JPH0313202B2 - - Google Patents
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- Publication number
- JPH0313202B2 JPH0313202B2 JP57079252A JP7925282A JPH0313202B2 JP H0313202 B2 JPH0313202 B2 JP H0313202B2 JP 57079252 A JP57079252 A JP 57079252A JP 7925282 A JP7925282 A JP 7925282A JP H0313202 B2 JPH0313202 B2 JP H0313202B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- weight
- composition
- called
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N29/00—Biocides, pest repellants or attractants, or plant growth regulators containing halogenated hydrocarbons
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/08—Oxygen or sulfur directly attached to an aromatic ring system
- A01N31/14—Ethers
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/22—O-Aryl or S-Aryl esters thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本発明は、稲の寄生虫を駆除する目的の新規な
組成物に関するものである。
本発明の主題は稲の寄生虫を駆除する目的の組
成物であり、この組成物は活性成分として一方で
は
●1R，3R）−３−（２，２−ジブロムビニル）−
２，２−ジメチルシクロプロパン−１−カルボ
ン酸（Ｓ）−α−シアノ−３−フエノキシベン
ジル（一般にデルタメトリンと呼ばれる）、
●1RS cis，trans）−３−（２，２−ジクロルビ
ニル）−２，２−ジメチルシクロプロパン−１
−カルボン酸３−フエノキシベンジル（一般に
ペルメトリンと呼ばれる）、
●1RS cis，trans）−３−（２，２−ジクロルビ
ニル）−２，２−ジメチルシクロプロパン−１
−カルボン酸（RS）α−シアノ−３−フエノ
キシベンジル（一般にサイペルメトリンと呼ば
れる）、
●２−（４−クロルフエニル）−３−メチル酪酸
（RS）α−シアノ−３−フエノキシベンジル
（フエンバレレートと呼ばれる）
及び
●２，２−ジメチル−3S−（1′，2′，2′，2′−テト
ラブロムエチル）シクロプロパン−1R−カル
ボン酸（Ｓ）α−シアノ−３−フエノキシベン
ジル（トラロメトリンと呼ばれる）
よりなる群から選択される少なくとも１種のピレ
スリノイド化合物を含有し、他方では
●０，０−ジイソプロピルホスホロチオ酸Ｓ−ベ
ンジル（キタジンＰと呼ばれる）、
●２−sec−ブチルフエニルメチルカルバメート
（BPMと呼ばれる）、
●１，１−ジクロル−２，２−ビス−（４−エチ
ルフエニル）エタン（ペルタンと呼ばれる）
及び
●１−ナフチル−メチルカルバメート（カルバリ
ール若しくはセビンと呼ばれる）
より成る群から選択されるカルバメート、有機塩
素化合物及び有機燐化合物の少なくとも１種含有
することを特徴とする。
前記ピレスリノイド化合物は周知化合物であ
り、本発明はより詳細にはすでに市販されている
ピレスリノイド化合物を含有する組成物に向けら
れる。
本発明の組成物中に使用される前記の有機塩素
化合物、有機燐化合物及びカルバメートも公知化
合物であり、例えばアール・ワーシングによつて
編集され、英国作物保護協議会により出版された
「殺虫剤マニユアル」、第６版（1979）に記載され
ている。
本発明の組成物は特にしばしば二成分若しくは
三成分組成物である。
本発明の主題は、特に、カルバメート、有機塩
素化合物及び有機燐化合物よりなる群から選択さ
れる少なくとも１種の化合物100〜2000重量部当
り１〜300重量部の前記ピレスリノイド化合物を
含有することを特徴とする組成物、殊にカルバメ
ート、有機塩素化合物及び有機燐化合物よりなる
群から選択される少なくとも１種の化合物100〜
1000重量部当り、好ましくは300〜600重量部当り
１〜10重量部、好ましくは４〜８重量部のデルタ
メトリンを含有することを特徴とする組成物であ
る。
本発明の組成物は大きな産業的興味を有し、稲
の寄生虫、特に稲の寄生虫である昆虫を駆除する
ことができる。
稲の寄生虫として最もよく知られた昆虫は、た
とえばニラパルバタ・ルゲンス（Nilaparvota
lugens）、ネフオテチツクス・ヴイレセンス
（Nephotettix virescens）及びソガテラ・フルシ
フエラ（Sogatella furcifera）のような横這科類
である。
近年、高収穫かつ短周期でありしかも稲喰い虫
に対してかなり耐性である種類の稲の開発が、稲
の横這科類すなわちこの作物に対し今日までそれ
程有害でなかつた昆虫の繁殖を誘発させた。数年
の間に全太平洋沿岸諸国において全く脅威となつ
たこの繁殖は、一方には生息環境の変化に関係す
ると思われ、新たな変種は従前のものより多くの
ひこばえを有し、日陰はこれら昆虫の繁殖を促進
すると思われ、また他方には全てのひこばえが充
分な光合成機能を示して既に形成された各穂に良
好な種子を稔らせ、次いで既に出芽したひこばえ
の個数を増大させるには窒素の投与量を著しく増
加する必要があることに関係すると思われる。
最後に、ウイルスの保菌体であるこれら昆虫に
対して活性であると共に標準的慣れ現象又は蘇生
現象を回避することのできる化合物は極めて少な
いことがわかつた。
今回、本発明の組成物は稲の寄生虫、特に横這
科類を駆除しうると共に、耐性現象及び蘇生現象
を回避することができることが見出された。
したがつて、本発明の組成物は経済的観点及び
衛生上の観点の両者から作物を保護することがで
きる。何故なら、作物は、防止すべき横這科類に
より伝染されるウイールス感染によつて面倒をひ
き起こされるからである。
後記に示す実験例は、極めて少量の前記ピレス
リノイド化合物と通常使用されるよりずつと少な
い量の有機塩素化合物、有機燐化合物又はカルバ
メートを含有する組成物により優秀な成績が得ら
れることを明確に示している。
本発明の組成物は相乗現象が明らかであり、特
に後記実験の４例から極めて明確に示される。
従来技術においては、どれもこの種の相乗作用
を予測しえなかつた。
本発明の組成物は、農芸化学工業の通常の方法
により製造することができる。
したがつて、本発明の主題は農業用途に対し条
件設定することを特徴とする上記の組成物であ
る。
農業用途に条件設定したこれら組成物におい
て、活性物質には他の１種若しくはそれ以上の殺
虫剤を添加することができる。
これら組成物は粉剤、粒剤、懸濁液、乳剤、溶
液、エアロゾル用溶液、或いはこの種の化合物の
使用の際通常使用されるその他製剤として提供す
ることができる。
活性成分に加え、これら組成物は一般にベヒク
ル及び（又は）非イオン性表面活性剤をも含有し
て、混合物を構成する物質の均一分散をさらに確
保する。使用するベヒクルは、たとえば水、アル
コール、炭化水素若しくはその他の有機溶剤、鉱
物性、動物性若しくは植物性油のような液体、或
いはたとえばタルク、粘土、シリケート又は珪藻
土のような粉末とすることができる。
さらに、本発明の組成物は新規であり、したが
つてそのものとして本発明の特許対象であること
を特記すべきである。これら組成物のうちに、特
に一方には前記ピレスリノイド化合物と他方には
下記化合物とを含有する組成物を挙げることがで
きる：
●１，１−ジクロル−２，２−ビス−（４−エチ
ルフエニル）エタン（即ちペルタン）、
●メチルカルバミン酸１−ナフチル（即ちカルバ
リール若しくはセビン）、
●メチルカルバミン酸２−sec−ブチルフエニル
（即ちBPMC）
及び
●０，０−ジイソプロピルホスホロチオ酸Ｓ−ベ
ンジル（即ちキタジンＰ）。
これら新規組成物のうち、特に実験例で製造さ
れる組成物を挙げることができる。
最後に、本発明の主題は、上記組成物の有効量
を稲作物に施こすことを特徴とする稲作物の殺虫
処理法である。
以下の例により本発明を例示するが、これらの
みに限定されない。
組成物の例
Ａ 次の成分を含有する水和性濃厚物を製造し
た：
BPMCとデルタメトリンとを含有する組成
物（デルタメトリン1.5ｇ当りBPMC100
ｇ） ……0.25ｇ
ピペロニルブトキシド ……１ｇ
ツイーン80 ……0.25ｇ
トパノールＡ ……0.1ｇ
水 ……98.4ｇ
Ｂ 次の成分を含有する乳化性濃厚物を製造し
た：
BPMCとデルタメトリンとを含有する組成
物（デルタメトリン1.5ｇ当りBPMC100ｇ
……1.25ｇ
ツイーン80 ……20ｇ
トパノール ……0.1ｇ
キシレン ……78.4ｇ
Ｃ デルタメトリン１ｇ当りセビン100ｇを含
有する組成物により組成物を交換して、上
記Ａに示したと同様に水和性濃厚物を製造し
た。
Ｄ デルタメトリン1.5ｇ当りペルタン100ｇを
含有する組成物により組成物を交換して、
上記Ｂに示したと同様に乳化性濃厚物を製造
した。
Ｅ セビン12.5ｇ当りフエンバレレート100ｇ
を含有する組成物により組成物を交換し
て、上記Ｂに示したと同様に乳化性濃厚物を
製造した。
Ｆ セビン８ｇ当りサイペルメトリン100ｇを
含有する組成物により組成物を交換して、
上記Ｂに示したと同様に乳化性濃厚物を製造
した。
Ｇ 次の活性成物を含有する組成物を製造し
た：
デルタメトリン ……５ｇ
BPMC ……300ｇ
トリアゾホス ……200ｇ
４〜６ｇのデルタメトリンと100〜600ｇの
BPMCと100〜400ｇのトリアゾホスとを用
いて同様な組成物を製造することができた。
Ｈ ジアジノンによりトリアゾホスを交換し
て、上記Ｇに記載したと同様な組成物を製造
した。
Ｉ カルバリールによりBPMCを交換して、
上記Ｇ又はＨで製造したものと同様な組成物
を製造した。
Ｊ ペルタンによりBPMCを交換して、上記
Ｇ及びＨに記載したものと同様な組成物を製
造した。
Ｋ キタジンＰによりBPMCを交換して、上
記Ｇに記載したものと同様な組成物を製造し
た。
ニラパルバタ・ルゲンス（以下、BPHと云
う）に対する本発明の組成物の殺虫活性に関す
る検討
５ｍ×８ｍの土地区画を使用した。１ヘクタ
ール当り水600の基準で一定圧力の二酸化炭
素噴霧器を用いて処理を行なつた。区画の表面
全体に組成物を散布した。
１区画当り32個の稲クランプにつきBPHの
検査を行なつた。
以下の試験−についての表中、〓１ヘク
タール当りの活性物質の投与量〓はｇで表わさ
れる。
The present invention relates to a novel composition for the purpose of combating rice parasites. The subject of the present invention is a composition for the purpose of combating rice parasites, which contains on the one hand as active ingredients ●1R,3R)-3-(2,2-dibromvinyl)-
2,2-dimethylcyclopropane-1-carboxylic acid (S)-α-cyano-3-phenoxybenzyl (commonly called deltamethrin), ●1RS cis, trans)-3-(2,2-dichlorovinyl)- 2,2-dimethylcyclopropane-1
-3-phenoxybenzyl carboxylate (commonly called permethrin), ●1RS cis, trans)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane-1
-Carboxylic acid (RS) α-cyano-3-phenoxybenzyl (commonly called cypermethrin), ●2-(4-chlorophenyl)-3-methylbutyrate (RS) α-cyano-3-phenoxybenzyl (called fenvalerate) and ●2,2-dimethyl-3S-(1',2',2',2'-tetrabromoethyl)cyclopropane-1R-carboxylic acid (S) α-cyano-3- phenoxybenzyl (called tralomethrin); on the other hand: ● S-benzyl 0,0-diisopropylphosphorothioate (called Kitazine P); ●2 -sec-butylphenyl methyl carbamate (called BPM), ● 1,1-dichloro-2,2-bis-(4-ethylphenyl)ethane (called pertan), and ● 1-naphthyl-methyl carbamate (also known as carbaryl or sevin). It is characterized by containing at least one kind of carbamate, organic chlorine compound, and organic phosphorus compound selected from the group consisting of Said pyrethrinoid compounds are well known compounds and the present invention is more particularly directed to compositions containing pyrethrinoid compounds that are already commercially available. The above-mentioned organochlorine compounds, organophosphorus compounds and carbamates used in the compositions of the invention are also known compounds, e.g. ”, 6th edition (1979). The compositions of the invention are particularly often binary or ternary compositions. The subject of the invention is particularly characterized in that it contains 1 to 300 parts by weight of said pyrethrinoid compound per 100 to 2000 parts by weight of at least one compound selected from the group consisting of carbamates, organochlorine compounds and organophosphorus compounds. compositions, in particular at least one compound selected from the group consisting of carbamates, organochlorine compounds and organophosphorus compounds
The composition is characterized in that it contains 1 to 10 parts by weight, preferably 4 to 8 parts by weight of deltamethrin per 1000 parts by weight, preferably 300 to 600 parts by weight. The composition of the present invention has great industrial interest and is capable of combating rice parasites, especially insects that are parasites of rice. The insects best known as rice parasites are, for example, Nilaparvota rugens (Nilaparvota lugens).
lugens), Nephotettix virescens and Sogatella furcifera. In recent years, the development of varieties of rice that are high-yielding, short-cycle, and fairly resistant to rice-boring insects has stimulated the proliferation of rice paraphytes, insects that have hitherto been less harmful to the crop. I let it happen. This breeding, which has become a total threat in all Pacific coastal countries within a few years, may be related, on the one hand, to changes in habitat, with the new variety having more burrows than its predecessors and requiring less shade. seems to promote the reproduction of these insects, and on the other hand, all the larvae show sufficient photosynthetic function to produce good seeds in each already formed panicle, and then the larvae that have already sprouted This may be related to the need to significantly increase the nitrogen dosage to increase the number of . Finally, it has been found that very few compounds are active against these insect carriers of the virus and are able to avoid the standard habituation or resuscitation phenomena. It has now been found that the composition of the present invention is capable of combating rice parasites, especially parasitoids, as well as avoiding resistance and resuscitation phenomena. The compositions of the invention are therefore able to protect crops both from an economic and a hygienic point of view. This is because the crops are troubled by viral infections transmitted by the paraphytes that are to be prevented. The experimental examples given below clearly demonstrate that excellent results can be obtained with compositions containing very small amounts of the pyrethrinoid compounds and slightly smaller amounts of organochlorine compounds, organophosphorus compounds or carbamates than are normally used. ing. The composition of the present invention clearly exhibits a synergistic phenomenon, which is particularly clearly shown in the four experimental examples described below. None of the prior art could have predicted this type of synergy. The composition of the present invention can be produced by a conventional method in the agricultural and chemical industries. The subject of the invention is therefore the above-mentioned composition, which is characterized in that it is adapted for agricultural use. In these compositions adapted for agricultural use, one or more other insecticides can be added to the active substance. These compositions can be presented as powders, granules, suspensions, emulsions, solutions, aerosol solutions, or other formulations commonly used in the use of compounds of this type. In addition to the active ingredient, these compositions generally also contain a vehicle and/or a nonionic surfactant to further ensure uniform dispersion of the substances making up the mixture. The vehicle used can be a liquid such as water, an alcohol, a hydrocarbon or other organic solvent, a mineral, animal or vegetable oil, or a powder such as talc, clay, silicate or diatomaceous earth. . Furthermore, it should be noted that the compositions of the present invention are novel and are therefore patentable subject matter as such. Among these compositions, mention may be made in particular of compositions containing the above-mentioned pyrethrinoid compounds on the one hand and the following compounds on the other hand: 1,1-dichloro-2,2-bis-(4-ethylphenyl) ethane (i.e., pertane), ● 1-naphthyl methylcarbamate (i.e., carbaryl or sevin), ● 2-sec-butylphenyl methylcarbamate (i.e., BPMC), and ● S-benzyl 0,0-diisopropylphosphorothioate (i.e., Kitazine P). . Among these new compositions, mention may particularly be made of the compositions produced in the experimental examples. Finally, the subject of the invention is a method for the insecticidal treatment of rice crops, characterized in that an effective amount of the above composition is applied to the rice crops. The invention is illustrated, but not limited to, by the following examples. Composition Example A A hydratable concentrate was prepared containing the following ingredients: Composition containing BPMC and deltamethrin (100 BPMC per 1.5 g of deltamethrin)
g) ...0.25 g Piperonyl Butoxide ...1 g Tween 80 ...0.25 g Topanol A ...0.1 g Water ...98.4 g B An emulsifiable concentrate containing the following ingredients was prepared: A composition containing BPMC and deltamethrin. (100g BPMC per 1.5g deltamethrin)
...1.25 g Tween 80 ...20 g Topanol ...0.1 g Xylene ...78.4 g C Hydrable concentrate as shown in A above, replacing the composition with a composition containing 100 g of Sevin per 1 g of deltamethrin was manufactured. D. replacing the composition with a composition containing 100 g of pertan per 1.5 g of deltamethrin;
An emulsifiable concentrate was prepared as described in B above. E Fuenvalerate 100g per 12.5g Sevin
An emulsifiable concentrate was prepared as described in B above, replacing the composition with a composition containing: F replacing the composition with a composition containing 100 g of cypermethrin per 8 g of sevin,
An emulsifiable concentrate was prepared as described in B above. G A composition containing the following active ingredients was prepared: Deltamethrin...5g BPMC...300g Triazophos...200g 4-6g deltamethrin and 100-600g
Similar compositions could be made using BPMC and 100-400 g of triazophos. A similar composition as described in G above was prepared by replacing the triazophos with H diazinon. I Replace BPMC with Carbaryl,
Compositions similar to those made in G or H above were prepared. Compositions similar to those described in G and H above were prepared by replacing BPMC with J Pertan. A composition similar to that described in G above was prepared by replacing BPMC with K Kitadine P. Study on the insecticidal activity of the composition of the present invention against Nilaparbata lugens (hereinafter referred to as BPH) A plot of land measuring 5 m x 8 m was used. Treatment was carried out using a constant pressure carbon dioxide atomizer on a basis of 600 ml of water per hectare. The composition was spread over the entire surface of the plot. BPH tests were conducted on 32 rice clamps per plot. In the tables for the following tests, the dose of active substance per hectare is expressed in g.
【表】
結論：この試験に関し、本発明の組成物は極め
て活性であり、極めて顕著な相乗特性を示す。Table: Conclusion: Regarding this test, the composition of the invention is very active and shows very pronounced synergistic properties.
【表】
結論：本発明の組成物は、極めて活性であり、
極めて顕著な相乗特性を示す。[Table] Conclusion: The composition of the present invention is highly active;
Exhibits very pronounced synergistic properties.
【表】【table】
【表】
結論：この試験に関し、本発明の組成物は極め
て活性であり、顕著な相乗特性を示す。Table: Conclusion: Regarding this test, the composition of the invention is highly active and exhibits significant synergistic properties.
【表】
結論：本発明の組成物は極めて活性であり、顕
著な相乗特性を示す。Table: Conclusion: The composition of the invention is highly active and exhibits significant synergistic properties.
Claims (1)
−２，２−ジメチルシクロプロパン−１−カル
ボン酸（Ｓ）α−シアノ−３−フエノキシベン
ジル（一般にデルタメトリンと呼ばれる）、 ●（1RS cis，trans）−３−（２，２−ジクロル
ビニル）−２，２−ジメチルシクロプロパン−
１−カルボン酸３−フエノキシベンジル（一般
にペルメトリンと呼ばれる）、 ●（1RS cis，trans）−３−（２，２−ジクロル
ビニル）−２，２−ジメチルシクロプロパン−
１−カルボン酸（RS）α−シアノ−３−フエ
ノキシベンジル（一般にサイペルメトリンと呼
ばれる）、 ●２−（４−クロルフエニル）−３−メチル酪酸
（RS）α−シアノ−３−フエノキシベンジル
（フエンバレレートと呼ばれる） 及び ●２，２−ジメチル−3S−（1′，2′，2′，2′−テト
ラブロムエチル）−シクロプロパン−1R−カル
ボン酸（Ｓ）α−シアノ−３−フエノキシベン
ジル（トラロメトリンと呼ばれる） よりなる群から選択される少なくとも１種のピレ
スリノイド化合物を含有し、他方では ●０，０−ジイソプロピルホスホロチオ酸Ｓ−ベ
ンジル（キタジンＰと呼ばれる）、 ●メチルカルバミン酸２−sec−ブチルフエニル
（BPMCと呼ばれる）、 ●１，１−ジクロル−２，２−ビス−（４−エチ
ルフエニル）エタン（ペルタンと呼ばれる） 及び ●メチルカルバミン酸１−ナフチル（カルバリ−
ル若しくはセビンと呼ばれる） より成る群から選択されるカルバメート、有機塩
素化合物及び有機燐化合物の少なくとも１種を含
有することを特徴とする稲の寄生虫を駆除するた
めの組成物。 ２ カルバメート、有機塩素化合物及び有機燐化
合物よりなる群から選択される少なくとも１種の
化合物100〜2000重量部当りに１〜300重量部のピ
レスリノイド化合物を含有することを特徴とする
特許請求の範囲第１項記載の組成物。 ３ カルバメート、有機塩素化合物及び有機燐化
合物よりなる群から選択される少なくとも１種の
化合物100〜1000重量部当り、好ましくは300〜
600重量部当りに１〜10重量部、好ましくは４〜
８重量部のデルタメトリンを含有することを特徴
とする特許請求の範囲第２項記載の組成物。 ４ 稲における横這科類の抑制を目的とすること
を特徴とする特許請求の範囲第１〜３項のいずれ
かに記載の組成物。 ５ 農業用途として条件設定することを特徴とす
る特許請求の範囲第１〜４項のいずれかに記載の
組成物。[Claims] 1. On the one hand, ●(1R,3R)-3-(2,2-dibromvinyl) as an active ingredient;
-2,2-dimethylcyclopropane-1-carboxylic acid (S) α-cyano-3-phenoxybenzyl (commonly called deltamethrin), ●(1RS cis, trans)-3-(2,2-dichlorovinyl) -2,2-dimethylcyclopropane-
3-Phenoxybenzyl 1-carboxylate (commonly called permethrin), ●(1RS cis,trans)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane-
1-Carboxylic acid (RS) α-cyano-3-phenoxybenzyl (commonly called cypermethrin), 2-(4-chlorophenyl)-3-methylbutyric acid (RS) α-cyano-3-phenoxy Benzyl (called fuenvalerate) and ●2,2-dimethyl-3S-(1',2',2',2'-tetrabromoethyl)-cyclopropane-1R-carboxylic acid (S) α-cyano- 3-phenoxybenzyl (referred to as tralomethrin); ● 2-sec-butylphenyl methylcarbamate (called BPMC), ● 1,1-dichloro-2,2-bis-(4-ethylphenyl)ethane (called pertane), and ● 1-naphthyl methylcarbamate (called carbali-
A composition for exterminating rice parasites, the composition comprising at least one of a carbamate, an organochlorine compound, and an organophosphorus compound selected from the group consisting of: 2. Claim 1, characterized in that the pyrethrinoid compound is contained in an amount of 1 to 300 parts by weight per 100 to 2,000 parts by weight of at least one compound selected from the group consisting of carbamates, organic chlorine compounds, and organic phosphorus compounds. Composition according to item 1. 3. Per 100 to 1000 parts by weight of at least one compound selected from the group consisting of carbamates, organochlorine compounds, and organophosphorus compounds, preferably 300 to 1000 parts by weight.
1 to 10 parts by weight per 600 parts by weight, preferably 4 to 10 parts by weight
A composition according to claim 2, characterized in that it contains 8 parts by weight of deltamethrin. 4. The composition according to any one of claims 1 to 3, characterized in that the composition is intended for suppressing Lycophyllidae in rice. 5. The composition according to any one of claims 1 to 4, characterized in that conditions are set for agricultural use.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8109514 | 1981-05-13 | ||
| FR8109514A FR2505611B1 (en) | 1981-05-13 | 1981-05-13 | NOVEL COMPOSITIONS FOR PEST CONTROL OF RICE CONTAINING ORGANOCHLORINE AND PYRETHRINOID |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58905A JPS58905A (en) | 1983-01-06 |
| JPH0313202B2 true JPH0313202B2 (en) | 1991-02-22 |
Family
ID=9258390
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57079252A Granted JPS58905A (en) | 1981-05-13 | 1982-05-13 | Novel composition for expelling rice parasite |
Country Status (7)
| Country | Link |
|---|---|
| JP (1) | JPS58905A (en) |
| KR (1) | KR880002244B1 (en) |
| BR (1) | BR8202744A (en) |
| FR (1) | FR2505611B1 (en) |
| GB (1) | GB2098069B (en) |
| IT (1) | IT1148170B (en) |
| MY (1) | MY8600725A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH19589A (en) * | 1981-06-08 | 1986-05-26 | Kumiai Chemical Industry Co | Insect pesticidal composition |
| JPS60128123A (en) * | 1983-12-14 | 1985-07-09 | Shinko Electric Co Ltd | Device for stopping mover in conveyor device |
| US4977186A (en) * | 1988-11-23 | 1990-12-11 | Troy Chemical Corporation | Wood preservative and soil treatment composition |
| JP2726402B2 (en) * | 1995-11-01 | 1998-03-11 | 農林水産省九州農業試験場長 | Planthopper control agent |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6037082B2 (en) * | 1976-11-22 | 1985-08-24 | 住友化学工業株式会社 | Mixed insecticidal composition |
| FR2386258A1 (en) * | 1977-04-06 | 1978-11-03 | Roussel Uclaf | Synergistic acaricidal compsn. for use against Panonychus - contg. a cyclopropane carboxylic ester and tri:chloro-bis-chlorophenyl ethanol |
| DD138932A5 (en) * | 1977-10-04 | 1979-12-05 | Hoechst Ag | INSECTICIDES AND ACARICIDE AGENTS |
| DE3062656D1 (en) * | 1979-02-21 | 1983-05-19 | Shell Int Research | Pesticidal compositions and their use |
-
1981
- 1981-05-13 FR FR8109514A patent/FR2505611B1/en not_active Expired
-
1982
- 1982-05-12 GB GB8213843A patent/GB2098069B/en not_active Expired
- 1982-05-12 KR KR8202069A patent/KR880002244B1/en not_active Expired
- 1982-05-12 BR BR8202744A patent/BR8202744A/en unknown
- 1982-05-12 IT IT48398/82A patent/IT1148170B/en active
- 1982-05-13 JP JP57079252A patent/JPS58905A/en active Granted
-
1986
- 1986-12-30 MY MY725/86A patent/MY8600725A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR880002244B1 (en) | 1988-10-20 |
| GB2098069A (en) | 1982-11-17 |
| GB2098069B (en) | 1985-02-27 |
| IT1148170B (en) | 1986-11-26 |
| FR2505611B1 (en) | 1985-10-25 |
| FR2505611A1 (en) | 1982-11-19 |
| JPS58905A (en) | 1983-01-06 |
| MY8600725A (en) | 1986-12-31 |
| KR830009711A (en) | 1983-12-23 |
| IT8248398A0 (en) | 1982-05-12 |
| BR8202744A (en) | 1983-04-19 |
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