JPH038782A - Production of glazed cement product - Google Patents

Production of glazed cement product

Info

Publication number
JPH038782A
JPH038782A JP14141489A JP14141489A JPH038782A JP H038782 A JPH038782 A JP H038782A JP 14141489 A JP14141489 A JP 14141489A JP 14141489 A JP14141489 A JP 14141489A JP H038782 A JPH038782 A JP H038782A
Authority
JP
Japan
Prior art keywords
cement product
glazed
cement
product
mortar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP14141489A
Other languages
Japanese (ja)
Other versions
JPH0610118B2 (en
Inventor
Kazuhiro Ogasawara
和博 小笠原
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tokai Concrete Industries Co Ltd
Original Assignee
Tokai Concrete Industries Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokai Concrete Industries Co Ltd filed Critical Tokai Concrete Industries Co Ltd
Priority to JP1141414A priority Critical patent/JPH0610118B2/en
Publication of JPH038782A publication Critical patent/JPH038782A/en
Publication of JPH0610118B2 publication Critical patent/JPH0610118B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Abstract

PURPOSE:To prevent cracking and destruction by coating the exterior surface of plain cement product of thin hollow shape with glaze, calcining and packing cement or concrete to the hollow part. CONSTITUTION:Cement is blended with fine aggregate, water and an admixture to give mortar or concrete, which is subjected to cast molding and cured to give a plain cement product 1 of thin hollow shape. Then glaze is applied to adjoining two faces 2 on the exterior surface of the product 1, the product is calcined and cured to fuse the glaze to the exterior surface 2. Then plural reinforcing bars 4 are arranged in the hollow part of the product 1, if necessary and mortar or concrete is packed into the hollow part to give a lump or thick glazed (reinforced) cement product of collapsed shape.

Description

【発明の詳細な説明】 〈発明の技術分野〉 本発明は、塊状又は厚肉状の中実形状のセメント製品の
表面に釉薬が融着した施釉セメント製品を製造する方法
に関する。
DETAILED DESCRIPTION OF THE INVENTION Technical Field of the Invention The present invention relates to a method for manufacturing a glazed cement product in which a glaze is fused to the surface of a solid cement product in the form of a lump or a thick wall.

〈従来の技術〉 この種の施釉セメント製品の製造法においては、モルタ
ル又はコンクリートを塊状又は厚肉状の中実形状に流し
込み成形して、所望の形状の鉄筋又は無筋のセメント製
品を形成する。
<Prior art> In this type of manufacturing method for glazed cement products, mortar or concrete is poured into a lumpy or thick solid shape to form a reinforcing bar or unreinforced cement product in the desired shape. .

次に、このセメント製品の表面には、釉薬を塗布し、釉
薬を表面に施したセメント製品を500〜900℃位の
温度で焼成して、釉薬をセメント製品の表面に融着し、
塊状又は厚肉状の中実形状の鉄筋又は無筋の施釉セメン
ト製品を得る。
Next, a glaze is applied to the surface of this cement product, and the cement product with the glazed surface is fired at a temperature of about 500 to 900°C to fuse the glaze to the surface of the cement product.
A glazed cement product having a solid shape of a lump or a thick wall is obtained.

〈発明が解決しようとする課題〉 ところが、上記の製造法によって得られた施釉セメント
製品は、ひび割れや破壊が生じていることが多い。
<Problems to be Solved by the Invention> However, the glazed cement products obtained by the above manufacturing method often have cracks or destruction.

また、施釉セメント製品が鉄筋を埋設した鉄筋セメント
製品である場合は、施釉セメント製品中の鉄筋が劣化し
て鉄筋の降伏点が低下していることが多い。
Further, when the glazed cement product is a reinforced cement product with embedded reinforcing bars, the reinforcing bars in the glazed cement product often deteriorate and the yield point of the reinforcing bars decreases.

即ち、上記の製造法においては、ひび割れや破壊が生じ
ていない塊状又は厚肉状の中実形状の鉄筋又は無筋の施
釉セメント製品を得ることが困難である。
That is, in the above-mentioned manufacturing method, it is difficult to obtain a solid-shaped reinforcing bar or unreinforced glazed cement product in the form of a block or thick wall that is free from cracks and fractures.

また、鉄筋の降伏点が低下していない塊状又は厚肉状の
中実形状の施釉鉄筋セメント製品を得ることが困難であ
る。
Furthermore, it is difficult to obtain a solid-shaped glazed reinforcing bar cement product in the form of a lump or a thick wall in which the yield point of the reinforcing bar is not lowered.

本発明の目的は、上記のような従来の課題を解決するこ
とである。
An object of the present invention is to solve the conventional problems as described above.

く課題が生ずる原因〉 上記の製造法において、施釉セメント製品にひび割れや
破壊が生ずる原因には、次のようなことが考えられる。
Causes of problems In the above manufacturing method, the following are possible causes of cracks and destruction of glazed cement products.

釉薬を施したセメント製品を焼成する際、塊状又は厚肉
状の中実形状のセメント製品は、表面の昇温か早くて内
部の昇温か遅く、表面と内部に大きな温度差が生じて、
表面の熱膨張量と内部の熱膨張量に大きな差が生じる。
When firing a glazed cement product, the surface of the cement product will rise quickly and the internal temperature will rise slowly, resulting in a large temperature difference between the surface and the inside.
A large difference occurs between the amount of thermal expansion on the surface and the amount of thermal expansion inside.

また、セメント製品は、焼成の際、内部の水分が気化し
て膨張するが、塊状又は厚肉状の中実形状のセメント製
品は、内部の水蒸気が外部に逃げ難く、内部に発生した
水蒸気によって大きな膨張圧力が発生する。
In addition, when cement products are fired, the moisture inside them evaporates and expands, but with cement products that are lumpy or thick-walled, it is difficult for the moisture inside them to escape to the outside, and the moisture generated inside the cement products is difficult to escape. Large expansion pressures are generated.

特に、セメント製品を流し込み成形した場合には、セメ
ント製品の含水率が高いので、内部に発生した水蒸気に
よる膨張圧力が非常に高い。
In particular, when a cement product is cast and molded, the moisture content of the cement product is high, so the expansion pressure due to the water vapor generated inside is extremely high.

施釉セメント製品が鉄筋を埋設した鉄筋セメント製品で
ある場合は、鉄筋とモルタル又はコンクリートの熱膨張
特性が異なるので、鉄筋の熱l11張量とモルタル又は
コンクリートの熱膨張量に差が生じる。
When the glazed cement product is a reinforced cement product with embedded reinforcing bars, the thermal expansion characteristics of the reinforcing bars and mortar or concrete are different, so there is a difference between the thermal tension of the reinforcing bars and the amount of thermal expansion of the mortar or concrete.

鉄筋は、800〜900℃の温度に達するまでは、温度
に比例して膨張する。
The reinforcing steel expands in proportion to temperature until it reaches a temperature of 800-900°C.

これに対し、モルタル又はコンクリートの熱膨張特性は
、材料の種類と配合割合によって異なるが、−船釣に言
えば、モルタル又はコンクリートは、骨材に珪岩や砂岩
を使用した場合は、低温域では膨張量が少ないが、珪岩
や砂岩に含まれている石英の変態温度である550〜6
00℃に達すると、膨張量が急激に増大し、温度に比例
して膨張しない。また、骨材に安山岩や玄武岩を使用し
た場合は、膨張量が鉄筋より相邑少なくなる。
On the other hand, the thermal expansion characteristics of mortar or concrete vary depending on the type and blending ratio of the materials, but in terms of boat fishing, mortar or concrete can The amount of expansion is small, but the transformation temperature of quartz contained in quartzite and sandstone is 550-6.
When the temperature reaches 00°C, the amount of expansion increases rapidly and does not expand in proportion to the temperature. Furthermore, when andesite or basalt is used as aggregate, the amount of expansion is smaller than that of reinforcing steel.

特に、モルタル又はコンクリートは、圧縮には強いが、
引張りには弱いので、鉄筋がモルタル又はコンクリート
より多く膨張すると、モルタル又はコンクリートに引張
応力が生じ、ひび割れが生じ易い。
In particular, mortar or concrete is resistant to compression, but
Since it is weak in tension, if the reinforcing steel expands more than the mortar or concrete, tensile stress will be generated in the mortar or concrete, making it prone to cracking.

また、上記の製造法において、施釉セメント製品中の鉄
筋が劣化して鉄筋の降伏点が低下する原因には1次のよ
うなことが考えられる。
Furthermore, in the above manufacturing method, the following is considered to be the primary reason why the reinforcing bars in the glazed cement product deteriorate and the yield point of the reinforcing bars decreases.

セメント製品中の鉄筋は、セメント製品の焼成の際、高
温に加熱され、その後、徐々に冷却されるので、鉄筋の
焼なましが行なわれる。
The reinforcing bars in cement products are heated to a high temperature during firing of the cement product, and then gradually cooled down, so that the reinforcing bars are annealed.

く課題を解決するための手段〉 本発明は、先ず、薄肉中空形状の無筋の施釉セメント製
品を製造し、その後、薄肉中空形状の無筋の施釉セメン
ト製品の中空部に鉄筋を配置して又は配置せずにモルタ
ル又はコンクリートを詰めて、塊状又は厚肉状の中実形
状の鉄筋又は無筋の施釉セメント製品を得るものである
Means for Solving the Problems> The present invention involves first manufacturing a thin-walled, hollow, unreinforced glazed cement product, and then placing reinforcing bars in the hollow portion of the thin-walled, hollow, unreinforced glazed cement product. Alternatively, it is not placed and filled with mortar or concrete to obtain a lumpy or thick-walled, solid-shaped reinforcing bar or unreinforced glazed cement product.

即ち、本発明は、モルタル又はコンクリートを薄肉中空
形状に成形して、薄肉中空形状の無筋のセメント製品を
形成し。
That is, in the present invention, mortar or concrete is formed into a thin-walled, hollow shape to form a thin-walled, hollow, unreinforced cement product.

セメント製品の外面に釉薬を施し、釉薬を外面に施した
セメント製品を焼成して、釉薬をセメント製品の外面に
融着し、 その後、セメント製品の中空部にモルタル又はコンクリ
ートを詰めて、塊状又は厚肉状の中実形状の施釉セメン
ト製品を得ることを特徴とする施釉セメント製品の製造
法である。
Glaze is applied to the outer surface of the cement product, and the cement product with the glaze applied to the outer surface is fired to fuse the glaze to the outer surface of the cement product.Then, the hollow part of the cement product is filled with mortar or concrete to form a block or This is a method for producing a glazed cement product, which is characterized by obtaining a thick-walled, solid-shaped glazed cement product.

また、本発明は、モルタル又はコンクリートを薄肉中空
形状に成形して、薄肉中空形状の無筋のセメント製品を
形成し、 セメント製品の外面に釉薬を施し、釉薬を外面に施した
セメント製品を焼成して、釉薬をセメント製品の外面に
融着し、 その後、セメント製品の中空部に鉄筋を配置してモルタ
ル又はコンクリートを詰めて、塊状又は厚肉状の中実形
状の施釉鉄筋セメント製品を得ることを特徴とする施釉
セメント製品の製造法である。
Furthermore, the present invention involves forming mortar or concrete into a thin hollow shape to form a thin hollow unreinforced cement product, applying a glaze to the outer surface of the cement product, and firing the cement product with the glaze applied to the outer surface. Then, the glaze is fused to the outer surface of the cement product, and then reinforcing bars are placed in the hollow part of the cement product and filled with mortar or concrete to obtain a glazed reinforced cement product with a solid shape in the form of a lump or thick wall. This is a method for manufacturing glazed cement products characterized by the following.

く作 用〉 本発明の製造法においては、焼成するセメント製品が薄
肉中空形状であるので、セメント製品の表面と内部に生
じる温度差が小さく、セメント製品の表面と内部の熱膨
張量の差が小さい。
Effect> In the manufacturing method of the present invention, since the cement product to be fired is thin-walled and hollow, the temperature difference between the surface and the inside of the cement product is small, and the difference in thermal expansion between the surface and the inside of the cement product is small. small.

その上、焼成するセメント製品が無筋であるので、鉄筋
とモルタル又はコンクリートの熱膨張量に差が生ずると
いうことがない。
Moreover, since the cement product to be fired is unreinforced, there is no difference in the amount of thermal expansion between reinforcing steel and mortar or concrete.

また、焼成するセメント製品が薄肉中空形状であるので
、焼成の際、セメント製品の内部に発生する水蒸気が外
部に逃げ易く、セメント製品の内部に発生した水蒸気に
よって発生する膨張圧力が小さい。
Furthermore, since the cement product to be fired is thin and hollow, the water vapor generated inside the cement product can easily escape to the outside during firing, and the expansion pressure generated by the water vapor inside the cement product is small.

本発明の製造法において、鉄筋を埋設した施釉鉄筋セメ
ント製品を製造する場合、焼成するセメント製品は、無
筋であるので、鉄筋とモルタル又はコンクリートの熱膨
張量に差が生ずるということがない。
In the production method of the present invention, when producing a glazed reinforced cement product with embedded reinforcing bars, the fired cement product is unreinforced, so there is no difference in the amount of thermal expansion between the reinforcing bars and mortar or concrete.

また、焼成するセメント製品は無筋である上、鉄筋は、
セメント製品の焼に#、後に、セメント製品の中空部に
配置するので、鉄筋が高温に加熱されず、鉄筋の焼なま
しが行なわれない。
In addition, the cement products to be fired are unreinforced, and the reinforcing bars are
Since the reinforcing bars are placed in the hollow part of the cement product after the cement product is fired, the reinforcing bars are not heated to a high temperature and the reinforcing bars are not annealed.

〈発明の効果〉 本発明の製造法においては、焼成するセメント製品の表
面と内部の熱膨張量の差が小さく、その上、鉄筋とモル
タル又はコンクリートの熱膨張量に差が生ずるというこ
とがなく、また、セメント製品の内部に発生した水蒸気
によって発生する膨張圧力が小さいので、ひび割れや破
壊が生じていない塊状又は厚肉状の中実形状の施釉セメ
ント製品が得られる。
<Effects of the Invention> In the manufacturing method of the present invention, the difference in the amount of thermal expansion between the surface and the inside of the cement product to be fired is small, and furthermore, there is no difference in the amount of thermal expansion between reinforcing bars and mortar or concrete. Moreover, since the expansion pressure generated by the water vapor generated inside the cement product is small, it is possible to obtain a glazed cement product in the form of a block or thick solid without cracking or destruction.

また、本発明の製造法においては、鉄筋の焼なましが行
なわれないので、鉄筋の降伏点が低下していない塊状又
は厚肉状の中実形状の施釉鉄筋セメント製品が得られる
Further, in the manufacturing method of the present invention, since the reinforcing bars are not annealed, a glazed reinforcing bar cement product in the form of a lump or a thick solid material whose yield point is not lowered can be obtained.

〈実施例〉 本例の製造法は、セメントlOO重量部、細骨材の砕砂
300重量部と水35重量部及び混和剤1重量部を混練
したモルタルを流し込み成形し、第1図に示すような箱
形状の薄肉中空形状の無筋のセメント製品lを形成し、
どのセメント製品1を70℃の温度で3時間蒸気養生す
る。
<Example> The manufacturing method of this example involves pouring and molding a mortar prepared by kneading 100 parts by weight of cement, 300 parts by weight of crushed fine aggregate, 35 parts by weight of water, and 1 part by weight of an admixture. forming a box-shaped, thin-walled, hollow unreinforced cement product l;
Which cement product 1 is steam cured at a temperature of 70°C for 3 hours.

なお1上記のモルタルは、粗骨材を含むコンクリートで
もよい、上記の蒸気養生は、オートクレーブ養生、気中
養生又は水中養生でもよい。
Note that 1. The above mortar may be concrete containing coarse aggregate, and the above steam curing may be autoclave curing, air curing, or underwater curing.

次に、セメント製品lは、その外面の隣接する2枚の面
2に釉薬を塗布し、850℃の温度で1時間焼成し、徐
冷後、1日水中養生する。
Next, the cement product 1 is coated with a glaze on two adjacent outer surfaces 2, fired at a temperature of 850° C. for 1 hour, slowly cooled, and then cured in water for 1 day.

なお、この養生は、蒸気養生又はオートクレーブ養生で
もよい。
Note that this curing may be steam curing or autoclave curing.

即ち、釉薬を外面の隣接2面2に融着した箱形状の薄肉
中空形状の無筋のセメント製品1を製造する。
That is, a box-shaped, thin-walled, hollow, unreinforced cement product 1 with glaze fused to two adjacent outer surfaces 2 is manufactured.

その後、セメント製品1の中空部3に、第2図に示すよ
うに、複数本の鉄筋4を配置し、セメント100重量部
、砕砂300重量部、水35重量部と膨張材5重量部及
び混和剤1重量部を混練したモルタル5を詰める。
Thereafter, a plurality of reinforcing bars 4 are placed in the hollow part 3 of the cement product 1, as shown in FIG. A mortar 5 in which 1 part by weight of the agent was kneaded was packed.

なお、この中埋めモルタル5は、粗骨材を含むコンクリ
ートでもよい。
Note that this filling mortar 5 may be concrete containing coarse aggregate.

即ち、釉薬を表面の隣接2面2に融着した略直方体状の
中実形状の施釉鉄筋セメント製品lを製造する。
That is, a glazed reinforcing cement product l having a substantially rectangular solid shape with glaze fused to two adjacent surfaces 2 is manufactured.

本例の製造法によって得られた略直方体状の中実形状の
施釉鉄筋セメント製品lは、第3図に示すように、歩道
りと車道Sの間の排水溝の段差部に沿って多数個が配列
され、釉薬を融着した表面の隣接2面2即ち施釉面の化
粧面2が歩行者や車中の人から見える露出位置に配置さ
れ、境界ブロックとして使用される。
As shown in Fig. 3, the solid-shaped glazed reinforcing cement product l obtained by the manufacturing method of this example is produced in large numbers along the stepped part of the drainage ditch between the sidewalk and the roadway S. are arranged, and two adjacent surfaces 2 of the surfaces fused with glaze, that is, the decorative surfaces 2 of the glazed surfaces, are placed at exposed positions visible to pedestrians and people in cars, and used as boundary blocks.

また、盛り上げた花壇の回りに沿って多数個が配列され
、化粧面2が露出位置に配置され、縁石ブロックとして
使用される。
Moreover, a large number of blocks are arranged along the periphery of a raised flower bed, and the decorative surface 2 is placed in an exposed position, and used as a curbstone block.

本例の製造法においては、中埋めモルタル5が膨張材を
含むので、セメント製品lと中埋めモルタル5の密着性
が良好である。
In the manufacturing method of this example, since the filling mortar 5 contains an expanding material, the adhesion between the cement product 1 and the filling mortar 5 is good.

本例の製造法においては、セメント製品lの中空部3に
鉄筋4を配置したが、鉄筋4は1強度上必要がなければ
、配置しなくてもよい。
In the manufacturing method of this example, the reinforcing bars 4 are arranged in the hollow part 3 of the cement product 1, but the reinforcing bars 4 may not be arranged if they are not necessary for the sake of strength.

また、9肉中空形状のセメント製品1を箱形状に形成し
、セメント製品1の中空部3にモルタル5を詰めて、中
実形状の施釉セメント製品lを略直方体状にしたが、第
4図に示すように、薄肉中空形状のセメント製品11を
扁平な筒形状に形成し、セメント製品11の中心孔の中
空部13に、鉄筋を配置して又は配置せずに1モルタル
又はコンクリートを詰めて、中実形状の施釉セメン、ト
製品1を厚肉板状にしてもよい。
In addition, a hollow cement product 1 was formed into a box shape, and the hollow part 3 of the cement product 1 was filled with mortar 5 to form a solid glazed cement product l into a substantially rectangular parallelepiped shape. As shown in the figure, a thin-walled hollow cement product 11 is formed into a flat cylindrical shape, and the hollow part 13 of the center hole of the cement product 11 is filled with mortar or concrete with or without reinforcing bars. The solid-shaped glazed cement product 1 may be made into a thick plate shape.

また、釉薬が融着した化粧面2は、セメント製品lの外
面の一部に形成したが、セメント製品の外面の全面に形
成してもよい。
Moreover, although the decorative surface 2 to which the glaze is fused is formed on a part of the outer surface of the cement product 1, it may be formed on the entire outer surface of the cement product.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明の実施例の製造法によって得られた中
間製品のセメント製品の斜視図である。 第2図は、回倒の製造法によって得られた最終製品の施
釉鉄筋セメント製品の斜視図である。 第3図は、同施釉鉄筋セメント製品の使用例を示す断面
図である。 第4図は、他の実施例の製造法によって得られた中間製
品のセメント製品の斜視図である。 l:セメント製品    2:外面2表面3:中空部 
      4:鉄 筋 5:中埋めモルタル
FIG. 1 is a perspective view of an intermediate cement product obtained by a manufacturing method according to an embodiment of the present invention. FIG. 2 is a perspective view of the final glazed reinforced cement product obtained by the rolling manufacturing method. FIG. 3 is a sectional view showing an example of use of the glazed reinforced cement product. FIG. 4 is a perspective view of an intermediate cement product obtained by a manufacturing method of another example. l: Cement product 2: External surface 2 Surface 3: Hollow part
4: Rebar 5: Filled mortar

Claims (1)

【特許請求の範囲】 1 モルタル又はコンクリートを薄肉中空形状に成形し
て、薄肉中空形状の無筋のセメント製品を形成し、 セメント製品の外面に釉薬を施し、釉薬を外面に施した
セメント製品を焼成して、釉薬をセメント製品の外面に
融着し、 その後、セメント製品の中空部にモルタル又はコンクリ
ートを詰めて、塊状又は厚肉状の中実形状の施釉セメン
ト製品を得ることを特徴とする施釉セメント製品の製造
法。 2 モルタル又はコンクリートを薄肉中空形状に成形し
て、薄肉中空形状の無筋のセメント製品を形成し、 セメント製品の外面に釉薬を施し、釉薬を外面に施した
セメント製品を焼成して、釉薬をセメント製品の外面に
融着し、 その後、セメント製品の中空部に鉄筋を配置してモルタ
ル又はコンクリートを詰めて、塊状又は厚肉状の中実形
状の施釉鉄筋セメント製品を得ることを特徴とする施釉
セメント製品の製造法。
[Scope of Claims] 1 Mortar or concrete is formed into a thin-walled hollow shape to form a thin-walled hollow unreinforced cement product, the outer surface of the cement product is glazed, and the glaze is applied to the outer surface of the cement product. It is characterized by firing to fuse the glaze to the outer surface of the cement product, and then filling the hollow part of the cement product with mortar or concrete to obtain a glazed cement product in the form of a block or thick solid. Method of manufacturing glazed cement products. 2. Mortar or concrete is formed into a thin-walled, hollow shape to form a thin-walled, hollow, unreinforced cement product, the outer surface of the cement product is glazed, and the glazed cement product is fired to remove the glaze. It is characterized by being fused to the outer surface of the cement product, and then placing reinforcing bars in the hollow part of the cement product and filling it with mortar or concrete to obtain a glazed reinforced cement product with a solid shape in the form of a lump or thick wall. Method of manufacturing glazed cement products.
JP1141414A 1989-06-02 1989-06-02 Method for manufacturing glazed cement products Expired - Lifetime JPH0610118B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1141414A JPH0610118B2 (en) 1989-06-02 1989-06-02 Method for manufacturing glazed cement products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1141414A JPH0610118B2 (en) 1989-06-02 1989-06-02 Method for manufacturing glazed cement products

Publications (2)

Publication Number Publication Date
JPH038782A true JPH038782A (en) 1991-01-16
JPH0610118B2 JPH0610118B2 (en) 1994-02-09

Family

ID=15291449

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1141414A Expired - Lifetime JPH0610118B2 (en) 1989-06-02 1989-06-02 Method for manufacturing glazed cement products

Country Status (1)

Country Link
JP (1) JPH0610118B2 (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6150918A (en) * 1984-08-20 1986-03-13 Ichimaru Fuarukosu Kk Liquid composition containing baicalin or baicalein and external drug for skin or skin cosmetic containing same
JPH01103974A (en) * 1987-10-14 1989-04-21 Takasago Ind Co Ltd Production of glazed inorganic material

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6150918A (en) * 1984-08-20 1986-03-13 Ichimaru Fuarukosu Kk Liquid composition containing baicalin or baicalein and external drug for skin or skin cosmetic containing same
JPH01103974A (en) * 1987-10-14 1989-04-21 Takasago Ind Co Ltd Production of glazed inorganic material

Also Published As

Publication number Publication date
JPH0610118B2 (en) 1994-02-09

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