピレンオキサイド付加物であって、 その分子量が１０００〜１００００の範囲にあるもの から選ばれた少なくとも１種３〜５０ 重量部、 （Ｂ）（ニ）炭素数１１〜２２の不飽和カルボン酸、又
は （ホ）上記（ニ）のカルボン酸に、炭素数 １１〜２２の飽和又は不飽和脂肪族 カルボン酸と炭素数１〜２２の飽和 又は不飽和脂肪族アルコールとのエ ステル（但し、カルボン酸又はアル コールの少なくとも一方が不飽和脂 肪族基を有する）の少なくとも１種 を酸価が２０ｍｇＫＯＨ／ｇ以上となる 様に混合した混合物、 にその３〜２５重量％の硫黄を付加した 有機硫黄化合物の少なくとも１種１〜３ ０重量部、及び （Ｃ）アルカノールアミン１〜３０重量部 を主成分として成ることを特徴とする水溶 性切削、研削用組成物。(1) (A) (a) an aliphatic alcohol having 12 to 18 carbon atoms, (b) a fatty acid amide having 12 to 18 carbon atoms, and (c) an ethylene oxide propylene oxide adduct of glycerin, the molecular weight of which is 3 to 50 parts by weight of at least one selected from those in the range of 1000 to 10000, (B) (d) unsaturated carboxylic acid having 11 to 22 carbon atoms, or (e) the carboxylic acid of (d) above; , an ester of a saturated or unsaturated aliphatic carboxylic acid having 11 to 22 carbon atoms and a saturated or unsaturated aliphatic alcohol having 1 to 22 carbon atoms (provided that at least one of the carboxylic acid or the alcohol has an unsaturated aliphatic group) 1 to 30 parts by weight of at least one organic sulfur compound with 3 to 25% by weight of sulfur added to (C). ) A water-soluble cutting and grinding composition comprising 1 to 30 parts by weight of an alkanolamine as a main component.
てその濃度が２０〜５０重量％になるように水に溶解さ
せたことを特徴とする切削、研削用組成物。(2) A composition for cutting and grinding, characterized in that the composition according to claim 1 is dissolved in water to a concentration of 20 to 50% by weight when used.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63265026A JPH02113082A (en) | 1988-10-20 | 1988-10-20 | Water-soluble cutting and grinding composition |
| JP5088149A JPH0739588B2 (en) | 1988-10-20 | 1993-03-22 | Water-soluble cutting and grinding composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63265026A JPH02113082A (en) | 1988-10-20 | 1988-10-20 | Water-soluble cutting and grinding composition |
| JP5088149A JPH0739588B2 (en) | 1988-10-20 | 1993-03-22 | Water-soluble cutting and grinding composition |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5088149A Division JPH0739588B2 (en) | 1988-10-20 | 1993-03-22 | Water-soluble cutting and grinding composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02113082A true JPH02113082A (en) | 1990-04-25 |
| JPH0571638B2 JPH0571638B2 (en) | 1993-10-07 |
Family
ID=26429584
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63265026A Granted JPH02113082A (en) | 1988-10-20 | 1988-10-20 | Water-soluble cutting and grinding composition |
| JP5088149A Expired - Lifetime JPH0739588B2 (en) | 1988-10-20 | 1993-03-22 | Water-soluble cutting and grinding composition |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5088149A Expired - Lifetime JPH0739588B2 (en) | 1988-10-20 | 1993-03-22 | Water-soluble cutting and grinding composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (2) | JPH02113082A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998008919A3 (en) * | 1996-08-30 | 1999-10-28 | Solutia Inc | Novel water soluble metal working fluids |
| WO2017141989A1 (en) * | 2016-02-16 | 2017-08-24 | 出光興産株式会社 | Water-soluble metalworking oil composition, metalworking fluid and metalworking method |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6206764B1 (en) * | 1997-04-17 | 2001-03-27 | The United States Of America As Represented By The Secretary Of Commerce | Methods for machining hard materials using alcohols |
| JP2000290676A (en) * | 1999-04-05 | 2000-10-17 | Idemitsu Kosan Co Ltd | Metalworking oil composition |
| US6413917B1 (en) * | 1999-07-21 | 2002-07-02 | Dainippon Ink And Chemicals, Inc. | Extreme-pressure additive, process for producing the same, cutting fluid, and grinding fluid |
| JP2002294267A (en) * | 2001-03-30 | 2002-10-09 | Dainippon Ink & Chem Inc | Cutting fluid and grinding fluid |
| JP4761096B2 (en) * | 2001-03-30 | 2011-08-31 | Ｄｉｃ株式会社 | Method for producing sulfurized hydroxy fatty acid dimer and salt thereof |
| DE102007041372A1 (en) * | 2007-08-30 | 2009-03-05 | Technische Universität Braunschweig Carolo-Wilhelmina | coolant |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS543105A (en) * | 1977-06-07 | 1979-01-11 | Dow Chemical Co | Oillinnwater type of lubricating and cooling liquid emulsion |
| JPS5698294A (en) * | 1980-01-09 | 1981-08-07 | Honda Motor Co Ltd | Water-soluble cutting oil |
| JPS58109596A (en) * | 1981-12-23 | 1983-06-29 | Caterpillar Mitsubishi Ltd | Water-soluble lubricant for tapping |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5412042B2 (en) * | 1973-08-10 | 1979-05-19 |
-
1988
- 1988-10-20 JP JP63265026A patent/JPH02113082A/en active Granted
-
1993
- 1993-03-22 JP JP5088149A patent/JPH0739588B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS543105A (en) * | 1977-06-07 | 1979-01-11 | Dow Chemical Co | Oillinnwater type of lubricating and cooling liquid emulsion |
| JPS5698294A (en) * | 1980-01-09 | 1981-08-07 | Honda Motor Co Ltd | Water-soluble cutting oil |
| JPS58109596A (en) * | 1981-12-23 | 1983-06-29 | Caterpillar Mitsubishi Ltd | Water-soluble lubricant for tapping |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998008919A3 (en) * | 1996-08-30 | 1999-10-28 | Solutia Inc | Novel water soluble metal working fluids |
| WO2017141989A1 (en) * | 2016-02-16 | 2017-08-24 | 出光興産株式会社 | Water-soluble metalworking oil composition, metalworking fluid and metalworking method |
| CN108603135A (en) * | 2016-02-16 | 2018-09-28 | 出光兴产株式会社 | Water-soluble metal working oil composition, metal working fluid and metal working method |
| KR20180115685A (en) * | 2016-02-16 | 2018-10-23 | 이데미쓰 고산 가부시키가이샤 | Water-soluble metal processing oil composition, metal working fluid and metal working method |
| JPWO2017141989A1 (en) * | 2016-02-16 | 2018-12-06 | 出光興産株式会社 | Water-soluble metalworking oil composition, metalworking fluid, and metalworking method |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0673392A (en) | 1994-03-15 |
| JPH0571638B2 (en) | 1993-10-07 |
| JPH0739588B2 (en) | 1995-05-01 |
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