JPH021917B2 - - Google Patents

Info

Publication number: JPH021917B2
Authority: JP; Japan
Prior art keywords: cathode compartment; chlorine; ions; compartment; cathode
Prior art date: 1988-02-16
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP63329519A

Other languages

English (en)

Japanese (ja)

Other versions

JPH01219185A (ja

Inventor

Ritsuputsutajin Mareku

Deii Makugiruarii Jeimuzu

Towaadosukii Tsubigunyuu

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Tenneco Canada Inc

Original Assignee

Tenneco Canada Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-02-16

Filing date

1988-12-28

Publication date

1990-01-16

1988-12-28 Application filed by Tenneco Canada Inc filed Critical Tenneco Canada Inc

1989-09-01 Publication of JPH01219185A publication Critical patent/JPH01219185A/ja

1990-01-16 Publication of JPH021917B2 publication Critical patent/JPH021917B2/ja

Status Granted legal-status Critical Current

Links

OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 111
235000019398 chlorine dioxide Nutrition 0.000 claims description 56
239000004155 Chlorine dioxide Substances 0.000 claims description 55
239000000460 chlorine Substances 0.000 claims description 51
229910052801 chlorine Inorganic materials 0.000 claims description 44
-1 chlorate ions Chemical class 0.000 claims description 39
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 33
239000001257 hydrogen Substances 0.000 claims description 33
229910052739 hydrogen Inorganic materials 0.000 claims description 33
XTEGARKTQYYJKE-UHFFFAOYSA-M chlorate Inorganic materials [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 claims description 32
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 30
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 27
238000000034 method Methods 0.000 claims description 21
BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 19
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
238000005341 cation exchange Methods 0.000 claims description 17
239000012528 membrane Substances 0.000 claims description 17
239000011780 sodium chloride Substances 0.000 claims description 15
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 9
239000006227 byproduct Substances 0.000 claims description 9
229910001919 chlorite Inorganic materials 0.000 claims description 9
229910052619 chlorite group Inorganic materials 0.000 claims description 9
239000002253 acid Substances 0.000 claims description 8
238000004519 manufacturing process Methods 0.000 claims description 7
239000000463 material Substances 0.000 claims description 6
235000011121 sodium hydroxide Nutrition 0.000 claims description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
229910002804 graphite Inorganic materials 0.000 claims description 4
239000010439 graphite Substances 0.000 claims description 4
239000002245 particle Substances 0.000 claims description 4
UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 4
229960002218 sodium chlorite Drugs 0.000 claims description 4
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 claims description 2
239000004020 conductor Substances 0.000 claims description 2
ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 claims description 2
239000003014 ion exchange membrane Substances 0.000 claims description 2
229940005989 chlorate ion Drugs 0.000 claims 2
239000003575 carbonaceous material Substances 0.000 claims 1
238000007599 discharging Methods 0.000 claims 1
239000007787 solid Substances 0.000 claims 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
238000006243 chemical reaction Methods 0.000 description 8
239000000243 solution Substances 0.000 description 8
QBWCMBCROVPCKQ-UHFFFAOYSA-N chlorous acid Chemical compound OCl=O QBWCMBCROVPCKQ-UHFFFAOYSA-N 0.000 description 7
238000005868 electrolysis reaction Methods 0.000 description 7
239000003792 electrolyte Substances 0.000 description 7
238000006722 reduction reaction Methods 0.000 description 7
239000007789 gas Substances 0.000 description 6
239000007864 aqueous solution Substances 0.000 description 5
239000000047 product Substances 0.000 description 5
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
239000003518 caustics Substances 0.000 description 4
238000010586 diagram Methods 0.000 description 4
230000010354 integration Effects 0.000 description 4
239000001301 oxygen Substances 0.000 description 4
229910052760 oxygen Inorganic materials 0.000 description 4
SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 4
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
238000003487 electrochemical reaction Methods 0.000 description 3
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 3
239000000126 substance Substances 0.000 description 3
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
230000015572 biosynthetic process Effects 0.000 description 2
XTEGARKTQYYJKE-UHFFFAOYSA-N chloric acid Chemical compound OCl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-N 0.000 description 2
238000010276 construction Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
230000004048 modification Effects 0.000 description 2
238000012986 modification Methods 0.000 description 2
229910000510 noble metal Inorganic materials 0.000 description 2
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
229920000557 Nafion® Polymers 0.000 description 1
229910000566 Platinum-iridium alloy Inorganic materials 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
229910045601 alloy Inorganic materials 0.000 description 1
239000000956 alloy Substances 0.000 description 1
239000012431 aqueous reaction media Substances 0.000 description 1
238000004061 bleaching Methods 0.000 description 1
239000011575 calcium Substances 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
238000012824 chemical production Methods 0.000 description 1
239000003638 chemical reducing agent Substances 0.000 description 1
229940005991 chloric acid Drugs 0.000 description 1
QBWCMBCROVPCKQ-UHFFFAOYSA-M chlorite Chemical compound [O-]Cl=O QBWCMBCROVPCKQ-UHFFFAOYSA-M 0.000 description 1
229940005993 chlorite ion Drugs 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
229910001882 dioxygen Inorganic materials 0.000 description 1
238000009826 distribution Methods 0.000 description 1
230000005611 electricity Effects 0.000 description 1
229910052735 hafnium Inorganic materials 0.000 description 1
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
239000000203 mixture Substances 0.000 description 1
229910052697 platinum Inorganic materials 0.000 description 1
HWLDNSXPUQTBOD-UHFFFAOYSA-N platinum-iridium alloy Chemical class [Ir].[Pt] HWLDNSXPUQTBOD-UHFFFAOYSA-N 0.000 description 1
239000011148 porous material Substances 0.000 description 1
230000002035 prolonged effect Effects 0.000 description 1
230000001737 promoting effect Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
239000000376 reactant Substances 0.000 description 1
229910001925 ruthenium oxide Inorganic materials 0.000 description 1
WOCIAKWEIIZHES-UHFFFAOYSA-N ruthenium(iv) oxide Chemical compound O=[Ru]=O WOCIAKWEIIZHES-UHFFFAOYSA-N 0.000 description 1
230000001568 sexual effect Effects 0.000 description 1
239000011734 sodium Substances 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
229910001415 sodium ion Inorganic materials 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000000758 substrate Substances 0.000 description 1
229910052715 tantalum Inorganic materials 0.000 description 1
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
239000010936 titanium Substances 0.000 description 1
239000004408 titanium dioxide Substances 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/34—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis
- C25B1/46—Simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine, e.g. by chlor-alkali electrolysis in diaphragm cells
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/24—Halogens or compounds thereof
- C25B1/26—Chlorine; Compounds thereof

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Electrochemistry (AREA)
Materials Engineering (AREA)
Metallurgy (AREA)
Organic Chemistry (AREA)
Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

JP63329519A 1988-02-16 1988-12-28 電解槽中での二酸化塩素の製造方法 Granted JPH01219185A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
CA558945		1988-02-16
CA000558945A CA1330964C (en)	1988-02-16	1988-02-16	Production of chlorine dioxide in an electrolytic cell

Publications (2)

Publication Number	Publication Date
JPH01219185A JPH01219185A (ja)	1989-09-01
JPH021917B2 true JPH021917B2 (id)	1990-01-16

Family

ID=4137450

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP63329519A Granted JPH01219185A (ja)	1988-02-16	1988-12-28	電解槽中での二酸化塩素の製造方法

Country Status (17)

Country	Link
EP (1)	EP0328818B1 (id)
JP (1)	JPH01219185A (id)
AR (1)	AR240340A1 (id)
AT (1)	ATE91306T1 (id)
AU (1)	AU604590B2 (id)
BR (1)	BR8807003A (id)
CA (1)	CA1330964C (id)
DE (1)	DE3882220T2 (id)
ES (1)	ES2041321T3 (id)
FI (1)	FI87936C (id)
NO (1)	NO173513C (id)
NZ (1)	NZ227199A (id)
PL (1)	PL160949B1 (id)
PT (1)	PT89221B (id)
RU (1)	RU1836493C (id)
YU (1)	YU46719B (id)
ZA (1)	ZA889170B (id)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA1324976C (en) *	1988-07-26	1993-12-07	Zbigniew Twardowski	Combined process for production of chlorine dioxide and sodium hydroxide
US7153586B2 (en)	2003-08-01	2006-12-26	Vapor Technologies, Inc.	Article with scandium compound decorative coating
US20070026205A1 (en)	2005-08-01	2007-02-01	Vapor Technologies Inc.	Article having patterned decorative coating
DE102007017625A1 (de) *	2007-04-12	2008-10-16	Hosni Dr. Khalaf	Verfahren zur Herstellung von Chlordioxid
FR2961756B1 (fr) *	2010-06-29	2014-03-07	Michelin Soc Tech	Systeme de production et d'alimentation en hydrogene et en chlorate de sodium, comportant un electrolyseur au chlorure de sodium pour produire le chlorate de sodium
US10590546B2 (en) *	2014-07-17	2020-03-17	Industrie De Nora S.P.A.	Catalytic or electrocatalytic generation of chlorine dioxide
CN114921799B (zh) *	2022-05-11	2024-09-06	上海交通大学	单原子阴阳极同时合成高纯二氧化氯气体的方法及其装置

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4426263A (en) *	1981-04-23	1984-01-17	Diamond Shamrock Corporation	Method and electrocatalyst for making chlorine dioxide
CA1252753A (en) *	1986-10-29	1989-04-18	Sterling Canada, Inc.	Selective removal of chlorine from solutions of chlorine dioxide and chlorine
CA1287815C (en) *	1987-05-29	1991-08-20	Marek Lipsztajn	Electrolytic production of chlorine dioxide
US4767510A (en) *	1987-06-03	1988-08-30	Tenneco Canada Inc.	Electrolytic protection of chlorine dioxide

1988
- 1988-02-16 CA CA000558945A patent/CA1330964C/en not_active Expired - Lifetime
- 1988-12-01 ES ES198888311380T patent/ES2041321T3/es not_active Expired - Lifetime
- 1988-12-01 AT AT88311380T patent/ATE91306T1/de not_active IP Right Cessation
- 1988-12-01 EP EP88311380A patent/EP0328818B1/en not_active Expired - Lifetime
- 1988-12-01 DE DE88311380T patent/DE3882220T2/de not_active Expired - Fee Related
- 1988-12-05 NZ NZ227199A patent/NZ227199A/en unknown
- 1988-12-07 NO NO885436A patent/NO173513C/no unknown
- 1988-12-07 ZA ZA889170A patent/ZA889170B/xx unknown
- 1988-12-14 PT PT89221A patent/PT89221B/pt not_active IP Right Cessation
- 1988-12-15 AU AU26977/88A patent/AU604590B2/en not_active Ceased
- 1988-12-21 AR AR312805A patent/AR240340A1/es active
- 1988-12-21 PL PL1988276597A patent/PL160949B1/pl unknown
- 1988-12-26 RU SU884613178A patent/RU1836493C/ru active
- 1988-12-27 YU YU235988A patent/YU46719B/sh unknown
- 1988-12-28 JP JP63329519A patent/JPH01219185A/ja active Granted
- 1988-12-30 BR BR888807003A patent/BR8807003A/pt not_active Application Discontinuation
1989
- 1989-01-13 FI FI890172A patent/FI87936C/fi not_active IP Right Cessation

Also Published As

Publication number	Publication date
ZA889170B (en)	1989-10-25
NO173513B (no)	1993-09-13
FI890172L (fi)	1989-08-17
PL276597A1 (en)	1989-08-21
PL160949B1 (pl)	1993-05-31
FI890172A0 (fi)	1989-01-13
NO173513C (no)	1993-12-22
EP0328818A2 (en)	1989-08-23
ES2041321T3 (es)	1993-11-16
PT89221B (pt)	1993-09-30
EP0328818A3 (en)	1989-12-06
AU2697788A (en)	1989-08-17
YU235988A (en)	1990-10-31
AR240340A1 (es)	1990-03-30
DE3882220T2 (de)	1994-02-17
YU46719B (sh)	1994-04-05
FI87936B (fi)	1992-11-30
DE3882220D1 (de)	1993-08-12
JPH01219185A (ja)	1989-09-01
AU604590B2 (en)	1990-12-20
NZ227199A (en)	1990-03-27
PT89221A (pt)	1990-03-08
NO885436L (no)	1989-08-17
EP0328818B1 (en)	1993-07-07
RU1836493C (ru)	1993-08-23
BR8807003A (pt)	1990-08-07
ATE91306T1 (de)	1993-07-15
FI87936C (fi)	1993-03-10
CA1330964C (en)	1994-07-26
NO885436D0 (no)	1988-12-07

Publication	Publication Date	Title
US4806215A (en)	1989-02-21	Combined process for production of chlorine dioxide and sodium hydroxide
US10988847B2 (en)	2021-04-27	Apparatus and method of preparing carbonate and/or formate from carbon dioxide
JPH07112924B2 (ja)	1995-12-06	塩素酸からの二酸化塩素の生成
JP2006503180A5 (id)	2006-11-30
KR910001138B1 (ko)	1991-02-25	이산화염소와 수산화나트륨의 제조방법
CN114450436A (zh)	2022-05-06	用于制备氯、一氧化碳和任选的氢的方法和电解设备
US4853096A (en)	1989-08-01	Production of chlorine dioxide in an electrolytic cell
JP4778320B2 (ja)	2011-09-21	過塩素酸化合物の電解合成方法
US5089095A (en)	1992-02-18	Electrochemical process for producing chlorine dioxide from chloric acid
US20030000848A1 (en)	2003-01-02	Electrolytic process for the production of chlorine dioxide
CA2265183C (en)	2008-01-08	Magnesium metal production
JPS61250187A (ja)	1986-11-07	アルカリ金属塩化物ブラインの電解方法
JPH021917B2 (id)	1990-01-16
US5466347A (en)	1995-11-14	Method for electrolyzing aqueous solution of alkali chloride
JP3561130B2 (ja)	2004-09-02	過酸化水素製造用電解槽
US6294070B1 (en)	2001-09-25	Process for electrolytically producing metal-amalgam
CN109055966A (zh)	2018-12-21	一种电化学-化学联合制备二氧化氯的方法
JPH08134676A (ja)	1996-05-28	次亜塩素酸ナトリウム溶液の製造方法及びクロレート溶液の製造方法
Ding et al.	1996	Electrolytic recovery of chlorine from hydrogen chloride gas with fused molten salt electrolyte LiCl/KCl
KR850000707B1 (ko)	1985-05-15	파라데이수를 향상의 염소산나트륨 제법
Hirakata et al.	1989	M. Shibuya and G. Ishi, 1) 2470 Handa, Shibukawa-shi, Gunma-ken 377 Japan