JPH02229742A - Noise insulating laminated glass - Google Patents
Noise insulating laminated glassInfo
- Publication number
- JPH02229742A JPH02229742A JP4921889A JP4921889A JPH02229742A JP H02229742 A JPH02229742 A JP H02229742A JP 4921889 A JP4921889 A JP 4921889A JP 4921889 A JP4921889 A JP 4921889A JP H02229742 A JPH02229742 A JP H02229742A
- Authority
- JP
- Japan
- Prior art keywords
- film
- glass
- layer
- laminated glass
- laminated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
- B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
- B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
- B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
- B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
- B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
Landscapes
- Joining Of Glass To Other Materials (AREA)
Abstract
Description
【発明の詳細な説明】 (産業上の利用分野) 本発明は遮音性合わせガラスに関する。[Detailed description of the invention] (Industrial application field) The present invention relates to sound-insulating laminated glass.
(従来の技術)
従来、対向させたガラス板の間に可塑化ポリビニルブチ
ラール膜に代表される接着性中間膜を積層接着してなる
遮音性合わせガラスが知られており、かかる遮音性合わ
せガラスは、例えば、自動車等の交通車両の窓ガラスや
建築物における窓ガラスに広く用いられている。(Prior Art) Conventionally, sound-insulating laminated glass has been known in which an adhesive interlayer film, typically a plasticized polyvinyl butyral film, is laminated and bonded between opposing glass plates. It is widely used for window glass of transportation vehicles such as automobiles and window glass of buildings.
最近、例えば、住宅環境の一層の改善を目指して、かか
る遮音性合わせガラスには、一層の遮音性が要求される
に至っており、特に、2000Hzを中心とするコイン
シデンス効果の生じる[1数域での遮音性の改善が強く
要求されている。このコインシデンス効果とは、ガラス
に音波が入射したとき、ガラスの剛性と慣性によって、
ガラス面上を横波が伝導し、この横波と入射音とが共鳴
し、その結果として、音の透過が起こる現象である.
上記したような従来の遮音性合わせガラスでは、200
0Hzを中心とする周波数域において、かかるコインシ
デンス効果による遮音性能の低下が避けられないのが実
情である。Recently, for example, with the aim of further improving the residential environment, such sound-insulating laminated glass has come to be required to have even higher sound-insulating properties. There is a strong demand for improved sound insulation. This coincidence effect is caused by the stiffness and inertia of the glass when a sound wave is incident on the glass.
This is a phenomenon in which transverse waves are transmitted on the glass surface, and the incident sound resonates with the transverse waves, resulting in sound transmission. Conventional sound-insulating laminated glass as mentioned above has a
The reality is that in a frequency range centered around 0 Hz, a reduction in sound insulation performance due to such a coincidence effect is unavoidable.
一殻に、遮音性合わせガラスの遮音性能は、周波数に対
する透過損失量として示される。従来の合わせガラスで
は、第1図に示すように、中高周波数域、即ち2000
Hz付近にて、コインシデンス効果によって、遮音性能
が低下する。JISによれば、遮音等級は、500Hz
以上では、透過損失量が一定値にて表わされている.従
って、コインシデンス効果による遮音性能の低下として
問題となるのは、コインシデンス効果によって生じる透
過損失量の極小部(以下、この極小部の透過損失量をT
L値という。)である。Firstly, the sound insulation performance of sound insulation laminated glass is expressed as the amount of transmission loss with respect to frequency. Conventional laminated glass, as shown in Figure 1, has a high frequency range of 2000
In the vicinity of Hz, the sound insulation performance decreases due to the coincidence effect. According to JIS, the sound insulation class is 500Hz.
In the above, the amount of transmission loss is expressed as a constant value. Therefore, the problem with deterioration of sound insulation performance due to the coincidence effect is the minimum part of the transmission loss caused by the coincidence effect (hereinafter, the transmission loss of this minimum part is T
This is called the L value. ).
そこで、従来、かかるTL値を高める手段として、合わ
せガラスの質量の増大、ガラス面積の細分化、ガラスの
辺比の増大、合わせガラス板の支持方法の改善等が提案
されているが、いずれも効果に乏しく、しかも、他の面
にて不利益を生じるので、実用的な改善方法とはいい難
い。Therefore, conventional methods of increasing the TL value have been proposed, such as increasing the mass of the laminated glass, subdividing the glass area, increasing the side ratio of the glass, and improving the method of supporting the laminated glass plate. Since it is not very effective and causes disadvantages in other aspects, it cannot be called a practical improvement method.
(発明が解決しようとする課題)
一般に、可塑化ポリビニルアセタール膜は、透明性、耐
候性、衝撃エネルギー吸収性等の特性のバランスがよく
とれており、遮音性合わせガラスにおけるすぐれた中間
膜であるが、本発明者らは、この膜に更にガラス転移点
が所定温度以下である層を配設積層することによって、
特に、前記コインシデンス効果による遮音性能の低下が
起こりにくい遮音性合わせガラスを得ることができるこ
とを見出して、本発明に至ったものである.従って、本
発明は、従来の遮音性合わせガラスにおける前記した問
題を解決するためになされたものであって、コインシデ
ンス効果による遮音性能の低下が起こりにくい遮音性合
わせガラスを提供することを目的とする。(Problems to be Solved by the Invention) In general, plasticized polyvinyl acetal films have well-balanced properties such as transparency, weather resistance, and impact energy absorption, and are excellent intermediate films for sound-insulating laminated glass. However, the present inventors added a layer having a glass transition point below a predetermined temperature to this film.
In particular, the inventors have discovered that it is possible to obtain a sound-insulating laminated glass that is less susceptible to deterioration in sound-insulating performance due to the coincidence effect, leading to the present invention. Therefore, the present invention was made in order to solve the above-mentioned problems in conventional sound-insulating laminated glass, and an object of the present invention is to provide a sound-insulating laminated glass in which deterioration in sound insulation performance due to the coincidence effect is less likely to occur. .
(課題を解決するための手段)
本発明は、高分子物質を主成分とするガラス転移温度が
15℃以下の層Aと可塑化ポリビニルアセクール膜Bと
がガラス板の間に積層されていることを特徴とする.
本発明において、上記の高分子物質を主成分とするガラ
ス転移温度が15℃以下の層Aとしては、例えば、塩化
ビニル80〜98.5重量%、メタクリル酸グリシジル
1〜10重量%及びエチレン0.5〜10重量%を共重
合して得られる熱可塑性樹脂100重量部に可塑剤40
〜60重量部を配合してなる樹脂組成物から形成される
ものを挙げることができる.ここに、可塑剤としては、
例えば、脂肪酸系可塑剤やフタル酸系可塑剤、リン酸系
可塑剤等が用いられる.
層Aの主成分として用いられる高分子物質としては、上
記以外にも、(メタ)アクリル酸のアルキルエステルや
、酢酸ビニルの単独重合体、共重合体等が挙げられる.
また、可塑化ボリビニルアセクール膜Bは、例えば、ポ
リビニルプチラール100重量部にグリコール系可塑剤
35〜45重量部を配合した組成物を押出成形等の常法
によって製膜して得ることができる。かかるポリビニル
アセクール膜は、通常、24〜32℃のガラス転移温度
を有する.ガラス転移温度が15℃以下の層Aは、例え
ば、前記主成分とする高分子物質に必要に応じて可塑剤
、添加剤等を配合し、溶剤を加えて溶液とし、これをガ
ラス板又はポリビニルアセタール膜Bに、例えばバーコ
ーター等を用いて塗布乾燥して溶剤を除去し、所定の膜
厚とする。通常、ポリビニルアセクール膜Bには、合わ
せガラスの製造時に、空気抜き特性を良好とするために
、多くの場合、エンボスが施されているので、層Aは、
上記溶液をガラス板に塗布して形成するのが好ましい。(Means for Solving the Problems) The present invention is characterized in that a layer A containing a polymeric substance as a main component and having a glass transition temperature of 15° C. or less and a plasticized polyvinyl acecool film B are laminated between glass plates. Features: In the present invention, layer A having a glass transition temperature of 15° C. or lower and containing the above-mentioned polymeric substance as a main component includes, for example, 80 to 98.5% by weight of vinyl chloride, 1 to 10% by weight of glycidyl methacrylate, and 0% of ethylene. 40 parts by weight of a thermoplastic resin obtained by copolymerizing 5 to 10% by weight of a plasticizer.
Examples include those formed from resin compositions containing up to 60 parts by weight. Here, as a plasticizer,
For example, fatty acid plasticizers, phthalic acid plasticizers, phosphoric acid plasticizers, etc. are used. In addition to the above, examples of polymeric substances used as the main component of layer A include alkyl esters of (meth)acrylic acid, homopolymers and copolymers of vinyl acetate, and the like. Furthermore, the plasticized polyvinyl acecool film B can be obtained, for example, by forming a film by a conventional method such as extrusion molding from a composition in which 100 parts by weight of polyvinyl butyral and 35 to 45 parts by weight of a glycol plasticizer are blended. can. Such a polyvinyl acecool film usually has a glass transition temperature of 24 to 32°C. Layer A having a glass transition temperature of 15° C. or less can be made by, for example, adding plasticizers, additives, etc. as necessary to the polymeric substance as the main component, adding a solvent to form a solution, and then forming the solution on a glass plate or polyvinyl resin. The acetal film B is coated and dried using, for example, a bar coater, and the solvent is removed to obtain a predetermined film thickness. Normally, polyvinyl acecool film B is often embossed to improve air venting properties during the production of laminated glass, so layer A is
Preferably, the solution is formed by applying the solution to a glass plate.
本発明による遮音性合わせガラスは、ガラス板−A−B
−ガラス板の如くに構成されていてもよいが、遮音性能
を高めるうえでガラス板−A−B−A−ガラス板の如く
に、層A及びポリビニルアセタール膜Bを積層するのが
好ましい.上記溶液としては、特に、限定されるもので
はないが、通常、層Aを形成する樹脂組成物の1〜20
重量%溶液、好ましくは2〜8重量%溶液が用いられる
。The sound-insulating laminated glass according to the present invention comprises glass plate-A-B
-Although it may be constructed like a glass plate, in order to improve the sound insulation performance, it is preferable to laminate the layer A and the polyvinyl acetal film B like a glass plate-A-B-A-glass plate. The above solution is not particularly limited, but usually 1 to 20% of the resin composition forming layer A.
A weight percent solution is used, preferably a 2-8 weight percent solution.
また、本発明によれば、層Aを形成する樹脂組成物は、
これをフィルムとし、ガラス仮− A − B一A−ガ
ラス板となるようにガラス板の間に積層することによっ
ても、遮音性合わせガラスを得ることができる。このよ
うな層Aを形成するフィルムは、従来、知られている通
常の流延法や押出法等によって得ることができる。Further, according to the present invention, the resin composition forming layer A is
A sound-insulating laminated glass can also be obtained by making this into a film and laminating it between glass plates to form a temporary glass plate. Such a film forming layer A can be obtained by conventionally known ordinary casting methods, extrusion methods, and the like.
層Aの厚さは、本発明においては、1μm以上、特に、
5〜50μmの範囲であることが望ましい。In the present invention, the thickness of layer A is 1 μm or more, particularly,
The thickness is preferably in the range of 5 to 50 μm.
厚さが1μmよりも薄いときは、前記TL値を有効に高
めることができない。When the thickness is thinner than 1 μm, the TL value cannot be effectively increased.
他方、ポリビニルアセタール膜Bは、その膜厚が0.
2〜l, 2重mの範囲であることが好ましい。On the other hand, the polyvinyl acetal film B has a film thickness of 0.
It is preferably in the range of 2 to 1, 2 m.
本発明による合わせガラスにおいては、層A及び膜B中
に占める膜Bの割合は、通常、75重量%以上とされる
ので、膜Bの前記すぐれた性質が保持される一方、ガラ
ス転移点が15℃以下の層Aが膜Bと共に配設積層され
るので、合わせガラスとしての良好な特性と遮音性とを
兼ね備えた遮音性合わせガラスを得ることができるので
ある。In the laminated glass according to the present invention, the proportion of film B in layer A and film B is usually 75% by weight or more, so that the above-mentioned excellent properties of film B are maintained, while the glass transition point is Since the layer A having a temperature of 15° C. or lower is arranged and laminated together with the film B, it is possible to obtain a sound-insulating laminated glass that has both good characteristics as a laminated glass and sound-insulating properties.
(発明の効果)
以上のように、本発明によれば、ガラス転移温度が15
℃以下の層Aと可塑化ボリビニルアセタール膜Bとをガ
ラス板の間に積層することによって、特に、2000H
Zを中心とする中高周波数域において、コインシデンス
効果による遮音性能の低下を防止することができる。(Effect of the invention) As described above, according to the present invention, the glass transition temperature is 15
In particular, by laminating the layer A and the plasticized polyvinyl acetal film B between the glass plates, the temperature at 2000H
In the medium and high frequency range centered on Z, deterioration of sound insulation performance due to the coincidence effect can be prevented.
(実施例)
以下に実施例を挙げて、本発明を説明する。尚、以下に
おいて、層A及び膜Bを形成する樹脂組成物としては、
次のものを用いた。(Example) The present invention will be described below with reference to Examples. In addition, in the following, the resin compositions forming layer A and film B are as follows:
The following were used.
ガース 10℃の Aの
塩化ビニル91重景%、メタクリル酸グリシジル2重量
%及びエチレン7重量%を共重合して熱可塑性樹脂を得
、この熱可塑性樹脂100重量部にジオクチルアジペー
トとジオクチルフタレートとの混合可塑剤40重量部を
配合して、調製した。A thermoplastic resin was obtained by copolymerizing 91% by weight of vinyl chloride, 2% by weight of glycidyl methacrylate, and 7% by weight of ethylene at 10°C, and 100 parts by weight of this thermoplastic resin was mixed with dioctyl adipate and dioctyl phthalate. It was prepared by blending 40 parts by weight of a mixed plasticizer.
ガース が−5℃の Aの
塩化ビニル91重量%、メタクリル酸グリシジル2mI
%及びエチレン7重量%を共重合して熱可塑性樹脂を得
、この熱可塑性樹脂100重量部にジオクチルアジペー
トとジオクチルフタレートとの混合可塑剤50重量部を
配合して、調製した.ガース 28〜30℃の
Bのl
また、膜Bは,次のようにして作製した。91% by weight of vinyl chloride in A at −5°C, 2ml of glycidyl methacrylate
% and 7% by weight of ethylene to obtain a thermoplastic resin, and 100 parts by weight of this thermoplastic resin was blended with 50 parts by weight of a mixed plasticizer of dioctyl adipate and dioctyl phthalate. Girth B at 28-30°C Film B was prepared as follows.
ボ1ビニルプチー−ル B
ポリビニルブチラール100重量部にトリエチレングリ
コールジー2−エチルプチラール40重量部を配合して
、これを厚さ0. 3 8 mのフ9ルムに成形した。1 Vinyl Butyral B 40 parts by weight of triethylene glycol di-2-ethyl butyral is blended with 100 parts by weight of polyvinyl butyral, and this is coated to a thickness of 0. It was molded into a 38 m long frame.
また、NA及び膜Bのガラス転移温度は、5aIIX5
cmXlmの膜について、粘弾性スペクト口メーターを
用い、1 0Hzの周波数における広い温度範囲の粘弾
性を測定し、貯蔵弾性率G゜と損失弾性率G”の比G”
/G”である損失正接tanδが極大値を示すときの温
度をもってガラス転移温度とした。In addition, the glass transition temperature of NA and film B is 5aIIX5
cmXlm film, the viscoelasticity was measured in a wide temperature range at a frequency of 10 Hz using a viscoelastic spectrometer, and the ratio of the storage elastic modulus G゜ to the loss elastic modulus G'' was determined.
The temperature at which the loss tangent tan δ, which is /G'', showed a maximum value was defined as the glass transition temperature.
実施例1
2枚のガラス板のそれぞれ片面にガラス転移温度がlθ
℃の層Aの樹脂組成物を溶剤に溶解した溶液を塗布し、
乾燥させて、膜厚50μmの塗膜を形成させた。この塗
膜を内側にして、2枚のガラス板の間に中間膜を置き、
積層接着させて、合わせガラスを作製した。Example 1 One side of each of two glass plates has a glass transition temperature lθ
Applying a solution in which the resin composition of layer A at ℃ is dissolved in a solvent,
It was dried to form a coating film with a thickness of 50 μm. With this paint film on the inside, place an interlayer film between two glass plates,
Laminated glass was produced by laminating and bonding.
この合わせガラスについて、遮音性能を測定し、コイン
シデンス部の谷の透過損失ITL値を求めたところ、3
5dBであった.
実施例2
実施例1において、ガラス転移温度が10℃の層Aに代
えて、ガラス転移温度が−5℃の層Aを用いた以外は、
実施例lと同様にして、合わせガラスを作製した.TL
値は、37dBであった。The sound insulation performance of this laminated glass was measured, and the transmission loss ITL value of the valley of the coincidence part was found to be 3.
It was 5dB. Example 2 In Example 1, except that layer A with a glass transition temperature of -5°C was used instead of layer A with a glass transition temperature of 10°C.
A laminated glass was produced in the same manner as in Example 1. T.L.
The value was 37 dB.
比較例エ
ガラス板の間に膜Bのみを配して、合わせガラスを作製
した。TL値は、29dBであった。Comparative Example A laminated glass was produced by disposing only the film B between glass plates. The TL value was 29 dB.
実施例3及び4
実施例lにおいて、層Aの膜厚を5μm及び1μmとし
た以外は、実施例1と同様にして、合わせガラスを作製
した.TL値は、それぞれ35dB及び34dBであっ
た.
実施例5
ガラス転移温度が10℃の層Aを予め押出成形にて厚み
50μmのフィルムとした。Examples 3 and 4 Laminated glass was produced in the same manner as in Example 1, except that the thickness of layer A was 5 μm and 1 μm in Example 1. The TL values were 35 dB and 34 dB, respectively. Example 5 Layer A having a glass transition temperature of 10° C. was previously extruded into a film having a thickness of 50 μm.
このフイルムと膜Bを用いて、ガラスーフィルムー膜B
−フイルムーガラスの構成に積層して、合わせガラスを
作製した。TL値は、35dBであった.
実施例6
実施例5において、ガラス転移温度が−5℃の層Aを用
いた以外は、実施例5と同様にして、合わせガラスを作
製した。TL値は、37dBであった。Using this film and membrane B, glass-film-membrane B
- A laminated glass was produced by laminating the structure of film glass. The TL value was 35dB. Example 6 A laminated glass was produced in the same manner as in Example 5, except that layer A having a glass transition temperature of -5°C was used. The TL value was 37 dB.
実施例7
実施例1において、層Aの膜厚を0.5μmとした以外
は、実施例1と同様にして、合わせガラスを作製した。Example 7 A laminated glass was produced in the same manner as in Example 1 except that the thickness of layer A was 0.5 μm.
TL値は、31dBであった。The TL value was 31 dB.
第1図は、遮音性合わせガラス板の遮音性能を周波数に
対する透過損失量として示すグラフである。
特許出願人 積水化学工業株式会社
代表者 廣田 馨
第1図
7fI彼数(HZ)FIG. 1 is a graph showing the sound insulation performance of a sound insulation laminated glass plate as a transmission loss amount versus frequency. Patent applicant: Sekisui Chemical Co., Ltd. Representative: Kaoru Hirota Figure 1 7 fI number (HZ)
Claims (1)
℃以下の層Aと可塑化ポリビニルアセタール膜Bとがガ
ラス板の間に積層されていることを特徴とする遮音性合
わせガラス。(1) Glass transition temperature of polymer material as main component is 15
A sound-insulating laminated glass characterized in that a layer A having a temperature of 0.degree. C. or less and a plasticized polyvinyl acetal film B are laminated between glass plates.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4921889A JPH02229742A (en) | 1989-02-28 | 1989-02-28 | Noise insulating laminated glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4921889A JPH02229742A (en) | 1989-02-28 | 1989-02-28 | Noise insulating laminated glass |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02229742A true JPH02229742A (en) | 1990-09-12 |
Family
ID=12824811
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4921889A Pending JPH02229742A (en) | 1989-02-28 | 1989-02-28 | Noise insulating laminated glass |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02229742A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5340654A (en) * | 1992-04-23 | 1994-08-23 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Interlayer film for laminated glass |
| JPH0797241A (en) * | 1993-09-29 | 1995-04-11 | Sekisui Chem Co Ltd | Sound insulating laminated glass |
| WO1998026927A1 (en) * | 1996-12-16 | 1998-06-25 | Minnesota Mining And Manufacturing Company | Damped glass and plastic laminates |
| US6903152B2 (en) | 2000-03-02 | 2005-06-07 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass and laminated glass |
| EP1866156A1 (en) | 2005-03-17 | 2007-12-19 | Solutia Inc. | Sound reducing wedge shaped polymer interlayers |
| US7510771B2 (en) | 2005-03-17 | 2009-03-31 | Solutia Incorporated | Sound reducing polymer interlayers |
| US7842395B2 (en) | 2006-11-01 | 2010-11-30 | Solutia Inc. | Multiple layer interlayers having a gradient region |
| DE102017107823A1 (en) | 2016-07-29 | 2018-02-01 | Hyundai Motor Company | Laminated resin film, laminated glass with resin film, and vehicle with laminated glass |
| DE102018004652A1 (en) | 2017-06-15 | 2018-12-20 | Skc Co., Ltd | Resin film for laminated glass and laminated glass and its manufacture |
| KR20190002398A (en) | 2018-12-27 | 2019-01-08 | 에스케이씨 주식회사 | Resin film for laminated glass, laminated glass comprising the same and manufacturing method of the laminated glass |
| JP2020073430A (en) * | 2014-09-12 | 2020-05-14 | 積水化学工業株式会社 | Interlayer film for laminated glass and laminated glass |
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| JPS6212185A (en) * | 1985-07-09 | 1987-01-21 | 田中貴金属工業株式会社 | Formation of cu thin film on quartz substrate |
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| JPS6212185A (en) * | 1985-07-09 | 1987-01-21 | 田中貴金属工業株式会社 | Formation of cu thin film on quartz substrate |
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5340654A (en) * | 1992-04-23 | 1994-08-23 | Sekisui Kagaku Kogyo Kabushiki Kaisha | Interlayer film for laminated glass |
| JPH0797241A (en) * | 1993-09-29 | 1995-04-11 | Sekisui Chem Co Ltd | Sound insulating laminated glass |
| KR100811031B1 (en) * | 1996-12-16 | 2008-03-07 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | Damped glass and plastic laminates |
| WO1998026927A1 (en) * | 1996-12-16 | 1998-06-25 | Minnesota Mining And Manufacturing Company | Damped glass and plastic laminates |
| US6132882A (en) * | 1996-12-16 | 2000-10-17 | 3M Innovative Properties Company | Damped glass and plastic laminates |
| KR100695696B1 (en) * | 1996-12-16 | 2007-03-16 | 미네소타 마이닝 앤드 매뉴팩춰링 캄파니 | Damped Glass and Plastic Laminates |
| US8278379B2 (en) | 2000-03-02 | 2012-10-02 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass and laminated glass |
| US7858683B2 (en) | 2000-03-02 | 2010-12-28 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass and laminated glass |
| US7468209B2 (en) | 2000-03-02 | 2008-12-23 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass and laminated glass |
| US8450405B2 (en) | 2000-03-02 | 2013-05-28 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass and laminated glass |
| US6903152B2 (en) | 2000-03-02 | 2005-06-07 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass and laminated glass |
| US8039536B2 (en) | 2000-03-02 | 2011-10-18 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass and laminated glass |
| EP2286993A1 (en) | 2000-03-02 | 2011-02-23 | Sekisui Chemical Co., Ltd. | Interlayer film for laminated glass and laminated glass |
| US8574706B2 (en) | 2005-03-17 | 2013-11-05 | Solutia Inc. | Sound reducing wedge shaped polymer interlayers |
| US7854993B2 (en) | 2005-03-17 | 2010-12-21 | Solutia Inc. | Sound reducing polymer interlayers |
| US7846532B2 (en) | 2005-03-17 | 2010-12-07 | Solutia Incorporated | Sound reducing wedge shaped polymer interlayers |
| US7510771B2 (en) | 2005-03-17 | 2009-03-31 | Solutia Incorporated | Sound reducing polymer interlayers |
| KR101310022B1 (en) * | 2005-03-17 | 2013-09-24 | 솔루티아 인코포레이티드 | Sound reducing wedge shaped polymer interlayers |
| EP1866156A1 (en) | 2005-03-17 | 2007-12-19 | Solutia Inc. | Sound reducing wedge shaped polymer interlayers |
| US7842395B2 (en) | 2006-11-01 | 2010-11-30 | Solutia Inc. | Multiple layer interlayers having a gradient region |
| US10967611B2 (en) | 2014-09-12 | 2021-04-06 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
| JP2020073430A (en) * | 2014-09-12 | 2020-05-14 | 積水化学工業株式会社 | Interlayer film for laminated glass and laminated glass |
| US10967612B2 (en) | 2014-09-12 | 2021-04-06 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
| US11135811B2 (en) | 2014-09-12 | 2021-10-05 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
| US11141958B2 (en) | 2014-09-12 | 2021-10-12 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
| US11235559B2 (en) | 2014-09-12 | 2022-02-01 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
| US11407205B2 (en) | 2014-09-12 | 2022-08-09 | Sekisui Chemical Co., Ltd. | Interlayer for laminated glass, and laminated glass |
| DE102017107823A1 (en) | 2016-07-29 | 2018-02-01 | Hyundai Motor Company | Laminated resin film, laminated glass with resin film, and vehicle with laminated glass |
| DE102017107823B4 (en) | 2016-07-29 | 2022-12-01 | Hyundai Motor Company | Resin film for laminated glass and laminated glass with the resin film |
| DE102018004652A1 (en) | 2017-06-15 | 2018-12-20 | Skc Co., Ltd | Resin film for laminated glass and laminated glass and its manufacture |
| KR20180136660A (en) | 2017-06-15 | 2018-12-26 | 에스케이씨 주식회사 | Resin film for laminated glass, laminated glass comprising the same and manufacturing method of the laminated glass |
| KR20190002398A (en) | 2018-12-27 | 2019-01-08 | 에스케이씨 주식회사 | Resin film for laminated glass, laminated glass comprising the same and manufacturing method of the laminated glass |
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