JPH03263473A - Corrosion-proof and moistureproof insulating coating composition and production of mounted circuit-board subjected to corrosion-proof and moistureproof insulation treatment - Google Patents

Corrosion-proof and moistureproof insulating coating composition and production of mounted circuit-board subjected to corrosion-proof and moistureproof insulation treatment

Info

Publication number
JPH03263473A
JPH03263473A JP23512790A JP23512790A JPH03263473A JP H03263473 A JPH03263473 A JP H03263473A JP 23512790 A JP23512790 A JP 23512790A JP 23512790 A JP23512790 A JP 23512790A JP H03263473 A JPH03263473 A JP H03263473A
Authority
JP
Japan
Prior art keywords
proof
corrosion
mounted circuit
moistureproof
triazole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP23512790A
Other languages
Japanese (ja)
Inventor
Masakatsu Obara
小原 正且
Eiji Omori
英二 大森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Resonac Corp
Original Assignee
Hitachi Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Chemical Co Ltd filed Critical Hitachi Chemical Co Ltd
Publication of JPH03263473A publication Critical patent/JPH03263473A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K3/00Apparatus or processes for manufacturing printed circuits
    • H05K3/22Secondary treatment of printed circuits
    • H05K3/28Applying non-metallic protective coatings

Landscapes

  • Paints Or Removers (AREA)

Abstract

PURPOSE:To obtain the subject composition capable of moistureproof insulation and prevention of corrosion and capable of providing a mounted circuit-board having an improved reliability by blending a (co)polymer of a specified alkyl (meth)acrylate and a specified amount of a triazole (derivative). CONSTITUTION:An objective composition containing (A) 100 pts.wt. (co)polymer of an alkyl (meth)acrylates such as butyl (meth)acrylate having 0-80 deg.C glass transition temperature and (B) 0.01-5 pts.wt. 1,2,4-triazole derivative such as benzotriazole, 1,2,4-triazole and/or 3-amino-1,2,4-triazole.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、防錆防湿絶縁塗料組成物および防錆防湿絶縁
処理された実装回路板の製造法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a rust-proofing, moisture-proofing insulating coating composition and a method for producing a mounted circuit board subjected to rust-proofing, moisture-proofing and insulation treatment.

(従来の技術) 従来、ガラス−エポキシ樹脂1紙−フェノール樹脂など
の積層板に配線図が印刷され、マイコン。
(Prior Art) Conventionally, wiring diagrams have been printed on a laminated board of glass, epoxy resin, paper, and phenol resin, etc., for microcontrollers.

抵抗体、コンデンサなどの各種電子部品が搭載された実
装回路板は、湿気、はこシなどから保護する目的で絶縁
処理が行われている。該絶縁処理方法には、アクリル樹
脂およびシリコーン樹脂を溶剤に溶解した防湿絶縁塗料
で保護コーティングする方法が広く採用されている。
Mounted circuit boards equipped with various electronic components such as resistors and capacitors are insulated to protect them from moisture and dust. As the insulation treatment method, a method of protective coating with a moisture-proof insulation paint made by dissolving acrylic resin and silicone resin in a solvent is widely adopted.

このような実装回路板は、過酷な環状下、特に高湿度下
で使用され1例えば自動車、洗濯機などの機器に搭載さ
れて使用される。
Such a mounted circuit board is used under harsh conditions, particularly under high humidity conditions, and is mounted on equipment such as automobiles and washing machines.

(発明が解決しようとする課題) しかしながら、従来の実装回路板用防湿絶縁塗料組成物
は、搭載電子部品のリード線の防湿絶縁及び補強には有
効であったが塩害及び硫化水素ガス、亜硫酸ガス等のガ
スに対する防錆効果が低く。
(Problems to be Solved by the Invention) However, although conventional moisture-proof insulating paint compositions for mounted circuit boards are effective for moisture-proof insulation and reinforcement of lead wires of mounted electronic components, they do not suffer from salt damage and hydrogen sulfide gas, sulfur dioxide gas. It has low rust prevention effect against gases such as.

実装回路板の金属面が腐食する問題があった。There was a problem that the metal surface of the mounted circuit board corroded.

本発BAh、  このような従来技術の欠点を改良して
、信頼性の高い実装回路板を得ることができる防錆防湿
絶縁塗料組成物およびこノ“1.を用いた防錆防湿絶縁
処理された実装回路板の製造法を提供することにある。
The present BAh is a rust-proof and moisture-proof insulating coating composition that can improve the shortcomings of the conventional technology and obtain a highly reliable mounted circuit board, and a rust-proof and moisture-proof insulation treatment using this "1." An object of the present invention is to provide a method for manufacturing a mounted circuit board.

(課題を解決−するだめの手段) 本発明け、 A)ガラス転移点が0−SO℃の″アクリ
ル酸のアルキルエステル及び/又はメタクリル酸のアル
ギルニスデルの重合体又はとれらの共重合体を100重
葉部ならびに13)ベンゾh IJアゾール、1,2,
4−トリアゾールおよび1.λ4−トリアゾール誘導体
からなる群から選ばノ′する少なくとも】種類を0.0
1〜5重量部含む防錆防湿絶縁塗料組成物さらにこの防
錆防湿絶縁塗料組成物で、実装回路板を塗装処理シフ、
乾燥させる防錆防湿絶縁処理された実装回路板の製造法
に関する。
(Solving the Problem - Means to Solve the Problem) The present invention provides: A) A polymer of acrylic acid alkyl ester and/or methacrylic acid argylnisder or a copolymer thereof having a glass transition point of 0-SO°C. heavy leaf part and 13) benzo h IJ azole, 1,2,
4-triazole and 1. λ4-triazole derivatives selected from the group consisting of at least 0.0
A rust-preventing, moisture-proofing insulating paint composition containing 1 to 5 parts by weight.
The present invention relates to a method for producing a mounted circuit board that is dried and subjected to rust-proofing, moisture-proofing and insulation treatment.

本発明におけるA)成分のガラス転移点<Tg)が0〜
80℃の上記の重合体又は共重合体は公知の重合体であ
り、既に知られた方法で製造されるものである。
The glass transition point <Tg) of component A) in the present invention is from 0 to
The above-mentioned polymer or copolymer at 80° C. is a known polymer and can be produced by a known method.

゛アクリル酸のアルキルエステル及びメタクリル酸のア
ルギルエステルとしでは1例えば゛アクリル酸メチル、
アクリル酸1丁プル、アクリル酸ブチル。
Examples of the alkyl esters of acrylic acid and the algyl esters of methacrylic acid include methyl acrylate,
1 block of acrylic acid, butyl acrylate.

メタクリル酸メザル、メタクリル酸丁チル、メタクリル
酸ブグル等があげられるがこれらに制限されるものでは
ない。アクリル酸のアルキルニスデルとメタクリル酸の
アルギルニスデルとの共重合体も用いられる。アクリル
酸の”アルキルニスカル又はメタクリル酸の′アルキル
エステルの重合体又はこれらの共重合体のガラス転移点
が0℃未満であると乾燥後にべたつきが残シ、まfc、
80℃を越えると塗膜が硬くなり、剥離やクラックが生
じやすくなる。好ましいガラス転移点は5〜30℃の範
囲とされる。
Examples include, but are not limited to, mesal methacrylate, clotyl methacrylate, and bugul methacrylate. Copolymers of alkyl nisder of acrylic acid and argyl nisder of methacrylic acid are also used. If the glass transition point of the alkyl ester of acrylic acid or the alkyl ester of methacrylic acid or a copolymer thereof is lower than 0°C, stickiness may remain after drying.
When the temperature exceeds 80°C, the coating film becomes hard and peels and cracks easily occur. A preferable glass transition point is in the range of 5 to 30°C.

本発明のB)成分の1.2.4−1!Jアゾ一ル誘導体
としては、−形式(1) (fr、だし、R,およびR′は水素または−NH2で
あり。
1.2.4-1 of B) component of the present invention! As the J azoyl derivative, -Form (1) (fr, dashi, R, and R' are hydrogen or -NH2.

1(と1t′は同一・でも異ってもよい。ただしRおよ
びR′が共に水素である場合を除く)であられされる化
合物であり、3−アミノ−1,2,4,−トリアゾール
、3,5.−ジ′γミノ−1,2,4−トリアゾール等
がある。
1 (and 1t' may be the same or different, except when R and R' are both hydrogen), and 3-amino-1,2,4-triazole, 3,5. -di'γmino-1,2,4-triazole and the like.

上記A)成分とB)成分との配合比は、A)成分100
重量部に対してB)成分が0401〜5重量部とされ。
The blending ratio of the above A) component and B) component is 100% of A) component.
The amount of component B) is 0401 to 5 parts by weight.

B)成分は好まし、<j’10.05〜3重量部とされ
る。
Component B) is preferably <j'10.05 to 3 parts by weight.

B)成分が0゜01重量部未満では防錆効果が少なく。If component B) is less than 0.01 parts by weight, the antirust effect will be low.

5重量部を越えると効果はあオ勺かわらない。If it exceeds 5 parts by weight, the effect will not change.

本発明になる防錆防湿絶縁塗料組成物は、トルエン、ギ
シレンなどの芳香族系溶剤、酢酸エチル。
The rust-proofing and moisture-proofing insulating coating composition according to the present invention uses aromatic solvents such as toluene and pyclene, and ethyl acetate.

酢酸ブチルなどのエステル系溶剤、メチルエチルケトン
、アセトンなどのケトン系溶剤等の溶剤。
Solvents such as ester solvents such as butyl acetate, ketone solvents such as methyl ethyl ketone and acetone.

顔料、染料などを必要に応じて含有[7てもよい。Pigments, dyes, etc. may be contained as necessary [7].

上記の溶剤等の成分は、塗料組成物に通常用いられる量
で用いられ、その使用量には特に制限はない。
The above-mentioned components such as the solvent are used in amounts normally used in coating compositions, and there are no particular restrictions on the amounts used.

防錆防湿絶縁処理された実装回路板は1本発明の前記塗
料組成物を実装回路板に、)・ケ塗り、浸漬、スブt・
・−などの塗布方法で塗布シフ、常温であへ るいは加熱し7て乾燥することにより得られる。
The mounted circuit board that has been subjected to rust-proofing and moisture-proofing insulation treatment is prepared by applying the coating composition of the present invention to the mounting circuit board by coating, dipping, or substituting.
It can be obtained by applying a coating method such as ・- or by heating and drying at room temperature.

(実施例) 次に本発明を実施例によりさらに詳j〜〈説明するが1
本発明はこれらに制限されるものではない。
(Example) Next, the present invention will be explained in more detail with reference to Examples.
The present invention is not limited to these.

なお1部、チとあるのは重葉部1重量%である。Note that 1 part and 1 are 1% by weight of the heavy leaf part.

実施例 アクリル重合体の合成 メタクリル酸ブチル214部、アクリル酸ブチル25部
およびトルエン150部を11の四つロセバラブルフラ
スコに仕込み窒素ガスを通しながら90℃まで昇温し保
温する。これにメタクリル酸ブチル200部、アクリル
酸ブチル21部、アゾビスインブチロニトリル3部を混
合溶解して溶液を2時間で滴下しながら重合を進める。
Example Synthesis of Acrylic Polymer 214 parts of butyl methacrylate, 25 parts of butyl acrylate and 150 parts of toluene were placed in a four-piece rosemovable flask (No. 11), heated to 90° C. and maintained while passing nitrogen gas. 200 parts of butyl methacrylate, 21 parts of butyl acrylate, and 3 parts of azobisin butyronitrile were mixed and dissolved in this, and the solution was added dropwise over 2 hours to proceed with polymerization.

その後110℃に昇温し、2時間保温し1重合を完了さ
せた後冷却し50℃になったらトルエン200部を仕込
み10分間攪拌し均一溶液とした。
Thereafter, the temperature was raised to 110°C, maintained for 2 hours to complete one polymerization, and then cooled. When the temperature reached 50°C, 200 parts of toluene was added and stirred for 10 minutes to form a homogeneous solution.

この溶液を用いて25μのフィルムを作りガラス転移点
(Tg )をTMS f熱的物理試験機)のペネトレー
ション法により測定したところ12℃で6 あった。
A 25μ film was made using this solution and its glass transition point (Tg) was measured at 12°C by the penetration method using a TMS (thermal physical tester).

表IK示す実施例1,2.3および比較例1゜2の配合
(数字の単位は部である)で防錆防湿絶縁塗料組成物を
得、これにガラスエポキシ鋼張積層板に配線図が印刷さ
れ、IC,コンデンサなどの各種電子部品が搭載された
実装回路板を各2枚浸漬塗布して50℃で1時間乾燥さ
せた。その後。
A rust-proof and moisture-proof insulating paint composition was obtained using the formulations of Examples 1, 2.3 and Comparative Example 1゜2 (numbers are in parts) shown in Table IK, and a wiring diagram was applied to a glass-epoxy steel-clad laminate. Two printed printed circuit boards each equipped with various electronic components such as ICs and capacitors were dip-coated and dried at 50° C. for 1 hour. after that.

各1枚の防錆防湿絶縁処理された実装回路板を5チ塩化
す) IJウム水溶液が入っている温度35℃雰囲気の
デシケータ内に放置し表に示す時間経過後に実装回路板
の組成物を通して観察される銅の回路部の錆の発生状態
を肉眼で観察した。また。
Each one of the mounted circuit boards treated with anti-rust and moisture-proof insulation was left in a desiccator containing an IJium aqueous solution at a temperature of 35°C, and after the time shown in the table had passed, the composition of the mounted circuit board was passed through. The state of rust on the observed copper circuit was observed with the naked eye. Also.

もう1枚の防錆防湿絶縁処理された実装回路板を硫化水
素ガスの濃度が100 ppmに設定された25℃の雰
囲気のデシケータ内に放置し表に示す時間経過後に実装
回路板の組成物を通して観察される銅の回路部の錆の発
生状態を肉眼で観察した。
Another mounted circuit board treated with anti-rust and moisture-proof insulation was left in a desiccator in an atmosphere at 25°C with a hydrogen sulfide gas concentration of 100 ppm, and after the time shown in the table had passed, the composition of the mounted circuit board was passed through. The state of rust on the observed copper circuit was observed with the naked eye.

表1 *1 錆発生状態二〇錆発生なし △錆一部発生 ×錆全面発生 *2 無処理の実装回路板を用いた。Table 1 *1 Rust occurrence status 20 No rust occurrence △Some rust occurs × Rust occurs all over *2 An untreated mounted circuit board was used.

(発明の効果) 本発明になる防錆防湿絶縁塗料組成物によシ。(Effect of the invention) According to the rust-proofing and moisture-proofing insulating coating composition of the present invention.

実装回路板の防湿絶縁と共に錆の発生を防止でき。It can prevent the occurrence of rust along with moisture-proof insulation of the mounted circuit board.

信頼性が向上された実装回路板を得ることができ7−A mounted circuit board with improved reliability can be obtained7-

Claims (1)

【特許請求の範囲】 1、A)ガラス転移点が0〜80℃のアクリル酸のアル
キルエステル及び/又はメタクリル酸のアルキルエステ
ルの重合体又はこれらの共重合体を100重量部ならび
にB)ベンゾトリアゾール、1,2,4−トリアゾール
および1,2,4−トリアゾール誘導体からなる群から
選ばれる少なくとも1種類を0.01〜5重量部含む防
錆防湿絶縁塗料組成物。 2、請求項1記載の防錆防湿絶縁塗料組成物で実装回路
板を塗装処理し、乾燥させることを特徴とする防錆防湿
絶縁処理された実装回路板の製造法。
[Claims] 1. A) 100 parts by weight of a polymer of an alkyl ester of acrylic acid and/or an alkyl ester of methacrylic acid having a glass transition point of 0 to 80°C, or a copolymer thereof, and B) benzotriazole. , 1,2,4-triazole and 1,2,4-triazole derivatives in an amount of 0.01 to 5 parts by weight of at least one member selected from the group consisting of 1,2,4-triazole and 1,2,4-triazole derivatives. 2. A method for producing a mounted circuit board subjected to a rust-proofing, moisture-proofing and insulation treatment, which comprises painting the mounted circuit board with the rust-proofing and moisture-proofing insulating coating composition according to claim 1, and drying the coated circuit board.
JP23512790A 1990-02-02 1990-09-05 Corrosion-proof and moistureproof insulating coating composition and production of mounted circuit-board subjected to corrosion-proof and moistureproof insulation treatment Pending JPH03263473A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2465590 1990-02-02
JP2-24655 1990-02-02

Publications (1)

Publication Number Publication Date
JPH03263473A true JPH03263473A (en) 1991-11-22

Family

ID=12144161

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23512790A Pending JPH03263473A (en) 1990-02-02 1990-09-05 Corrosion-proof and moistureproof insulating coating composition and production of mounted circuit-board subjected to corrosion-proof and moistureproof insulation treatment

Country Status (1)

Country Link
JP (1) JPH03263473A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018009108A (en) * 2016-07-14 2018-01-18 ユケン工業株式会社 Anti-corrosion coating solution

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5247032A (en) * 1975-10-11 1977-04-14 Mitsubishi Monsanto Chem Co Synthetic resin composition for coating metal
JPS5824270A (en) * 1981-08-05 1983-02-14 Canon Inc Electrophotographing device
JPS59171646A (en) * 1983-03-19 1984-09-28 住友金属工業株式会社 Temporary rust-prevention treated steel pipe
JPS6067681A (en) * 1983-09-20 1985-04-18 Sumitomo Chem Co Ltd Corrosion-proof method of prestressed concrete
JPS60219268A (en) * 1984-04-14 1985-11-01 Denki Kagaku Kogyo Kk Coating resin composition and coating method
JPS60260662A (en) * 1984-06-08 1985-12-23 Toagosei Chem Ind Co Ltd Corrosion-preventive composition
JPS61223061A (en) * 1985-03-28 1986-10-03 Japan Exlan Co Ltd Aqueous antifouline coating compound
JPS62236872A (en) * 1986-04-08 1987-10-16 Hitachi Chem Co Ltd Rust-rpeventive and moistureproof insulating coating composition for metallic circuit board
JPS6339969A (en) * 1986-08-02 1988-02-20 Aisin Chem Co Ltd Acrylic baking paint composition
JPS63199772A (en) * 1987-02-17 1988-08-18 Toagosei Chem Ind Co Ltd Corrosion-preventive composition
JPH01172472A (en) * 1987-12-28 1989-07-07 Nippon Paint Co Ltd Coating-type chromate film treating agent

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5247032A (en) * 1975-10-11 1977-04-14 Mitsubishi Monsanto Chem Co Synthetic resin composition for coating metal
JPS5824270A (en) * 1981-08-05 1983-02-14 Canon Inc Electrophotographing device
JPS59171646A (en) * 1983-03-19 1984-09-28 住友金属工業株式会社 Temporary rust-prevention treated steel pipe
JPS6067681A (en) * 1983-09-20 1985-04-18 Sumitomo Chem Co Ltd Corrosion-proof method of prestressed concrete
JPS60219268A (en) * 1984-04-14 1985-11-01 Denki Kagaku Kogyo Kk Coating resin composition and coating method
JPS60260662A (en) * 1984-06-08 1985-12-23 Toagosei Chem Ind Co Ltd Corrosion-preventive composition
JPS61223061A (en) * 1985-03-28 1986-10-03 Japan Exlan Co Ltd Aqueous antifouline coating compound
JPS62236872A (en) * 1986-04-08 1987-10-16 Hitachi Chem Co Ltd Rust-rpeventive and moistureproof insulating coating composition for metallic circuit board
JPS6339969A (en) * 1986-08-02 1988-02-20 Aisin Chem Co Ltd Acrylic baking paint composition
JPS63199772A (en) * 1987-02-17 1988-08-18 Toagosei Chem Ind Co Ltd Corrosion-preventive composition
JPH01172472A (en) * 1987-12-28 1989-07-07 Nippon Paint Co Ltd Coating-type chromate film treating agent

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2018009108A (en) * 2016-07-14 2018-01-18 ユケン工業株式会社 Anti-corrosion coating solution

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