JPH02117979A - Stain-resistant polishing composition - Google Patents
Stain-resistant polishing compositionInfo
- Publication number
- JPH02117979A JPH02117979A JP27164288A JP27164288A JPH02117979A JP H02117979 A JPH02117979 A JP H02117979A JP 27164288 A JP27164288 A JP 27164288A JP 27164288 A JP27164288 A JP 27164288A JP H02117979 A JPH02117979 A JP H02117979A
- Authority
- JP
- Japan
- Prior art keywords
- wax
- polishing agent
- silicone
- water
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005498 polishing Methods 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 title claims abstract description 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 12
- 239000000126 substance Substances 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- 239000002904 solvent Substances 0.000 abstract description 7
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000003995 emulsifying agent Substances 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000004033 plastic Substances 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000002023 wood Substances 0.000 abstract description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000011863 silicon-based powder Substances 0.000 abstract 1
- 229920002545 silicone oil Polymers 0.000 description 8
- 239000001993 wax Substances 0.000 description 8
- 229920002050 silicone resin Polymers 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000212892 Chelon Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004166 Lanolin Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 235000019388 lanolin Nutrition 0.000 description 1
- 229940039717 lanolin Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000011146 organic particle Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 235000011118 potassium hydroxide Nutrition 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、自動車の車体あるいは電気機器等の塗装面、
または家具その他の塗装面、とくに金属、木、プラスチ
ック等の表面に容易に塗布し、垢の付着がなく、耐久性
の良い艶出しを与える改良された艶出し剤に関する。[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to painted surfaces of automobile bodies or electrical equipment, etc.
The present invention also relates to an improved polishing agent that can be easily applied to furniture and other painted surfaces, especially metal, wood, plastic, etc. surfaces, and provides a durable polish without the adhesion of grime.
（従来の技術）
従来、ワックス類を主体とする艶出し剤としては数多く
提案されており、ワックス、ワックス状物、シリコーン
オイル、マたはシリコーンレジン等を溶剤に溶解した溶
剤型、または溶剤に溶解後、水で乳化した乳化型で、形
状は液状、ペースト状あぶいは固型状で使用されている
。(Prior art) Many polishing agents based on waxes have been proposed in the past. After dissolving, it is emulsified with water, and is used in liquid form, while paste-like foam is used in solid form.
（発明が解決しようとする問題点）
しかしながら、これら従来の艶出し剤は光沢は得られる
ものの、太陽光線、雨等の自然条件下、水洗してもなか
なか除去されない、油性のｔηれ垢が着き易いと云う欠
点がある。(Problems to be Solved by the Invention) However, although these conventional polishing agents can provide gloss, they leave oil-based stains that are difficult to remove even when washed with water under natural conditions such as sunlight and rain. It has the disadvantage of being easy.
（問題点を解決するための手段）
本発明者等は、上記の実情のもと、垢の付着しな（・（
詳しくは水洗しても除去できない油性の汚れ垢の付着を
防止する）艶出し剤を得ることを目的として種々検討を
重ねたところ、汚れ垢は、主として艶出し剤中のシリコ
ーンオイルおよびシリコーンレジンに起因するので、先
づ、これを少くするかもしくは使用しないことに着眼し
、次いで、このシリコーンオイルおよびシリコーンレジ
ンを少くすることによる作業性（とくに拭きとり性）の
低下は、特定のパウダーを使用することにより容易に補
われることを知見した。本発明はこの知見に基づくもの
であり、ワックスおよび／またはワックス状物質からな
る艶出し剤中にシリコーンパウダーを含有することを特
徴とする垢付着防止性の艶出し剤組成物を要旨とする。(Means for solving the problem) Under the above-mentioned circumstances, the inventors of the present invention,
After conducting various studies with the aim of obtaining a polishing agent (preventing the adhesion of oil-based dirt and grime that cannot be removed even by washing with water), we found that dirt and grime are mainly caused by the silicone oil and silicone resin in the polishing agent. First, we focused on reducing or not using silicone oil and silicone resin, and then we considered reducing workability (especially wiping performance) by reducing the amount of silicone oil and silicone resin. We found that this can be easily compensated for by doing so. The present invention is based on this knowledge, and its gist is a polishing agent composition with anti-scum adhesion properties, which is characterized by containing silicone powder in a polishing agent made of wax and/or a waxy substance.
以下、本発明の詳細な説明する。The present invention will be explained in detail below.
本発明の艶出し剤の主たる成分は、従来から慣用されて
いるカルナバワックス、モンタンワックス、パラフィン
ワックス、マイクロクリスタリンワックス、ポリエチレ
ンワックス等の天然または合成ワックス、またはステア
リン酸、硬化ヒマシ油、ラノリン、金属石けん等の油脂
、脂肪酸およびその誘導体等のワックス状物質が用いら
れる。The main components of the polishing agent of the present invention are conventionally used natural or synthetic waxes such as carnauba wax, montan wax, paraffin wax, microcrystalline wax, and polyethylene wax, or stearic acid, hydrogenated castor oil, lanolin, and metals. Oils and fats such as soap, waxy substances such as fatty acids and derivatives thereof are used.
更に合成樹脂類が用いられることもある。これらは工業
用ガソリン、灯油、ミネラルスピリット、ノルマルハラ
フィン系溶剤、イソパラフィン系溶剤等の溶剤に溶解し
た溶剤型として、あるいはこの溶剤型のものに乳化剤を
加えて水で乳化した乳化型として使用される。また、オ
レイン酸、ステアリン酸等の脂肪酸にトリエタノールア
ミン、モルホリン、苛性カリ等のアルカリ物質を水とと
もに加えて加熱し、けん化してゲルとしても使用される
。Furthermore, synthetic resins may also be used. These are used as a solvent type dissolved in a solvent such as industrial gasoline, kerosene, mineral spirits, normal halaffinic solvents, isoparaffinic solvents, etc., or as an emulsified type in which an emulsifier is added to the solvent type and emulsified with water. Ru. It is also used as a gel by adding an alkaline substance such as triethanolamine, morpholine, or caustic potash to a fatty acid such as oleic acid or stearic acid together with water, heating it, and saponifying it.
本発明ではシリコーンパウダーを使用するが、これは主
として球状に超微粒子化したシリコーンゴム弾性体であ
り、耐熱性、耐寒性、耐候性などの点で、従来の有機系
の微粒子にはないシリコーン特有の性質を有するもので
ある。これはトーレシリコーン■より” トレフイルＥ
シリーズ”として販売されており、平均粒径３〜７０μ
ｍのものである。In the present invention, silicone powder is used, which is mainly a silicone rubber elastic body made into ultra-fine spherical particles, and has unique characteristics of silicone that conventional organic particles do not have in terms of heat resistance, cold resistance, weather resistance, etc. It has the following characteristics. This is from Toray Silicone ■” Toray Fil E
Series”, with an average particle size of 3 to 70 μm.
It belongs to m.
本発明の艶出し剤の配合割合（以下、％は重量％を示す
）としては、ワックスおよび／またはワックス状物を通
常、０．５〜５０％、好ましくは１〜３０％、溶剤を０
〜５０％、水３０〜９９％、乳化剤０．１〜ｌＯ％程度
である。シリコーンパウダーは余り多いと研磨剤の効果
を悪くするので、艶出し剤に対し通常、５％以下、好ま
しくは３％以下程度添加する。更に必要に応じ、増粘剤
、研磨剤、ゲル化剤、帯電防止剤、紫外線吸収剤等を補
助的に添加してもよい。The blending ratio of the polishing agent of the present invention (hereinafter % indicates weight %) is usually 0.5 to 50%, preferably 1 to 30% of wax and/or wax-like material, and 0% of solvent.
-50%, water 30-99%, and emulsifier 0.1-10%. If too much silicone powder is used, the effect of the polishing agent will be deteriorated, so it is usually added to the polishing agent in an amount of about 5% or less, preferably 3% or less. Furthermore, if necessary, thickeners, abrasives, gelling agents, antistatic agents, ultraviolet absorbers, etc. may be added auxiliary.
（発明の効果）
本発明の艶出し剤は、シリコーンパウダーを含有するこ
とにより、ぬり伸しおよび拭きとり作業性、とくに拭き
とり性が優れる。従って、従来の艶出し剤中のシリコー
ンオイルおよびシリコーンレジンを少量もしくは皆無と
することができ、これらに起因する汚れ垢の付着を完全
に防止することができる。すなわち、水洗することによ
り容易に除去できる水性の汚れは付着しても、水洗によ
り除去されにくい油性の汚れ垢の付着はない。なお、こ
のシリコーンパウダーに対し、予じめジメチルシリコー
ンオイル等のシリコーンオイルを少量（例えば５〜４０
％程度）含浸したものを使用すれば、艶出し剤のすべり
性は良くなり、作業性はより一層改善される。この場合
、少量のシリコーンオイルは、シリコーンパウダーとと
もに拭キとりの際除去されるので粕付着の原因となるこ
とはない。(Effects of the Invention) The polishing agent of the present invention has excellent spreadability and wiping workability, especially wiping property, by containing silicone powder. Therefore, the amount of silicone oil and silicone resin in conventional polishing agents can be reduced to a small amount or completely eliminated, and the adhesion of dirt and grime caused by these can be completely prevented. That is, even if water-based stains that are easily removed by washing with water are attached, oil-based dirt and scales that are difficult to remove by washing are not attached. Note that a small amount of silicone oil such as dimethyl silicone oil (for example, 5 to 40% silicone oil) is added to this silicone powder in advance.
%), the smoothness of the polishing agent will be improved and workability will be further improved. In this case, a small amount of silicone oil is removed together with the silicone powder during wiping, so it does not cause scum to adhere.
（実施例）
次に実施例により、本発明を更に具体的に説明するが、
本発明はその要旨を超えない限り、以下の実施例に限定
されるものではない。(Example) Next, the present invention will be explained in more detail with reference to Examples.
The present invention is not limited to the following examples unless it exceeds the gist thereof.
実施例１
ケロン７２３．００％、バラロイドＢ−６７（アクリル
レジン、ロームアンドハース社製） １．５０％おヨヒ
ステアリン酸２．５０％を混合機中で７５°Ｃに加熱し
て撹拌混合した。これにナトリウムメタシリゲート１．
３５％を溶解した温水を加えて撹拌して乳化した。乳化
終了後、シリコーンパウダー（トーレンリコン社製、ト
レフイルＥシリーズＥ−５００） ２．００％、スーパ
ーフロス（珪酸塩パウダー、ジョンマンビレ社製） ７
．００％、アルミナ粉２．５０％及び水（バランス）を
加えてワックス艶出し剤を得た。Example 1 Chelon 723.00%, Valaloid B-67 (acrylic resin, manufactured by Rohm and Haas) 1.50% and 2.50% yohystearic acid were heated to 75°C in a mixer and mixed with stirring. . Add sodium metasiligate 1.
Warm water containing 35% of the solution was added and stirred to emulsify. After emulsification, add 2.00% silicone powder (Toren Licon Co., Ltd., Trefil E Series E-500), Super Floss (silicate powder, John Manbire Co., Ltd.) 7
．． 00%, alumina powder 2.50% and water (balance) were added to obtain a wax polish.
この艶出し剤についてのテスト結果を次に示す。Test results for this polish are shown below.
普通塗装の白色車の中から新車及び中古車を任意に２０
台選び、各車のボンネット、天井及びトランク部分の左
右に、それぞれ本発明のワックスと比較例として市販品
２種（Ａ社及びＢ社）の白色車専用のクリーナーワック
スを塗り分けた。塗布後２週間及び４週間経過後、洗車
前後の垢の付着程度を肉眼にて各ドライバーに評価して
もらった。このテストを気象条件を考慮して、時期をか
えて３回くり返えし行ない、３回の平均結果を表−１に
示す。Choose 20 new or used cars from among white cars with regular paint.
A selected car was selected, and the wax of the present invention and two commercially available cleaner waxes (Company A and Company B) specially designed for white cars were applied separately to the left and right sides of the hood, ceiling, and trunk of each car. Two and four weeks after application, each driver was asked to visually evaluate the degree of dirt adhesion before and after washing the car. This test was repeated three times at different times, taking into account the weather conditions, and the average results of the three tests are shown in Table 1.
表−１ 上；も、′、；Table-1 Top; also, ′,;
Claims (1)
出し剤中にシリコーンパウダーを含有することを特徴と
する垢付着防止性の艶出し剤組成物。1) A polishing agent composition with anti-skull adhesion properties, characterized by containing silicone powder in a polishing agent consisting of wax and/or a waxy substance.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27164288A JPH02117979A (en) | 1988-10-27 | 1988-10-27 | Stain-resistant polishing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27164288A JPH02117979A (en) | 1988-10-27 | 1988-10-27 | Stain-resistant polishing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02117979A true JPH02117979A (en) | 1990-05-02 |
Family
ID=17502897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27164288A Pending JPH02117979A (en) | 1988-10-27 | 1988-10-27 | Stain-resistant polishing composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02117979A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05144817A (en) * | 1991-11-18 | 1993-06-11 | Matsushita Electric Ind Co Ltd | Electronic part mounting/connecting body and manufacture thereof |
| JPH10298497A (en) * | 1997-04-24 | 1998-11-10 | Kao Corp | Polishing composition for hard surface and method for polishing hard surface |
| US6117830A (en) * | 1996-05-07 | 2000-09-12 | Kao Corporation | Liquid detergent composition for hard surface and method for cleaning hard surface |
| JP2010163553A (en) * | 2009-01-16 | 2010-07-29 | Nicca Chemical Co Ltd | Abrasive composition and polishing method |
| CN102993983A (en) * | 2012-12-14 | 2013-03-27 | 吴江市利达上光制品有限公司 | Spray type sterilization leather polishing agent and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61159474A (en) * | 1984-12-29 | 1986-07-19 | Toshiba Silicone Co Ltd | Lustering agent composition |
-
1988
- 1988-10-27 JP JP27164288A patent/JPH02117979A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61159474A (en) * | 1984-12-29 | 1986-07-19 | Toshiba Silicone Co Ltd | Lustering agent composition |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05144817A (en) * | 1991-11-18 | 1993-06-11 | Matsushita Electric Ind Co Ltd | Electronic part mounting/connecting body and manufacture thereof |
| US6117830A (en) * | 1996-05-07 | 2000-09-12 | Kao Corporation | Liquid detergent composition for hard surface and method for cleaning hard surface |
| JPH10298497A (en) * | 1997-04-24 | 1998-11-10 | Kao Corp | Polishing composition for hard surface and method for polishing hard surface |
| JP2010163553A (en) * | 2009-01-16 | 2010-07-29 | Nicca Chemical Co Ltd | Abrasive composition and polishing method |
| CN102993983A (en) * | 2012-12-14 | 2013-03-27 | 吴江市利达上光制品有限公司 | Spray type sterilization leather polishing agent and preparation method thereof |
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