JPH04204701A - Production of multicolor display device - Google Patents

Abstract

PURPOSE:To allow the disposition of many color patterns by electrodepositing and applying a photosensitive resin layer on the conductive layer of a substrate, patterning the electrodeposited photosensitive resin and adhering coloring materials of prescribed colors on the resin layers, thereby forming the patterned and colored layers of the prescribed colors. CONSTITUTION:The transparent conductive layer 2 is formed on the transparent substrate 1. The transparent conductive layer 2 is energized and the photosensitive electrodeposition resin compsn. (for example, positive type) is electrodeposited in an electrodeposition bath. A mask having desired patterns is then imposed on the positive type photosensitive resin layer 3 and the resin layer is exposed and developed, by which the patterns are formed. Further, the coloring material of the prescribed color (for example, red) is sprayed and adhered onto the electrodeposited pattern layers. Further, these stages are repeated plural times according to the number of colors. The colored film formed on one sheet of the transparent electrode acts as a mask even if the electrodeposition method is used and, therefore, the color filters are selectively formed and the many color patterns are disposed on the common transparent electrode without separating the transparent electrode.

Description

DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for manufacturing a multicolor display device used to make a display element such as a liquid crystal multicolor.

(Prior Art) There are various methods for forming a color filter on the substrate of a display element, but the methods that are currently attracting attention are a method using electrodeposition and a method of patterning a pigment-dispersed resist using photolithography. There is. For example, JP-A-6
1-272720 discloses forming a conductive layer on a substrate,
A method is disclosed in which a positive photosensitive film is formed thereon, exposed to light, the exposed portion is removed, and then a colored layer of a desired color is formed by electrodeposition. In the case of this method, it is necessary to perform a peeling process in which the entire Bong-type photosensitive coating that has been exposed and developed is once removed, and then a positive-type photosensitive coating is formed again, which complicates the process.

JP-A-1-152449 discloses that a colored negative photosensitive resin composition is spin-coded onto a substrate, exposed and developed to form a portion of a color filter colored, for example, red, and then coated with another color. A method is disclosed in which applying a non-permeable photosensitive resin composition using a spin cord, exposing and developing the composition is repeated. According to this method, it is essential to use a spin tool, and it is difficult to coat a large area with a uniform thickness. In addition, since a colored layer of another color is spin-neated on top of the colored layer that has already been formed, a step is formed and the color is uneven.

In addition, JP-A No. 52-57239 discloses that in the electrodeposition coating process, before baking, various powders, especially metal powders and colored resin powders, are attached and baked on the obtained electrodeposition coating film. A post-painting treatment method is disclosed. According to this method,
The particle size of metal powder and colored resin powder is large, on the order of tens of microns, and the resulting coating film is therefore thick, on the order of tens of microns. Moreover, the particle sizes of the various powders used are large and light transmission is insufficient, making it impossible to obtain a transparent film.

(Problems to be Solved by the Invention) The present invention provides a method for manufacturing a multicolor display device using electrodeposition and adhesion of coloring materials without the above-mentioned drawbacks.

(Means for Solving the Problems) That is, the present invention includes (a) forming a conductive layer on the entire surface of a substrate, (b) coating a photosensitive resin layer on the conductive layer, and (c) applying a photosensitive resin layer to the conductive layer. patterning the electrodeposited photosensitive resin layer; (d) forming a patterned colored layer of a predetermined color by adhering a coloring material of a predetermined color on the patterned resin layer; (e) the above. Provided is a method for manufacturing a multicolor display device, characterized in that steps (b) to (d) are repeated a necessary number of times depending on the number of colors.

Further, the present invention includes (a) forming a conductive layer on the entire surface of the substrate, (f) coating a positive resist on the conductive layer, and (g) patterning by exposing and developing into a predetermined pattern. (h) forming an electrodeposited film on the exposed conductive layer by electrodeposition; (i) forming a patterned predetermined colored layer by adhering a coloring material of a predetermined color thereon; j) Provides a method for manufacturing a multicolor display device, characterized in that the steps (g) to (i) are repeated according to the number of colors.

Further, the present invention provides (a) forming a conductive layer on the entire curve of the substrate-H, (k) forming an electrodeposited resin layer by electrodeposition on the conductive layer-Li, and (ρ) forming a button thereon. 4/ Apply “T” Renst 1, (m
) Patterning is performed by exposing and developing a predetermined novel pattern, (n) A predetermined patterned colored layer is formed by adhering a coloring material of a predetermined color to the exposed electrodeposition resin layer 1-, (0 ) Provides a method for manufacturing a multicolor display device, characterized in that (m) and (n) are repeated according to the number of colors.

The present invention will be explained based on FIG.

FIGS. 1(A) to 1(W) are T diagrams showing the manufacturing process of the multicolor display device of the present invention.

First, as shown in FIG. 1(X), a transparent conductive layer 2 is formed on a transparent substrate 1. The substrate 1 may be any substrate commonly used in multicolor display devices, such as a glass substrate, a plastic substrate, or the like.

For the transparent conductive material formed on the substrate 1, it is preferable to use a material containing, for example, tin oxide, indium oxide, or manganese oxide as a component.

Next, as shown in Fig. 1), a transparent conductive @1': current is applied to electrodeposit a photosensitive electrolyte resin composite (for example, positive type) in an electrodeposition bath. Electrodeposition (The photosensitive resin electrodeposition bath used is (1) a film-forming component and a 2-type photosensitive resin (11) with 4 properties and bath stability adjusted, Organic solvents used to facilitate production (iii) Basic substances to make the positive photosensitive resin soluble in water, and as necessary (for coating surface, electrodeposition properties, solution stability) Consists of various auxiliaries to improve sex, etc.
An example of an old mold made of luminous resin is λ, for example, Japanese Patent Application Laid-open No. 61-2470.
It is described in Publication No. 90].

Next, as shown in the step in Figure 1 (B), a 4'' mask with a desired pattern is placed on the lower 2-type photosensitive resin layer 3.
2. Batteries are generated by exposure and development.

Here, the "mask" and developing technology are known C) technologies.

Furthermore, as shown in Figure 1 (c), JT'x(:
σ) Colorant (for example, red) is sprayed and adhered onto the electrodeposited pattern layer. The colorant used here is material #1 with a minute particle size, which is a composite of resin particles and pigments or dyes.

Such coloring materials are described in detail in Japanese Patent Application Laid-Open No. 2124909, Japanese Patent Application No. 1-270020, and the like.

In the present invention, the colorant to be adhered to the obtained electrodeposited film contains particles having a particle size of 001 to 07 μm, preferably 001 to 0.3 μm, in an amount of 30% by weight or more, preferably 50% by weight of the total particles. It is desirable to have a particle size distribution of F or less.

Conventionally, colored resins in which a certain type of pigment is dispersed in a transparent resin have been known, but the particle size of the pigment used there is significantly larger than that of the present invention, resulting in poor transparency. Even if it were used in color filters, etc., it would not be possible to obtain a product with sufficient sensitivity due to its low transmittance.

In order to form a colorant having the desired particle size distribution as described above, a material with a minute particle size, which is a composite of resin particles and pigments or dyes, is separated by centrifugation or by using a glass filter, membrane filter, etc. Filtration: Koyo ``I-I'm in charge of the powder.''
) lr+1: , λF large particle size adhesive material can be removed and swallowed.

Furthermore, as shown in FIG. 1(d), while forming a patterned red colored film on the transparent conductive layer, the transparent conductive layer 2 is energized to undergo light exposure electrodeposition in an electrodeposition bath. Electrodeposition of the membrane takes place.

When electrodeposited, the photosensitive electrodeposited film will not be applied to the red colored film-1 because it will not be a red colored film or an insulating film.

As shown in Figure 1 (E) as well as Figure 1 (B),
A mask with a desired pattern for forming the second colored film is placed L7, exposed and developed (FIG. 1 (E)).

Similarly, a patterned green colored film is formed by adhering a green coloring material (FIG. 1(f)).

Similarly, a third colored film (e.g., blue) is placed on top of the mask (Fig. 1 0)), and exposed and developed (Fig. 1 0)). (H)) Furthermore, three colored layers of red, green, and blue are formed on the transparent conductive layer 1- by adhering a blue coloring material (FIG. 1(S)).

Usually, in a display element, the colored layers are red, green, and blue, but if four or more colors (including black stripes) are required, the photosensitive electrodeposited film is used as the colored layer of red, green, and blue. It may be formed by repeating the steps of electrodepositing in the gap and then adhering a black coloring material. In addition, in the case of black stripes, other than this method, they may be formed in the gaps of the color filter by another coloring method known to those skilled in the art.

Further, as shown in FIG. 1-(X), a transparent conductive layer 2 is formed on a transparent substrate 1.

Next, as shown in FIG. 1(A), a positive photosensitive resin composition 7 is uniformly applied to the transparent conductive layer. The positive photosensitive resin composition may be one in which the exposed portion is eluted with a developer; examples thereof include a compound of diazonium salt and rose formaldehyde condensation 71i described in Japanese Patent Publication No. 38-11365. Photosensitive resin composition containing
No. 3627, Special Publication No. 28403, Special Publication No. 1977-
Photosensitive resin compositions containing ortho-quinonediants (or ortho-quinone diants) described in No. 9610 town specifications, etc., JP-A-59-45439 and Japanese Patent Application No. 1-132126 Examples include photosensitive resin compositions described in the book. In the present invention, it is necessary to perform exposure and development multiple times with the same positive photosensitive resin composition, and necessary measures for this purpose (for example, providing a protective layer so as not to be modified by a developer) can be taken. Some of the photosensitive resin compositions described above do not require such means.

A mask having a predetermined pattern is placed on the positive photosensitive resin composition 7, and exposed to light to make the exposed portion of the photosensitive resin composition layer eluted, and then eluted with a predetermined eluent. A patterned substrate is obtained (see FIG. 1 (B). Masks and elution techniques are known.

This substrate has a conductive layer partially exposed as shown in FIG. 1(C).

Next, as shown in FIG. 1(C), electricity is applied to the transparent conductive layer to perform electrodeposition of an electrodeposition resin composition 8 in an electrodeposition bath. The electrodeposition resin composition may be a resin composition used for ordinary electrodeposition coating or a resin composition having adhesive properties as a coating film.

Furthermore, as shown in FIG. 1(D), a coloring material of a predetermined color (for example, red) is sprayed and adhered onto the adhesive pattern layer. The coloring materials used here are shown in Figure 1 (A) to (S).
It is similar to the one used in .

Next, as shown in FIG. 1(F), a mask is placed on the colored layer and the positive photosensitive resin layer formed on the substrate and exposed to light to form a photosensitive resin in the exposed area in the same manner as above. The material layer is eluted to obtain a patterned substrate (Fig. 1 (F))
.

Furthermore, as shown in FIG. 1(G), an electric current is applied to the conductive layer 2 to form an electrodeposited film by electrodeposition in an electrodeposition bath.

Similarly, a green colored film is formed on the patterned layer by adhering a green coloring material (FIG. 1(G)).

Similarly, a third colored film (for example, blue) is exposed and developed to obtain a patterned substrate (Fig. 1 (H)), and an electrodeposited film is further deposited on a transparent substrate by electrodeposition. Figure 1 (
(2)) By adhering the blue coloring material, three colored films of red, green, and blue are formed on the transparent conductive layer (see Figure 1 (
J) and (K)).

The black stripe is processed in the same manner as described above.

Further, as shown in FIG. 1(X), a transparent conductive layer 1 is formed on the transparent substrate 1.

Next, as shown in FIG. 1(i), electricity is applied to the transparent conductive layer to perform electrodeposition of the electrodeposition resin composition 8 in an electrodeposition bath.

Further, a positive photosensitive resin composition 7 is uniformly applied to the electrodeposited resin layer (FIG. 1(ii)).

A mask having a predetermined pattern is placed on this positive photosensitive resin composition 7, and a patterned substrate is obtained by exposure and development (FIG. 1 (iii)).

Next, as shown in FIG. 1(iv), a colorant 4 of a predetermined color (for example, red) is sprayed and adhered onto the exposed pattern layer.

Next, as shown in FIG. 1(v), a mask is placed on the colored layer and the bond-type photosensitive resin layer formed on the substrate, and a patterned substrate is obtained by exposing and developing. Figure 1 (he・)).

Similarly, by adhering a green coloring material, a turned green colored film is formed (FIG. 1(vi)).

Similarly, the third colored film (for example, blue) is also turned into a transparent conductive layer (Fig. 1 (ν1i)) by adhering the blind coloring material to red, green, and blue. Three colored films are formed (Fig. 1-III (viii) and (
ix)).

The coloring material may be completely fixed in the adhesive film by heating and flowing the adhesive film after adhesion.

When the adhesive electrodeposited film is exposed to light, it is usually 40QmJ/at room temperature.
cm' will cure, but if you want to increase the fastness of the colored layer, you can increase the irradiation amount. Further, in the case where the 6-layer material is iron-sand-like, it may be hardened by heat treatment.

Transparent electrodes are formed on the substrate on which the colored layer is formed by a method such as gamma deposition or sno<tsuttaring, resulting in a multicolor display device,
used.

(Examples) The present invention will be explained in more detail with reference to Examples 5. The present invention is not limited to these Examples.

Reference Example 1 [Preparation of positive-type adhesive photosensitive cobblestone resin composition] 63 parts by weight of methacrylic acid, N-butylene acrylate, methyl methacrylate, and rose 1-loki/stynone, 4
Weight average molecular weight 15.00 at 90 parts, 68 parts, and 379 parts
Copolymerization to 0 1. Then 0-naphthoquinone-(1,21-
7 Azido (2) Sulfonyl chloride is reacted in an amount sufficient to esterify 100% of the hydroxyl groups of Barahito Roki/Suchishin, and the resulting anionic Bone-type photosensitive bamboo resin composition is produced by producing senile glycol monobutyl ether. The solution was diluted to a non-volatile content of 75%, neutralized with 0.7 equivalents of monoethanolamine, and adjusted to a non-volatile content of 10% with pure water.

-2 Bay-2 [Preparation of 0.5 g of azobisisobutyronitrile in 50 g of quinton containing 15 g of tert-butyl acrylate, 150 g of 1-butyl acrylate, and 200 g of methyl methacrylate.
g was added thereto, and the mixture was heated and stirred at 60°C for 10 hours in a nitrogen stream. After cooling, the reaction product was diluted with tetrahydrofuran and washed with petroleum ether/methanol. The polymer is 4
2.5 g (yield 850%) and number average molecular weight (GPC
) was 51,000. This polymer was dissolved in tetrahydrofuran so that the solid content was 20% by weight, and triphenylsulfonium hexaflu A loantimo-I.
was added in an amount of 10% by weight based on the polymer to obtain a positive photosensitive resin composition.

$614 "Preparation of adhesive electrodeposited resin composition" Copolymerize methacrylic acid, N-butyl acrylate, and methyl methacrylate at 10.0 parts, 882 parts, and 18 parts to a weight average molecular weight of 12,000, and then non-volatile with ethylene glycol monobutyl ether. diluted to 75%, neutralized with 0.8 equivalents of triethylamine, and diluted with pure water to 10% non-volatile content.
[Example-4] Preparation of powder coloring material] Temperature controller, before introduction of nitrogen, dropping row] 600 g of cyclohexanone in a 20 separable flask equipped with an ink type stirring blade and a reflux condenser Preparation temperature: 05°C to F
It was 1a. Here, 70 g of dimethylaminopropyl methacrylamide 1 350 g of cyclohequinyl methacrylate
, t-butyl methacrylate 140g, styrene 140g
2 g of a mixed solution of 42 g of azobisisobutyronitrile
It was dripped from dropping row 1 over time. After finishing the dripping, 1
After continuing polymerization at this temperature for an hour, a mixed solution of 42 g of azobisisobutyronitrile and 100 g of cyclohexanone was added dropwise over 1 hour, and the mixture was further stirred at this temperature for 1 hour to synthesize a basic pigment dispersion. On the other hand, as an acidic pigment dispersant, 800 g of cyclohexanone was charged into a U-circuit vessel similar to Juki's, and the temperature was raised to 100°C. A mixed solution of 24 g of azobisisobutyronitrile and 100 g of acetone, a mixed solution of 320 g of chlorhequinyl methacrylate and 80 g of styrene, and a mixed solution of 16 g of thiomalic acid and 80 g of acetone were added dropwise from separate dropping funnels over 2 hours. , and stirred for a further 2 hours at this temperature. During this time, acetone was removed using a decanter.

50g of the pigment dispersant shown in Table 1 and 100g of the pigment were combined with 400g of styrene monomer, and 30g of N-butyl methacrylate.
0 g and 1700 g of glass peas were mixed for 2 hours using a sand grinder, and the glass peas were removed by filtration to prepare a pigment dispersion paste.

Table 1: In the same reaction vessel used for preparing the pigment dispersant, replace the tilted paddle type stirring blade with 915 g of normal propagate in the reaction vessel.
, 285 g of distilled water, 22 g of partially saponified polyvinyl acetate such as 14 g of polyvinylpyrrolidone were charged, and the mixture was heated at 85°
The temperature was raised to C. Here, pigment dispersion paste 240 of Table-1
Next, 90 g of styrene monomer, 90 g of lauroyl peroxide, and 0 g of V-4012 were added.

After polymerization at this temperature for 24 hours, 110,000 rpm
The mixture was centrifuged, filtered through a 1μ glass filter, washed with methanol three times, and dried under vacuum. As a result of analyzing the particle size distribution of this colorant using a Coulter N4 submicron particle analyzer, the average particle size was 0.2 μm, and particles having a particle size of 0.01 to 0.3 μm accounted for 96% of all particles.

Example 1 An IT○ (indium tin oxide) transparent conductive layer 2 was formed on a glass substrate l by a sputtering method, and a positive electrode was attached to the transparent conductive layer 2 using the positive adhesive photosensitive electrodeposited resin composition of Reference Example 1. A negative electrode is glued to the metal container of the bath containing the object, and a 100 volt DC voltage is applied for 1 minute to deposit a transparent positive-type adhesive photosensitive resin composition of about 2 microns on the conductive film, washed with water, and then dried. In this way, a positive photosensitive resin composition 3 was obtained all over the transparent conductive film.

Next, it was exposed to light using a high-pressure mercury lamp through a mask with a predetermined pattern, and heated at 50°C with a 0.5% caustic soda aqueous solution.
By spray development for 30 seconds, the exposed areas were eluted and the transparent adhesive resin composition was patterned on the ITO conductive layer 2.

Next, the red powder coloring material of Reference Example 4 was sprayed onto this substrate to adhere the coloring material, and the coloring material was heated to 100° C. to fix it. After that, a positive electrode was connected to the substrate having this red colored film 4, a negative electrode was connected to the transparent adhesive electrodeposited resin composition and a metal container, and a DC voltage of 100 V was applied for 1 minute to create a transparent film with a thickness of about 2 microns. An adhesive electrodeposited resin composition was deposited in the gaps between the red colored films. Thereafter, the substrate was pulled up and thoroughly washed with water. At this time, even if a voltage is applied to the substrate, the adhesive photosensitive electrodeposited resin composition is not formed on the already formed red colored film because it is an insulating film.

After washing with water, it is dried and exposed and developed through a mask having a predetermined pattern, thereby forming a red colored film and a patterned film of the adhesive resin composition.

The green powder coloring material 5 was again sprayed onto this substrate to adhere the coloring material, and the coloring material was heated to 100.degree. C. to fix it. This process was repeated in the order of red, green, and blue.

Example 2 An ITO transparent conductive layer was formed on a glass substrate similar to that of Example 1, and the positive photosensitive resin composition of Reference Example 2 was uniformly coated onto this substrate at a thickness of about 2 microns using a spin coater.

Next, it was exposed to light using a high-pressure mercury lamp through a mask with a predetermined pattern, and heated at 50°C with a 0.3% caustic soda aqueous solution.
After spray development for 60 seconds, the exposed areas were eluted, and the positive photosensitive resin composition was patterned on the ITO conductive layer 2. A positive electrode was connected to this substrate, a metal container containing the adhesive electrodeposited resin composition of Reference Example 3 was connected to the negative electrode, and a DC voltage of 100 V was applied for 30 seconds to form an adhesive resin composition of about 2 microns. were formed in the gaps of the patterned positive photosensitive resin composition.

Next, the red powder coloring material of Reference Example 4 was sprayed onto this substrate to adhere the coloring material, and the coloring material was heated to 100° C. 5 to be fixed. Thereafter, the substrate having the red colored film and the film of the positive photosensitive resin composition is exposed and developed through a mask to be patterned again.

Furthermore, an adhesive film of about 2 microns was formed by electrodepositing the adhesive electrodeposited resin composition in the same way, and a green coloring material was sprayed onto the film to adhere it, followed by heating and fixing at 100°C.This process was repeated in red, green and blue. Repeated in order.

A glass substrate 1 with an ITO transparent conductive layer 2 similar to that in Example 1 was connected to the positive electrode, a metal container containing the adhesive electrodeposited resin composition of Reference Example 3 was connected to the negative electrode, and a voltage of 100 volts was applied. A DC voltage of about 1 micron was applied for 1 minute to form an adhesive electrodeposited resin on the entire surface. Further, a positive photosensitive resin composition was uniformly applied thereon to a thickness of about 2 microns using a spin coater.

Then, it was exposed to light with a high-pressure mercury lamp through a mask with a predetermined pattern, and heated to 50°C with a 3% caustic soda aqueous solution.
Spray development was carried out for 60 seconds, and the exposed area was eluted and the tim fat was exposed and turned into a dimensional turn.

Next, the red powder coloring material of Reference Example 4 was sprayed onto this substrate, the material was adhered, and the material was heated to 100'(') to fix it. The substrate having the film was exposed and developed through a mask 5 to be patterned again.

Furthermore, a green powder coloring material was sprayed, adhered, and fixed in the same manner.

Repeat this process for red, green, and blue.

(Effects of the Invention) As explained above, according to the method of the present invention, even though the electrodeposition method is used, the colored film formed on the transparent electrodes 1 acts as a mask, so that the colored film can be selectively colored. Because filters can be formed, it is possible to arrange multiple color patterns on a common transparent electrode without separating the transparent electrodes. Not only is it possible to keep the voltage constant and form the film thickness of the same color filter uniformly, but also it is possible to form the film thickness between color filters of different colors using i@coating and adhesive fixing. In addition, it is difficult to coat expensive materials with a good yield when applying a colored resist using a spin coater, such as the pigment dispersion method, but with the method of the present invention, Enables efficient and uniform application by adhesion and fixation of coloring materials.

Therefore, this color filter can be employed in an active matrix type liquid crystal color filter panel in which color filters are formed on a common transparent electrode that is not separated, and high-quality display images can be realized due to the above-mentioned advantages.

[Brief explanation of the drawing]

FIG. 1 is a cross-sectional view showing the manufacturing process of the present invention.
(S), (A) to (1) and (1) to (ix) each indicate a different process. Number 1 in the diagram: Transparent substrate, 2
. . . Transparent conductive layer, 3. Adhesive photosensitive electrodeposition resin composition. 4... Powder coloring material (e.g. red), 5... Powder coloring material (e.g. green), 6... Powder coloring material (e.g. blue) 7
・Bon mold/strike, 8 Adhesive electrodeposited resin composition. Patent applicant Nippon Paint Co., Ltd.

Claims (5)

[Claims] (1) (a) forming a conductive layer on the entire surface of the substrate; (b) electrodepositing a photosensitive resin layer on the conductive layer; (c) patterning the electrodeposited photosensitive resin layer; (d) forming a patterned colored layer of a predetermined color by adhering a coloring material of a predetermined color on the patterned resin layer; A method for manufacturing a multicolor display device characterized by repeating the required number of times depending on the number of colors. (2) (a) forming a conductive layer on the entire surface of the substrate; (f) applying a positive resist on the conductive layer; (g) patterning by exposing and developing a predetermined pattern; ( h) forming an electrodeposited film on the exposed conductive layer by electrodeposition; (i) forming a patterned predetermined colored layer by adhering a coloring material of a predetermined color thereon; (j) A method for manufacturing a multicolor display device, characterized in that the steps (g) to (i) are repeated according to the number of colors. (3) (a) forming a conductive layer on the entire surface of the substrate; (k) forming an electrodeposited resin layer on the conductive layer by electrodeposition; (l) applying a positive resist thereon; m) patterning by exposure and development into a predetermined pattern; (n) forming a patterned predetermined colored layer by adhering a coloring material of a predetermined color on the exposed electrodeposited resin layer; ( o) A method for manufacturing a multicolor display device, characterized in that (m) and (n) are repeated according to the number of colors. (4) The colorant of a predetermined color has a particle size distribution such that particles with a particle size of 1 μm or more account for 10% by weight or less, preferably 5% by weight or less of the total particles. Compositions according to items (1) to (3). (5) In the coloring material of a predetermined color, particles with a particle size of 1 μm or more account for 5% by weight or less of the total particles, and the particle size is 0.01 to 0.0 μm.
7 μm particles account for 30% by weight or more of the total particles, preferably 5
The composition according to claims (1) to (4), characterized in that it has a particle size distribution of 0% by weight or more.