JPH039758A - Transparent gel-like aromatic composition - Google Patents
Transparent gel-like aromatic compositionInfo
- Publication number
- JPH039758A JPH039758A JP1144232A JP14423289A JPH039758A JP H039758 A JPH039758 A JP H039758A JP 1144232 A JP1144232 A JP 1144232A JP 14423289 A JP14423289 A JP 14423289A JP H039758 A JPH039758 A JP H039758A
- Authority
- JP
- Japan
- Prior art keywords
- aluminum
- fragrance
- ethylhexanate
- transparent gel
- ethylhexanoate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 125000003118 aryl group Chemical group 0.000 title abstract description 5
- 239000003205 fragrance Substances 0.000 claims abstract description 34
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 18
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 18
- VAROLYSFQDGFMV-UHFFFAOYSA-K di(octanoyloxy)alumanyl octanoate Chemical compound [Al+3].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O.CCCCCCCC([O-])=O VAROLYSFQDGFMV-UHFFFAOYSA-K 0.000 claims abstract description 18
- 235000007586 terpenes Nutrition 0.000 claims abstract description 15
- -1 terpene hydrocarbon compounds Chemical class 0.000 claims description 11
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 13
- 239000003349 gelling agent Substances 0.000 abstract description 7
- 150000003505 terpenes Chemical class 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 10
- 229930195733 hydrocarbon Natural products 0.000 description 8
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 6
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 239000000344 soap Substances 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- GRWFGVWFFZKLTI-IUCAKERBSA-N (-)-α-pinene Chemical compound CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 description 3
- 238000001879 gelation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 241000207199 Citrus Species 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 235000020971 citrus fruits Nutrition 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 235000001510 limonene Nutrition 0.000 description 2
- 229940087305 limonene Drugs 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 2
- XOKSLPVRUOBDEW-UHFFFAOYSA-N pinane Chemical compound CC1CCC2C(C)(C)C1C2 XOKSLPVRUOBDEW-UHFFFAOYSA-N 0.000 description 2
- GRWFGVWFFZKLTI-UHFFFAOYSA-N rac-alpha-Pinene Natural products CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- 150000000133 (4R)-limonene derivatives Chemical class 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- 235000004347 Perilla Nutrition 0.000 description 1
- 244000124853 Perilla frutescens Species 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- 125000003447 alpha-pinene group Chemical group 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- CEGOLXSVJUTHNZ-UHFFFAOYSA-K aluminium tristearate Chemical compound [Al+3].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CEGOLXSVJUTHNZ-UHFFFAOYSA-K 0.000 description 1
- 229940063655 aluminum stearate Drugs 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 150000002628 limonene derivativess Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- XULSCZPZVQIMFM-IPZQJPLYSA-N odevixibat Chemical compound C12=CC(SC)=C(OCC(=O)N[C@@H](C(=O)N[C@@H](CC)C(O)=O)C=3C=CC(O)=CC=3)C=C2S(=O)(=O)NC(CCCC)(CCCC)CN1C1=CC=CC=C1 XULSCZPZVQIMFM-IPZQJPLYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 229930004008 p-menthane Natural products 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229930006728 pinane Natural products 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、透明ゲル状芳香剤組成物に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to transparent gel fragrance compositions.
更に詳しくは、本発明はジ−２−エチルヘキサン酸アル
ミニウムを主成分として含有するオクチル酸アルミニウ
ム、芳香剤キャリヤーとしてテルペン系炭化水素化合物
及び香料を含有する透明ゲル状芳香剤組成物に関する。More specifically, the present invention relates to a transparent gel-like fragrance composition containing aluminum octylate containing aluminum di-2-ethylhexanoate as a main component, a terpene hydrocarbon compound as a fragrance carrier, and a fragrance.
従来、炭化水素類のゲル化剤として金属石けん、特にス
テアリン酸アルミニウム（モノ、ジ、トリ塩）及び２−
エチルヘキサン酸アルミニウムが知られている。Traditionally, metal soaps have been used as gelling agents for hydrocarbons, especially aluminum stearate (mono-, di-, and tri-salts) and di-
Aluminum ethylhexanoate is known.
特に、２−エチルヘキサン酸アルミニウムは、炭化水素
類を透明にゲル化することは公知である（油がかたまる
くすり、化学の領域Ｖｏｗ、３６゜Ｎｏ、１０ ６９７
〜７０１ １９８２）しかし、従来の２−エチルヘキサ
ン酸アルミニウムをゲル化剤として使用する場合、透明
なゲル状芳香剤を得るには６０℃以上に加熱する必要が
あり、又、６０℃以上に加熱すると高粘度となり、芳香
剤を容器に充填するのが困難である等の欠点があった。In particular, aluminum 2-ethylhexanoate is known to transparently gel hydrocarbons (Oil Clumps Drugs, Chemistry Domain Vow, 36° No. 10 697
~701 1982) However, when conventional aluminum 2-ethylhexanoate is used as a gelling agent, it is necessary to heat it to 60°C or higher to obtain a transparent gel-like fragrance; This resulted in a high viscosity, which had drawbacks such as difficulty in filling the container with the fragrance.
また、発火点の低い溶剤を常温又はそれ以下の温度でゲ
ル化しうる２−エチルヘキサン酸アルミニウムを製造す
る方法も知られている（特公昭３６−１０４７６号公報
）。Also known is a method for producing aluminum 2-ethylhexanoate which can gel a solvent with a low ignition point at room temperature or lower (Japanese Patent Publication No. 10476/1983).
該公報に記載されている方法は、２−エチルヘキサン酸
１モルに対し１．１５〜１．８モルの範囲に於て苛性ア
ルカリを反応させ２−エチルヘキサン酸のアルカリ塩水
溶液に過剰のアルカリを存在せしめ、これにアルミニウ
ム塩題の水溶液を反応させ、且つ生成した２−エチルヘ
キサン酸アルミニウムを１００℃以下で乾煙し１０５℃
に於ける乾燥滅失量３〜８％保有するに到るを限度とし
て乾燥を中止することにより２−エチルヘキサン酸アル
ミニウムゲル化剤を得る方法である。The method described in this publication involves reacting caustic alkali in a range of 1.15 to 1.8 mol with respect to 1 mol of 2-ethylhexanoic acid, and adding an excess of alkali to an aqueous solution of an alkali salt of 2-ethylhexanoic acid. was reacted with an aqueous solution of aluminum salt, and the produced aluminum 2-ethylhexanoate was dried at 100°C or lower and heated to 105°C.
This is a method of obtaining an aluminum 2-ethylhexanoate gelling agent by stopping drying until the amount lost on drying reaches 3 to 8%.
該方法により得られた２−エチルヘキサン酸アルミニウ
ムは、一応常温において低沸点溶媒に溶解し、透明なゲ
ルを生成するものの、乾煙時の温度が高い為か、その製
造ｏ −） ）により、あるいはゲル化する溶媒の種類
によっては分散性が悪く、また生成したゲルの透明性が
悪い等という問題があった。Aluminum 2-ethylhexanoate obtained by this method dissolves in a low-boiling point solvent at room temperature and produces a transparent gel, but due to its production o -)), perhaps due to the high temperature during drying, Alternatively, depending on the type of gelling solvent, there have been problems such as poor dispersibility and poor transparency of the resulting gel.
本発明は、粘稠性の非常に低い状態で容器に充填するこ
とができ、且つ、加熱することなくテルペン系炭化水素
化合物をキャリヤーとする安定な透明なゲル状芳香剤組
成物を提供することを目的とするものである。An object of the present invention is to provide a stable, transparent gel-like aromatic composition that can be filled into a container in a state of very low viscosity and that uses a terpene-based hydrocarbon compound as a carrier without heating. The purpose is to
〔問題点を解決するための手段］
本発明は、ジ−２−エチルヘキサン酸アルミニウムを主
成分とし、少量のトリ−２−エチルヘキサン酸アルミニ
ウムを含有しているオクチル酸アルミニウム１〜１５重
量％、テルペン系炭化水素化合物４０重量％以上及び香
料０．１〜４０重量％を含有することを特徴とする透明
ゲル状芳香剤である。[Means for Solving the Problems] The present invention provides aluminum octylate containing 1 to 15% by weight of aluminum di-2-ethylhexanoate as a main component and a small amount of aluminum tri-2-ethylhexanoate. , a transparent gel-like fragrance characterized by containing 40% by weight or more of a terpene hydrocarbon compound and 0.1 to 40% by weight of a fragrance.
本発明は、極く最近開発されたアルミニウム石けんの製
造方法である、２−エチルヘキサン酸のアルカリ金属塩
とアルミニウム塩とを、弐ＨＯ−ＡＩ（ＲＣＯＯ）、
’？：’示されるシソ−１１０重量部に対し式 Ａ Ｉ
（ＲＣＯＯ） ３で示されるトリソープ１３重量部が
生成する割合で水溶液復分解法で反応させ（なお式中Ｒ
ＣＯＯは２−エチルヘキサン酸残基を示す）、生成した
アルミニウム石けんを品温５０℃を越えない温度で乾燥
することにより得られるジ−２−エチルヘキサン酸アル
ミニウムを主成分とし、少量のトリル２−ニチルヘキサ
ン酸アルミニウムを含有するオクチル酸アルミニウム石
けんをゲル化剤として用いるものである。The present invention is a very recently developed method for producing aluminum soap, in which alkali metal salt of 2-ethylhexanoic acid and aluminum salt are combined into
'? :' Formula A I for 110 parts by weight of the indicated perilla
(RCOO) 3 was reacted by an aqueous solution decomposition method at a rate that produced 13 parts by weight of trisoap (in the formula, R
(COO indicates 2-ethylhexanoic acid residue), the main component is aluminum di-2-ethylhexanoate obtained by drying the produced aluminum soap at a temperature not exceeding 50°C, and a small amount of tolyl 2 - An aluminum octylate soap containing aluminum nitylhexanoate is used as a gelling agent.
その理由は、このようにして得られたオクチル酸アルミ
ニウムは、特にテルペン系炭化水素化合物及び香料を含
有する芳香剤中に加熱することなく均一に分散し所定時
間経過後に安定で透明なゲルを生成するばかりでなく、
ジソープに対するトリソーブの割合を上記範囲内で変化
させることによりゲル化までの時間を調整することがで
きるからである。The reason for this is that the aluminum octylate obtained in this way can be uniformly dispersed into fragrances containing terpene hydrocarbon compounds and fragrances without heating, and forms a stable and transparent gel after a certain period of time. Not only do
This is because the time until gelation can be adjusted by changing the ratio of trisorb to disoap within the above range.
本発明の透明ゲル状芳香剤組成物は、２−エチルヘキサ
ン酸アルミニウムを１〜１５重量％、好ましくは３〜１
０重量％使用する。The transparent gel fragrance composition of the present invention contains 1 to 15% by weight, preferably 3 to 1% by weight of aluminum 2-ethylhexanoate.
Use 0% by weight.
２−エチルヘキサン酸アルミニウムが１重量％より少な
いと、ゲルの安定性が不十分であり、１５重量％より多
いと揮散残量が多くなり好ましくない。If aluminum 2-ethylhexanoate is less than 1% by weight, the stability of the gel will be insufficient, and if it is more than 15% by weight, the amount remaining after volatilization will increase, which is not preferable.
本発明においては、組成物中にテルペン系炭化水素化合
物をキャリヤーとして４０重量％以上用いる。In the present invention, 40% by weight or more of a terpene hydrocarbon compound is used as a carrier in the composition.
テルペン系炭化水素化合物としては、例えばα−ピネン
、β−ピネン、リモネン、ジペンテン、ｐ−メンタン、
ピナン、■−ｐ−メンテン並びにリモネンダイマー ジ
ペンテンダイマー又はその水添物、又はこれらの混合物
、又はこれらの混合物を主成分とするもの、例えば天然
精油、例えばα−ピネンを主成分とするテレピン油、α
−リモネンを主成分とするオレンジ油及びレモン油等を
挙げることができる。Examples of terpene hydrocarbon compounds include α-pinene, β-pinene, limonene, dipentene, p-menthane,
Pinane, ■-p-menthene, limonene dimer, dipentene dimer, hydrogenated products thereof, or mixtures thereof, such as natural essential oils, such as turpentine oil whose main component is α-pinene, α
- Examples include orange oil and lemon oil, which have limonene as a main component.
特にα−リモネンは、その香気からシトラス系調合香料
の重要な成分であり、シトラス系芳香剤のキャリヤーと
して特に優れている。In particular, α-limonene is an important component of citrus-based fragrance preparations because of its aroma, and is particularly excellent as a carrier for citrus-based fragrances.
これらのテルペン系炭化水素をキャリヤーとして用いる
と天然の風味を出すのに良く、また、芳香剤の匂いが最
後まで変わりにくいという特徴がある。When these terpene-based hydrocarbons are used as a carrier, they are good for bringing out natural flavors, and they also have the characteristic that the aroma of the aromatic agent does not change easily until the end.
テルペン系炭化水素にはイソパラフィン系炭化水素及び
ノルマルパラフィン系炭化水素等を混合して用いること
ができる。A mixture of isoparaffinic hydrocarbons, normal paraffinic hydrocarbons, and the like can be used as the terpene hydrocarbon.
このような炭化水素化合物も本発明の透明ゲル状芳香剤
組成物に含まれるもので、混合物として４０重量％以上
配合することができる。Such hydrocarbon compounds are also included in the transparent gel fragrance composition of the present invention, and can be blended in an amount of 40% by weight or more as a mixture.
イソパラフィン系炭化水素及びノルマルパラフィン系炭
化水素としては示性式でＣ，）Ｉ、８〜Ｃｌ６Ｌ４の範
囲のものが特に好適である。As isoparaffinic hydrocarbons and normal paraffinic hydrocarbons, those having a specific formula of C,)I,8 to Cl6L4 are particularly suitable.
テルペン系炭化水素化合物の添加量が４０重量％より少
ないとゲル化剤である２−エチルヘキサン酸アルミニウ
ムが溶解しにくくなり好ましくない。If the amount of the terpene hydrocarbon compound added is less than 40% by weight, aluminum 2-ethylhexanoate, which is a gelling agent, becomes difficult to dissolve, which is not preferable.
本発明の透明ゲル状芳香剤組成物において、香料はテル
ペン系炭化水素化合物に可溶であれば如何７よる香料を
用いてもよい。香料は、０．１〜４０重蛍％の範囲で用
いる。０．１重電％未満では適度の芳香が得られなくな
り、一方、４０重重指を越えて用いてもさほどの効果は
ない。In the transparent gel fragrance composition of the present invention, any fragrance may be used as long as it is soluble in the terpene hydrocarbon compound. The fragrance is used in a range of 0.1 to 40%. If the amount is less than 0.1%, it will not be possible to obtain a suitable fragrance, while if it is used in excess of 40%, there will be no significant effect.
また、本発明の透明ゲル状芳−香剤組成物においては、
必要に応じて他の添加剤、例えば酸化防止剤（例えばＢ
ＨＴ等）や増粘剤であるエチルセルロース、エチルヒド
ロキシエチルセルロース、色素などその他の添加剤を適
宜使用できる。Furthermore, in the transparent gel fragrance composition of the present invention,
Other additives may be added as necessary, such as antioxidants (e.g. B
HT, etc.), thickeners such as ethyl cellulose, ethyl hydroxyethyl cellulose, and pigments, and other additives can be used as appropriate.
本発明の透明ゲル状芳香剤組成物の製造にあたっては、
２−エチルヘキサン酸アルミニウム、テルペン系炭化水
素化合物及び香料を室温で混合し、均一な溶液とした後
容器に充填すると１０〜３０分後にゲル化が起り、透明
で安定なゲル状芳香剤が得られる。In producing the transparent gel fragrance composition of the present invention,
Aluminum 2-ethylhexanoate, a terpene-based hydrocarbon compound, and a fragrance are mixed at room temperature to form a homogeneous solution, and when the mixture is filled into a container, gelation occurs after 10 to 30 minutes, yielding a transparent and stable gel-like fragrance. It will be done.
実施例１〜４
ジ−２−エチルヘキサン酸アルミニウム１００重量部に
対し、表−１に示す重量部のトリ−２−エチルヘキサン
酸アルミニウム含有量となる割合になるように、２−エ
チルヘキサン酸のナトリウム塩の水溶液と硫酸アルミニ
ウム水溶液とを化学量論的割合で反応させ、表−１に示
す品温で乾煙した（以下、この方法で得られた生成物を
ＤＴＳＭと略称する）
なお、ジ−ソープ及びトリ−ソープの生成反応式を示す
と次のとおりである。Examples 1 to 4 2-ethylhexanoic acid was added to 100 parts by weight of aluminum di-2-ethylhexanoate so that the content of aluminum tri-2-ethylhexanoate was in parts by weight shown in Table 1. An aqueous solution of the sodium salt of and an aqueous aluminum sulfate solution were reacted in stoichiometric proportions, and dried smoked at the temperature shown in Table 1 (hereinafter, the product obtained by this method is abbreviated as DTSM). The reaction formula for producing di-soap and tri-soap is as follows.
ジ−ソーブ
４ｔｌ Ｃ０ＯＨ＋ＡＩ、（ＳＯ，）３＋６ＮａＯＨ２
（ＲＣＯＯ） ２ＡＩ ・Ｏ）ｌ＋ ３Ｎａ２ＳＯ４＋
４）１２０ト リ − ソ − プ
ロ Ｒ−ＣＯ［１）１＋Ａｌ２（Ｓ［１４） ３ ＋６
Ｎａ［ＩＨ２（ＲＣＯＯ）ｓＡＩ＋３Ｎａ、ｓｏ、
＋ ６８，０（ＲＣＯＯＨは２−エチルヘキサン酸で
ある）ま室温にて放置したところ、放置１５分後からゲ
ル化がはじまり１時間後には高粘度の透明な安定性のよ
いゲル状芳香剤が得られた。一方、一般に市販されてい
る２−エチルヘキサン酸アルミニウム（オクトープＡＩ
Ｂ：ホープ製薬（株）製）を用いた比較例１においては
室温では全くゲル化しなかったが、該混合物を攪拌しな
がら６０℃以上に加熱すると透明なゲル状芳香剤が得ら
れたが容器への充填が非常に困難であった。G-Sorb 4tl C0OH+AI, (SO,)3+6NaOH2
(RCOO) 2AI ・O)l+ 3Na2SO4+
4) 120 tri-so-pro R-CO[1)1+Al2(S[14) 3 +6
Na[IH2(RCOO)sAI+3Na,so,
+ 68,0 (RCOOH is 2-ethylhexanoic acid) When left at room temperature, gelation began after 15 minutes, and a highly viscous, transparent, and highly stable gel-like fragrance was formed after 1 hour. Obtained. On the other hand, generally commercially available aluminum 2-ethylhexanoate (octope AI)
B: Comparative Example 1 using Hope Pharmaceutical Co., Ltd.) did not gel at all at room temperature, but when the mixture was heated to 60°C or higher while stirring, a transparent gel-like fragrance was obtained, but the container It was very difficult to fill.
各成分の配合割合等を表−２に示す。Table 2 shows the blending ratio of each component.
実施例−５
香料及びＢＨＴをα−リモネンに溶解して２００−のビ
ーカーに入れる。攪拌しながら実施例１で得られたＯＴ
ＳＭの粉末を添加してそのま表
２
状芳香剤組成物は低温から高温まで透明性及び粘度の変
化がなく、安定性の良いものであった。Example-5 Flavor and BHT are dissolved in α-limonene and placed in a 200-cm beaker. OT obtained in Example 1 while stirring
After adding SM powder, the fragrance composition shown in Table 2 had good stability, with no change in transparency or viscosity from low to high temperatures.
室温で２ヶ月揮敗性テストを行ったが、その間ゲル状芳
香剤の透明性は維持された。各成分の配合割合を表−３
に示す。A volatility test was conducted at room temperature for two months, during which time the gel fragrance maintained its transparency. Table 3 shows the blending ratio of each component.
Shown below.
注：オクトーブＡＩ ８はジ−２−エチルヘキサン酸ア
ルミニウムよりなる従来のゲ
ル化剤である。Note: Octobe AI 8 is a conventional gelling agent consisting of aluminum di-2-ethylhexanoate.
実施例−６
実施例−５と同様の方法で表−３に示す透明ゲル状芳香
剤組成物を製造した。この透明ゲル実施例−７
実施例−５と同様の方法で表−４に示す成分の透明ゲル
状芳香剤組成物を製造した。この透明ゲル状芳香剤組成
物も同様に透明性、安定性の良いものであった。Example 6 A transparent gel-like fragrance composition shown in Table 3 was produced in the same manner as in Example 5. Transparent Gel Example 7 A transparent gel fragrance composition having the components shown in Table 4 was produced in the same manner as in Example 5. This transparent gel fragrance composition also had good transparency and stability.
表 手 続 補 正 」已 平成１年１１月２１ 日table Continuation of the procedure Correction ” 已 November 21, 1999
Claims (1)
し、少量のトリ−２−エチルヘキサン酸アルミニウムを
含有するオクチル酸アルミニウム１〜１５重量％、テル
ペン系炭化水素化合物４０重量％以上及び香料０．１〜
４０重量％を含有することを特徴とする透明ゲル状芳香
剤組成物。1. 1 to 15% by weight of aluminum octylate containing aluminum di-2-ethylhexanoate as the main component and a small amount of aluminum tri-2-ethylhexanoate, 40% by weight or more of terpene hydrocarbon compounds, and 0.0% fragrance. 1~
A transparent gel-like fragrance composition characterized by containing 40% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1144232A JP2767285B2 (en) | 1989-06-08 | 1989-06-08 | Transparent gel fragrance composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1144232A JP2767285B2 (en) | 1989-06-08 | 1989-06-08 | Transparent gel fragrance composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH039758A true JPH039758A (en) | 1991-01-17 |
| JP2767285B2 JP2767285B2 (en) | 1998-06-18 |
Family
ID=15357318
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1144232A Expired - Lifetime JP2767285B2 (en) | 1989-06-08 | 1989-06-08 | Transparent gel fragrance composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2767285B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002102325A (en) * | 2000-09-27 | 2002-04-09 | Taiyo Corp | Transparent gelatinous aromatic composition |
| JP2003073690A (en) * | 2001-09-06 | 2003-03-12 | T Hasegawa Co Ltd | Fragrance composition |
| JP2007284628A (en) * | 2006-04-20 | 2007-11-01 | Arakawa Chem Ind Co Ltd | Metal soap, method for producing the same and oil-absorbing material |
| CN111035787A (en) * | 2019-12-31 | 2020-04-21 | 江门市和馨香精技术有限公司 | Fragrance and preparation method and application thereof |
| JP2021115229A (en) * | 2020-01-24 | 2021-08-10 | 東邦インターナショナル株式会社 | Small aromatic generator |
-
1989
- 1989-06-08 JP JP1144232A patent/JP2767285B2/en not_active Expired - Lifetime
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002102325A (en) * | 2000-09-27 | 2002-04-09 | Taiyo Corp | Transparent gelatinous aromatic composition |
| JP2003073690A (en) * | 2001-09-06 | 2003-03-12 | T Hasegawa Co Ltd | Fragrance composition |
| JP2007284628A (en) * | 2006-04-20 | 2007-11-01 | Arakawa Chem Ind Co Ltd | Metal soap, method for producing the same and oil-absorbing material |
| CN111035787A (en) * | 2019-12-31 | 2020-04-21 | 江门市和馨香精技术有限公司 | Fragrance and preparation method and application thereof |
| JP2021115229A (en) * | 2020-01-24 | 2021-08-10 | 東邦インターナショナル株式会社 | Small aromatic generator |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2767285B2 (en) | 1998-06-18 |
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