JPH0267196A - Thermal transfer material - Google Patents
Thermal transfer materialInfo
- Publication number
- JPH0267196A JPH0267196A JP63219566A JP21956688A JPH0267196A JP H0267196 A JPH0267196 A JP H0267196A JP 63219566 A JP63219566 A JP 63219566A JP 21956688 A JP21956688 A JP 21956688A JP H0267196 A JPH0267196 A JP H0267196A
- Authority
- JP
- Japan
- Prior art keywords
- thermal transfer
- protective layer
- layer
- ink layer
- colorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 18
- 239000010410 layer Substances 0.000 claims abstract description 23
- 239000011241 protective layer Substances 0.000 claims abstract description 21
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 12
- 239000000194 fatty acid Substances 0.000 claims abstract description 12
- 229930195729 fatty acid Natural products 0.000 claims abstract description 12
- 239000003086 colorant Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 239000002985 plastic film Substances 0.000 claims abstract description 8
- 229920006255 plastic film Polymers 0.000 claims abstract description 8
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 5
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 5
- -1 fatty acid imide Chemical class 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 229920006122 polyamide resin Polymers 0.000 claims description 5
- 239000000203 mixture Substances 0.000 abstract description 8
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 abstract description 4
- 239000006229 carbon black Substances 0.000 abstract description 3
- 150000003949 imides Chemical class 0.000 abstract description 3
- 239000004952 Polyamide Substances 0.000 abstract description 2
- 229920002647 polyamide Polymers 0.000 abstract description 2
- 238000010186 staining Methods 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 26
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000010408 film Substances 0.000 description 11
- 239000011247 coating layer Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000000020 Nitrocellulose Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 101000697856 Rattus norvegicus Bile acid-CoA:amino acid N-acyltransferase Proteins 0.000 description 1
- 241001440356 Renodes Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- FTQWRYSLUYAIRQ-UHFFFAOYSA-N n-[(octadecanoylamino)methyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCNC(=O)CCCCCCCCCCCCCCCCC FTQWRYSLUYAIRQ-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000013518 transcription Methods 0.000 description 1
- 230000035897 transcription Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】 （産業上の利用分野） 本発明は感熱転写材料に関する。[Detailed description of the invention] (Industrial application field) The present invention relates to thermal transfer materials.
（従来の技術およびその課題）
近年、ファクシミリ、ワードプロセッサー、コンピュー
タ端末プリンター等に感熱転写材料か非常に多（用いら
れている。一般的な感熱転写材料は薄いプラスチックフ
ィルムの上に熱転写インキ層を１役けたものであり、サ
ーマルプリンターにかけろと感熱転写インキか受像紙」
二に転写され鮮明な転与像をつくり出ケ事ができろ。一
般事務用としては現在流通している熱転写材料で充分そ
の［−１的を達していると考えられる。(Prior art and its problems) In recent years, thermal transfer materials have been widely used in facsimile machines, word processors, computer terminal printers, etc. Typical thermal transfer materials are made by forming one layer of thermal transfer ink on a thin plastic film. It's a useful item, so I recommend using thermal transfer ink or receiver paper for a thermal printer.''
It will be transferred to the second image to create a clear transferred image and be able to appear. For general office use, the thermal transfer materials currently in circulation are considered to be sufficient to reach the -1 target.
しかし物流関係および製造工場関係におけるラベル・プ
リンターにおいても感熱転写材料か非常に多く使用され
だしてきた。特に製造工場においてはその環境及び充填
物の種類、後加工の問題等により転写画像に１００〜１
２０℃以上の耐熱性をその特性として求める°■が多く
なってきた。However, thermal transfer materials have also come into widespread use in label printers used in logistics and manufacturing plants. Particularly in manufacturing plants, the transferred image may have a 100 to 1
More and more products require heat resistance of 20°C or higher as a characteristic.
しかし、１００〜１２０℃以上の耐熱特性を満足する転
写画像を構成できる熱転写（オ和は現在のところけに出
ていないのか実情である。However, the reality is that thermal transfer (Owa), which can form transferred images that satisfy heat resistance characteristics of 100 to 120° C. or higher, is not currently available.
本発明者等は先に熱転写インキを融点１２０℃以上を有
する特定の物質を用いて形成−・）−ると、高い耐熱性
、例えば１００〜１２０℃以」二の温度に耐える感熱転
写材料が得られることを見出し、特許出願しｌ二（持に
１１１昭Ｇ ２ １２７８０号）。この転写１科は侵・
１ｆ−特性をら−、ているか、転写ｎノ、の表面Ｃ・汚
イ：やノコリンク包４，５時の両像のく１１等かン１＋
み１゛）イ会た。The present inventors have previously discovered that by forming a thermal transfer ink using a specific substance with a melting point of 120°C or higher, a thermal transfer material with high heat resistance, for example, resistant to temperatures of 100 to 120°C or higher, can be obtained. He discovered that it could be obtained and filed a patent application (No. 111, Showa G2, No. 12780). This transcription family is invasive.
1f-Characteristics, transfer n-, surface C/dirty: and Noco link envelopes 4 and 5 o'clock both images 11 etc. Kan 1+
1゛) I met.
（課題を解決Ａ゛るためのＬ段）
本イこ明は前記特許出願の感熱転写トづ料を史に改良し
一２′熱転Ｊ）インキ層−１，に央に特定組成の表面保
護層を設ｊ）７、ことによ：１．１ｌｉｃた特性の熱転
写材木［をｉ’＞７−１
即’５．忙イ己明はｌｑさ２〜１５μのプラスチックフ
ィルム（３）の表面に熱転！メインキ層（１）とその１
−のノ乏面保護層（２）とをイｊ°シ、裏面に耐熱保護
層（・１）を何する感熱転パ了相科におい一ζ、該熱転
写インキ層（１）か（ａ）ｉａ点＋２０°Ｃ以上の脂肪
酸アミドよたは脂肪酸イミド、 （［））融祖１００℃
以」二う）ポリアミド樹脂よたはヒニ゛し樹脂１ｊよび
（ｃ ）イ゛１色剤を含ｒ丁しか一ノ該々面保護層（２
）か土、記熱転写インキ層の用いノー成分（ａ）ｊ；よ
び（ｂ）を含ａオるか成分（ｃ ）を含まないことを特
徴とする感熱転写（材料を提供する。(Step L to solve the problem A) The present invention is based on the improvement of the thermal transfer toner of the above-mentioned patent application. A protective layer may be applied to a thermal transfer material with a property of 1.1lic. The heat is transferred to the surface of the plastic film (3) with a thickness of 2 to 15μ! Main layer (1) and part 1
- What type of heat-resistant protective layer (1) is placed on the back side of the protective layer (2), and what type of heat-sensitive transfer layer (1) is placed on the back side, the thermal transfer ink layer (1) (a) Fatty acid amide or fatty acid imide with an ia point of +20°C or higher, ([)) fused to 100°C
2) Polyamide resin or vinyl resin 1j and (c) 1 colorant containing only one surface protective layer (2).
) The thermal transfer ink layer is characterized in that it contains no components (a) and (b) or does not contain component (c).
本発明Ｑ）熱転写インキに配合し得る脂肪酸アミドは融
点＋２０’Ｃ以上、・・）らので、５メチレンヒスステ
アロアミドまノニ（よニーｒ−レノヒスステアロアミド
等が挙げ−）れる。より１１体的には−Ｉ′−マートＬ
から市販υ）アーモワノ′！スＥＩ３Ｓか挙げられる９
、脂肪酸イミドし同様融点１２０°Ｃ以上が必要で、例
えば脂肪酸イミドはグリコ・ケミカル社から市販のアク
ラワックスーＣか好適で、・うる。脂肪酸アミドおよび
イミドはｊ１１独てら、両層を混合して用いて乙よい。The fatty acid amide that can be blended into the heat transfer ink of the present invention (Q) has a melting point of +20'C or more, and examples thereof include 5-methylene hisstearamide. More specifically, -I'-mart L
Commercially available from υ) Armowano′! 9 that can be mentioned as EI3S
Similarly to fatty acid imides, a melting point of 120° C. or higher is required. For example, the fatty acid imide is preferably Acrawax-C commercially available from Glyco Chemical Company. Fatty acid amide and imide may be used alone or in a mixture of both layers.
ポリアミド樹脂およびヒニル樹脂ら融点１００℃以上を
必要と一４′る。ポリアミド樹脂の例としてよ重合脂肪
酸ポリアミド荀を指が挙げられ１、ｊ−り好適なもυ）
としては富士化成工業（朱式会社う１１゛、市販の１・
−マイ）”＃＋３１０が挙げられろ。ヒール樹脂の例と
しては塩化ヒニル樹脂、酢酸ヒニル樹脂、エチレン酢酸
ビニル用型、）体が挙げられる２、特に三片ポリケミカ
ル社から市販のＥＶ、Ａ、−１５０か好適である。Polyamide resins and vinyl resins require a melting point of 100°C or higher. Examples of polyamide resins include polymerized fatty acid polyamides.
As for Fuji Kasei Kogyo (Shushiki Kaisha U11゛, commercially available 1.
Examples of heel resins include hinyl chloride resin, hinyl acetate resin, ethylene vinyl acetate type, )2, especially EV, A commercially available from Mikata Polychemical Co., Ltd. , -150 is preferable.
熱転写インキの組成にしいて融点１４０℃の（ａ）脂肪
酸アミドまたは指’Ｉ／；酸イミドと（ｂ）ポリアミド
樹脂またはヒニル樹１１ｈの比率かＩ・１〜５１の範囲
に才、いて最ら適正であるのは樹脂比率か１より多く舊
れば熱転写性が極端に悪くなる。脂ＩＩ／ｊ酸アミドと
脂肪酸イミドのワンクス比率か５１より多くなわば、塗
工さメまた熱転写インキがフィルムよＧ）剥落しゃ、）
−＜なり、特に冬の低１ＭＬ時（１００Ｃ以下）におい
てはプリンター走行時にフィル！、 ｊ二り剥落しノニ
インギがプリンター走行時又は受１象＜４（に付着しＦ
ｌｕ々のｌ・ラブルの原因となる。It is most appropriate that the composition of the thermal transfer ink has a melting point of 140°C and a ratio of (a) fatty acid amide or acid imide to (b) polyamide resin or vinyl resin 11h in the range of 1 to 51. The reason for this is that if the resin ratio is greater than 1, the thermal transferability will be extremely poor. If the ratio of fat II/J acid amide to fatty acid imide is greater than 51, the coating or thermal transfer ink may peel off.)
- Fill when the printer is running, especially at low 1ML in winter (below 100C)! When the printer is running or when the noni-ingi peels off, it adheres to the
It causes l/ruble in lu.
熱転写インキは上記成分の他に着色剤を配合ける。着色
剤は通常カーボンブラックであるか、必要に応じ他の４
色剤、例えばシアニンブルー、レーキレソ１゛、カーミ
ンレノド、シアニングリー／、ハノザーイエロー、パー
マネントイエローラ用いてらよい。着色剤のインキ中の
配合量は通常３〜３０重屯％、好ましくは５〜２ＣＪ！
Ｉｆｍ％である。The thermal transfer ink may contain a coloring agent in addition to the above components. The colorant is usually carbon black or other four as required.
Colorants such as cyanine blue, Lakereso 1, carmine renode, cyanine green/, Hanother yellow, and permanent yellow may be used. The amount of colorant added in the ink is usually 3 to 30% by weight, preferably 5 to 2 CJ!
Ifm%.
熱転写インキは溶剤に溶解してプラスチ・ｌクフィルム
（２）し）上に塗工”）゛る。使用し得る溶剤の例とし
てはトルエニ／、エン、ノール、イソプロピルアルコ−
ル
熱転写インキの塗上層：よ乾燥固形分層として１５μ〜
５ ０μが適正であり、最Ｊａ塗工層は各プリンター及
び受＠！祇の種類により決定される（例えば神崎サーマ
ル・プリンターに−８１０８にては熱転写インキ塗り層
３．７１１〜１ ０μか最適である）。Thermal transfer inks are dissolved in a solvent and applied onto the plastic film (2). Examples of solvents that can be used are toluene, ene, alcohol, and isopropyl alcohol.
Coating layer of thermal transfer ink: 15 μm as a dry solid layer
50μ is appropriate, and the maximum Ja coating layer can be applied to each printer and receiver@! It is determined by the type of paper (for example, for Kanzaki thermal printer -8108, a thermal transfer ink coating layer of 3.711 to 10μ is optimal).
表面保護層（２）は着色剤は使用しない他は転写インキ
と同一組成物である３。The surface protective layer (2) has the same composition as the transfer ink except that no colorant is used.
表面保護層の作用により，熱転写時において熱転写材料
と受像紙の汚れを防市すると共に表面保護層がバインダ
ー層となり非后に鮮明な転写画像か得られろ。１００〜
１２０℃以上の耐熱特性を満足する転写画像の構成には
上記表面保護１１′４を設けろことが最良であると，）
結壜により本発明を完成させた。The action of the surface protective layer prevents stains on the thermal transfer material and image receiving paper during thermal transfer, and the surface protective layer also acts as a binder layer, allowing a clear transferred image to be obtained afterward. 100～
It is best to provide the above-mentioned surface protection 11'4 for the configuration of a transferred image that satisfies heat resistance characteristics of 120°C or higher.)
The present invention was completed by making a bottle.
表面保１尊層（２）は熱；云石インキ層と同様に塗工さ
れる。、表面保護層（２）の１′スさは特に限定されな
いか、（１ 、 、１〜１．・１μｍ′：ある。０．４
μより薄いと転写時の表面汚わ防１に効１■か充分てな
く、・１μ上り１°Ｊいと熱伝導性か悪くなるため転写
不良５・）欠へを仔計る。The surface protection layer (2) is applied in the same manner as the heat-treated ink layer. , the 1' thickness of the surface protective layer (2) is not particularly limited or (1, , 1 to 1..1 μm': 0.4
If it is thinner than μ, it will not be effective enough to prevent surface stains during transfer (1), and if it is 1 μ and 1°J, the thermal conductivity will be poor, so plan for poor transfer (5).
本発明に月ｊいろフラスチソクフィル１、に３）と射精
保護ＪＮ’ｉ （＝１ ）とは、従４６感熱転写材料に
一般に使用されてい・しらのを用いればよい。In the present invention, the color filters 1 and 3) and the ejaculation protection JN'i (=1) may be those commonly used in J-46 heat-sensitive transfer materials.
フ゛う只チックフィルム（３）はηさ２〜１５μを１丁
するポリ」−ヂレンテレフタレート、ポリエステルフィ
ルム、ポリカーボネートフィルム、ｌ−リアセ千ルセノ
１ハＪ−スー′イルム等が例示されるが、特に好ましく
よ面１熱性がよく、かつ極めて薄いフィルｌ、を得るこ
とのてきるポリエチレンテレフタレートで、うる
耐熱保護’？Ｂ （１）はプラスチツタフィルムかサー
マルへｌト（こ融着現象（スティッキング）をおこし、
プリンターの走行に支障をおこすのを防く目的にて構成
され、好適には本発明者等による特開昭６０−１９０３
ＬＪ ０号公報に記載のニトロセルロースと酢酸セル
１１−スを組、）せたらのが挙げられる。Examples of the film (3) include polyethylene terephthalate, polyester film, polycarbonate film, and l-liacetic film (3) having a diameter of 2 to 15 μm. Particularly preferred is polyethylene terephthalate, which has good heat resistance and can provide an extremely thin film for heat-resistant protection. B (1) causes plastic ivy film or thermal sticking.
It is configured for the purpose of preventing interference with the running of the printer, and is preferably disclosed in Japanese Patent Application Laid-Open No. 60-1903 by the present inventors.
An example is a combination of nitrocellulose and acetic acid cellulose described in LJ No. 0 (LJ 0).
二ｌ・ロセルロースとへ′Ｉ酸セルロースの混合比重役
び塗工１Δ（乾燥固型分として）はプリンターの機種に
より決定されろ。The mixing specific gravity and coating ratio (as a dry solid content) of dicellulose and cellulose hemolyte (as dry solid content) are determined by the printer model.
（実施例） 以下実施例をあげて本発明を説明する。(Example) The present invention will be explained below with reference to Examples.
垢極例−１
［Δ］本発明の熱転写インキを以下の方法により調製し
た。Example 1 [Δ] Thermal transfer ink of the present invention was prepared by the following method.
成 分 重量部
アーモワックスＣＢＳ ２０．０トーマイト＃
ｌ３１０ １０．０カーホンブラツク
８．０エタノール ２００
トルエン ４２０
１００．０
上記処方の各原料４ボールミル、サンドミル、アトライ
ター等を使用して練肉することによりへ転写インキが得
られ、メイヤーバ一方式のフィルムコーターを使用して
乾燥固型分として１．５〜５．０μの塗工層にプラスチ
ツタフィルムに塗りすることにより熱転写材料（熱転写
インキ層のみ）を得た。Ingredients Part by weight Armowax CBS 20.0 Tomite #
l310 10.0 car phone black
8.0 ethanol 200
Toluene 420 100.0 A transfer ink is obtained by kneading each of the raw materials in the above formulation using a ball mill, sand mill, attritor, etc., and a dry solid content of 1 is obtained using a Meyer bar type film coater. A thermal transfer material (thermal transfer ink layer only) was obtained by coating a plastic ivy film with a coating layer of .5 to 5.0 μm.
Ｂ 本ｆ明のに面保護層は」二足［Ａ］の処方よＩ）着
色剤カーボッブラックを取り除いｆコ下記処方υ−）各
ｊ＋ｌ料をｒ、Ａ と同一の製造方法、塗工方法にて
塗にするごとにより熱転写ＩＡ料（熱転写インキ層、友
面保護層塗］−フｒルム）を得た。B. The surface protective layer is the same as [A]. I) Remove the coloring agent Carbo Black and apply the following formula. A thermal transfer IA material (thermal transfer ink layer, friendly surface protective layer coating)-r film was obtained by applying each coat according to the method.
）（分 坪数
アーモワｌクスト：ＢＳ ２０．０トーマイド
１１３＋０ １０．０ユ、タノール
２００トル」、ン ４
２０害籠桝１
［Ａ］ 本発明の熱転写インキを以下の通り凋製しノこ
。) (minutes tsubo armoikust: BS 20.0 Tomide 113+0 10.0 Yu, Tanor
200 torr”, n 4
20 Harm basket 1 [A] The thermal transfer ink of the present invention was made as follows.
盛−ラン
アクラワックス−（：
ＥＶＡ−１５０
カーボンブラック
トルエン
重量部
上記処方の各１＋Ｉ Ｉ）を実施例１と同様に製造、塗
工、１′ろことによ０熱転写（オ料（熱転写インキ層の
み）を得ｊ−０
［８３下記処方の各原料を実施例１と同様に製造、塗１
・３−ることにより熱転写（オ料（熱転写インキ層、表
面保護層塗工フィルム）を得た。Mori-Ran Acra Wax (EVA-150 Carbon Black Toluene Weight Parts Each of the above formulations + II) was manufactured and coated in the same manner as in Example 1. ) was obtained.
・3- A thermal transfer material (thermal transfer ink layer, surface protective layer coated film) was obtained.
慮−分 重量部
アクラワノクス−０２０，０
ＦＶＡ−１５０５，０
トルエン ７０．０比較例１および
２
［−記実施例１および２の表面保護層を塗工していない
乙のを得、それぞれ比較例１および２とした。Consideration: Parts by weight Akrawanox-020.0 FVA-1505.0 Toluene 70.0 Comparative Examples 1 and 2 [- Obtained from Examples 1 and 2 without coating the surface protective layer, respectively, Comparative Examples 1 and 2.
比較例３ 従来処方の熱転写インキを以下のように調製しノー。Comparative example 3 A conventionally formulated thermal transfer ink was prepared as follows.
成 分 重ｔｎ部
カルナウバワックス ４０．０エステルガ１３
５０
パラフィンワックス ３Ｄ、０カーボンブラン
ク ２０．０１００．０
１−記処方の各ｊ４：ｊ Ｌｌを９０〜１００℃にて溶
融分散後３本ロール、サンドミル、アトライター等によ
り紗肉することによζ）熱転写インキか得られ、９０〜
１１０℃にてフレキ、ノ方式のフィルムコーターを使用
して１．５ＩＺ〜５．０μの塗工層にプラスチック１イ
ルノ・に塗上］４−ることにより熱転写フ、ｆルム（熱
転写ｒンキ層のみ）を得た。Ingredients Heavy tn carnauba wax 40.0 Esterga 13
50 Paraffin wax 3D, 0 carbon blank 20.0100.0 1- Melt and disperse each j4:j Ll of the prescribed recipe at 90 to 100°C and then gauze it with a three-roll, sand mill, attritor, etc. ) Thermal transfer ink is obtained, 90 ~
Coat a coating layer of 1.5IZ to 5.0μ on a plastic layer using a flexible film coater at 110°C] only).
駁Ｖ週
以北の熱転写材料（熱転写ｒンキ層のみ）に次の組成の
耐熱保護（ンキを０．２ｕ〜１５μの塗工層にメイヤー
バ一方式フィルムコーターにて塗工層ることにより熱転
写フィルムを得た。A thermal transfer film is created by applying heat-resistant protection (ink) of the following composition to a coating layer of 0.2u to 15μ using a Meyer bar one-type film coater on a heat transfer material (thermal transfer layer only) made north of Pierre V week. I got it.
耐熱保護インキ
ニトロセルロースＳＳＩ、’４ １２．０重を部酢酸セ
ル〔Ｊ−スＬ−２０３，０
エタノール ２５０酢酸エチル
１０．０酢酸ブチル
ｌ（１，０ニドｒｊプロパン ４０．０＋
００．０
以りのごとくして得られた熱転写フィルムを神崎サーマ
ル・プリンターｌぐ−８１０８に装？７ Ｌ、ブリット
・アウトした画像について耐熱性をみ〕二ところ表−川
のごとくとなり本発明の（Ｔｌ）性か証明された。Heat-resistant protective ink Nitrocellulose SSI, '4 12.0 parts by weight Acetate cell [J-S L-203,0 Ethanol 250 Ethyl acetate
10.0 Butyl acetate
l(1,0nido rj propane 40.0+
00.0 The thermal transfer film obtained as described above was loaded into Kanzaki thermal printer lg-8108. 7L, the heat resistance of the blit-out image was examined and the results were as good as the table below, proving the (Tl) property of the present invention.
第１図；す、本発明感熱転写材料の断面図である。
図中、■はカーホンインキ層、２は表面保護層、３はプ
ラスチックフィルム、４：よ耐熱保護腎を示す。
特許出願人 内外カーボッインキ株式会社代 理 人
弁理士 青 山 葆 ほか２名ρ
４！
・さFIG. 1 is a sectional view of the heat-sensitive transfer material of the present invention. In the figure, ■ indicates a carphone ink layer, 2 indicates a surface protective layer, 3 indicates a plastic film, and 4 indicates a heat-resistant protective layer. Patent applicant Naigai Carbo Ink Co., Ltd. Agent
Patent attorney Aoyama Ao and 2 others ρ 4! ·difference
Claims (1)
面に熱転写インキ層（１）とその上の表面保護層（２）
とを有し、裏面に耐熱保護層（４）を有する感熱転写材
料において、該熱転写インキ層（１）が（ａ）融点１２
０℃以上の脂肪酸アミドまたは脂肪酸イミド、（ｂ）融
点１００℃以上のポリアミド樹脂またはビニル樹脂およ
び（ｃ）着色剤を含有し、かつ該表面保護層（２）が上
記熱転写インキ層の用いた成分（ａ）および（ｂ）を含
有するが成分（ｃ）を含まないことを特徴とする感熱転
写材料。1. A thermal transfer ink layer (1) on the surface of a plastic film (3) with a thickness of 2 to 15μ and a surface protective layer (2) on top of it.
and a heat-resistant protective layer (4) on the back surface, wherein the thermal transfer ink layer (1) has (a) a melting point of 12
The surface protective layer (2) contains a fatty acid amide or fatty acid imide having a temperature of 0° C. or higher, (b) a polyamide resin or vinyl resin having a melting point of 100° C. or higher, and (c) a colorant, and the surface protective layer (2) is a component used in the thermal transfer ink layer. A thermal transfer material characterized in that it contains (a) and (b) but does not contain component (c).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63219566A JPH0267196A (en) | 1988-09-01 | 1988-09-01 | Thermal transfer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63219566A JPH0267196A (en) | 1988-09-01 | 1988-09-01 | Thermal transfer material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0267196A true JPH0267196A (en) | 1990-03-07 |
| JPH059278B2 JPH059278B2 (en) | 1993-02-04 |
Family
ID=16737519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63219566A Granted JPH0267196A (en) | 1988-09-01 | 1988-09-01 | Thermal transfer material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0267196A (en) |
-
1988
- 1988-09-01 JP JP63219566A patent/JPH0267196A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH059278B2 (en) | 1993-02-04 |
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