JPH0393702A - Insect repellent for clothing - Google Patents
Insect repellent for clothingInfo
- Publication number
- JPH0393702A JPH0393702A JP22849289A JP22849289A JPH0393702A JP H0393702 A JPH0393702 A JP H0393702A JP 22849289 A JP22849289 A JP 22849289A JP 22849289 A JP22849289 A JP 22849289A JP H0393702 A JPH0393702 A JP H0393702A
- Authority
- JP
- Japan
- Prior art keywords
- clothing
- moth
- linne
- oxime
- proofing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000077 insect repellent Substances 0.000 title claims description 17
- YGNXYFLJZILPEK-UHFFFAOYSA-N n-cyclopentylidenehydroxylamine Chemical compound ON=C1CCCC1 YGNXYFLJZILPEK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004480 active ingredient Substances 0.000 claims abstract 3
- 230000006378 damage Effects 0.000 abstract description 10
- 239000007787 solid Substances 0.000 abstract description 8
- 230000009965 odorless effect Effects 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 4
- 241000238631 Hexapoda Species 0.000 abstract description 3
- 239000000654 additive Substances 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 4
- 241000131287 Dermestidae Species 0.000 abstract 1
- 241000214558 Nemapogon granella Species 0.000 abstract 1
- 208000001649 Pica Diseases 0.000 abstract 1
- 241000130771 Tinea pellionella Species 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 241000894007 species Species 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 7
- 241000252233 Cyprinus carpio Species 0.000 description 6
- 241000607479 Yersinia pestis Species 0.000 description 6
- VEZUQRBDRNJBJY-UHFFFAOYSA-N cyclohexanone oxime Chemical compound ON=C1CCCCC1 VEZUQRBDRNJBJY-UHFFFAOYSA-N 0.000 description 6
- 150000002923 oximes Chemical class 0.000 description 6
- 241000254173 Coleoptera Species 0.000 description 5
- 239000003814 drug Substances 0.000 description 5
- 229940079593 drug Drugs 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- ZNBNBTIDJSKEAM-UHFFFAOYSA-N 4-[7-hydroxy-2-[5-[5-[6-hydroxy-6-(hydroxymethyl)-3,5-dimethyloxan-2-yl]-3-methyloxolan-2-yl]-5-methyloxolan-2-yl]-2,8-dimethyl-1,10-dioxaspiro[4.5]decan-9-yl]-2-methyl-3-propanoyloxypentanoic acid Chemical compound C1C(O)C(C)C(C(C)C(OC(=O)CC)C(C)C(O)=O)OC11OC(C)(C2OC(C)(CC2)C2C(CC(O2)C2C(CC(C)C(O)(CO)O2)C)C)CC1 ZNBNBTIDJSKEAM-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 150000001728 carbonyl compounds Chemical class 0.000 description 1
- 210000000038 chest Anatomy 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000000245 forearm Anatomy 0.000 description 1
- 229910000378 hydroxylammonium sulfate Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 235000010746 mayonnaise Nutrition 0.000 description 1
- 239000008268 mayonnaise Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 238000006146 oximation reaction Methods 0.000 description 1
- 239000002728 pyrethroid Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】 産業上の利用分野 本発明は新規な衣料用防虫剤に関する。[Detailed description of the invention] Industrial applications The present invention relates to a novel insect repellent for clothing.
従来の技術及び問題点
従来、衣料用防虫剤としてはパラジクロ口ベンゼン、ナ
フタリン、樟脳等が広く用いられている。Conventional Technologies and Problems Conventionally, paradicrobenzene, naphthalene, camphor, and the like have been widely used as insect repellents for clothing.
これらは衣料に併置し、その昇華性蒸気により衣料を害
虫から守るものである。しかしながら、これらの衣料用
防虫剤は本来害虫の忌避を主な効果とするものであり、
特有の臭気を有する。そのため、この臭気が保存衣料へ
の移臭や着用時の不快感等となり、衣料用防虫剤におけ
る課題となっている。このような状況下で最近、無臭の
薬剤としてピレスロイド系の衣料用防虫剤が多く用いら
れている。しかしながら、常温で液体であるこれらの薬
剤は、布や紙のような物質に含浸させて用いるため終点
がわかりにくいという欠点がある。また高価な薬剤であ
るためごく少量しか使用することができず、このためタ
ンス等の衣料保存用具の中で十分に薬剤濃度が上昇せず
効力が弱いという欠点をも有する。従って、無臭で防虫
効果を発揮する固体の安価な防虫剤が当業界で望まれて
いる。These are placed alongside clothing to protect the clothing from pests with its sublimated vapor. However, the main effect of these insect repellents for clothing is to repel pests;
It has a characteristic odor. Therefore, this odor transfers to stored clothing and causes discomfort when worn, posing a problem in insect repellents for clothing. Under these circumstances, pyrethroid insect repellents for clothing have recently been widely used as odorless chemicals. However, these drugs, which are liquid at room temperature, have the disadvantage that it is difficult to determine the end point because they are used by impregnating materials such as cloth or paper. Furthermore, since it is an expensive drug, only a small amount can be used, and therefore, the drug concentration does not rise sufficiently in clothes storage tools such as chests of drawers, resulting in weak efficacy. Therefore, there is a need in the art for a solid, inexpensive insect repellent that is odorless and has an insect repellent effect.
本発明は、常温で固体の無臭・昇華性物質で食害抑制・
殺虫効果のある、入手容易な衣料用防虫剤を提供するこ
とを目的として成されたものである。The present invention uses odorless and sublimable substances that are solid at room temperature to suppress feeding damage.
The purpose of this invention is to provide an easily available insect repellent for clothing that has an insecticidal effect.
問題点を解決するための手段
本発明によれば、シクロペンタノンオキシムを含有する
衣料用防虫剤が提供される。Means for Solving the Problems According to the present invention, there is provided an insect repellent for clothing containing cyclopentanone oxime.
本発明者らの研究によると、常温で固体の無臭・昇華性
物質であるシクロペンタノンオキシムに、衣料害虫に対
する顕著な食害抑制及び殺虫効果があることが見い出さ
れた。本発明者らはシクロヘキサノンオキシムについて
も同様の検討を行ったが、゛シクロベンタノンオキシム
と異なり、食害抑制及び殺虫効果のいずれに於いても不
十分であることを認めた。さらに本発明のシクロベンタ
ノンオキシムは入手容易でかつ安全性が高く、一般家庭
で用いられる可能性の高い衣料用防虫剤として特に有用
である。According to research conducted by the present inventors, it has been found that cyclopentanone oxime, which is an odorless and sublimable substance that is solid at room temperature, has a remarkable effect of suppressing feeding damage and killing insects on clothing. The present inventors conducted a similar study on cyclohexanone oxime, but found that, unlike cyclobentanone oxime, it was insufficient in both feeding damage suppression and insecticidal effects. Further, the cyclobentanone oxime of the present invention is easily available and highly safe, and is particularly useful as an insect repellent for clothing, which is likely to be used in general households.
シクロペンタノンオキシムは、融点５６．５℃、沸点１
９６℃、エーテル及びエタノールに可溶、水に微溶、常
温で固体の昇華性物質である。シクロベンタノンオキシ
ムは、通常のオキシム化反応により容易に合成でき、例
えばカルボニル化合物であるシクロペンタノンをヒドロ
キシルアミン硫酸塩溶液に加えかき混ぜた後、水酸化ナ
トリウムで中和して合成できる。Cyclopentanone oxime has a melting point of 56.5°C and a boiling point of 1
It is a sublimable substance that is soluble in ether and ethanol at 96°C, slightly soluble in water, and solid at room temperature. Cyclobentanone oxime can be easily synthesized by a conventional oximation reaction, for example, by adding cyclopentanone, which is a carbonyl compound, to a hydroxylamine sulfate solution, stirring it, and then neutralizing it with sodium hydroxide.
本発明のシクロペンタノンオキシムは、無臭の昇華性物
質であり、衣料害虫の食害に対する抑制作用及び殺虫効
果を有し、衣料用防虫剤として有用である。The cyclopentanone oxime of the present invention is an odorless sublimable substance, has an inhibitory effect on the feeding damage of clothing pests and an insecticidal effect, and is useful as an insect repellent for clothing.
本発明のシクロペンタノンオキシムは単独、又は必要に
応じ他の防虫剤や適当な添加剤と共に、タブレット又は
より大きな固形剤として用いられる。さらに本発明のシ
クロペンタノンオキシムは、これを溶解可能な適当な溶
媒、例えばエーテル、エタノール等に溶解し、布や紙の
様な多孔性物質に含浸させて用いることもできる。又粉
末、粒剤としても用いることができる。上記各製剤にお
いて、本発明のシクロペンタノンオキシムは単独又は必
要に応じ他の物質と併用して用いられる。The cyclopentanone oxime of the present invention can be used alone, or optionally together with other insect repellents and suitable additives, in the form of tablets or larger solid formulations. Furthermore, the cyclopentanone oxime of the present invention can also be used by dissolving it in a suitable solvent such as ether, ethanol, etc. and impregnating it into a porous material such as cloth or paper. It can also be used as powder or granules. In each of the above formulations, the cyclopentanone oxime of the present invention is used alone or in combination with other substances as necessary.
本発明のシクロベンタノンオキシムを含有する衣料用防
虫剤の適用される害虫としては、一般に衣料を害する害
虫、例えばイガ、コイガ、ジュウタンガ、ヒメカツオブ
シムシ、ヒメマル力ツオブシムシ、シラオビカツオブシ
ムシ等が挙げられる。Examples of pests to which the insect repellent for clothing containing cyclobentanone oxime of the present invention can be applied include pests that generally harm clothing, such as the bur moth, carp moth, Japanese carp moth, Japanese carp beetle, Japanese carp beetle, Japanese carp beetle, and white-tailed carp beetle.
本発明のシクロペンタノンオキシムの安全性は、以下の
様に非常に高いものである。即ち、皮膚刺激性を調べる
ため、その飽和蒸気中で４０℃、１週間保存のモスリン
を３人のヒト前腕内側に貼り２４時間観察しても、なん
ら異常が見られなかった。さらにシクロベンタノンオキ
シムの急性毒性はマウスでのＬＤ５０が１２００ｍｇ／
ｋｇであり、毒性の低いことが知られている。このよう
に高度の安全性を有する本発明のシクロペンタノンオキ
シムは、その使用が一般家庭においてなされる可能性の
高い、衣料用防虫剤として優れたものである。The safety of the cyclopentanone oxime of the present invention is extremely high as described below. That is, in order to investigate skin irritation, muslin stored in saturated steam at 40° C. for one week was applied to the inside of three human forearms and observed for 24 hours, but no abnormality was observed. Furthermore, the acute toxicity of cyclobentanone oxime has an LD50 of 1200 mg/mice.
kg, and is known to have low toxicity. The cyclopentanone oxime of the present invention, which has such a high degree of safety, is excellent as an insect repellent for clothing, which is likely to be used in general households.
発明の効果
本発明のシクロベンタノンオキシムは、入手容易な常温
で固体の無臭・昇華性物質であり、衣料害虫の食害に対
する抑制作用及び殺虫効果を有し、衣料用防虫剤として
有効である。Effects of the Invention The cyclobentanone oxime of the present invention is an odorless, sublimable substance that is solid at room temperature and is easily available, and has an inhibitory effect on the feeding damage of clothing pests and an insecticidal effect, and is effective as an insect repellent for clothing.
以下に本発明をより詳細に説明するため実施例を挙げる
。Examples are given below to explain the present invention in more detail.
実施例
シクロペンタノンオキシム（ｃ ｐ ｏ）又は対照薬剤
としてシクロヘキサノンオキシム（ＣＨＯ）の各々２０
０ｍｇを、５００ｍ／のマヨネーズ瓶に入れ、これにヒ
メカツオブシムシ又はイガ１０頭と布を入れて２５℃、
２週間放置した。コントロールとして薬剤を用いない同
様の瓶を同時に放置した。結果を第１表及び第２表に示
す。表中、食害率はコントロールの食害量を１００％と
した割合を表す。また、 口は食害率、匡司は死中率を
示す。Example 20 each of cyclopentanone oxime (c p o) or cyclohexanone oxime (CHO) as control drug
Put 0mg into a 500m mayonnaise bottle, add 10 Japanese cutlet beetles or burrs and a cloth, and heat at 25℃.
It was left for two weeks. A similar bottle without drug was left at the same time as a control. The results are shown in Tables 1 and 2. In the table, the feeding damage rate represents the percentage based on the amount of feeding damage in the control as 100%. In addition, mouth indicates the feeding damage rate, and Tadashi indicates the mortality rate.
Claims (1)
する衣料用防虫剤。(1) An insect repellent for clothing containing cyclopentanone oxime as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22849289A JPH0393702A (en) | 1989-09-04 | 1989-09-04 | Insect repellent for clothing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22849289A JPH0393702A (en) | 1989-09-04 | 1989-09-04 | Insect repellent for clothing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0393702A true JPH0393702A (en) | 1991-04-18 |
Family
ID=16877308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22849289A Pending JPH0393702A (en) | 1989-09-04 | 1989-09-04 | Insect repellent for clothing |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0393702A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1076166C (en) * | 1993-12-28 | 2001-12-19 | 株式会社大贵 | Granular moth-proofing material |
| JP2021009988A (en) * | 2019-06-28 | 2021-01-28 | 株式会社Ｓｃｒｅｅｎホールディングス | Substrate processing method and substrate processing apparatus |
-
1989
- 1989-09-04 JP JP22849289A patent/JPH0393702A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1076166C (en) * | 1993-12-28 | 2001-12-19 | 株式会社大贵 | Granular moth-proofing material |
| JP2021009988A (en) * | 2019-06-28 | 2021-01-28 | 株式会社Ｓｃｒｅｅｎホールディングス | Substrate processing method and substrate processing apparatus |
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