JPH0293676A - elastic fixing roller - Google Patents
elastic fixing rollerInfo
- Publication number
- JPH0293676A JPH0293676A JP24824888A JP24824888A JPH0293676A JP H0293676 A JPH0293676 A JP H0293676A JP 24824888 A JP24824888 A JP 24824888A JP 24824888 A JP24824888 A JP 24824888A JP H0293676 A JPH0293676 A JP H0293676A
- Authority
- JP
- Japan
- Prior art keywords
- roller
- tetrafluoroethylene
- fixing roller
- porous
- pfa
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000010410 layer Substances 0.000 claims abstract description 18
- 229920001971 elastomer Polymers 0.000 claims abstract description 16
- 239000000463 material Substances 0.000 claims abstract description 12
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 12
- 239000004945 silicone rubber Substances 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229920001577 copolymer Polymers 0.000 claims abstract description 9
- 239000011247 coating layer Substances 0.000 claims abstract description 8
- 229920001973 fluoroelastomer Polymers 0.000 claims abstract 2
- 239000000843 powder Substances 0.000 claims description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 6
- 229910052731 fluorine Inorganic materials 0.000 claims description 6
- 239000011737 fluorine Substances 0.000 claims description 6
- 238000010304 firing Methods 0.000 claims description 5
- 238000010030 laminating Methods 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract description 9
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract description 9
- 239000011148 porous material Substances 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 239000000203 mixture Substances 0.000 abstract description 3
- -1 polytetrafluoroethylene Polymers 0.000 abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 210000000078 claw Anatomy 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000003475 lamination Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Fixing For Electrophotography (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は、例えば複写機、ラインプリンターファクシミ
リ等の定着部等に用いるローラ即ち弾性定着ローラに関
するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a roller, ie, an elastic fixing roller, used in a fixing section of a copying machine, a line printer facsimile, etc., for example.
(従来の技術)
複写機等の定着部は通常第3図のような構成になってお
り、加熱定着ローラ(10)と加圧定着ローラ(11)
の間を、トナー(12)の転写されたコピー紙(13)
を通すことによって熱(通常は170℃〜200℃)と
圧力によってコピー紙に画像を定着するという方式が、
安全性、経済性々どの点から一般に採用されている。(Prior Art) The fixing unit of a copying machine or the like usually has a configuration as shown in Fig. 3, which includes a heating fixing roller (10) and a pressure fixing roller (11).
Copy paper (13) with toner (12) transferred between
This method uses heat (usually 170°C to 200°C) and pressure to fix the image on the copy paper by passing it through.
It is generally adopted due to its safety and economic efficiency.
この場合、加熱定着ローラ(10)としては、アルミニ
クム等の金属やセラミック、耐熱性のプラスチックから
成るローラ基材即ちローラ芯(14)の表面に、トナー
の離型性をあげるために弗素樹脂を数十μmコーティン
グしたもの、あるいは18以下の厚みのシリコーンゴム
や弗素ゴムを被覆したもの(これらコーティングあるい
は被覆を(15)で示す)が、また加圧定着ローラ(1
1)としては、アルミニクム等から成るローラ基材(1
6)に硬度が数十度の耐熱ゴム(一般にはシリコーンゴ
ムカ用イられる)を数域の厚みに被覆したもの(この被
覆を(17)で示す)が用いられる。In this case, the heating fixing roller (10) is made of metal such as aluminum, ceramic, or heat-resistant plastic, and the surface of the roller core (14) is coated with fluororesin to improve the release properties of the toner. A pressure fixing roller (15) coated with several tens of micrometers, or coated with silicone rubber or fluorine rubber with a thickness of 18 or less (these coatings or coatings are indicated by (15)) is also used as a pressure fixing roller (15).
1) is a roller base material (1) made of aluminum or the like.
For 6), a heat-resistant rubber (generally silicone rubber is used) having a hardness of several tens of degrees is coated with a thickness of several ranges (this coating is shown as (17)).
尚、分離爪(18)はコピー紙の巻き付きを防止するた
めのもので、幅敗笥のものが4〜5箇所に取り付けられ
ており、通常は加熱定着ローラ側のみであるが、高速機
や両面コピーの場合には第6図のように加圧定着ローラ
側にも分離爪(19)が収り付けられる。なお・第3図
中(20)は定着画像、(23)はヒータである。The separation claws (18) are used to prevent the copy paper from getting wrapped around the copy paper, and are installed in 4 to 5 locations. In the case of double-sided copying, a separation claw (19) is also installed on the pressure fixing roller side as shown in FIG. Note that (20) in FIG. 3 is a fixed image, and (23) is a heater.
上記のこのようなゴムローラは、コピー紙が巻き付いた
りした時に、この分離爪によってえぐり取られて破損し
使えなくなる事がある。この為本出願人が先に開発し特
許出願したような、特開昭60−179770号に記載
の、ローラ基材の外層に4弗化エチレン樹脂の多孔質体
を被せ、その多孔部に液状シリコーンゴムを含浸させて
硬化させたローラがあり、このローラは、分離爪により
破損しにくく、寿命的にも数倍のびることは記載の内容
の通りである。When the above-mentioned rubber roller is wrapped around the copy paper, it may be gouged out by the separating claw and become damaged, rendering it unusable. For this purpose, the outer layer of the roller base material is covered with a porous body of tetrafluoroethylene resin, as described in JP-A-60-179770, which the present applicant previously developed and applied for a patent. There is a roller impregnated with silicone rubber and cured, and as described, this roller is less likely to be damaged by separation claws and has a lifespan several times longer.
(発明が解決しようとする課題)
この先に開発した(特開昭60−179770号)、四
弗化エチレン樹脂の多孔質体に耐熱性のゴムを含浸、硬
化させたもののうち、四弗化エチレン樹脂の多孔質体層
を多孔質体を積層、焼成して形成したものについては、
層間の接着力が不充分で、使用中に剥離の問題があり、
これが耐久性という点で不安定な要因の1つであった。(Problems to be Solved by the Invention) Of the previously developed (Japanese Unexamined Patent Publication No. 60-179770), which is a porous body of tetrafluoroethylene resin impregnated with heat-resistant rubber and cured, tetrafluoroethylene For those formed by laminating and firing porous resin layers,
The adhesion between the layers is insufficient, causing peeling problems during use.
This was one of the causes of instability in terms of durability.
なお弗素樹脂をコーティングしたローラは弾性かないた
めコピーの画質が悪い、定着が劣る、紙しわが生じやす
い等の欠点がある。Note that rollers coated with fluororesin are not elastic, so they have drawbacks such as poor copy image quality, poor fixing, and paper wrinkles.
上記に鑑み、本発明はこのような問題点を解消するため
開発されたものである。In view of the above, the present invention has been developed to solve these problems.
(問題点を解決するための手段)
即ち本発明の第1の弾性定着ローラは、コピー紙上に形
成されたトナー像を2個のローラ間に通して定着する装
置に使用される定着ローラに於いて、ローラ基材の外側
に、四弗化エチレン樹脂(ポリテトラフルオロエチレン
)(PTFE)とテトラフルオロエチレン−パーフルオ
ロアルキルビニルエーテル共重合体(PFA)又はテト
ラフルオロエチレン−へキサフルオロプロピレン共重合
体(FEP )との混合物の多孔質体を2層以上積層、
焼成したものの多孔部に例えばシリコーンゴム、弗素ゴ
ム等の耐熱性のゴムを含浸、硬化して構成した被覆層を
有することを特徴とするものである。(Means for Solving the Problems) That is, the first elastic fixing roller of the present invention is a fixing roller used in a device that fixes a toner image formed on copy paper by passing it between two rollers. Then, on the outside of the roller base material, tetrafluoroethylene resin (polytetrafluoroethylene) (PTFE) and tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA) or tetrafluoroethylene-hexafluoropropylene copolymer Laminating two or more layers of porous material of a mixture with (FEP),
It is characterized by having a coating layer formed by impregnating and curing a heat-resistant rubber such as silicone rubber or fluorine rubber in the porous portion of the fired product.
又本発明の第2の弾性定着ローラは、コピー紙上に形成
されたトナー像を2個のローラ間に通して定着する装置
に使用される定着ローラに於いて、ローラ基材の外側に
、四弗化エチレン(ポリテトラフルオロエチレン)樹脂
(PTFE)の多孔質体の層間にテトラフルオロエチレ
ン−パーフルオロアルキルビニルエーテル共電a体(P
F A )又はテトラフルオロエチレン−ヘキサフル
オロプロピレン共重合体(FEP)の、粉末を散在させ
或いは網状体を介在させ2層以上積層、焼成したものの
多孔部に例えばシリコーンゴム、弗素ゴム等の耐熱性の
ゴムを含浸、硬化して構成した被覆層を有することを特
徴とするものである。The second elastic fixing roller of the present invention is a fixing roller used in a device that fixes a toner image formed on copy paper by passing it between two rollers. Tetrafluoroethylene-perfluoroalkyl vinyl ether coelectric a material (P
Two or more layers of F A ) or tetrafluoroethylene-hexafluoropropylene copolymer (FEP) are laminated with powder interspersed or with a network interposed, and then fired, and heat-resistant materials such as silicone rubber or fluorine rubber are added to the porous parts of the product. It is characterized by having a coating layer formed by impregnating and curing rubber.
なお上記第1、第2の弾性定着ローラに於いて、積層の
仕方は、シート状体の連続的巻回、非連続的巻回或いは
チューブ状体の積層等何れでもよく特に限定されるもの
ではない。In the first and second elastic fixing rollers, the method of lamination may be continuous winding of sheet-like bodies, non-continuous winding, or lamination of tube-like bodies, and is not particularly limited. do not have.
(作用)
上記第1、第2の発明に於いて、PFA又はFEPは多
孔質体積層、焼成時に積層間の融着の働きをなす。これ
は溶融粘度(poise)がPTFEの101′〜10
”(340〜380℃)に対し、PFAの104〜10
5(380℃)、FEPの4X (10〜10 )(3
80℃)と低いため溶融したときに四弗化エチレン樹脂
多孔部にくい込むことに因る。(Function) In the first and second aspects of the invention, PFA or FEP functions to fuse the laminated layers during porous lamination and firing. This has a melt viscosity (poise) of PTFE of 101' to 10
”(340-380℃), PFA's 104-10
5 (380℃), 4X (10~10) of FEP (3
This is because the temperature is low (80°C), so when it melts, it sinks into the pores of the tetrafluoroethylene resin.
なお第2の発明に於いて、PFA又はFEPの粉末を散
在させるの意味は、粉末がシートを形成しないことの意
味であり、これは多孔質体の多孔部を層間で連通し置く
ためであり、耐熱性のゴムの多孔質体への含浸に必要で
あるからである。又PFA又はFEPの網状体を用いる
理由も同様である。In addition, in the second invention, the meaning of scattering PFA or FEP powder is the meaning that the powder does not form a sheet, and this is because the pores of the porous body are placed in communication between the layers. This is because it is necessary for impregnating heat-resistant rubber into a porous body. The reason for using a PFA or FEP network is also the same.
以下に例示の図面を用いて本発明の詳細な説明する。The present invention will be explained in detail below using the illustrative drawings.
本発明の第1の弾性定着ローラは、第1図に示す様に、
ローラ基材即ちローラ芯(1)の外側にPTFEとPF
A(又はFEP)との混合物の多孔質体が積層、焼成さ
れ、これの多孔部に耐熱性のゴム例えばシリコーンゴム
、弗素ゴム等が含浸、硬化された被覆層(2)が構成さ
れたものである。The first elastic fixing roller of the present invention, as shown in FIG.
PTFE and PF on the outside of the roller base material, that is, the roller core (1)
A porous body made of a mixture with A (or FEP) is laminated and fired, and a coating layer (2) is formed by impregnating and hardening a heat-resistant rubber such as silicone rubber or fluorine rubber in the porous parts. It is.
又本発明の第2の弾性ローラは、第2図に示す様にロー
ラ基材即ちローラ芯(1)の外側にPTFEの多孔質体
(4)が層間にPFA(又はFEP )の粉末(3)を
散在させて或いはPFA(又はFEP )の網状体(3
つを介在させて積層、焼成され、これの多孔部に例えば
シリコーンゴム、弗素ゴA 等d; f浸、硬化された
被覆層(5)が構成されたものである。Further, as shown in FIG. 2, the second elastic roller of the present invention has a porous body (4) of PTFE on the outside of the roller base material, that is, the roller core (1), and a powder (3) of PFA (or FEP) between the layers. ) or a network of PFA (or FEP) (3
A covering layer (5) of, for example, silicone rubber, fluorine rubber A, etc., is immersed and cured in the porous portion of the layer.
(実施例) 以下に本発明の実施例を述べる。(Example) Examples of the present invention will be described below.
実施例1゜
外径25mのアルミニクム芯金ローラの外周にプライf
(TCW−8808GV、ダイキン工業製)を塗装し
乾燥させた。この上にPFAディスバージョン(AD−
2CR1ダイキン工業製)を塗装した後、焼成を行った
。Example 1゜Ply f on the outer periphery of an aluminum cored roller with an outer diameter of 25 m.
(TCW-8808GV, manufactured by Daikin Industries) was painted and dried. On top of this, PFA disversion (AD-
2CR1 (manufactured by Daikin Industries) was coated, and then fired.
PTFE樹脂7フイ7 、< クダー(F−104、ダ
イキン工業製)にPFA樹脂粉末(MP−102、三井
70ロケミカル社製〕を第1表に示す比率で混合し、成
型、延伸を行うことにより製作した気孔率80チ厚さ6
0μmの未焼成の多孔質シートを上記ローラに焼成後1
1111の厚さになるように巻き付け、焼成した。By mixing PTFE resin (F-104, manufactured by Daikin Industries) and PFA resin powder (MP-102, manufactured by Mitsui 70 Rochemical Co., Ltd.) at the ratio shown in Table 1, and performing molding and stretching. Manufactured porosity 80cm thickness 6
1 After firing the 0μm unfired porous sheet on the above roller
It was wrapped to a thickness of 1111 mm and fired.
この多孔質層にシリコンゴム(KE109、信越化学製
)を含浸させ、硬化させた。This porous layer was impregnated with silicone rubber (KE109, manufactured by Shin-Etsu Chemical) and cured.
実施例2
外径25簡のアルミニクム芯金ローラの外周に7’ライ
マを塗装し乾燥させた。この上にPFAディスバージョ
ンを塗装した後、焼成を行った。Example 2 A 7' limer was coated on the outer periphery of an aluminum cored roller having an outer diameter of 25 strips and dried. After coating PFA dispersion on this, baking was performed.
PTFE樹脂ファインパクダーを成型、延伸を行うこと
により製作した気孔率80%厚さ60μmの未焼成の多
孔質シートに、PFAディスバージョン(AD−2CR
)を塗布しながら焼成後1W+になるように巻き付け、
焼成した。PFA disversion (AD-2CR
) while applying it, wrap it so that it becomes 1W+ after firing,
Fired.
この多孔質層にシリコーンゴムを含浸させ、硬化させた
。This porous layer was impregnated with silicone rubber and cured.
これらのローラの、巻き付けた層の間の接着強度を測定
した。その結果を第1表に示す。The adhesive strength between the wrapped layers of these rollers was measured. The results are shown in Table 1.
第 1 表
第 1 表
(発明の効果)
以上の様に本発明によれば、ローラ基材外側の多孔質体
積層間の接着強度の大きい弾性定着ローラが得られ、耐
久性の向上に役立つ。Table 1 Table 1 (Effects of the Invention) As described above, according to the present invention, an elastic fixing roller with high adhesive strength between the porous laminated layers on the outside of the roller base material can be obtained, which is useful for improving durability.
々お本発明の弾性ローラは加熱定着ローラ(1o)ばか
りではなく、加圧定着ローラ(11)としても(第3図
参照)更に又耐熱性、離型性を要する弾性ローラとして
も広く使用出来る。The elastic roller of the present invention can be widely used not only as a heat fixing roller (1o), but also as a pressure fixing roller (11) (see Figure 3), and also as an elastic roller that requires heat resistance and mold release properties. .
又上記の弾性定着ローラは、四弗化エチレン樹JIIK
充IE剤(着色、熱伝導率の向上等のため)を配合した
ものを使ってもよく、本発明はこれらを勿論含むもので
ある。The above elastic fixing roller is made of tetrafluoroethylene JIIK.
A filler containing an IE filler (for coloring, improving thermal conductivity, etc.) may be used, and the present invention naturally includes these.
第1.2図は共に本発明の弾性ローラの構成を示した断
面図、第3図は従来の定着装置の側面図を夫々例示して
いる。
(1)・・・ローラ基材(ローラ芯)、(2)・・・被
覆層、(3)・・・PFA又はFEP粉末、(3′)・
・・PFA又はFEP網状体、(4)・・・PTFE多
孔質体、(5)・・・被覆層、(10)・・・加熱定着
ローラ、(11)・・加圧定着ローラ、(13)・・・
コピー紙
代理人 弁理士 吉 竹 昌 司 。1.2 are sectional views showing the structure of the elastic roller of the present invention, and FIG. 3 is a side view of a conventional fixing device. (1)... Roller base material (roller core), (2)... Covering layer, (3)... PFA or FEP powder, (3')...
... PFA or FEP network, (4) ... PTFE porous material, (5) ... coating layer, (10) ... heat fixing roller, (11) ... pressure fixing roller, (13 )...
Copy paper agent and patent attorney Masashi Yoshitake.
Claims (2)
間に通して定着する装置に使用される定着ローラに於い
て、ローラ基材の外側に、四弗化エチレン樹脂(PTF
E)とテトラフルオロエチレン−パーフルオロアルキル
ビニルエーテル共重合体(PFA)又はテトラフルオロ
エチレン−ヘキサフルオロプロピレン共重合体(FEP
)との混合物の多孔質体を2層以上積層、焼成したもの
の多孔部に例えばシリコーンゴム、弗素ゴム等の耐熱性
のゴムを含浸、硬化して構成した被覆層を有することを
特徴とする弾性定着ローラ。(1) In a fixing roller used in a device that fixes a toner image formed on copy paper by passing it between two rollers, tetrafluoroethylene resin (PTF) is used on the outside of the roller base material.
E) and tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA) or tetrafluoroethylene-hexafluoropropylene copolymer (FEP)
) is laminated and fired in two or more layers, and has a coating layer formed by impregnating and curing a heat-resistant rubber such as silicone rubber or fluorine rubber in the porous part. Fuser roller.
間に通して定着する装置に使用される定着ローラに於い
て、ローラ基材の外側に、四弗化エチレン樹脂(PTF
E)多孔質体の層間に、テトラフルオロエチレン−パー
フルオロアルキルビニルエーテル共重合体(PFA)又
はテトラフルオロエチレン−ヘキサフルオロプロピレン
共重合体(FEP)の、粉末を散在させ或いは網状体を
介在させ二層以上積層、焼成したものの多孔部に例えば
シリコーンゴム、弗素ゴム等の耐熱性のゴムを含浸、硬
化して構成した被覆層を有することを特徴とする弾性定
着ローラ。(2) In a fixing roller used in a device that fixes a toner image formed on copy paper by passing it between two rollers, tetrafluoroethylene resin (PTF) is used on the outside of the roller base material.
E) Powder of tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA) or tetrafluoroethylene-hexafluoropropylene copolymer (FEP) is interspersed or a network is interposed between the layers of the porous body. An elastic fixing roller characterized in that it has a coating layer formed by laminating and firing multiple layers and impregnating and curing heat-resistant rubber such as silicone rubber or fluororubber into the porous parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24824888A JPH0293676A (en) | 1988-09-30 | 1988-09-30 | elastic fixing roller |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP24824888A JPH0293676A (en) | 1988-09-30 | 1988-09-30 | elastic fixing roller |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0293676A true JPH0293676A (en) | 1990-04-04 |
Family
ID=17175354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP24824888A Pending JPH0293676A (en) | 1988-09-30 | 1988-09-30 | elastic fixing roller |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0293676A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH044037U (en) * | 1990-04-23 | 1992-01-14 | ||
| EP0619534A3 (en) * | 1993-04-08 | 1995-08-23 | Japan Gore Tex Inc | Elastic fixing roller. |
| JPH10120856A (en) * | 1996-10-23 | 1998-05-12 | Showa Electric Wire & Cable Co Ltd | Fluororesin composition, fluororesin tube, fluororesin film, and roller |
| US11988983B2 (en) | 2021-10-04 | 2024-05-21 | Canon Kabushiki Kaisha | Fixing member, method for producing the same, fixing apparatus, and electrophotographic image forming apparatus |
| US12001158B2 (en) | 2021-10-04 | 2024-06-04 | Canon Kabushiki Kaisha | Fixing member, method for producing the same, fixing apparatus, and electrophotographic image forming apparatus |
-
1988
- 1988-09-30 JP JP24824888A patent/JPH0293676A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH044037U (en) * | 1990-04-23 | 1992-01-14 | ||
| EP0619534A3 (en) * | 1993-04-08 | 1995-08-23 | Japan Gore Tex Inc | Elastic fixing roller. |
| JPH10120856A (en) * | 1996-10-23 | 1998-05-12 | Showa Electric Wire & Cable Co Ltd | Fluororesin composition, fluororesin tube, fluororesin film, and roller |
| US11988983B2 (en) | 2021-10-04 | 2024-05-21 | Canon Kabushiki Kaisha | Fixing member, method for producing the same, fixing apparatus, and electrophotographic image forming apparatus |
| US12001158B2 (en) | 2021-10-04 | 2024-06-04 | Canon Kabushiki Kaisha | Fixing member, method for producing the same, fixing apparatus, and electrophotographic image forming apparatus |
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