JPH0383836A - Ink for patterning and article patterned using the same ink - Google Patents
Ink for patterning and article patterned using the same inkInfo
- Publication number
- JPH0383836A JPH0383836A JP21947189A JP21947189A JPH0383836A JP H0383836 A JPH0383836 A JP H0383836A JP 21947189 A JP21947189 A JP 21947189A JP 21947189 A JP21947189 A JP 21947189A JP H0383836 A JPH0383836 A JP H0383836A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- phosphate
- patterning
- patterned
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000059 patterning Methods 0.000 title claims abstract description 10
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 8
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 7
- 239000010452 phosphate Substances 0.000 claims abstract description 7
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 claims abstract description 6
- -1 phosphate compound Chemical class 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 9
- 239000003513 alkali Substances 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 3
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract description 2
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract description 2
- 229910000403 monosodium phosphate Inorganic materials 0.000 abstract description 2
- 235000019799 monosodium phosphate Nutrition 0.000 abstract description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 abstract description 2
- 239000001488 sodium phosphate Substances 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 235000010216 calcium carbonate Nutrition 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 239000011369 resultant mixture Substances 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 23
- 229910052782 aluminium Inorganic materials 0.000 description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 11
- 230000007423 decrease Effects 0.000 description 10
- 239000002253 acid Substances 0.000 description 8
- 238000002844 melting Methods 0.000 description 8
- 230000008018 melting Effects 0.000 description 8
- 210000003298 dental enamel Anatomy 0.000 description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- 235000014692 zinc oxide Nutrition 0.000 description 3
- 239000000654 additive Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 238000007667 floating Methods 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000005355 lead glass Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000005365 phosphate glass Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 101100348017 Drosophila melanogaster Nazo gene Proteins 0.000 description 1
- 229910001323 Li2O2 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 235000011008 sodium phosphates Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229910000404 tripotassium phosphate Inorganic materials 0.000 description 1
- 235000019798 tripotassium phosphate Nutrition 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 239000010913 used oil Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000004017 vitrification Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
- C03C8/08—Frit compositions, i.e. in a powdered or comminuted form containing phosphorus
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はアルミニウムはうろう製品等への模様付けに好
適な、低温焼付けの可能な模様付は用インク及びこれに
より模様付けされた製品に関するものである。Detailed Description of the Invention (Industrial Application Field) The present invention relates to a patterning ink that can be baked at low temperatures and is suitable for patterning aluminum products, etc., and to products patterned with the same. It is something.
（従来の技術）
建築用パネル、家庭用器物等に用いられているアルミニ
ウムはうろう製品に対して模様付けを行う場合、材料の
アルミニウムが６２０°Ｃで軟化溶融するため、これ以
下の温度で有機塗料やほうろうを焼きつける方法を取る
必要がある。しかし有機塗料では固さや耐候性が悪く、
応用範囲が限定されている。またアルミニウムはうろう
製品に対してほうろうによる模様付けを行う場合には低
融点の鉛ガラス系の有鉛はうろうが用いられており、５
０〜９０％のｐｂｏを含有するために家庭用器物等につ
いては食品衛生法による規制がある。一方建材分野につ
いては法的規制はないもののＰｂＯの含有率が高いため
に焼付は時に発色が著しく制約され、高明度、高彩度の
発色が得られずくすんだ色になってしまう欠点がある。(Prior art) When applying patterns to aluminum products used in construction panels, household utensils, etc., the aluminum material softens and melts at 620°C, so it cannot be used at temperatures below this temperature. It is necessary to use a method of baking organic paint or enamel. However, organic paints have poor hardness and weather resistance.
The scope of application is limited. In addition, when applying patterns to products using enamel, enamel, which is made of lead glass with a low melting point, is used.
Household utensils and the like are regulated by the Food Sanitation Law because they contain 0 to 90% PBO. On the other hand, in the field of building materials, although there are no legal regulations, due to the high content of PbO, color development is sometimes severely restricted by baking, resulting in dull colors without being able to obtain high brightness and high chroma color development.
このように発色がくすんでしまう原因は、フリット粉末
と顔料とをスクリーンオイルで混練してスクリーン印刷
用のインクとしたとき、約５００℃でスクリーンオイル
からの炭素の昇華とフリットの軟化溶融とがほぼ同時に
起こり、はうろう中に炭素が吸蔵されてしまい黒ずむた
めと考えられる。The reason why the color becomes dull is that when frit powder and pigment are kneaded with screen oil to make screen printing ink, carbon sublimes from the screen oil and the frit softens and melts at about 500°C. This occurs almost simultaneously and is thought to be due to carbon being absorbed in the wax and turning dark.
（発明が解決しようとする課題）
本発明は上記したような従来の問題を解決して、アルミ
ニウムはうろう製品等に対して６２０°Ｃ以下の低温で
焼付けができ、食品衛生法上の問題がなく、しかも黒ず
みのない鮮明な発色が得られる模様付は用インク及びこ
れにより模様付けされた製品を提供するために完成され
たものである。(Problems to be Solved by the Invention) The present invention solves the above-mentioned conventional problems. Aluminum can be baked at a low temperature of 620°C or less for products such as aluminum, and does not meet the problems under the Food Sanitation Law. This ink has been completed to provide a patterned ink that provides clear color development without dark spots and to provide products patterned with the ink.
（課題を解決するための手段）
上記の課題を解決するための本発明は、重量％でＰｚＯ
ｓ ３０〜７０％、＾１ｔ（１＋ ３〜２０％、Ｎ
ａ２Ｏ ５〜２０％、にｚｏ３〜１０％、Ｌｉｔｏ
３〜１０％、ＺｎＯ３〜１５％、ｒｔｏｔ ３〜１５
％、Ｂ意０３ １〜１０％、ＢａＯ１〜１０％の組成の
リン酸系のフリット１００重量部とこれに対して外配添
加された２〜８重量部のリン酸アルカリ化合物あるいは
アルカリ土類金属酸化物とからなり、水性インクとして
の性質を持つことを特徴とする１１！１付は用インクと
、これを用いて模様付けされた製品とを要旨とするもの
である。(Means for Solving the Problems) The present invention for solving the above problems is based on PzO
s 30-70%, ^1t(1+ 3-20%, N
a2O 5-20%, Nizo3-10%, Lito
3-10%, ZnO3-15%, rtot 3-15
%, Bi03 1-10%, 100 parts by weight of a phosphoric acid frit having a composition of 1-10% BaO and 2-8 parts by weight of an alkali phosphate compound or an alkaline earth metal externally added thereto. 11!1, which is composed of oxides and has the properties of an aqueous ink, and products patterned using the ink.
このように本発明の第１の特徴は、通常使用されている
ＰｂＯを多量に含有する鉛ガラス系のフリットに代えて
、ＰｔＯｓを主成分とする上記組成のリン酸ガラス系の
フリットを用いたことである。このリン酸ガラス系のフ
リットは低融点でアルミニウムと熱膨脹係数が近く、ま
たＰｂＯを含有しないので食品衛生法上の規制を受ける
ことがない。As described above, the first feature of the present invention is that instead of the normally used lead glass frit containing a large amount of PbO, a phosphate glass frit with the above composition containing PtOs as a main component is used. That's true. This phosphate glass frit has a low melting point, a coefficient of thermal expansion close to that of aluminum, and does not contain PbO, so it is not subject to regulations under the Food Sanitation Act.
なお、各成分の数（ｉ１＠定の理由は次の通りであり、
この点は後述する実施例４のデータからも明らかである
。In addition, the reason for the number of each component (i1 @ constant is as follows,
This point is also clear from the data of Example 4, which will be described later.
まずＰ２Ｏ．が３０％未満であると低温溶融が不可能と
なり、逆に７０％を越えると耐酸性、耐候性が低下する
。ＡｌｚＯｓは３％未満であるとやはり耐酸性、耐候性
が低下し、２０％を越えると低温溶融が不可能となる。First, P2O. If it is less than 30%, low-temperature melting will be impossible, and if it exceeds 70%, acid resistance and weather resistance will decrease. If AlzOs is less than 3%, the acid resistance and weather resistance will deteriorate, and if it exceeds 20%, low-temperature melting will be impossible.
Ｎａ２Ｏ１ＫｚＯ、ＬｉｚＯが数値限定範囲より不足
すると溶融性、密着性が低下し、逆に多すぎると溶融性
のみならず耐酸性、耐候性も低下する。 ＺｎＯが５％
未満であると硬度が低下し、１５％を越えると溶融性、
耐酸性等が低下する。 ＴｉＯ□が３％未満であると耐
酸性、耐候性が低下し、１５％を越えると溶融性が低下
する。 ８１０３が１％未満となると密着性が低下し、
１０％を越えると耐酸性、耐候性が低下する。ＢａＯが
１％未満となると密着性が低下し、１０％を越えると溶
融性が著しく低下する。If the amount of Na2O1KzO or LizO is less than the numerically limited range, the meltability and adhesion will decrease, and if it is too much, not only the meltability but also the acid resistance and weather resistance will decrease. 5% ZnO
If it is less than 15%, the hardness will decrease, and if it exceeds 15%, it will be meltable.
Acid resistance etc. decrease. If TiO□ is less than 3%, acid resistance and weather resistance will decrease, and if it exceeds 15%, meltability will decrease. When 8103 is less than 1%, adhesion decreases,
If it exceeds 10%, acid resistance and weather resistance will decrease. If BaO is less than 1%, the adhesion will decrease, and if it exceeds 10%, the meltability will be significantly decreased.
次に本発明の第２の重要な特徴は、通常用いられている
スクリーンオイルを含む油性のインクに代えて、水性イ
ンクとしたことである。このためにリン酸系のフリット
１００重量部に対して、リン酸アルカリ化合物又はアル
カリ土類金属酸化物を２〜８重量部外配添加し、湿式粉
砕することによりフリットｍ酸中のリン酸成分のイオン
化又はアルカリ成分のイオン化を行わせ、外配添加のリ
ン酸アルカリ化合物やアルカリ土類金属酸化物と水和反
応を生ずるようにして水性インク化を可能とした。ここ
でリン酸アルカリ化合物としてはリン酸ナトリウム、リ
ン酸カリウム、リン酸カルシウム等が代表的なものであ
り、アルカリ土類金属酸化物としては亜鉛華、炭酸カル
シウム等が代表的なものである。Next, the second important feature of the present invention is that a water-based ink is used instead of the normally used oil-based ink containing screen oil. For this purpose, 2 to 8 parts by weight of an alkali phosphate compound or an alkaline earth metal oxide are added to 100 parts by weight of a phosphoric acid-based frit, and the phosphoric acid component in the frit m-acid is wet-pulverized. or ionization of the alkali component to cause a hydration reaction with the externally added alkali phosphate compound or alkaline earth metal oxide, making it possible to create a water-based ink. Here, representative alkali phosphate compounds include sodium phosphate, potassium phosphate, calcium phosphate, etc., and representative alkaline earth metal oxides include zinc white, calcium carbonate, etc.
なおこれらの外配添加量が２％未満では印刷部分が流れ
て印刷の境界部にインクかにじむ現象が生じ易くなり、
逆に添加量が５％を越えると印刷後にインクのレベリン
グが働かず孔が空くピンホール現象が生じ易くなる。Note that if the amount of these external additives is less than 2%, the printed area tends to flow and the ink bleeds at the printing boundary.
On the other hand, if the amount added exceeds 5%, the leveling of the ink will not work after printing and the pinhole phenomenon will likely occur.
以下に本発明の実施例を示す。Examples of the present invention are shown below.
（実施例）
実施例１−アルミニウムはうろう鍋への模様付けｐｉｏ
ｓ ６５％、Ａ１１ａｓ ３％、Ｎａｚｏ １０％
、Ｋ２Ｏ５％、Ｌｉｔｏ ３％、Ｚｎ０７％、Ｔｉ１
ｔ ４％、Ｂ＋＋（ｈ ２％、Ｂａ０ １％の組成の
リン酸系フリット１００重量部に、リン酸二水素ナトリ
ウム５重量部、亜鉛華１重量部、水分６０重量部を外配
添加し、ボールミルにて粉砕して簡便粒度で２００メツ
シユアンダー０．１ｇに調製した。このようにして得ら
れたインクは水和反応が進みゲル状の性状を示した。こ
の水性インクをシルクスクリーン法によりアル２ニウム
はうろう鍋へ印刷し、１００°ＣＸ２分の乾燥後に５２
０’ＣＸ１０分の焼付けを行い、はうろう模様付けされ
たアルミニウムはうろう鍋を得た。印刷面はにじみやピ
ンホールがなく、美しい鮮明な発色が得られた。(Example) Example 1 - Patterning on an aluminum pot
s 65%, A11as 3%, Nazo 10%
, K2O5%, Lito 3%, Zn07%, Ti1
To 100 parts by weight of a phosphoric acid frit having a composition of t 4%, B++ (h 2%, Ba0 1%), 5 parts by weight of sodium dihydrogen phosphate, 1 part by weight of zinc white, and 60 parts by weight of water were externally added, It was pulverized in a ball mill to obtain a particle size of 200 mesh under 0.1 g.The ink thus obtained underwent a hydration reaction and exhibited gel-like properties.This aqueous ink was processed by silk screen method. Al2nium is printed on a pot, and after drying at 100°C for 2 minutes,
Baking was carried out at 0'CX for 10 minutes to obtain a floating aluminum pot with a floating pattern. The printed surface had no bleeding or pinholes, and beautiful, clear colors were obtained.
実施例２−ガラスびんへの模様付け
Ｐ２Ｏ５５０％、Ａ１１１０３５％、Ｎａ２Ｏ ８％、
Ｋ２Ｏ３％、Ｌｉ２Ｏ ３％、Ｚｎ０１０％、Ｔｉｅ！
ｌＱ％、Ｂｔｕｓ ５％、Ｂａ０４％の組成のリン酸系
フリット１００重量部に、リン酸三カリウム１０重量部
と水分６０重量部を外配添加し、ボールミルにて粉砕し
簡便粒度で２００メツシュアンダー０．５８にｌｉ＆！
して水性インクを得た。この水性インクを曲面印刷ので
きるシルクスクリーン印刷機によりガラスびんの表面に
印刷し、１００″ＣＸ５分の乾燥後に５５０℃×１０分
の焼付けを行った。印刷面は鮮明でにじみやピンホール
のない美しい発色が得られた。Example 2 - Patterning on glass bottles P2O 550%, A111035%, Na2O 8%,
K2O3%, Li2O 3%, Zn010%, Tie!
10 parts by weight of tripotassium phosphate and 60 parts by weight of water were externally added to 100 parts by weight of a phosphoric acid frit having a composition of lQ%, Btus 5%, and Ba 04%, and the mixture was ground in a ball mill to give a convenient particle size of 200 mesh. Li&! under 0.58!
A water-based ink was obtained. This water-based ink was printed on the surface of a glass bottle using a silk screen printer capable of printing on curved surfaces, and after drying at 100"C for 5 minutes, it was baked at 550℃ for 10 minutes.The printed surface was clear and free of smudges and pinholes. Beautiful color development was obtained.
実施例３−鉄はうろう板への模様付け
ｐｉｏｓ ５５％、Ａｌｔｏｓ ４％、ＮａｇＯ９％
、Ｋｉｏ ５％、Ｌｉ２Ｏ２％、ＺｎＯ８％、ＴＮＯｘ
５％、Ｂｔｕｓ ５％、Ｂａ０７％の組成のリン酸系
フリット１００重量部に対して、炭酸カルシウム５重量
部、顔料１０重量部、水分６０重量部を外配添加し、ボ
ール藁ルにて粉砕し２００メツシュアンダー０．３ｇに
調製して水性インクを得た。この水性インクを用いて１
２００ Ｘ ２４００ｎｍ＋の鉄はうろう板上の全面に
シルクスクリーン法により点絵柄を印刷し、２００℃×
２分の乾燥後に５４０°ＣＸ５分の焼付けを行った。印
刷面は鮮明でにじみやピンホールのない美しい発色が得
られた。Example 3 - Patterning on iron board Pios 55%, Altos 4%, NagO 9%
, Kio 5%, Li2O2%, ZnO8%, TNOx
5% Btus, 5% Btus, and 100 parts by weight of a phosphoric acid frit with a composition of 07% Ba, 5 parts by weight of calcium carbonate, 10 parts by weight of pigment, and 60 parts by weight of water were added externally, and the mixture was ground in a ball straw mill. Then, 0.3 g of 200 mesh under was prepared to obtain a water-based ink. 1 using this water-based ink
200 x 2400 nm+ iron is printed with a dot pattern on the entire surface of the plate using the silk screen method, and heated at 200°C x
After drying for 2 minutes, baking was performed at 540° C. for 5 minutes. The printed surface was clear and had beautiful colors with no bleeding or pinholes.
実施例４−アルミニウムはうろう仮への模様付は表１に
示される各組成のインクを実施例１と同様の方法で作成
し、板厚０．４ ａｍのアルミニウムはうろう板へスク
リーン印刷後に５２０°ＣＸ３分の焼付けを行った。各
はうろう性能及び印刷性能を調査した結果を表２に示す
。なお外配添加物は試薬１級品である。またほうろう性
能の判定は次の基準に拠った。Example 4 - Patterning on an aluminum plate was created using inks of each composition shown in Table 1 in the same manner as in Example 1, and screen printing was performed on an aluminum plate with a thickness of 0.4 am. Afterwards, baking was performed at 520°C for 3 minutes. Table 2 shows the results of investigating the drift performance and printing performance of each. The external additives are first grade reagents. Furthermore, the evaluation of enamel performance was based on the following criteria.
溶は状態；目視観察にてほうろうガラス化状態を判定し
、溶融を０１反溶融をΔ、不溶を×とした。Melting is a state; the state of enamel vitrification was determined by visual observation, and melting was given as 0, non-melting was given as Δ, and non-melting was given as ×.
耐酸性： ＪＩＳ Ｒ４３０１５，９項により、１０％
クエン酸の１５分スポットテストを行った。変化なしを
Ａ、変化ありをＢとした。Acid resistance: 10% according to JIS R43015, Section 9
A 15 minute spot test of citric acid was performed. No change was rated A, and change was rated B.
密着性： ＪＩＳ Ｒ４３０１５，５項により２００ｇ
の鋼球を４５ｃｍの高さからほうろう表面に落下させ、
剥離ありをＡ、剥離なしをＢとした。Adhesion: 200g according to JIS R43015, Section 5
A steel ball is dropped from a height of 45 cm onto the enamel surface,
The sample with peeling was graded A, and the sample with no peeling was graded B.
ウェザ−メータ； ＪＩＳ Ｋ ５４００により紫外線
による促進試験を行った。変化なしをＡ、変化ありをＢ
とした。Weather meter: An accelerated test using ultraviolet rays was conducted according to JIS K 5400. A for no change, B for change
And so.
硬度：モース硬度計により測定した。Hardness: Measured using a Mohs hardness meter.
（発明の効果）
本発明は以上に説明したように、有鉛フリットを使用し
ないのでガラス食器、陶磁器製食器等へのほうろうによ
る模様付けを可能としたもので、しかも従来のインクに
比較して１００℃程度も焼付は温度を下げることができ
るので、アルミニウムはうろうへの模様付けに適し、低
温焼付による経済的なメリットも大である。また本発明
のインクはスクリーンオイルを用いないので、作業環境
が良化し、また炭素による印刷面の黒ずみ現象がなくな
り生命な発色を得ることができる。更に本発明のインク
によればスクリーン印刷が可能となり、従来のスプレー
塗布の場合には約５０％の釉薬がロスとなっていたのに
対し、インクのロスをゼロとすることができる。(Effects of the Invention) As explained above, the present invention does not use leaded frit, so it is possible to apply patterns on glass tableware, ceramic tableware, etc. using enamel. Since baking can lower the temperature by as much as 100 degrees Celsius, aluminum is suitable for adding patterns to hollows, and low-temperature baking has great economic benefits. Furthermore, since the ink of the present invention does not use screen oil, the working environment is improved, and the phenomenon of darkening of the printed surface due to carbon is eliminated, making it possible to obtain vivid color development. Furthermore, the ink of the present invention enables screen printing, and can reduce ink loss to zero, whereas in conventional spray coating, approximately 50% of the glaze is lost.
よって本発明は、従来の問題点を一掃した模様付は用イ
ンク及びこれにより模様付けされた製品として、産業の
発展に寄与するところは極めて大きいものがある。Therefore, the present invention greatly contributes to the development of industry as a patterned ink that eliminates the conventional problems and products that are patterned using the same.
Claims (1)
３３〜２０％、Ｎａ＿２Ｏ５〜２０％、Ｋ＿２Ｏ３〜１
０％、Ｌｉ＿２３〜１０％、ＺｎＯ５〜１５％、ＴｉＯ
＿２３〜１５％、Ｂ＿２Ｏ＿３１〜１０％、ＢａＯ１〜
１０％の組成のリン酸系のフリット１００重量部と、こ
れに対して外配添加された２〜８重量部のリン酸アルカ
リ化合物あるいはアルカリ土類金属酸化物とからなり、
水性インクとしての性質を持つことを特徴とする模様付
け用インク。 ２、請求項１に記載の模様付け用インクを用いて模様付
けされたことを特徴とする製品。[Claims] 1. P_2O_530-70% by weight, Al_2O_
33-20%, Na_2O5-20%, K_2O3-1
0%, Li_23~10%, ZnO5~15%, TiO
_23~15%, B_2O_31~10%, BaO1~
Consisting of 100 parts by weight of a phosphoric acid frit with a composition of 10% and 2 to 8 parts by weight of an alkali phosphate compound or alkaline earth metal oxide added externally to the frit,
A patterning ink characterized by having the properties of a water-based ink. 2. A product characterized by being patterned using the patterning ink according to claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21947189A JP2634250B2 (en) | 1989-08-25 | 1989-08-25 | Patterning ink and products patterned thereby |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21947189A JP2634250B2 (en) | 1989-08-25 | 1989-08-25 | Patterning ink and products patterned thereby |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0383836A true JPH0383836A (en) | 1991-04-09 |
| JP2634250B2 JP2634250B2 (en) | 1997-07-23 |
Family
ID=16735953
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21947189A Expired - Lifetime JP2634250B2 (en) | 1989-08-25 | 1989-08-25 | Patterning ink and products patterned thereby |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2634250B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1167310A1 (en) * | 2000-06-28 | 2002-01-02 | Ferro France S.A.R.L. | Enamel composition |
| EP1190994A1 (en) * | 2000-09-22 | 2002-03-27 | Ferro France S.A.R.L. | White enamel for aluminized or galvanized steel |
| JP2008308393A (en) * | 2007-06-18 | 2008-12-25 | Noritake Co Ltd | Lead-free low softening point glass, lead-free low softening point glass composition, lead-free low softening point glass paste, and fluorescent display tube |
| EP2163531A1 (en) * | 2008-09-11 | 2010-03-17 | Samsung SDI Co., Ltd. | Material for forming barrier ribs and pdp comprising the same |
| US8227988B2 (en) | 2008-09-11 | 2012-07-24 | Samsung Sdi Co., Ltd | Material for forming barrier ribs, barrier ribs formed using the material and PDP comprising the barrier ribs |
| EP2662341A1 (en) * | 2012-05-10 | 2013-11-13 | LG Electronics, Inc. | Glass composition, preparation method thereof, and cooking appliance including the same |
| EP3533770A1 (en) * | 2018-02-28 | 2019-09-04 | Lg Electronics Inc. | Coating composition and cooking appliance |
| EP3702336A4 (en) * | 2017-10-27 | 2021-08-18 | Nikon Corporation | OPTICAL GLASS, AND OPTICAL ELEMENT, CEMENT LENS, OPTICAL SYSTEM, INTERCHANGEABLE CAMERA LENS AND OPTICAL DEVICE USING LEDIT OPTICAL GLASS |
-
1989
- 1989-08-25 JP JP21947189A patent/JP2634250B2/en not_active Expired - Lifetime
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1167310A1 (en) * | 2000-06-28 | 2002-01-02 | Ferro France S.A.R.L. | Enamel composition |
| WO2002002471A1 (en) * | 2000-06-28 | 2002-01-10 | Ferro France - S.A.R.L. | Enamel composition |
| US7005396B2 (en) * | 2000-06-28 | 2006-02-28 | Ferro France-S.A.R.L. | Enamel composition |
| EP1190994A1 (en) * | 2000-09-22 | 2002-03-27 | Ferro France S.A.R.L. | White enamel for aluminized or galvanized steel |
| US6566289B2 (en) | 2000-09-22 | 2003-05-20 | Ferro France - S.A.R.L. | White enamel for aluminized or galvanized steel |
| JP2008308393A (en) * | 2007-06-18 | 2008-12-25 | Noritake Co Ltd | Lead-free low softening point glass, lead-free low softening point glass composition, lead-free low softening point glass paste, and fluorescent display tube |
| EP2163531A1 (en) * | 2008-09-11 | 2010-03-17 | Samsung SDI Co., Ltd. | Material for forming barrier ribs and pdp comprising the same |
| US8227988B2 (en) | 2008-09-11 | 2012-07-24 | Samsung Sdi Co., Ltd | Material for forming barrier ribs, barrier ribs formed using the material and PDP comprising the barrier ribs |
| EP2662341A1 (en) * | 2012-05-10 | 2013-11-13 | LG Electronics, Inc. | Glass composition, preparation method thereof, and cooking appliance including the same |
| US9302932B2 (en) | 2012-05-10 | 2016-04-05 | Lg Electronics Inc. | Glass composition, preparation method thereof, and cooking appliance including the same |
| EP3702336A4 (en) * | 2017-10-27 | 2021-08-18 | Nikon Corporation | OPTICAL GLASS, AND OPTICAL ELEMENT, CEMENT LENS, OPTICAL SYSTEM, INTERCHANGEABLE CAMERA LENS AND OPTICAL DEVICE USING LEDIT OPTICAL GLASS |
| US11724959B2 (en) | 2017-10-27 | 2023-08-15 | Nikon Corporation | Optical glass, and optical element, cemented lens, optical system, interchangeable lens for camera and optical device using same |
| EP4365643A3 (en) * | 2017-10-27 | 2024-05-22 | Nikon Corporation | Optical glass, and optical element, cemented lens, optical system, interchangeable lens for camera and optical device using same |
| US12234183B2 (en) | 2017-10-27 | 2025-02-25 | Nikon Corporation | Optical glass, and optical element, cemented lens, optical system, interchangeable lens for camera and optical device using same |
| EP3533770A1 (en) * | 2018-02-28 | 2019-09-04 | Lg Electronics Inc. | Coating composition and cooking appliance |
| US11339086B2 (en) | 2018-02-28 | 2022-05-24 | Lg Electronics Inc. | Coating composition and cooking appliance |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2634250B2 (en) | 1997-07-23 |
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