JPH0316905B2 - - Google Patents
Info
- Publication number
- JPH0316905B2 JPH0316905B2 JP58117818A JP11781883A JPH0316905B2 JP H0316905 B2 JPH0316905 B2 JP H0316905B2 JP 58117818 A JP58117818 A JP 58117818A JP 11781883 A JP11781883 A JP 11781883A JP H0316905 B2 JPH0316905 B2 JP H0316905B2
- Authority
- JP
- Japan
- Prior art keywords
- decorative surface
- panel
- plate material
- printing
- clear
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 claims description 28
- 238000004049 embossing Methods 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 238000007639 printing Methods 0.000 claims description 10
- 239000011248 coating agent Substances 0.000 claims description 6
- 238000000576 coating method Methods 0.000 claims description 6
- 239000003973 paint Substances 0.000 claims description 5
- 239000003086 colorant Substances 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 2
- 229920005749 polyurethane resin Polymers 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 description 10
- 238000000465 moulding Methods 0.000 description 10
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007646 gravure printing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- -1 amine compounds Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000004984 aromatic diamines Chemical class 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000007644 letterpress printing Methods 0.000 description 1
- NHLUVTZJQOJKCC-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCN(C)C NHLUVTZJQOJKCC-UHFFFAOYSA-N 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】
本発明は金属板材の化粧面に任意模様を印刷
し、その後で所定深さで、かつ所定幅の凹凸模様
をエンボス加工して意匠性と立体感、および耐久
性を改善したパネルを高速で製造しうる装置に関
する。
建築用内、外壁材としては、金属板を成形した
パネルが多数、使用されている。しかしながら、
この種パネルは平板のもの、もしくは単にエンボ
ス加工を施したものしか市販されていなかつた。
その結果、この種のパネルは立体感と意匠性、耐
候性に欠け、しかも平担で、冷たい化粧面のパネ
ルしか製造できなかつた。さらに、エンボス加工
においては、化粧面などの塗膜にクラツクが発生
すると共に、歪なども大きく現われ、パネル自体
が捻れたり、反つたりする不利があつた。また、
この種パネルを形成する際は、印刷部の乾燥時間
が装置全体の生産能力となり、従来の乾燥手段は
熱によつて行なつていたため、乾燥に10分位の時
間を要する不利があつた。
本発明は上記の欠点を除去すると共に前記した
要望に応えるため、板材に任意の凹凸模様を加工
し、次に板材の表面に化粧塗膜、例えばクリヤー
を施して化粧塗膜の亀裂(クラツク)を防止し、
印刷模様の変化を阻止し、かつ化粧面にエンボス
加工による陰影と、印刷模様に描き出された陰影
によつてパネルに十分な立体感、意匠性、自然感
を具備せしめられると共に、インク、透明塗料の
乾燥時間を大幅に短縮でき、その上に美しい仕上
がり面となるパネルを製造できる装置を提案する
ものである。
以下に図面を用いて、本発明に係るパネル製造
装置の一実施例について詳細に説明する。第1図
は上記装置の概略構成図で、1はパネル用板材送
出部で所謂、パネル用板材である金属薄板A(以
下、単に板材Aという)を装着したブレーキ付の
アンコイラ2とピンチローラ3からなり、板材A
を次工程に連続的に送給するためのものである。
4は印刷部でバツクアツプローラ5とコーテング
ローラ6とからなり、板材Aの化粧面、ここでは
表面全面に1色、あるいは多色からなるインクB
で任意模様をグラビア印刷、オフセツト印刷、ス
クリーン印刷、凸版印刷、平板印刷のいずれかの
方法によつて印刷するものである。なお、印刷は
化粧面の任意面に行なうものである。7は塗装部
で化粧面のインクBが未乾燥の状態のときに表面
に対し透明塗料、あるいはカラー塗料(以下、単
にクリヤーという)Cを塗布するためのものであ
り、例えばロールコータ、カーテンフロコータ、
スプレーなどの1つのからものである。8は触媒
蒸気室で板材Aを搬送するためのローラ9と触媒
10をほぼ密封した状態に保持するカバー11と
から構成したものである。特に、触媒10として
はアミン系のもので、各種有機アミン化合物、具
体例としては、2級あるいは3級アミンで、例え
ばトリエチレンジアミン(商品名Dabco)、芳香
族ジアミン、ジメチルヘキサデシルアミン、エチ
ルアミン等の1種を蒸気にしてカバー10内に充
満し、クリヤーCを短時間の間に反応硬化するの
に役立つものである。勿論、触媒蒸気室8は圧
力、換気に十分に注意した安全構造が施してあ
る。12はエンボス加工機で上、下ロール13,
14の外周面に相互に噛み合う雄、雌型の凹凸模
様を有し、これを板材Aの板厚、および凹凸の深
さ等に応じて加圧可能に支持するような構成とし
たものである。15は成形機で、例えば10段、20
段、32段等の段数を有し、前記板材Aを例えば、
ほぼ樋状に成形するためのものである。また、成
形幅はシングル、あるいはダブル幅等のいずれで
も可能な機構である。なお、成形機15は板材A
をその入口から出口までの間にフラワー図に沿つ
て順に樋状に成形するためエンボス加工時の歪、
変形を板材Aの幅方向、および移送方向に沿つて
逃がし、これら歪、変形の残留を最小限に抑える
ことができる。16は切断機で必要に応じて設置
するものであり、フライングカツタ、回転式、プ
レス式等のいずれかである。17は搬送機であ
る。
次に本発明に係るパネル製造装置の動作につい
て説明する。いま、板材Aとして0.27mm厚さのプ
ライマー鋼板(幅1000mm)を1000mボビンに巻回
したものをアンコイラ2に装着した。また、イン
クBのタイプとしては水性アクリルワニス(固形
分40%)と顔料からなるものであり、これをグラ
ビア印刷機によつて印刷し、クリヤーCとしては
ポリウレタン樹脂を用意し、触媒蒸気室8の触媒
10としては、トリエチレンジアミンを準備し、
第2図に示すようなパネルDを製造すると仮定す
る。まず、板材Aの始端をピンチローラ3に案内
し、これを印刷部4に送給する。印刷部4では板
材Aの化粧面に第3図aに示すようにインクBを
木目模様のパターンで印刷する。次に第3図bに
示すように化粧面に対しクリヤーCを塗装部7
(ロールコータ)により塗布し、加熱部8に送給
する。触媒蒸気室8ではクリヤーCをトリエチル
ジアミンの触媒作用で短時間に反応、硬化させ、
エンボス加工機12に送給する。エンボス加工機
12では、クリヤーCがまだ冷却されない状態の
ときに、板材Aの全幅、一定幅、あるいは一部分
に任意模様を、例えば第3図cに示すように施
し、成形機15に送給する。成形機15では第2
図に示す断面形状に成形し、その出口から帯状の
パネルDが連続して送出され、これを所定長さに
切断機16で切切断し、搬送機17で搬送し、パ
ネルDとするものである。
そこで、このようにして製造したパネルDの化
粧面に対し、塩水噴霧テスト(JIS−Z−2371、
1000Hr)を行なつたところ、全く錆が認められ
なかつた。これはクリヤーCがエンボス加工、成
形加工における耐摩性を大幅に改善した結果であ
る。なお、比較例としてはクリヤーCなしの板材
Aの化粧面を同じようにテストしたところ、エン
ボス加工時に部分的に仕上げ塗膜にクラツクが認
められたし、成形後にはさらに多くの部分で、か
つより深くクラツクが見られた結果、塩水噴霧テ
ストは悪いものであつた。さらに比較例ではエン
ボス加工、成形加工において化粧面の印刷模様が
延びたり、縮んだりした状態が直接に露出してい
るため、美観性に欠けるが、実施例ではそのよう
な外観とならなかつた。また、パネルの製造時間
は触媒蒸気室8の代りに、ヒータを用いたときに
は、上記実施例に比べて約3〜10倍の時間を費や
し、かつ仕上り面も平滑でなかつた。
以上説明したのは本発明に係る装置の一実施例
にすぎず、第1図において1点鎖線で示す位置に
予熱機を設置し、よりエンボス加工による悪影響
を除去するように構成することもできる。また、
エンボス加工機12と成形機15間にリベラ18
を設置することもできる。
上述したように本発明に係るパネル製造装置に
よれば、市販の板材、例えばカラー鋼板等の表
面処理鋼板、プライマー鋼板、プレコート板、ア
ルミニウム板、銅板等の化粧面に任意模様を1
色、または多色刷で印刷し、その上に仕上塗料、
例えば透明なクリヤーを施したため、鮮明で、陰
影、色彩感に富む模様で、しかも耐候性にすぐれ
たパネルを製造できる特徴がある。板材に印刷
を施した後に任意深さで、かつ任意の凹凸模様を
エンボス加工するため、立体感が倍加され、しか
も印刷模様はクリヤーで被覆されているため、エ
ンボス加工、成形によつても縮んだり、伸びたり
して外観をひどく損ねることがなく、かつ耐食性
にすぐれたパネルを製造できる特徴がある。エ
ンボス加工を板材の必要幅にのみ施すことができ
るため基材の歪、変形を最小限に抑えることがで
きる特徴がある。エンボス加工を施した後に直
ちに樋状に形成し、エンボス加工により生じた
歪、変形を幅方向、および長手方向に逃がし、残
留歪による寸法変形、凹凸が起きるのを抑制でき
る特徴がある。パネルの製造時間が従前に比較
して約2〜10倍位、短縮でき、しかも美しく、均
一な膜厚の仕上り面のクリヤーとすることができ
る特徴がある。 [Detailed description of the invention] The present invention prints an arbitrary pattern on the decorative surface of a metal plate material, and then embosses a concave-convex pattern with a predetermined depth and a predetermined width to improve design, three-dimensional effect, and durability. The present invention relates to an apparatus capable of manufacturing improved panels at high speed. Many panels made of metal sheets are used as interior and exterior wall materials for buildings. however,
This type of panel was only commercially available as a flat panel or simply embossed.
As a result, this type of panel lacked three-dimensionality, design, and weather resistance, and was only able to be manufactured as a flat panel with a cold decorative surface. Furthermore, in embossing, cracks occur in the coating film on the decorative surface, etc., and large distortions appear, and the panel itself has the disadvantage of twisting or warping. Also,
When forming this type of panel, the drying time of the printing section becomes the production capacity of the entire device, and conventional drying means use heat, which has the disadvantage of requiring about 10 minutes for drying. In order to eliminate the above-mentioned drawbacks and meet the above-mentioned demands, the present invention processes a board material into an arbitrary uneven pattern, and then applies a decorative coating film, such as clear, to the surface of the board material to prevent cracks in the decorative coating film. prevent,
This prevents changes in the printed pattern, and provides the panel with sufficient three-dimensionality, design, and natural feel due to the embossed shading on the decorative surface and the shading drawn on the printed pattern. This paper proposes an apparatus that can significantly shorten the drying time of panels and produce panels with beautiful finished surfaces. An embodiment of the panel manufacturing apparatus according to the present invention will be described in detail below with reference to the drawings. FIG. 1 is a schematic configuration diagram of the above-mentioned apparatus, where 1 is a panel sheet material delivery section, and an uncoiler 2 with a brake and a pinch roller 3 are equipped with a thin metal sheet A (hereinafter simply referred to as sheet material A), which is a so-called panel sheet material. Consisting of plate material A
This is to continuously feed the water to the next process.
Reference numeral 4 denotes a printing section, which is composed of a back-up roller 5 and a coating roller 6, and ink B consisting of one color or multiple colors is applied to the decorative surface of the plate material A, in this case, the entire surface.
An arbitrary pattern is printed using any of the following methods: gravure printing, offset printing, screen printing, letterpress printing, and lithographic printing. Note that printing is performed on any decorative surface. 7 is a device for applying transparent paint or color paint (hereinafter simply referred to as clear) C to the surface of the decorative surface when the ink B on the decorative surface is not dry; for example, a roll coater or a curtain floor. Kota,
It is a single object such as a spray. Reference numeral 8 comprises rollers 9 for conveying the plate material A in the catalyst vapor chamber and a cover 11 for holding the catalyst 10 in a substantially hermetically sealed state. In particular, the catalyst 10 is an amine-based catalyst, such as various organic amine compounds, such as secondary or tertiary amines such as triethylenediamine (trade name: Dabco), aromatic diamine, dimethylhexadecylamine, ethylamine, etc. One type of steam is used to fill the cover 10 and is useful for reaction-curing Clear C in a short period of time. Of course, the catalyst vapor chamber 8 has a safety structure that takes sufficient care of pressure and ventilation. 12 is an embossing machine with upper and lower rolls 13,
The outer peripheral surface of the plate 14 has male and female uneven patterns that engage with each other, and is configured to be supported so that it can be pressurized depending on the thickness of the plate material A, the depth of the unevenness, etc. . 15 is a molding machine, for example, 10 stages, 20
The plate material A has a number of stages, such as 32 stages, and the plate material A is, for example,
It is intended to be formed into a roughly gutter shape. Further, the mechanism allows molding width to be either single width or double width. In addition, the molding machine 15
Since it is formed into a gutter shape in order along the flower diagram from the entrance to the exit, distortion during embossing,
The deformation can be released along the width direction of the plate material A and the transport direction, and the residual distortion and deformation can be minimized. Reference numeral 16 denotes a cutting machine which is installed as required, and is either a flying cutter, a rotary type, a press type, or the like. 17 is a conveyor. Next, the operation of the panel manufacturing apparatus according to the present invention will be explained. Now, as plate material A, a 0.27 mm thick primer steel plate (width 1000 mm) wound around a 1000 m bobbin was attached to uncoiler 2. The type of ink B consists of water-based acrylic varnish (solid content 40%) and pigment, which is printed by a gravure printing machine, and the clear C is a polyurethane resin prepared in the catalyst vapor chamber 8 . As the catalyst 10, triethylenediamine is prepared,
Assume that panel D as shown in FIG. 2 is manufactured. First, the starting end of the plate material A is guided to the pinch roller 3, and then fed to the printing section 4 . The printing section 4 prints ink B on the decorative surface of the board material A in a woodgrain pattern as shown in FIG. 3a. Next, as shown in Figure 3b, clear C is applied to the decorative surface on the painted area 7.
(roll coater) and fed to the heating section 8 . In the catalyst vapor chamber 8 , Clear C is reacted and cured in a short time by the catalytic action of triethyldiamine.
It is fed to the embossing machine 12 . In the embossing machine 12, while the clear C has not yet been cooled, an arbitrary pattern is applied to the entire width, a fixed width, or a part of the plate material A, as shown in FIG. . In the molding machine 15, the second
It is formed into the cross-sectional shape shown in the figure, and a strip-shaped panel D is continuously sent out from the outlet, cut into a predetermined length by a cutter 16, and transported by a conveyor 17 to form a panel D. be. Therefore, the decorative surface of Panel D manufactured in this way was subjected to a salt spray test (JIS-Z-2371,
When the test was carried out for 1000 hours, no rust was observed at all. This is the result of Clear C's greatly improved wear resistance during embossing and molding. As a comparative example, when the decorative surface of plate material A without Clear C was tested in the same way, cracks were observed in the finished coating film in some areas during embossing, and cracks were observed in even more areas after molding. The salt spray test was poor as a result of deeper cracks. Furthermore, in the comparative example, the printed pattern on the decorative surface was directly exposed during embossing and molding, resulting in a lack of aesthetics, but the example did not have such an appearance. Furthermore, when a heater was used in place of the catalyst vapor chamber 8 , the panel manufacturing time was about 3 to 10 times longer than in the above embodiment, and the finished surface was not smooth. What has been described above is only one embodiment of the apparatus according to the present invention, and it is also possible to install a preheater at the position indicated by the dashed line in FIG. 1 to further eliminate the adverse effects of embossing. . Also,
A liberator 18 is placed between the embossing machine 12 and the molding machine 15.
can also be installed. As described above, according to the panel manufacturing apparatus according to the present invention, an arbitrary pattern can be formed on the decorative surface of commercially available plate materials, for example, surface-treated steel plates such as color steel plates, primer steel plates, pre-coated plates, aluminum plates, copper plates, etc.
Color or multicolor printing and finishing paint on top of it,
For example, because it is coated with a transparent clear material, it is possible to produce panels with clear patterns that are rich in shadows and colors, and that are also highly weather resistant. After printing on the board material, we emboss it at any depth and with any uneven pattern, which doubles the three-dimensional effect.Furthermore, since the printed pattern is covered with clear, it will not shrink during embossing or molding. It is characterized by the ability to produce panels with excellent corrosion resistance and without causing significant deterioration in appearance due to bending or stretching. Since embossing can be applied only to the required width of the plate material, distortion and deformation of the base material can be minimized. It is characterized by being formed into a gutter-like shape immediately after embossing, allowing strain and deformation caused by embossing to escape in the width and length directions, thereby suppressing dimensional deformation and unevenness due to residual strain. The panel manufacturing time can be reduced by about 2 to 10 times compared to conventional methods, and it also has the advantage of producing a clear finished surface with a beautiful and uniform thickness.
第1図は本発明に係るパネル製造装置の一実施
例を示す構成略図、第2図は本発明に係る上記装
置により製造されたパネルの一例を示す斜視図、
第3図a〜cはパネルの製造過程を示す説明図で
ある。
1……板材送出部、4……印刷部、8……触媒
蒸気室、12……エンボス加工機、15……成形
機。
FIG. 1 is a schematic configuration diagram showing an embodiment of a panel manufacturing apparatus according to the present invention, and FIG. 2 is a perspective view showing an example of a panel manufactured by the above-mentioned apparatus according to the present invention.
FIGS. 3a to 3c are explanatory diagrams showing the manufacturing process of the panel. 1 ... Plate delivery section, 4 ... Printing section, 8 ... Catalyst vapor chamber, 12 ... Embossing machine, 15... Molding machine.
Claims (1)
部と、該送出部から連続して送給される板材の化
粧面に一色または多色からなる任意模様を直接に
印刷する印刷部と、印刷された化粧面にポリウレ
タン樹脂系透明塗料を施す塗装部と、該化粧面に
塗布された透明塗料を反応固化する触媒蒸気室
と、該蒸気室から連続して送給される板材の所定
領域にエンボス加工を施す凹凸型の模様を外周面
に設けた上下ロール式のエンボス加工機と、該エ
ンボス加工された板材を所定形状に連続して成形
する成形機とを備え、前記板材送出部から成形機
までを直線的に配設したことを特徴とするパネル
の製造装置。1. A board material delivery section consisting of an uncoiler and a pinch roller, a printing section that directly prints an arbitrary pattern of one color or multiple colors on the decorative surface of the board materials continuously fed from the delivery section, and the printed decorative surface. A coating section where a polyurethane resin transparent paint is applied to the decorative surface, a catalytic steam chamber where the transparent paint applied to the decorative surface is reacted and solidified, and a predetermined area of the plate material that is continuously fed from the steam chamber is embossed. It is equipped with an upper and lower roll type embossing machine with a concavo-convex pattern on the outer circumferential surface, and a forming machine that continuously forms the embossed plate material into a predetermined shape. A panel manufacturing device characterized in that the panel is arranged in a manner that
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58117818A JPS607968A (en) | 1983-06-28 | 1983-06-28 | Device for producing panel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58117818A JPS607968A (en) | 1983-06-28 | 1983-06-28 | Device for producing panel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS607968A JPS607968A (en) | 1985-01-16 |
| JPH0316905B2 true JPH0316905B2 (en) | 1991-03-06 |
Family
ID=14721011
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58117818A Granted JPS607968A (en) | 1983-06-28 | 1983-06-28 | Device for producing panel |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS607968A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007032466A1 (en) | 2005-09-15 | 2007-03-22 | Aska Pharmaceutical Co., Ltd. | Heterocyclic compound, and production process and use thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0477440U (en) * | 1990-11-21 | 1992-07-07 |
-
1983
- 1983-06-28 JP JP58117818A patent/JPS607968A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007032466A1 (en) | 2005-09-15 | 2007-03-22 | Aska Pharmaceutical Co., Ltd. | Heterocyclic compound, and production process and use thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS607968A (en) | 1985-01-16 |
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