JPH0323085B2 - - Google Patents

Info

Publication number: JPH0323085B2
Authority: JP; Japan
Prior art keywords: resin; washed; acrylic resin; formula; general formula
Prior art date: 1984-03-22
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP60055746A

Other languages

English (en)

Japanese (ja)

Other versions

JPS60217206A (ja

Inventor

Fuiripiini Andorea

Karotsubi Renaato

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

SIRAC Srl

Original Assignee

SIRAC Srl

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1984-03-22

Filing date

1985-03-22

Publication date

1991-03-28

1985-03-22 Application filed by SIRAC Srl filed Critical SIRAC Srl

1985-10-30 Publication of JPS60217206A publication Critical patent/JPS60217206A/ja

1991-03-28 Publication of JPH0323085B2 publication Critical patent/JPH0323085B2/ja

Status Granted legal-status Critical Current

Links

239000011347 resin Substances 0.000 claims abstract description 66
229920005989 resin Polymers 0.000 claims abstract description 66
229910052796 boron Inorganic materials 0.000 claims abstract description 21
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 20
238000004519 manufacturing process Methods 0.000 claims abstract description 12
239000011159 matrix material Substances 0.000 claims abstract description 7
229920000178 Acrylic resin Polymers 0.000 claims description 17
239000004925 Acrylic resin Substances 0.000 claims description 17
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 15
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 claims description 13
ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
238000000034 method Methods 0.000 claims description 12
239000008367 deionised water Substances 0.000 claims description 10
229910021641 deionized water Inorganic materials 0.000 claims description 10
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
-1 halide ion Chemical class 0.000 claims description 6
229910052736 halogen Inorganic materials 0.000 claims description 6
150000002367 halogens Chemical group 0.000 claims description 6
INGFKPJXXCEHLX-UHFFFAOYSA-N 2-phenyl-1,3,5,2,4,6-trioxatriborinane Chemical compound B1OBOB(O1)c1ccccc1 INGFKPJXXCEHLX-UHFFFAOYSA-N 0.000 claims description 5
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims description 5
239000003960 organic solvent Substances 0.000 claims description 5
229920000058 polyacrylate Polymers 0.000 claims description 5
239000003054 catalyst Substances 0.000 claims description 3
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 2
150000001450 anions Chemical class 0.000 claims description 2
BRTALTYTFFNPAC-UHFFFAOYSA-N boroxin Chemical compound B1OBOBO1 BRTALTYTFFNPAC-UHFFFAOYSA-N 0.000 claims description 2
238000009833 condensation Methods 0.000 claims description 2
230000005494 condensation Effects 0.000 claims description 2
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 2
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
125000006527 (C1-C5) alkyl group Chemical group 0.000 claims 1
230000008707 rearrangement Effects 0.000 claims 1
239000002250 absorbent Substances 0.000 abstract description 3
230000002745 absorbent Effects 0.000 abstract description 3
JCQLYHFGKNRPGE-FCVZTGTOSA-N lactulose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 JCQLYHFGKNRPGE-FCVZTGTOSA-N 0.000 abstract description 3
229960000511 lactulose Drugs 0.000 abstract description 3
PFCRQPBOOFTZGQ-UHFFFAOYSA-N lactulose keto form Natural products OCC(=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O PFCRQPBOOFTZGQ-UHFFFAOYSA-N 0.000 abstract description 3
125000001453 quaternary ammonium group Chemical group 0.000 abstract description 3
229920003180 amino resin Polymers 0.000 abstract 1
239000000243 solution Substances 0.000 description 13
239000000203 mixture Substances 0.000 description 11
230000007935 neutral effect Effects 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 7
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
239000002245 particle Substances 0.000 description 6
239000011148 porous material Substances 0.000 description 6
238000004537 pulping Methods 0.000 description 6
238000004132 cross linking Methods 0.000 description 5
238000005406 washing Methods 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
206010042674 Swelling Diseases 0.000 description 3
150000001720 carbohydrates Chemical class 0.000 description 3
235000014633 carbohydrates Nutrition 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
238000003756 stirring Methods 0.000 description 3
239000000126 substance Substances 0.000 description 3
230000008961 swelling Effects 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
239000011324 bead Substances 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
238000011110 re-filtration Methods 0.000 description 2
230000008929 regeneration Effects 0.000 description 2
238000011069 regeneration method Methods 0.000 description 2
239000011780 sodium chloride Substances 0.000 description 2
WEERVPDNCOGWJF-UHFFFAOYSA-N 1,4-bis(ethenyl)benzene Chemical compound C=CC1=CC=C(C=C)C=C1 WEERVPDNCOGWJF-UHFFFAOYSA-N 0.000 description 1
GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
239000004793 Polystyrene Substances 0.000 description 1
239000004372 Polyvinyl alcohol Substances 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
125000005037 alkyl phenyl group Chemical group 0.000 description 1
WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
239000001110 calcium chloride Substances 0.000 description 1
229910001628 calcium chloride Inorganic materials 0.000 description 1
239000001913 cellulose Substances 0.000 description 1
229920002678 cellulose Polymers 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
238000006482 condensation reaction Methods 0.000 description 1
239000006071 cream Substances 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
150000004985 diamines Chemical class 0.000 description 1
238000001035 drying Methods 0.000 description 1
229930182830 galactose Natural products 0.000 description 1
239000011521 glass Substances 0.000 description 1
229910001867 inorganic solvent Inorganic materials 0.000 description 1
239000003049 inorganic solvent Substances 0.000 description 1
239000008101 lactose Substances 0.000 description 1
KVKFRMCSXWQSNT-UHFFFAOYSA-N n,n'-dimethylethane-1,2-diamine Chemical compound CNCCNC KVKFRMCSXWQSNT-UHFFFAOYSA-N 0.000 description 1
229920000768 polyamine Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920002451 polyvinyl alcohol Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
239000000047 product Substances 0.000 description 1
230000000750 progressive effect Effects 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229920002050 silicone resin Polymers 0.000 description 1
239000002904 solvent Substances 0.000 description 1
238000005891 transamination reaction Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F30/00—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F30/04—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F30/06—Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing boron
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K13/00—Sugars not otherwise provided for in this class
- C13K13/005—Lactulose
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/08—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing boron
- C—CHEMISTRY; METALLURGY
- C13—SUGAR INDUSTRY
- C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
- C13K13/00—Sugars not otherwise provided for in this class

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Polymers & Plastics (AREA)
Medicinal Chemistry (AREA)
Health & Medical Sciences (AREA)
General Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
Developing Agents For Electrophotography (AREA)
Pens And Brushes (AREA)
Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

JP60055746A 1984-03-22 1985-03-22 高選択性吸収剤能力のある安定な硼素樹脂の製造方法 Granted JPS60217206A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
IT20177/84A IT1173459B (it)	1984-03-22	1984-03-22	Resine boroniche stabili ad elevato potere assorbente selettivo
IT20177A/84		1984-03-22

Publications (2)

Publication Number	Publication Date
JPS60217206A JPS60217206A (ja)	1985-10-30
JPH0323085B2 true JPH0323085B2 (de)	1991-03-28

Family

ID=11164447

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP60055746A Granted JPS60217206A (ja)	1984-03-22	1985-03-22	高選択性吸収剤能力のある安定な硼素樹脂の製造方法

Country Status (11)

Country	Link
US (2)	US4506036A (de)
EP (1)	EP0159521B1 (de)
JP (1)	JPS60217206A (de)
KR (1)	KR910008314B1 (de)
AT (1)	ATE31068T1 (de)
CA (1)	CA1202746A (de)
DE (1)	DE3561063D1 (de)
DK (1)	DK127585A (de)
GB (1)	GB2156356B (de)
IE (1)	IE57855B1 (de)
IT (1)	IT1173459B (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
IT1173459B (it) *	1984-03-22	1987-06-24	Sirac Spa	Resine boroniche stabili ad elevato potere assorbente selettivo
IT1215406B (it) *	1987-04-03	1990-02-08	Sirac Spa	Resine boroniche stabili di elevato poytere assorbente selettivo.
IT1215407B (it) *	1987-04-03	1990-02-08	Sirac Spa	Resine boroniche di elevato potere assorbente selettivo.
AU628674B2 (en) *	1989-10-19	1992-09-17	Nippon Oil And Fats Company, Limited	Polymer complexes of a sugar response type
IT1271449B (it) *	1993-04-28	1997-05-28	Inalco Spa	Procedimento per la preparazione di lattulosio cristallino da sciroppi commerciali
US6306959B1 (en) *	1996-05-03	2001-10-23	Warner Lambert Company	Rapid purification by polymer supported quench
US6171503B1 (en) *	1998-03-16	2001-01-09	Dalhousie University	Use of tetraphenyloborate for extraction of ammonium ions and amines from water
CN118725166B (zh) *	2024-07-31	2025-02-14	江苏海普功能材料有限公司	多羟基螯合树脂及其制备方法和除硼方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2834539A1 (de) *	1978-08-07	1980-02-21	Basf Ag	Makroporoese polymere als traegermaterial zur kovalenten bindung von proteinen
JPS5664657A (en) *	1979-11-01	1981-06-01	Asahi Chem Ind Co Ltd	Hydrophilic filler for chromatography
US4357311A (en) *	1980-10-03	1982-11-02	Warner-Lambert Company	Substrate for immunoassay and means of preparing same
IT1173459B (it) *	1984-03-22	1987-06-24	Sirac Spa	Resine boroniche stabili ad elevato potere assorbente selettivo

1984
- 1984-03-22 IT IT20177/84A patent/IT1173459B/it active
- 1984-07-16 US US06/631,104 patent/US4506036A/en not_active Expired - Fee Related
- 1984-07-17 GB GB08418208A patent/GB2156356B/en not_active Expired
- 1984-07-17 CA CA000459005A patent/CA1202746A/en not_active Expired
- 1984-12-26 US US06/686,272 patent/US4542161A/en not_active Expired - Lifetime
1985
- 1985-03-14 AT AT85102934T patent/ATE31068T1/de not_active IP Right Cessation
- 1985-03-14 EP EP85102934A patent/EP0159521B1/de not_active Expired
- 1985-03-14 IE IE660/85A patent/IE57855B1/en not_active IP Right Cessation
- 1985-03-14 DE DE8585102934T patent/DE3561063D1/de not_active Expired
- 1985-03-21 DK DK127585A patent/DK127585A/da not_active Application Discontinuation
- 1985-03-21 KR KR1019850001852A patent/KR910008314B1/ko not_active Expired
- 1985-03-22 JP JP60055746A patent/JPS60217206A/ja active Granted

Also Published As

Publication number	Publication date
GB8418208D0 (en)	1984-08-22
GB2156356B (en)	1987-06-10
EP0159521B1 (de)	1987-11-25
EP0159521A1 (de)	1985-10-30
US4542161A (en)	1985-09-17
GB2156356A (en)	1985-10-09
US4506036A (en)	1985-03-19
DK127585D0 (da)	1985-03-21
IE57855B1 (en)	1993-04-21
IE850660L (en)	1985-09-22
DE3561063D1 (en)	1988-01-07
JPS60217206A (ja)	1985-10-30
ATE31068T1 (de)	1987-12-15
CA1202746A (en)	1986-04-01
KR910008314B1 (ko)	1991-10-12
IT8420177A0 (it)	1984-03-22
IT1173459B (it)	1987-06-24
KR850006686A (ko)	1985-10-16
DK127585A (da)	1985-09-23

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