JPH0214864A - Production of decorative tile - Google Patents
Production of decorative tileInfo
- Publication number
- JPH0214864A JPH0214864A JP16206488A JP16206488A JPH0214864A JP H0214864 A JPH0214864 A JP H0214864A JP 16206488 A JP16206488 A JP 16206488A JP 16206488 A JP16206488 A JP 16206488A JP H0214864 A JPH0214864 A JP H0214864A
- Authority
- JP
- Japan
- Prior art keywords
- tile
- clay
- weight
- foaming agent
- specific gravity
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 239000004927 clay Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004088 foaming agent Substances 0.000 claims abstract description 8
- 239000000853 adhesive Substances 0.000 claims abstract description 7
- 230000001070 adhesive effect Effects 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- 238000005266 casting Methods 0.000 claims abstract 3
- 238000010304 firing Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 7
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 239000006260 foam Substances 0.000 claims description 2
- 230000005484 gravity Effects 0.000 abstract description 10
- 238000005034 decoration Methods 0.000 abstract description 5
- 238000005187 foaming Methods 0.000 abstract description 4
- 238000010422 painting Methods 0.000 abstract description 4
- 239000002994 raw material Substances 0.000 abstract 3
- 238000001354 calcination Methods 0.000 abstract 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 description 2
- 229910002114 biscuit porcelain Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000008262 pumice Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000102542 Kara Species 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 235000011054 acetic acid Nutrition 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 229910001562 pearlite Inorganic materials 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Porous Artificial Stone Or Porous Ceramic Products (AREA)
Abstract
Description
【発明の詳細な説明】
、産−業一り辺−利UW二野−
本発明は、軽量で扱い易い装飾用タイルの製造方法に関
する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for producing decorative tiles that are lightweight and easy to handle.
且」L技」1
タイルは装飾効果のある陶器として、古くから広範に使
用されているが、重い(比重2.25 )破れ易い、大
平面が得難く、特に大平面で平滑な面は得難いという陶
器本来の欠点があるため、壁画的な屋内装飾品や、屋上
に設置する今治1反的な屋外装飾品などに使用すること
は困難であった。``L Technique'' 1 Tiles have been widely used as pottery with a decorative effect since ancient times, but they are heavy (specific gravity 2.25) and break easily, and it is difficult to obtain large flat surfaces, especially large and smooth surfaces. Because of these inherent drawbacks of pottery, it was difficult to use it for indoor decorations such as wall paintings or outdoor decorations such as those placed on rooftops in Imabari.
が じょうと る
そこで、本発明では、比重が軽<(1,0以下)しかも
強度は従来の製品と大差ない装飾性に富んだタイルを提
供することを課題とする。Therefore, the object of the present invention is to provide a highly decorative tile that has a specific gravity of light (<1.0 or less) and a strength that is not much different from conventional products.
るための
本発明者は、無機発泡剤と比重の軽い凝灰に1粉との併
用によって、上記課題を解決する方法を見出した。The inventor of the present invention has found a method for solving the above problem by using an inorganic blowing agent and tuff powder having a light specific gravity in combination.
即ち、本発明の方法は、堆積粘土35〜70重置部、無
機発泡剤1〜6重量部、凝灰岩$5130〜55重量部
と少量の酸及び水分を含有する組成物を、を昆合放置し
て発泡膨張させた後、流度を調整し、鋳形し、焼成した
後、化粧土をコーティングし、焼成後、装飾加工するこ
とを特徴とする。That is, in the method of the present invention, a composition containing 35 to 70 parts of deposited clay, 1 to 6 parts by weight of an inorganic blowing agent, 5,130 to 55 parts by weight of tuff, and small amounts of acid and water is left to stand. After foaming and expanding, the flow rate is adjusted, molding is performed, and after firing, the product is coated with decorative clay, and after firing, it is decorated.
Di積粘土は、本発明の方法では、バインダーとして働
くものであり、木節粘土が主に使用されるが、その使用
量は40重量%以上であるのが好ましい。In the method of the present invention, the Di clay works as a binder, and Kibushi clay is mainly used, and the amount used is preferably 40% by weight or more.
次に、無機発泡剤としては、炭酸塩や重炭酸塩などが主
に使用されるが、これらの使用にあっては、その発泡作
用を促進するための酸を併用するのが好ましく、この酸
としては、一般に酢酸、クエン酸、リンゴ酸、酒石酸な
どの有機酸を使用するのが好ましい。Next, as inorganic foaming agents, carbonates and bicarbonates are mainly used, but when using these, it is preferable to use an acid to promote the foaming action. It is generally preferred to use organic acids such as acetic acid, citric acid, malic acid, tartaric acid, and the like.
次に、凝灰岩とは、一般に軽石及び岩サイと呼ばれるも
のを含むが、本発明では、気孔の多い軽石類を使用する
のが好ましい。凝灰岩は、本発明のタイルを軽量化する
ために粉末化して、添加使用するものであるが、凝灰岩
の添加によって、製品は脆くなり、融点も下がるため、
製品強度及び耐火性の点なら、一般に40〜50重量%
程度の割合で使用するのが好ましい。Next, tuff includes what is generally called pumice and rock tuff, but in the present invention, it is preferable to use pumice, which has many pores. Tuff is powdered and added to make the tile of the present invention lighter; however, the addition of tuff makes the product brittle and lowers its melting point.
In terms of product strength and fire resistance, it is generally 40 to 50% by weight.
It is preferable to use it in proportions.
なお、本発明で使用する組成物は、これら3成分の他に
補助剤として、その他の粘土類、軟化点調整剤、接着性
改良剤、色調調整剤(珪酸ジルコン)などを添加しても
よい。In addition to these three components, the composition used in the present invention may contain other clays, softening point regulators, adhesion improvers, color tone regulators (zircon silicate), etc. as auxiliaries. .
本発明では、このような堆積粘土、無機発泡剤、凝灰岩
粉と少量の酸及び水分を含有する組成物を、t;L合装
置して発泡膨張させた後、鋳形しやすい粘度に流度を調
整するが、この調整には、水ガラス及びアルカリ電解質
などの電解質を添加するのが好ましい。特にアルカリ電
解質の添加が好ましく、炭酸ソーダ0.4重量%程度の
添加では、水分20重量%以下でも十分な流度が得られ
、作業性よく鋳形できる。In the present invention, a composition containing such deposited clay, an inorganic foaming agent, tuff powder, and a small amount of acid and water is foamed and expanded in a t; For this adjustment, it is preferable to add an electrolyte such as water glass and an alkaline electrolyte. It is particularly preferable to add an alkaline electrolyte, and by adding about 0.4% by weight of soda carbonate, a sufficient flow rate can be obtained even when the water content is 20% by weight or less, and molding can be performed with good workability.
なお、鋳形後の乾燥収縮によって、インゴットにひび破
れが生ずる危険性がある場合には、上記流度調整時に、
パーライト粉(約900メソシユ)を10重量%程度添
加することによって防止できる。In addition, if there is a risk that the ingot may crack due to drying shrinkage after molding, when adjusting the flow rate above,
This can be prevented by adding about 10% by weight of perlite powder (approximately 900 mesoyu).
なお、鋳形には、一般に、内壁に石膏板を張った木枠の
箱を使用するのが好ましい。In addition, it is generally preferable to use a wooden frame box whose inner wall is covered with plasterboard as the mold.
製品の気孔をできるだけ一定に制御するためには、各成
分の調合、添加水温、発泡熟成時の室温等は20 ’C
以上であるのが好ましい。In order to control the pores of the product as constant as possible, the preparation of each ingredient, the temperature of added water, and the room temperature during foam aging must be kept at 20'C.
The above is preferable.
次に、インゴットされたものの焼成は、焼成収縮が生ず
るため、着床面を小さくする。焼成温度が1000℃を
越える場合は約10%を越える焼成収縮が見られ、80
0℃前後では7%の焼成収縮が見られる。なお、焼成は
、20〜b特に20〜b
で実施するのが好ましい。Next, when the ingot is fired, the landing surface is made smaller because firing shrinkage occurs. When the firing temperature exceeds 1000°C, firing shrinkage of more than 10% is observed, and 80%
A firing shrinkage of 7% is observed at around 0°C. Incidentally, the firing is preferably carried out at a temperature of 20-b, particularly 20-b.
本発明では、このようにして焼成した後、化粧土をコー
ティングし、着床焼成することによって、比重1以下(
例えば0.6〜0.8)と軽量でありながら、通常のタ
イル(比重2.25 )と全く遜色のない装飾タイルに
容易に仕上げることができる。In the present invention, after firing in this way, the clay is coated and fired with a specific gravity of 1 or less (
Although it is lightweight (for example, 0.6 to 0.8), it can be easily finished as a decorative tile that is comparable to ordinary tiles (specific gravity 2.25).
化粧土としては、所謂エンゴベイが使用されればよく、
このコーティングによって、凝灰岩粉の存在及び無機発
泡剤により形成された気孔の存在は、外観的には全く目
立たなくなり、各種釉薬の適用などにより1.美しい陶
器に仕上がるのである。As a makeup soil, it is sufficient to use so-called engobei,
With this coating, the presence of tuff powder and the presence of pores formed by the inorganic foaming agent become completely inconspicuous in appearance, and by applying various glazes, etc. The result is beautiful pottery.
本発明では、インゴ7)表面に彫刻加工を施すことも可
能であり、通常の彫刻工具で非常に作業性よく彫刻を施
すことができる。彫刻面は、十分水洗した後、ロード油
の希薄液でよく浄化した上に化粧上をコーティングする
のがよい。約700℃で焼成した後、着色施釉し、約8
50℃で焼成することにより、軽量にして立体的な内面
が形成される。In the present invention, it is also possible to perform engraving on the surface of the ingot 7), and the engraving can be performed with very good workability using ordinary engraving tools. After thoroughly washing the engraved surface with water, it is best to thoroughly purify it with a dilute solution of road oil before applying a decorative coating. After firing at approximately 700℃, it is colored and glazed, and the
By firing at 50°C, a lightweight three-dimensional inner surface is formed.
なお、本発明では、複数枚のインゴットを接着剤で接合
して、従来得られなかったような大きな面積のタイルに
製造することもできる。この場合、接着剤としては、接
着後彫刻加工、移動等ができ、かつ表面を均一な状態に
施釉仕上げできるものを使用する必要がある。この接着
剤としては、陶土を含む無機バインダーとCMCを併合
するものが好ましいことがわかっている。In addition, in the present invention, a plurality of ingots can be bonded together with an adhesive to produce a tile with a large area that could not be obtained conventionally. In this case, it is necessary to use an adhesive that can be engraved, moved, etc. after adhesion, and can be glazed to a uniform surface. It has been found that the preferred adhesive is one that combines CMC with an inorganic binder containing china clay.
CMCは、インゴットを彫刻加工や移動等に十分耐える
状態で接着するが、加熱により、焼失し、表面の仕上げ
加工に影響を及ぼさない。これに対して、焼成後は、唐
±(鉛白)を含む無機バインダーが有効に作用するもの
であり、例えば唐土を主成分とし、これにガラス(ソー
ダガラス)粉末、Na、に系ソーダ、ソーダ灰、鉛丹(
Pb0)等を混合した無機バインダーが接着力を発揮す
る1代表的な無機バインダーは唐±70%、水ガラス1
0%、Si0□20%からなるものである。CMC bonds the ingot in a state that is sufficient to withstand engraving, movement, etc., but it burns out when heated and does not affect surface finishing. On the other hand, after firing, an inorganic binder containing Karachi (lead white) acts effectively. For example, Karachi is the main component, and glass (soda glass) powder, Na, sodium based soda, Soda ash, red lead (
An inorganic binder mixed with Pb0) etc. exhibits adhesive strength.1 Typical inorganic binders are Kara ±70%, Water Glass1
0%, Si0□20%.
なお、接着後の加工度は少ない程好ましいので、接着す
る場合には、図面により、別個の主加工削りを加えた後
、接着し、修正加工し、これを約600℃で素焼焼成し
、接着効果が充分に発揮されたものにエンゴベイ化粧、
彫刻加工、絵付、施釉するのが好ましい。In addition, the lower the degree of processing after adhesion, the better, so when adhering, add a separate main machining according to the drawing, then adhere, correct the process, bisque fired at about 600 degrees Celsius, and bond. Engobey makeup is effective.
Carving, painting, and glazing are preferred.
実施例1
本節粘土の泥状物、炭酸バリウム及び凝灰岩粉固形重量
比率で4”l:3:40の割合で混合し、これに酢酸を
少量添加し、−昼夜寝かし、発泡膨張させた。その後、
炭酸ソーダ0.4重量%と900メノソエのパーライト
わ110重量%を添加し、適度な粘性に調整し、これを
、内壁に石禽板を張った木枠の箱(100X400X5
00mm)に流鋳した。Example 1 Sludge of this knot clay, barium carbonate and tuff powder were mixed at a solid weight ratio of 4"l:3:40, a small amount of acetic acid was added thereto, and the mixture was left to rest day and night for foaming and expansion. Then ,
Add 0.4% by weight of soda carbonate and 110% by weight of 900% pearlite to adjust the viscosity to an appropriate level.
00mm).
得られたインゴットを十分乾燥させた後、20〜b 0℃で焼成した。After sufficiently drying the obtained ingot, 20~b It was fired at 0°C.
その結果、比重約0.7、吸水率5%以下、膨張率5.
OX 1O−h(800℃以下)の耐酸性に優れた製品
が得られた。As a result, the specific gravity was approximately 0.7, the water absorption rate was 5% or less, and the expansion rate was 5.
A product with excellent acid resistance of OX 1O-h (800°C or lower) was obtained.
これに、蛙目粘土35重量部、カオリン65重量部、珪
酸ジルコン5重量部からなるスリップ泥漿に、炭酸鉛(
鉛白・唐土)を15重量%添加した化粧土をコーティン
グし、700℃で着床焼成した。In addition, lead carbonate (
It was coated with a decorative clay containing 15% by weight of lead white and clay, and fired at 700°C.
このようにして得た製品は、通常の陶磁器同様に、施釉
し、美しいタイルに仕上げることができた。The products obtained in this way could be glazed and made into beautiful tiles in the same way as regular ceramics.
実施例2゜
実施例1と同様にして得たインゴット9個を、3列に並
べ、CMCを主成分とする糊剤と、唐±70%、水ガラ
ス10%、5iOz20%からなる無機バインダーをt
riの割合で混合した接着剤で接合し、乾燥後、600
℃で素焼焼成し、全面に化粧土をコーティングし、その
後仕上げ加工することによって、広面積の装飾タイルを
、1枚物として製造することができた。本発明のタイル
は軽量であるため、このタイルは、実施例1同様に非常
に軽量であるため、屋上などへの設置も何ら問題なく、
非常に作業性よ〈実施できた。Example 2 Nine ingots obtained in the same manner as in Example 1 were arranged in three rows, and a sizing agent containing CMC as a main component and an inorganic binder consisting of 70% porcelain, 10% water glass, and 20% 5iOz were added. t
Joined with adhesive mixed at a ratio of ri, and after drying, 600
By bisque firing at ℃, coating the entire surface with clay, and then finishing, it was possible to produce decorative tiles with a wide area as a single piece. Since the tile of the present invention is lightweight, this tile, like Example 1, is very lightweight, so it can be installed on rooftops etc. without any problem.
It was very easy to work.
発明の効果
本発明の方法では、比重1.0以下というような非常に
軽い装飾用タイルを製造できる。また、こ・のタイルは
陶器本来の装飾性及び機能性を有するだけでなく、多孔
性であるため、防音性、保温性等にも優れ、芸術的分野
、建築的分野いれにも非常に広範に利用できるものとな
る。Effects of the Invention According to the method of the present invention, very light decorative tiles with a specific gravity of 1.0 or less can be produced. In addition, this tile not only has the decorative and functional properties inherent to ceramics, but because it is porous, it has excellent soundproofing and heat retention properties, and is widely used in both artistic and architectural fields. It will be available for use.
更に、本発明では、接着により、3 m 2 というよ
うな大面積のタイルをも、一体形成が可能であるため、
非常に商品価値の高いものとなる。Furthermore, in the present invention, it is possible to integrally form tiles with a large area of 3 m 2 by adhesion.
It has extremely high commercial value.
Claims (2)
量部、凝灰岩粉30〜55重量部と少量の酸及び水分を
含有する組成物を、混合放置して発泡膨張させた後、流
度を調整し、鋳形し、焼成した後、化粧土をコーティン
グし、焼成後、装飾加工することを特徴とする装飾用タ
イルの製造方法。(1) A composition containing 35 to 70 parts by weight of sedimentary clay, 1 to 6 parts by weight of an inorganic foaming agent, 30 to 55 parts by weight of tuff powder, and a small amount of acid and water is mixed and left to foam and expand; A method for manufacturing a decorative tile, which comprises adjusting the flow rate, casting, firing, coating with decorative clay, and performing decorative processing after firing.
CMC併合する接着剤組成物で接合し、乾燥、焼成した
後に上記コーティングを施すことを特徴とする請求項(
1)記載の方法。(2) Claim characterized in that the above-mentioned cast product is bonded with an inorganic binder containing clay and an adhesive composition that combines CMC, and the above-mentioned coating is applied after drying and baking.
1) The method described.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16206488A JPH0662349B2 (en) | 1988-06-29 | 1988-06-29 | Decorative tile manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16206488A JPH0662349B2 (en) | 1988-06-29 | 1988-06-29 | Decorative tile manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0214864A true JPH0214864A (en) | 1990-01-18 |
| JPH0662349B2 JPH0662349B2 (en) | 1994-08-17 |
Family
ID=15747403
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16206488A Expired - Fee Related JPH0662349B2 (en) | 1988-06-29 | 1988-06-29 | Decorative tile manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0662349B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001322864A (en) * | 2000-05-09 | 2001-11-20 | Oribe Seito Kk | Ceramic decorative material and method of manufacturing the same |
-
1988
- 1988-06-29 JP JP16206488A patent/JPH0662349B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001322864A (en) * | 2000-05-09 | 2001-11-20 | Oribe Seito Kk | Ceramic decorative material and method of manufacturing the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0662349B2 (en) | 1994-08-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |