JPH0214818A - アルミナーチタニア複合体 - Google Patents
アルミナーチタニア複合体Info
- Publication number
- JPH0214818A JPH0214818A JP1109005A JP10900589A JPH0214818A JP H0214818 A JPH0214818 A JP H0214818A JP 1109005 A JP1109005 A JP 1109005A JP 10900589 A JP10900589 A JP 10900589A JP H0214818 A JPH0214818 A JP H0214818A
- Authority
- JP
- Japan
- Prior art keywords
- titania
- alumina
- composite
- precipitated
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 title abstract description 248
- 239000002131 composite material Substances 0.000 title abstract description 103
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 50
- 239000003054 catalyst Substances 0.000 abstract description 50
- 238000000034 method Methods 0.000 abstract description 36
- 239000002245 particle Substances 0.000 abstract description 27
- 239000011159 matrix material Substances 0.000 abstract description 25
- 238000002441 X-ray diffraction Methods 0.000 abstract description 24
- 238000006243 chemical reaction Methods 0.000 abstract description 13
- 238000002156 mixing Methods 0.000 abstract description 13
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract description 11
- 150000004645 aluminates Chemical class 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 4
- 229910010270 TiOCl2 Inorganic materials 0.000 abstract description 3
- 239000003513 alkali Substances 0.000 abstract description 3
- 230000002378 acidificating effect Effects 0.000 abstract description 2
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 abstract description 2
- 229910010062 TiCl3 Inorganic materials 0.000 abstract 1
- 229910010298 TiOSO4 Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 239000010419 fine particle Substances 0.000 abstract 1
- KADRTWZQWGIUGO-UHFFFAOYSA-L oxotitanium(2+);sulfate Chemical compound [Ti+2]=O.[O-]S([O-])(=O)=O KADRTWZQWGIUGO-UHFFFAOYSA-L 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 238000000975 co-precipitation Methods 0.000 description 25
- 239000000243 solution Substances 0.000 description 16
- 150000003608 titanium Chemical class 0.000 description 16
- 238000009826 distribution Methods 0.000 description 13
- 230000000694 effects Effects 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 238000005470 impregnation Methods 0.000 description 9
- 238000001354 calcination Methods 0.000 description 7
- 150000002739 metals Chemical class 0.000 description 7
- 238000000465 moulding Methods 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 238000007796 conventional method Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000009827 uniform distribution Methods 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 229910052750 molybdenum Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000001747 exhibiting effect Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000011733 molybdenum Substances 0.000 description 3
- 150000002898 organic sulfur compounds Chemical class 0.000 description 3
- 125000002524 organometallic group Chemical group 0.000 description 3
- 238000005504 petroleum refining Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- -1 TiO□ Chemical class 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- XFVGXQSSXWIWIO-UHFFFAOYSA-N chloro hypochlorite;titanium Chemical compound [Ti].ClOCl XFVGXQSSXWIWIO-UHFFFAOYSA-N 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012452 mother liquor Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 150000003609 titanium compounds Chemical class 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical group [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000011174 green composite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- KVOIJEARBNBHHP-UHFFFAOYSA-N potassium;oxido(oxo)alumane Chemical compound [K+].[O-][Al]=O KVOIJEARBNBHHP-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229910000349 titanium oxysulfate Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910001868 water Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US18719688A | 1988-04-28 | 1988-04-28 | |
| US187196 | 1988-04-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0214818A true JPH0214818A (ja) | 1990-01-18 |
Family
ID=22687980
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1109005A Pending JPH0214818A (ja) | 1988-04-28 | 1989-04-27 | アルミナーチタニア複合体 |
Country Status (2)
| Country | Link |
|---|---|
| EP (1) | EP0339640A1 (fr) |
| JP (1) | JPH0214818A (fr) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000342967A (ja) * | 1999-03-31 | 2000-12-12 | Toyota Motor Corp | 排ガス浄化用触媒とその製造方法及び排ガス浄化方法 |
| JP2002001115A (ja) * | 1999-10-27 | 2002-01-08 | Idemitsu Kosan Co Ltd | 金属化合物担持処理耐火性無機酸化物担体及び該担体を用いた水素化処理触媒 |
| JP2009525248A (ja) * | 2006-02-03 | 2009-07-09 | ザッハトレーベン ヒェミー ゲゼルシヤフト ミット ベシュレンクテル ハフツング | 酸化物混合物 |
| US20150144532A1 (en) * | 2012-06-20 | 2015-05-28 | Advanced Refining Technologies Llc | Resid hydrotreating catalyst containing titania |
| US10279335B2 (en) | 2012-02-17 | 2019-05-07 | Advanced Refining Technologies Llc | Spheroidal resid hydrodemetallation catalyst |
| US10584288B2 (en) | 2012-02-17 | 2020-03-10 | Advanced Refining Technologies Llc | Extruded resid demetallation catalyst |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5962367A (en) * | 1994-11-04 | 1999-10-05 | Dequing Chemical Industry And Technologies Co., Ltd. | Titania (TiO2) support and process for preparation and use of the same |
| WO1996014152A1 (fr) * | 1994-11-04 | 1996-05-17 | Deqing Chemical Industry And Technology Development Company | SUPPORT EN DIOXYDE DE TITANE (TiO2), SON PROCEDE DE PREPARATION ET SON UTILISATION |
| CN1088092C (zh) * | 1999-05-18 | 2002-07-24 | 中国石油化工集团公司 | 烃类加氢精制催化剂 |
| EP1145763B1 (fr) | 1999-10-27 | 2012-07-04 | Idemitsu Kosan Co., Ltd. | Catalyseur d'hydrotraitement pour huile hydrocarbonee, support pour celle-ci et procede d'hydrotraitement d'huile hydrocarbonee |
| CN1107534C (zh) * | 2000-05-19 | 2003-05-07 | 中国石油化工集团公司 | 一种含钛氢氧化铝的制备方法 |
| DE10352816A1 (de) * | 2003-11-12 | 2005-06-09 | Sachtleben Chemie Gmbh | Verfahren zur Herstellung eines hochtemperaturstabilen, TiO2-haltigen Katalysators oder Katalysatorträgers |
| CN100441298C (zh) * | 2004-04-20 | 2008-12-10 | 中国石油化工股份有限公司 | 氧化钛-氧化铝复合载体及其制备方法和应用 |
| CN1331605C (zh) * | 2004-10-29 | 2007-08-15 | 中国石油化工股份有限公司 | 一种含硅和钛的氧化铝载体及其制备方法 |
| CN103100379B (zh) * | 2011-11-14 | 2015-04-15 | 中国石油化工股份有限公司 | 一种氧化钛-氧化铝复合物的制造方法 |
| US11583846B2 (en) | 2014-11-25 | 2023-02-21 | Graver Technologies Llc | High capacity adsorbent for oxyanions and cations and method for making the same |
| US10343154B2 (en) * | 2014-11-25 | 2019-07-09 | Graver Technologies Llc | High capacity adsorbent for fluoride ion and oxyanions of phosphorous and arsenic and method for making the same |
| JP6456204B2 (ja) * | 2015-03-24 | 2019-01-23 | 千代田化工建設株式会社 | 芳香族炭化水素の水素化触媒及びそれを用いた水素化処理方法 |
| AU2021201922B2 (en) * | 2020-04-30 | 2022-10-20 | Graver Technologies Llc | High capacity adsorbent for oxyanions and cations and method for making the same |
| CN115337957B (zh) * | 2021-05-14 | 2025-03-18 | 中国石油化工股份有限公司 | 一种含钼介孔氧化铝分子筛及其制备方法和应用 |
| CN113731391A (zh) * | 2021-08-27 | 2021-12-03 | 江苏朗润环保科技有限公司 | 一种高抗氧低温有机硫水解催化剂及其制备方法 |
| CN113979471B (zh) * | 2021-12-02 | 2023-06-23 | 西安元创化工科技股份有限公司 | 一种金红石型二氧化钛纳米复合物的合成方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4141962A (en) * | 1973-04-09 | 1979-02-27 | Rhone-Progil | Catalysts for treating gases containing sulphur compounds |
| US4312785A (en) * | 1979-04-06 | 1982-01-26 | Uop Inc. | Process for the conversion of aromatic hydrocarbons |
| DK373784A (da) * | 1983-06-16 | 1986-02-02 | Du Pont | Fremgangsmaade og katalysator til fremstilling af dimethylether |
| DE3534741A1 (de) * | 1985-09-28 | 1987-04-09 | Basf Ag | Verfahren zur entfernung von schwefelverbindungen aus gasstroemen |
-
1989
- 1989-04-27 JP JP1109005A patent/JPH0214818A/ja active Pending
- 1989-04-27 EP EP89107646A patent/EP0339640A1/fr not_active Withdrawn
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000342967A (ja) * | 1999-03-31 | 2000-12-12 | Toyota Motor Corp | 排ガス浄化用触媒とその製造方法及び排ガス浄化方法 |
| JP2002001115A (ja) * | 1999-10-27 | 2002-01-08 | Idemitsu Kosan Co Ltd | 金属化合物担持処理耐火性無機酸化物担体及び該担体を用いた水素化処理触媒 |
| JP2009525248A (ja) * | 2006-02-03 | 2009-07-09 | ザッハトレーベン ヒェミー ゲゼルシヤフト ミット ベシュレンクテル ハフツング | 酸化物混合物 |
| US10279335B2 (en) | 2012-02-17 | 2019-05-07 | Advanced Refining Technologies Llc | Spheroidal resid hydrodemetallation catalyst |
| US10584288B2 (en) | 2012-02-17 | 2020-03-10 | Advanced Refining Technologies Llc | Extruded resid demetallation catalyst |
| US10589254B2 (en) | 2012-02-17 | 2020-03-17 | Advanced Refining Technologies Llc | Spheroidal resid hydrodemetallation catalyst |
| US20150144532A1 (en) * | 2012-06-20 | 2015-05-28 | Advanced Refining Technologies Llc | Resid hydrotreating catalyst containing titania |
| US9415384B2 (en) * | 2012-06-20 | 2016-08-16 | Advanced Refining Technologies Llc | Resid hydrotreating catalyst containing titania |
| US9675965B2 (en) | 2012-06-20 | 2017-06-13 | Advanced Refining Technologies Llc | Resid hydrotreating catalyst containing titania |
| JP2018134635A (ja) * | 2012-06-20 | 2018-08-30 | アドバンスド・リフアイニング・テクノロジーズ・エルエルシー | チタニアを含有する改良された残油水素化処理触媒 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0339640A1 (fr) | 1989-11-02 |
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