JPH02229897A

JPH02229897A - Bleaching detergent composition

Info

Publication number: JPH02229897A
Application number: JP1230775A
Authority: JP
Inventors: Muneo Aoyanagi; 青柳　宗郎; Mutsumi Kuroda; 睦黒田; Hiroyuki Araki; 宏幸荒木; Akio Taguchi; 田口　昭男
Original assignee: Kao Corp
Current assignee: Kao Corp
Priority date: 1988-09-22
Filing date: 1989-09-06
Publication date: 1990-09-12

Abstract

PURPOSE:To provide the subject composition containing a peroxide, a bleaching activator and a mixture of surfactants such as an alkylbenzenesulfonic acid salt at specific ratios, having high bleaching effect and effective in preventing the redeposition of soiling. CONSTITUTION:The objective composition contains (A) 3-30wt.% of a peroxide capable of forming hydrogen peroxide when dissolved in water, (B) 0.1-30wt.% of a bleaching activator capable of forming an organic peracid having cationic group by reacting with hydrogen peroxide and (C) 10-50wt.% of a surfactant mixture composed of (i) an alkylbenzenesulfonic acid salt, (ii) an olefinsulfonic acid salt and (iii) a polyoxyethylene alkyl ether at weight ratios of the components i, ii and iii falling within the range enclosed by the points (88%, 10%, 2%), (45%, 53%, 2%), (45%, 30%, 25%) and (65%, 10%, 25%) on triangular coordinates.

Description

【発明の詳細な説明】〔産業上の利用分野〕本発明は特定の漂白活性化剤を含有する漂白洗剤組成物
に関する．〔従来の技術〕従来より漂白洗剤には過炭酸ソーダ、過硼酸ソーダなど
の酸素系漂白剤が配合されている。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to bleaching detergent compositions containing specific bleach activators. [Prior Art] Conventionally, bleaching detergents contain oxygen bleaching agents such as sodium percarbonate and sodium perborate.

酸素系漂白剤は塩素系漂白剤に《らべ漂白力が弱く各種
漂白活性化剤が併用されている。代表的な活性化剤とし
て、テトラアセチルエチレンジアミン、アセトキシベン
ゼンスルホン酸ソーダ、イソノナノイルオキシベンゼン
スルホン酸ソーダ、テトラアセチルグリコリルウリル、
グルコースペンタアセテートなどが汎用されている．（発明が解決しようとする諜題〕本発明者らは、前述した漂白活性化剤より優れた活性化
効果を示す漂白活性化剤について研究した結果、カチオ
ン基を有する活性化剤であり、しかも過酸化水素と反応
してカチオン基を有する有機過酸を生成する活性化剤が
漂白力を著しく向上することを見い出した。衣類あるい
は汚れの多くは負に帯電しているので、これらの漂白活
性化剤が衣類又は汚れの表面上に吸着あるいは濃縮され
た状態で存在し漂白効率を高めているものと推測される
．しかしながら、さらに研究を続けた結果、カチオン基
を有する漂白活性化剤を配合した漂白洗剤は再汚染の問
題を生ずることが判明した．〔課題を解決するための手段〕本発明者らは、漂白洗剤系にカチオン基を有する漂白活
性化剤を併用すべ《鋭意研究した結果、特定の界面活性
剤併用系であれば前述の再汚染の問題を解決できること
を見い出し本発明を完成した．即ち、本発明は、（ａ）　　水に溶解して過酸化水素を生成する過酸化物
３〜３０重量％（ｂ）過酸化水素と反応してカチオン基を有する有機過
酸を生成する漂白活性化剤０．１〜３０重量％（ｃ）　　アルキルベンゼンスルホン酸塩（ｄ）　　オ
レフィンスルホン酸塩（ｅ）　　ポリオキシエチレンアルキルエーテル（ｃ）
　＋　（ｄ）　＋　（ｅ）−１０　〜５０重量％（ｃ）
，　（ｄ）．　（ｅ）３成分の配合比は添付図面に示す
三角図表の点Ａ’（ｃ成分８８％、ｄ成分１０％、ｅ成
分２％）、Ｂ（ｃ成分４５％、ｄ成分５３％、ｅ成分２
％）、Ｃ（ｃ成分４５％、ｄ成分３０％、ｅ成分２５％
）、Ｄ（ｃ成分６５％、ｄ成分１０％、ｅ成分２５％）
で囲まれた範囲内にあるを含有することを特徴とする漂
白洗剤組成物を提供するものである．本発明に用いられる（ａ）成分の水に溶解して過酸化水
素を生成する過酸化物としては有機及び無機過酸化水素
付加物である炭酸ナトリウム・過酸化水素付加物（過炭
酸ソーダ）、トリポリリン酸ナトリウム・遇酸化水素付
加物、ビロリン酸ナトリウム・過酸化水素付加物、尿素
・過酸化水素付加物、又は４Ｎａ冨ＳＯａ・２ＨｚＯｔ
−ＮａＣｌ等が例示される．又、過ホウ酸ナトリウムー
水化物、過ホウ酸ナトリウム四水化物、過酸化ナトリウ
ム、過酸化カルシウム等の無機過酸化物も使用できる．
この中でも特に炭酸ナトリウム・過酸化水素付加物、過
ホウ酸ナトリウムー水化物、過ホウ酸ナトリウム四水化
物が好ましい。Oxygen bleach has weaker bleaching power than chlorine bleach, so various bleach activators are used in combination. Typical activators include tetraacetylethylenediamine, sodium acetoxybenzenesulfonate, sodium isononanoyloxybenzenesulfonate, tetraacetylglycolyluril,
Glucose pentaacetate is commonly used. (Spiritual Problem to be Solved by the Invention) As a result of research into a bleach activator that exhibits an activation effect superior to that of the bleach activator described above, the present inventors found that it is an activator that has a cationic group, and that It has been found that an activator that reacts with hydrogen peroxide to produce an organic peracid with a cationic group significantly improves bleaching power.Since most clothing and stains are negatively charged, the bleaching activity of these It is assumed that the bleaching agent exists in an adsorbed or concentrated state on the surface of clothing or stains, increasing bleaching efficiency.However, as a result of further research, it was found that a bleach activator with a cationic group was added. It has been found that the bleaching detergents used in the bleaching process cause the problem of recontamination. [Means for solving the problem] As a result of intensive research, the present inventors have discovered that it is possible to use a bleach activator having a cationic group in combination with the bleaching detergent system. The present invention has been completed by discovering that the above-mentioned recontamination problem can be solved by using a combination system with a specific surfactant. (b) 0.1 to 30% by weight of a bleach activator that reacts with hydrogen peroxide to produce an organic peracid having a cationic group (c) Alkylbenzene sulfonate (d) Olefin sulfonic acid Salt (e) Polyoxyethylene alkyl ether (c)
+ (d) + (e) -10 to 50% by weight (c)
, (d). (e) The blending ratio of the three components is point A' (88% c component, 10% d component, 2% e component) and B (45% c component, 53% d component, e component) on the triangular diagram shown in the attached drawing. 2
%), C (c component 45%, d component 30%, e component 25%
), D (c component 65%, d component 10%, e component 25%)
The present invention provides a bleaching detergent composition characterized by containing the following: Component (a) used in the present invention, a peroxide that dissolves in water to produce hydrogen peroxide, includes organic and inorganic hydrogen peroxide adducts such as sodium carbonate/hydrogen peroxide adduct (soda percarbonate); Sodium tripolyphosphate/hydrogen oxide adduct, sodium birophosphate/hydrogen peroxide adduct, urea/hydrogen peroxide adduct, or 4Na-rich SOa/2HzOt
-NaCl etc. are exemplified. Inorganic peroxides such as sodium perborate hydrate, sodium perborate tetrahydrate, sodium peroxide, and calcium peroxide can also be used.
Among these, particularly preferred are sodium carbonate/hydrogen peroxide adduct, sodium perborate hydrate, and sodium perborate tetrahydrate.

（ａ）成分の過酸化物は本発明の組成物中に３〜３０重
量％、好ましくは５〜１５重量％配合される。Component (a), peroxide, is blended in the composition of the present invention in an amount of 3 to 30% by weight, preferably 5 to 15% by weight.

本発明に用いられる（ロ）成分の過酸化水素と反応して
カチオン基を有する有機過酸を生成する漂白活性化剤と
しては、例えば、次のような化合物が挙げられる．Ｒ，（ｍはｌ〜ｌ２、特に１〜５が好ましく、ｎは１〜１０
、特に１〜５が好ましい．）である＊ａ＋ｂはａ−０，
ｂ＋Ｏであるが、又はａ−１，ｂ−１である＊　Ｒ．，
　Ｒ，は炭素数１〜３のアルキル基又はヒドロキシアル
キル基である．ｌは１〜ｌ２であり、Ｃは０又は１であ
る．Ｌは脱離基であり、下記の（イ）〜（夕）から選ば
れる．式（１）中、Ｒ，はＣ，〜ｌ、特にＣ１〜１４の直鎖又
はル基、Ｒ．はＣ，〜Ｃ４のアルキレン基％　Ｒ９はフ
エニル基又はＣＩＯ〜Ｃ，。のアルキル基、ＹはＨ又は
Ｏ　　　　　　　　Ｒ．リ金属を表す。）一般式＜１）においてＸ−は無機又は有機の対イ（力）
　　−０−Ｒ＊　　．　　　　（ヨ）グリセリン残基，
又は（タ）糖誘導体残基（式中、Ｒ４は０１〜Ｃ８のアルキル基、Ｒｓ．Ｒｈは
Ｈ又はＣ１〜Ｃ２のアルキル基、Ｒ？はＣｌ〜Ｃよのア
ルキＲ，ｏ：炭素数１〜２０のアルキル基Ｒｌｌ＋　ＲＩＢ’炭素数１〜３のアルキル基又はヒド
ロキシアルキル基？　：　１〜２０Ｙ：Ｈ，ＣＯ■Ｃ）　．ｓｏｓＣ）　，ＣＯｔＭ又はＳ
Ｏ，Ｍ　（．目はＨ又はアルカリ金属）ｘ　：アニオン（但し、ＹがＣＯｚＯ，ＳＯｓＯの時は
Ｘはない．）Ｒ目Ｒｈｏ　　Ｎ　　ＧＨｚ　　ＣＮＸθ （ＩＩＩ）ＬｚＲｌｏ＋　ＲＩｌ＋　Ｒｌｔ＋　×’上記と同じＬｚＲｌＯ＋　ＲＩＩ＋　Ｒｌ！＋　ｘ’上記と同じＩ：　
１〜３ＲＩＩ＋　Ｒｌ！＋　ｘ二上記と同じＲ＋＋，　Ｒ＋ｚ　：炭素数１〜３のアルキル基又はヒ
ドロキシアルキル基ｎ　：１〜１６Ｘ．Ｙは上記と同じｅ１ポリアルキレンボリアミンの−Ｎ−ＣＨｔＣＮ誘導体本
発明における（ロ）成分は、これらの例に示されるよう
に過酸化水素と反応してカチオン基を有する有機過酸を
生成する構造を有していればよく、これらの化合物に限
定されるものではない．（ｂ）成分の漂白活性化剤は組
成物中に０．１〜３０重量％、好ましくは２〜１５重量
％配合される。Examples of the bleach activator used in the present invention that reacts with hydrogen peroxide (component (b)) to produce an organic peracid having a cationic group include the following compounds. R, (m is 1 to 12, preferably 1 to 5, and n is 1 to 10
, particularly preferably 1 to 5. ), *a+b is a-0,
b+O, or a-1, b-1*R. ，
R is an alkyl group or a hydroxyalkyl group having 1 to 3 carbon atoms. l is 1 to l2, and C is 0 or 1. L is a leaving group and is selected from the following (a) to (y). In formula (1), R represents C, ~l, especially a C1-14 straight chain or group, R. is a C, ~C4 alkylene group % R9 is a phenyl group or CIO~C, an alkyl group, Y is H or O R. Represents metal. ) In the general formula <1), X- is an inorganic or organic pair (force)
-0-R*. (Y) Glycerin residue,
or (ta) sugar derivative residue (in the formula, R4 is an alkyl group of 01 to C8, Rs.Rh is H or an alkyl group of C1 to C2, R? is an alkyl group of Cl to C, o: carbon number 1 ~20 alkyl group Rll+ RIB' Alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms?: 1 to 20 Y:H, CO■C). sosC) , COtM or S
O, M (.th is H or alkali metal) x: Anion (However, when Y is COzO, SOsO, there is no X.) Rth Rho N GHz CN Xθ (III) Lz Rlo+ RIl+ Rlt+ ×'Same as above Lz RlO+ RII+ Rl! + x' Same as above I:
1-3 RII+ Rl! +x2 Same as above R++, R+z: Alkyl group or hydroxyalkyl group having 1 to 3 carbon atoms n: 1 to 16 X. Y is the same as above e1 -N-CHtCN derivative of polyalkylene polyamine Component (b) in the present invention reacts with hydrogen peroxide to produce an organic peracid having a cationic group, as shown in these examples. The compound is not limited to these compounds as long as it has the following structure. Component (b), a bleach activator, is incorporated in the composition in an amount of 0.1 to 30% by weight, preferably 2 to 15% by weight.

本発明に用いられる（ｃ）成分のアルキルベンゼンスル
ホン酸塩としては、平均炭素数１０〜１６のアルキル基
を有する直鎖又は分岐鎖アルキルベンゼンスルホン酸塩
が挙げられ、（ｄ）成分のオレフィンスルホン酸塩とし
ては平均１０〜２０の炭素原子を１分子中に有するオレ
フィンスルホン酸塩が挙げられる．　（ｃ），　（ｄ）
成分の対イオンとしてはナトリウム、カリウム等のアル
カリ金属イオンが挙げられる．（ｅ）成分のボリオヰシ
エチレン（■）アルキルエーテルとしては平均炭素数１０〜２０のアル
キル基を有し、１〜３０モルのエチレンオキサイドを付
加したボリオキシエチレンアルキルエーテルが挙げられ
る。Examples of the alkylbenzene sulfonate as the component (c) used in the present invention include linear or branched alkylbenzene sulfonates having an alkyl group having an average carbon number of 10 to 16, and the olefin sulfonate as the component (d). Examples include olefin sulfonates having an average of 10 to 20 carbon atoms in one molecule. (c), (d)
Counter ions of the components include alkali metal ions such as sodium and potassium. Examples of the polyoxyethylene (■) alkyl ether of component (e) include polyoxyethylene alkyl ether having an alkyl group having an average carbon number of 10 to 20 and to which 1 to 30 moles of ethylene oxide are added.

本発明の組成物中の（ｃ），　（ｄ）．　（ｅ）成分は
前述し７た配合比範囲になければならない。この範囲外
ではカチオン性の有機過酸を生成する漂白活性化剤を使
用した場合再汚染防止効果が不十分である．　（ｃ）．
　（ｄ）．　（ｅ）成分の配合比の好ましい範囲は、Ｅ
（ｃ成分８４％、ｄ成分１３％、ｅ成分３％）、Ｆ（ｃ
成分５０％、ｄ成分４７％、ｅ成分３％）、Ｇ（ｃ成分
５０％、ｄ成分３０％、ｅ成分２０％）、Ｈ（ｃ成分６
７％、ｄ成分１３％、ｅ成分２０％）で囲まれた範囲で
ある。（ｃ），　（ａ）．　（ｅ）成分は本発明の組成
物中に総量で１０〜５０重量％、好ましくは１５〜４０
重量％配合される。(c), (d) in the composition of the invention. Component (e) must be in the mixing ratio range specified in 7 above. Outside this range, if a bleach activator that generates a cationic organic peracid is used, the recontamination prevention effect will be insufficient. (c).
(d). The preferred range of the blending ratio of component (e) is E
(c component 84%, d component 13%, e component 3%), F (c component
component 50%, d component 47%, e component 3%), G (c component 50%, d component 30%, e component 20%), H (c component 6
7%, d component 13%, e component 20%). (c), (a). Component (e) is present in the composition of the present invention in a total amount of 10 to 50% by weight, preferably 15 to 40% by weight.
% by weight is added.

本発明の組成物には次の様な漂白洗剤常用成分を必要に
応じて配合し得る。If necessary, the composition of the present invention may contain the following commonly used bleaching detergent ingredients.

即ち、ケイ酸塩、炭酸塩、セスキ炭酸塩−、硫酸塩、オ
ルトリン酸塩、ビロリン酸塩、トリボリリン酸塩、クエ
ン酸塩、イソクエン酸塩、エチレンジアミン四酢酸塩、
ニトリロトリ酢酸塩、ポリアセクールカルボン酸塩、ゼ
オライトなどのビルグー類が普通４０〜７５重量％配合
される。namely, silicates, carbonates, sesquicarbonates, sulfates, orthophosphates, birophosphates, tribolyphosphates, citrates, isocitrates, ethylenediaminetetraacetates,
Bilgu compounds such as nitrilotriacetate, polyacecool carboxylate, and zeolite are usually blended in an amount of 40 to 75% by weight.

又、他のアニオン界面活性剤、ノニオン界面活性剤、両
性界面活性剤なども適宜配合し得る。In addition, other anionic surfactants, nonionic surfactants, amphoteric surfactants, etc. may also be blended as appropriate.

その他ポリビニルアルコール、ポリビニルビロリドン、
カルボキシメチルセルロース、ポリエチレングリコール
、ポリアクリル酸塩などの再汚染防止剤、プロテアーゼ
、エスペラーゼ、リバーゼ、セルラーゼなどの酵素、そ
の他ケーキング防止剤、酸化防止剤、螢光染料、青味付
剤、光活性化漂白剤、香料なども配合される。Others polyvinyl alcohol, polyvinyl pyrrolidone,
Recontamination inhibitors such as carboxymethyl cellulose, polyethylene glycol, and polyacrylates, enzymes such as protease, esperase, revertase, and cellulase, other caking inhibitors, antioxidants, fluorescent dyes, blue tinting agents, and photoactivated bleaching. Agents and fragrances are also included.

〔Example〕

以下実施例に基づいて本発明を説明するが、本発明はこ
れら実施例に限定されるものではない。尚、実施例にお
いて、漂白率及び再汚染防止能の試験は以下に示す方法
によって行った。The present invention will be described below based on Examples, but the present invention is not limited to these Examples. In addition, in the Examples, the bleaching rate and the recontamination prevention ability were tested by the methods shown below.

く漂白率の試験法〉洗剤濃度０．０８３％の洗浄液に下記方法で訓製した紅
茶汚染布（８Ｘ８ｃｆｆｌ、５枚）を入れ夕・ーゴトメ
ーターで２０゜Ｃ、１０分洗浄した後、水洗い、乾燥後
、下記方法により漂白率を求めた．紅茶汚染布：日東紅茶（黄色パッケージ）８０ｇを３１のイオン交換
水にて約１５分間煮沸後、糊抜きしたサラシ木綿でこし
、この液に木綿金中＃　２００３布を浸し，、約１５分
間煮沸する，そのまま火よりおろし、２時間程度放置後
自然乾燥させ、洗液に色のつかなくなるまで水洗し、脱
水、プレス後、８Ｃ１１Ｘ８（？１１の試験片とし、実
験に供した。Test method for bleaching rate> Put black tea-stained cloths (8 x 8 cffl, 5 pieces) prepared in the following manner into a cleaning solution with a detergent concentration of 0.083%, wash with a Gotometer at 20°C for 10 minutes, then wash with water and dry. After that, the bleaching rate was determined using the method below. Tea-contaminated cloth: Boil 80g of Nitto black tea (yellow package) in 31 ion exchange water for about 15 minutes, strain it through a desiccated cotton cloth, soak a cotton gold cloth #2003 in this liquid, and boil it for about 15 minutes. Then, it was removed from the heat, left to stand for about 2 hours, then air-dried, washed with water until the washing liquid became colorless, dehydrated, pressed, and then used as a test piece of 8C11X8 (?11) for the experiment.

紅茶汚染布の漂白率：反射率は日、オ電色工業■製ＮＤＲ−ｉ０１ＤＰで４６
０ｎｍフィルターを使用して測定した。Bleaching rate of black tea contaminated fabric: Reflectance is 46 for NDR-i01DP manufactured by Ohdenshoku Kogyo ■
Measured using a 0 nm filter.

〈再汚染防止能の試験法〉（１）試験布木綿（２００３布）を１０Ｘ１０ｃｍに裁断し試験布出
する。<Test method for anti-recontamination ability> (1) Test cloth Cotton (2003 cloth) is cut into 10 x 10 cm pieces and a test cloth is prepared.

（２）汚れ疎水性固体汚れ二カーボンブラック，平均粒径０．１　
μ 親水性固体汚れ：鹿沼赤玉土，　２００メンシュのフル
イにかけた通過品（３）実験条件温度；２０゜Ｃ硬度：４”ＤＨ洗剤濃度？　０．０８３％７ηれ；カーボン　０．２５　ｇ　／　１泥　　　　　
２．５ｇ／Ｅターゴトメーター１０Ｏｒ．　ｐ．ｍで１０分汚染、流
水すすぎ（４）実験方法１！のビーカーに、カーボン及び泥を指定量、サンプリ
ングし、指定濃度に溶かした洗剤液を少しずつ入れ、ガ
ラス捧で分散させ、温度を調整し、ターゴトメータ・−
・の試料カップに入れ、試験布３枚を投入し、１００ｒ
．ｐ．ｍで１０分間汚染させ、流水ですすぎ、プレス乾
燥し、日本電色工業■製ＮＤＲ−１０１ＤＰにて再ｌη
染防止率を求めた。(2) Soil hydrophobic solid stain two carbon black, average particle size 0.1
μ Hydrophilic solid stain: Kanuma Akadama clay, passed through a 200-mensie sieve (3) Experimental conditions Temperature: 20°C Hardness: 4”DH Detergent concentration? 0.083% 7η R; Carbon 0.25 g/1 mud
2.5g/E Tergotometer 10Or. p. Contaminated with m for 10 minutes, rinsed with running water (4) Experiment method 1! Sample the specified amount of carbon and mud into a beaker, add detergent solution dissolved to the specified concentration little by little, disperse with a glass spoon, adjust the temperature, and place a sample with a tergotometer.
・Put 3 test cloths into the sample cup and heat for 100r.
．． p. contaminated for 10 minutes with water, rinsed with running water, press dried, and recontaminated with NDR-101DP manufactured by Nippon Denshoku Kogyo.
The stain prevention rate was determined.

Ｒ（０）・・・原布の反射率Ｒ　（Ｓ）・・・汚染後の反射率実施例１下記配合組成を有する漂白洗剤を製造し、漂白率及び再
汚染防止率を求めた。結果を表−１に示す。R(0)...Reflectance of original fabric R(S)...Reflectance after staining Example 1 A bleaching detergent having the following composition was produced, and the bleaching rate and re-staining prevention rate were determined. The results are shown in Table-1.

〈洗剤配合組成〉ポリエチレングリコール（ＭＷ１３０００）プロテアー
ゼ水２号珪酸ソーダ炭酸ソーダ４Ａ型ゼオライト硫酸ソーダ過炭酸ソーダ実施例２下記配合組成を有する漂白洗剤を製造し、漂白率及び再
汚染防止率を求めた。結果を表−２に示す。<Detergent formulation> Polyethylene glycol (MW 13000) Protease water No. 2 Sodium silicate Sodium carbonate Type 4A zeolite Sodium sulfate Sodium percarbonate Example 2 A bleaching detergent having the following formulation was manufactured, and the bleaching rate and recontamination prevention rate were determined. . The results are shown in Table-2.

〈洗剤配合組成〉直鎖ドデシルベンゼン　　　　　　　２２重量％スルホ
ン酸ソーダボリオキシエチレ２アルキルエーテル（ｃ＋ｚ−＋４ＥＯ＝　８　）牛脂脂肪酸ソー
ダ２号珪酸ソーダ炭酸ソーダ４Ａ型ゼオライト硫酸ソーダ過炭酸ソーダ漂白活性化剤（表−２）ポリエチレングリコール（ＭＷ６０００）プロテアーゼ水４．<Detergent composition> Linear dodecylbenzene 22% by weight Sodium sulfonate polyoxyethylene 2 alkyl ether (c+z-+4EO=8) Sodium tallow fatty acid No. 2 Sodium silicate Sodium carbonate 4A type zeolite Sodium sulfate Sodium percarbonate Bleach activator ( Table 2) Polyethylene glycol (MW6000) protease water 4.

[Brief explanation of the drawing]

第１図は本発明の（ｃ）、（ｄ）、（ｅ）３成分の配合比を示す三角図である． FIG. 1 shows (c) of the present invention. (d), (e) Mixing ratio of three components This is a triangular diagram showing .

Claims

[Claims] 1. (a) 3 to 30% by weight of peroxide that dissolves in water to produce hydrogen peroxide (b) Reacts with hydrogen peroxide to produce an organic peracid having a cationic group. Bleach activator 0.1-30% by weight (c) Alkylbenzene sulfonate (d) Olefin sulfonate (e) Polyoxyethylene alkyl ether (c) + (
d) + (e) = 10-50% by weight (c), (d), (e
) The blending ratio of the three components is determined by point A (c) on the triangular diagram shown in the attached drawing.
component 88%, d component 10%, e component 2%), B (c component 45%, d component 53%, e component 2%), C (c component 45%).
%, d component 30%, e component 25%), D (c component 65%
, 10% of component d, and 25% of component e).