JPH021299B2 - - Google Patents

Info

Publication number
JPH021299B2
JPH021299B2 JP20564382A JP20564382A JPH021299B2 JP H021299 B2 JPH021299 B2 JP H021299B2 JP 20564382 A JP20564382 A JP 20564382A JP 20564382 A JP20564382 A JP 20564382A JP H021299 B2 JPH021299 B2 JP H021299B2
Authority
JP
Japan
Prior art keywords
photosensitive layer
photoreceptor
image
conductive substrate
selenium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP20564382A
Other languages
Japanese (ja)
Other versions
JPS5994761A (en
Inventor
Akio Arai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Electric Co Ltd
Original Assignee
Fuji Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Electric Co Ltd filed Critical Fuji Electric Co Ltd
Priority to JP20564382A priority Critical patent/JPS5994761A/en
Publication of JPS5994761A publication Critical patent/JPS5994761A/en
Publication of JPH021299B2 publication Critical patent/JPH021299B2/ja
Granted legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G5/00Recording-members for original recording by exposure, e.g. to light, to heat or to electrons; Manufacture thereof; Selection of materials therefor
    • G03G5/02Charge-receiving layers
    • G03G5/04Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
    • G03G5/08Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic
    • G03G5/082Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor characterised by the photoconductive material being inorganic and not being incorporated in a bonding material, e.g. vacuum deposited
    • G03G5/08207Selenium-based

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Photoreceptors In Electrophotography (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は導電性基体上にセレン系光導電材料か
らなる感光層を形成する電子写真用感光体の製造
方法に関する。 この種の感光体には、複写機、プリンタなどで
帯電、露光による潜像形成後、現像、転写により
紙面へ画像を形成し、最後に表面に残つている電
荷の除去と画像形成に供し得なかつた残留トナー
のクリーニングを行うという一連のプロセスが施
こされる。従来電子写真感光体は、画像形成、信
頼性の点などから感光層表面が平滑でなければな
らないとされていた。しかし感光層表面があまり
平滑すぎると次のような欠点がある。 (1) クリーニングブレードと感光体との摩擦力が
増大し、画像上白すじを呈する画像欠損となる
きずが感光層表面に発生する。 (2) トナーと感光体との密着力が増大し、ナトー
の転写性、クリーニング性が悪くなる。 (3) 転写紙との密着力が増大し、紙の分離性が悪
くなる。 このような欠点を除くには、感光層表面がある
程度荒れている方がよいことが最近分かつてき
た。しかし現在汎用されている感光体は感光層の
光導電材料に純Se合金が使用され、導電性基体
上に真空蒸着法などにより無定形Se系材料が被
着している。このようなSe系感光層表面は異物
が接触すると結晶化が起こり、またすじのような
加工痕が生ずると画像に出てしまうので表面加工
などは考えられなかつた。 本発明は感光層の光導電特性を害することな
く、その表面を適当な荒さで粗面化する感光体の
製造方法を提供することを目的とする。 この目的は電子写真用感光体の製造方法におい
て、導電性基体上にセレン・砒素合金からなる感
光層を被着後、この感光層表面を液体ホーニング
法により表面粗さ0.1〜1.0μmに粗面化することに
より達成される。 以下図を引用して本発明の実施例について説明
する。第1図に示すように、導電性基体1、例え
ばアルミニウム円筒上にセレンあるいはセレン合
金からなる感光層2を従来と同様に蒸着する。次
いで第2図に示すようにそのような感光層を被着
したアルミニウム円筒11を回転テーブル12の
上に立て、回転させながら矢印13で示すその軸
方向に往復運動するノズル14から微粉の砥粒を
含む液体噴流15を感光層表面に吹き付けて第1
図に誇張して示された粗面3を得る。光導電材料
としてSe−As合金を用いた感光層の表面を粗面
化した場合の加工条件、表面粗度、画像およびク
リーニング性の良否を第1表を示す。表中〇印は
良、△印はやや不良、×印は使用不能を示す。
The present invention relates to a method for manufacturing an electrophotographic photoreceptor in which a photosensitive layer made of a selenium-based photoconductive material is formed on a conductive substrate. This type of photoreceptor can be used in a copier, printer, etc. to form a latent image by charging and exposure, then developing and transferring to form an image on the paper surface, and finally remove the charge remaining on the surface and use it for image formation. A series of processes are performed to clean the remaining toner. Conventionally, it has been believed that electrophotographic photoreceptors must have a smooth surface of the photosensitive layer from the viewpoint of image formation and reliability. However, if the surface of the photosensitive layer is too smooth, there are the following drawbacks. (1) The frictional force between the cleaning blade and the photoreceptor increases, causing scratches on the surface of the photoreceptor layer that cause image defects such as white streaks on the image. (2) The adhesion between the toner and the photoconductor increases, resulting in poor NATO transferability and cleaning performance. (3) The adhesion to the transfer paper increases and the separation of the paper deteriorates. It has recently been found that in order to eliminate such defects, it is better for the surface of the photosensitive layer to be rough to some extent. However, in the currently widely used photoreceptors, a pure Se alloy is used as the photoconductive material of the photosensitive layer, and an amorphous Se-based material is deposited on the conductive substrate by a vacuum evaporation method or the like. The surface of such a Se-based photosensitive layer crystallizes when foreign matter comes into contact with it, and any processing marks such as streaks would appear on the image, so surface processing could not be considered. SUMMARY OF THE INVENTION An object of the present invention is to provide a method for producing a photoreceptor in which the surface of the photoreceptor layer can be roughened to an appropriate roughness without impairing the photoconductive properties of the photoreceptor layer. The purpose of this is to apply a photosensitive layer made of a selenium-arsenic alloy onto a conductive substrate, and then roughen the surface of this photosensitive layer to a surface roughness of 0.1 to 1.0 μm using a liquid honing method. This is achieved by Embodiments of the present invention will be described below with reference to the drawings. As shown in FIG. 1, a photosensitive layer 2 made of selenium or a selenium alloy is deposited on a conductive substrate 1, for example an aluminum cylinder, in a conventional manner. Next, as shown in FIG. 2, the aluminum cylinder 11 coated with such a photosensitive layer is placed on a rotary table 12, and as it is rotated, fine abrasive grains are injected from a nozzle 14 that reciprocates in the axial direction indicated by an arrow 13. A liquid jet 15 containing
A rough surface 3, which is shown exaggerated in the figure, is obtained. Table 1 shows processing conditions, surface roughness, image quality, and cleanability when the surface of a photosensitive layer using Se-As alloy as a photoconductive material was roughened. In the table, ○ indicates good quality, △ indicates slightly poor quality, and × indicates unusable.

【表】 液体ホーニング法によれば感光層表面は梨地状
の不規則粗面が得られ、粗さ0.1〜3.0μmの範囲で
加工痕が画像に出ることなく、白すじのような画
像欠損の発生もなく良好であつた。ただし、表面
粗さが4μm以上であると表面凹部にトナーが入り
込み、逆にクリーニング不良となる。また点状の
帯電むらが生じ画像欠損となる。従つて液体ホー
ニングによる表面粗さは40μmを超えない範囲が
使用され、特に0.1〜1.0μmの範囲が適当である。 以上述べたように本発明は基体上に生成された
鏡面状の感光層表面を液体ホーニング法により適
度に粗面化するので、導電性基体の表面粗さ、蒸
着条件等微妙な設定の必要がなく、従来通り感光
層形成方法が適用できるので容易にトナーの転写
性、紙の分離性、クリーニング性の良好な電子写
真用感光体を得ることができ、特にセレンひ素感
光体においてその効果は極めて大きい。
[Table] According to the liquid honing method, the surface of the photosensitive layer has a satin-like irregular roughness, and there are no processing marks in the image with a roughness in the range of 0.1 to 3.0 μm, and there are no image defects such as white streaks. The condition was good with no outbreaks. However, if the surface roughness is 4 μm or more, toner will enter the surface recesses, resulting in poor cleaning. In addition, point-like charging unevenness occurs, resulting in image defects. Therefore, the surface roughness obtained by liquid honing is preferably within a range of not exceeding 40 μm, and particularly within the range of 0.1 to 1.0 μm. As described above, in the present invention, the surface of the mirror-like photosensitive layer formed on the substrate is appropriately roughened by the liquid honing method, so delicate settings such as the surface roughness of the conductive substrate and the deposition conditions are required. Since the conventional photosensitive layer formation method can be applied, it is possible to easily obtain electrophotographic photoreceptors with good toner transfer properties, paper separation properties, and cleaning properties, and this effect is particularly great for selenium arsenide photoreceptors. big.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の一実施例による感光体の概念
的部分断面図、第2図は本発明の実施のための装
置の一例を示す断面図である。 1…導電性基体、2…感光層、3…粗面、11
…アルミニウム円筒、14…ノズル、15…砥粒
を含む液体噴流。
FIG. 1 is a conceptual partial cross-sectional view of a photoreceptor according to an embodiment of the present invention, and FIG. 2 is a cross-sectional view showing an example of an apparatus for carrying out the present invention. DESCRIPTION OF SYMBOLS 1... Conductive substrate, 2... Photosensitive layer, 3... Rough surface, 11
...aluminum cylinder, 14... nozzle, 15... liquid jet containing abrasive grains.

Claims (1)

【特許請求の範囲】[Claims] 1 導電性基体上にセレン・砒素合金からなる感
光層を被着後、この感光層表面を液体ホーニング
法により表面粗さ0.1〜1.0μmに粗面化することを
特徴とする電子写真用感光体の製造方法。
1. A photoreceptor for electrophotography, characterized in that a photoreceptor layer made of a selenium-arsenic alloy is deposited on a conductive substrate, and then the surface of this photoreceptor layer is roughened to a surface roughness of 0.1 to 1.0 μm by a liquid honing method. manufacturing method.
JP20564382A 1982-11-24 1982-11-24 Manufacture of electrophotographic photosensitive body Granted JPS5994761A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP20564382A JPS5994761A (en) 1982-11-24 1982-11-24 Manufacture of electrophotographic photosensitive body

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP20564382A JPS5994761A (en) 1982-11-24 1982-11-24 Manufacture of electrophotographic photosensitive body

Publications (2)

Publication Number Publication Date
JPS5994761A JPS5994761A (en) 1984-05-31
JPH021299B2 true JPH021299B2 (en) 1990-01-11

Family

ID=16510284

Family Applications (1)

Application Number Title Priority Date Filing Date
JP20564382A Granted JPS5994761A (en) 1982-11-24 1982-11-24 Manufacture of electrophotographic photosensitive body

Country Status (1)

Country Link
JP (1) JPS5994761A (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2682105B2 (en) * 1988-04-25 1997-11-26 富士電機株式会社 Reproducing method of electrophotographic photoreceptor

Also Published As

Publication number Publication date
JPS5994761A (en) 1984-05-31

Similar Documents

Publication Publication Date Title
US5068762A (en) Electrophotographic charging device
JPH0157900B2 (en)
JPH021299B2 (en)
US5362588A (en) Electrophotographic photosensitive member and apparatus including same
JPH0569216B2 (en)
JPH0588392A (en) Electrophotographic sensitive body and substrate used for it and its manufacture
JP2878030B2 (en) Electrophotographic photoreceptor
JPH0217020B2 (en)
JP3710304B2 (en) Electrophotographic equipment
JPH0535424B2 (en)
JPH079541B2 (en) Electrophotographic photoconductor
JPH0157897B2 (en)
JPS58174956A (en) Manufacture of electrophotographic receptor
JPS59135473A (en) Electrophotographic sensitive body
JPS6146968A (en) Reproducing method of electrophotographic sensitive body
JPS58115464A (en) Polishing method for photosensitive body
JPS63129381A (en) Cleaning device
JP2782955B2 (en) Electrophotographic photoreceptor substrate and method of manufacturing the same
JPS58184177A (en) Electrophotographic device
JPH0120742B2 (en)
JP2002040697A (en) Electrophotographic photoreceptor and electrophotographic apparatus
JP2656374B2 (en) Image recording device
JPH02220065A (en) Electrophotographic sensitive body
JPS63311259A (en) Electrophotographic sensitive body
JPH09297422A (en) Electrophotographic equipment