JPH04219306A - 硫化水素の酸化方法 - Google Patents

硫化水素の酸化方法

Info

Publication number: JPH04219306A
Authority: JP; Japan
Prior art keywords: bismuth; vanadium; catalyst; oxygen; reaction zone
Prior art date: 1991-01-17
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

JP3044571A

Other languages

English (en)

Japanese (ja)

Other versions

JPH0581521B2 (da

Inventor

William Ward John

ジョン　ウイリアム　ワード

Henry Hass Robert

ロバート　ヘンリー　ハツス

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Union Oil Company of California

Original Assignee

Union Oil Company of California

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-01-17

Filing date

1991-01-17

Publication date

1992-08-10

1991-01-17 Application filed by Union Oil Company of California filed Critical Union Oil Company of California

1991-01-17 Priority to JP3044571A priority Critical patent/JPH04219306A/ja

1992-08-10 Publication of JPH04219306A publication Critical patent/JPH04219306A/ja

1993-11-15 Publication of JPH0581521B2 publication Critical patent/JPH0581521B2/ja

Status Granted legal-status Critical Current

Links

RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 title claims description 142
229910000037 hydrogen sulfide Inorganic materials 0.000 title claims description 138
230000003647 oxidation Effects 0.000 title description 11
238000007254 oxidation reaction Methods 0.000 title description 11
239000007789 gas Substances 0.000 claims abstract description 80
229910052797 bismuth Inorganic materials 0.000 claims abstract description 65
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 62
229910052720 vanadium Inorganic materials 0.000 claims abstract description 52
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 51
238000006243 chemical reaction Methods 0.000 claims abstract description 48
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 37
239000001301 oxygen Substances 0.000 claims abstract description 37
229910052760 oxygen Inorganic materials 0.000 claims abstract description 37
230000001590 oxidative effect Effects 0.000 claims abstract description 17
239000003054 catalyst Substances 0.000 claims description 169
GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 60
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 60
238000000034 method Methods 0.000 claims description 38
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 21
239000000203 mixture Substances 0.000 claims description 21
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 10
239000010457 zeolite Substances 0.000 claims description 10
229910021536 Zeolite Inorganic materials 0.000 claims description 6
NNLOHLDVJGPUFR-UHFFFAOYSA-L calcium;3,4,5,6-tetrahydroxy-2-oxohexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(=O)C([O-])=O.OCC(O)C(O)C(O)C(=O)C([O-])=O NNLOHLDVJGPUFR-UHFFFAOYSA-L 0.000 claims description 6
238000002485 combustion reaction Methods 0.000 claims description 6
229910001935 vanadium oxide Inorganic materials 0.000 claims description 6
XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims description 5
229910000323 aluminium silicate Inorganic materials 0.000 claims description 5
230000002209 hydrophobic effect Effects 0.000 claims description 5
239000004480 active ingredient Substances 0.000 claims description 3
230000015572 biosynthetic process Effects 0.000 claims description 3
239000012876 carrier material Substances 0.000 claims description 3
239000000463 material Substances 0.000 claims description 3
235000012239 silicon dioxide Nutrition 0.000 claims description 3
229910000416 bismuth oxide Inorganic materials 0.000 claims description 2
229910002026 crystalline silica Inorganic materials 0.000 claims description 2
TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 2
238000010438 heat treatment Methods 0.000 claims description 2
239000011949 solid catalyst Substances 0.000 claims 3
UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims 1
239000007787 solid Substances 0.000 abstract description 3
244000118350 Andrographis paniculata Species 0.000 abstract 1
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 100
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 60
WMWLMWRWZQELOS-UHFFFAOYSA-N bismuth(iii) oxide Chemical compound O=[Bi]O[Bi]=O WMWLMWRWZQELOS-UHFFFAOYSA-N 0.000 description 46
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 45
229910052717 sulfur Inorganic materials 0.000 description 37
239000011593 sulfur Substances 0.000 description 37
DPSWNBLFKLUQTP-UHFFFAOYSA-N bismuth vanadium Chemical compound [V].[Bi] DPSWNBLFKLUQTP-UHFFFAOYSA-N 0.000 description 22
230000000694 effects Effects 0.000 description 21
239000000243 solution Substances 0.000 description 17
239000000047 product Substances 0.000 description 13
230000009849 deactivation Effects 0.000 description 12
RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 11
HUUOUJVWIOKBMD-UHFFFAOYSA-N bismuth;oxygen(2-);vanadium Chemical compound [O-2].[O-2].[O-2].[O-2].[V].[Bi+3] HUUOUJVWIOKBMD-UHFFFAOYSA-N 0.000 description 10
239000007800 oxidant agent Substances 0.000 description 10
239000000377 silicon dioxide Substances 0.000 description 10
LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 10
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 9
UNTBPXHCXVWYOI-UHFFFAOYSA-O azanium;oxido(dioxo)vanadium Chemical compound [NH4+].[O-][V](=O)=O UNTBPXHCXVWYOI-UHFFFAOYSA-O 0.000 description 9
238000004898 kneading Methods 0.000 description 8
150000001622 bismuth compounds Chemical class 0.000 description 7
230000000052 comparative effect Effects 0.000 description 7
238000002474 experimental method Methods 0.000 description 7
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 7
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 6
-1 bismuth vanadate) Chemical class 0.000 description 6
238000005470 impregnation Methods 0.000 description 6
229910017604 nitric acid Inorganic materials 0.000 description 6
239000012264 purified product Substances 0.000 description 6
KSECJOPEZIAKMU-UHFFFAOYSA-N [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] Chemical class [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] KSECJOPEZIAKMU-UHFFFAOYSA-N 0.000 description 5
230000003197 catalytic effect Effects 0.000 description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
238000002441 X-ray diffraction Methods 0.000 description 4
150000001336 alkenes Chemical class 0.000 description 4
238000001354 calcination Methods 0.000 description 4
229910052593 corundum Inorganic materials 0.000 description 4
238000002156 mixing Methods 0.000 description 4
239000002245 particle Substances 0.000 description 4
150000003682 vanadium compounds Chemical class 0.000 description 4
229910001845 yogo sapphire Inorganic materials 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 3
239000003929 acidic solution Substances 0.000 description 3
238000003915 air pollution Methods 0.000 description 3
150000001621 bismuth Chemical class 0.000 description 3
229910002092 carbon dioxide Inorganic materials 0.000 description 3
239000002131 composite material Substances 0.000 description 3
238000001125 extrusion Methods 0.000 description 3
229930195733 hydrocarbon Natural products 0.000 description 3
150000002430 hydrocarbons Chemical class 0.000 description 3
229910052750 molybdenum Inorganic materials 0.000 description 3
XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
239000003513 alkali Substances 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
125000003118 aryl group Chemical group 0.000 description 2
230000033228 biological regulation Effects 0.000 description 2
JHXKRIRFYBPWGE-UHFFFAOYSA-K bismuth chloride Chemical compound Cl[Bi](Cl)Cl JHXKRIRFYBPWGE-UHFFFAOYSA-K 0.000 description 2
125000004432 carbon atom Chemical group C* 0.000 description 2
JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 2
150000001875 compounds Chemical class 0.000 description 2
238000009833 condensation Methods 0.000 description 2
230000005494 condensation Effects 0.000 description 2
238000005336 cracking Methods 0.000 description 2
230000003247 decreasing effect Effects 0.000 description 2
XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 2
239000001257 hydrogen Substances 0.000 description 2
229910052739 hydrogen Inorganic materials 0.000 description 2
239000007788 liquid Substances 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
229920000609 methyl cellulose Polymers 0.000 description 2
239000001923 methylcellulose Substances 0.000 description 2
235000010981 methylcellulose Nutrition 0.000 description 2
229910052759 nickel Inorganic materials 0.000 description 2
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
239000002244 precipitate Substances 0.000 description 2
238000002203 pretreatment Methods 0.000 description 2
230000019635 sulfation Effects 0.000 description 2
238000005670 sulfation reaction Methods 0.000 description 2
150000003464 sulfur compounds Chemical class 0.000 description 2
UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 description 2
229910000352 vanadyl sulfate Inorganic materials 0.000 description 2
VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
DJHGAFSJWGLOIV-UHFFFAOYSA-K Arsenate3- Chemical class [O-][As]([O-])([O-])=O DJHGAFSJWGLOIV-UHFFFAOYSA-K 0.000 description 1
229910016264 Bi2 O3 Inorganic materials 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
229910002651 NO3 Inorganic materials 0.000 description 1
CBIFDJDRCNEMQB-UHFFFAOYSA-N [Al].O[As](O)(O)=O Chemical compound [Al].O[As](O)(O)=O CBIFDJDRCNEMQB-UHFFFAOYSA-N 0.000 description 1
230000002378 acidificating effect Effects 0.000 description 1
ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
229910052786 argon Inorganic materials 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
229910000417 bismuth pentoxide Inorganic materials 0.000 description 1
229910052796 boron Inorganic materials 0.000 description 1
YZYDPPZYDIRSJT-UHFFFAOYSA-K boron phosphate Chemical compound [B+3].[O-]P([O-])([O-])=O YZYDPPZYDIRSJT-UHFFFAOYSA-K 0.000 description 1
229910000149 boron phosphate Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
239000000969 carrier Substances 0.000 description 1
238000007084 catalytic combustion reaction Methods 0.000 description 1
238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
229910000151 chromium(III) phosphate Inorganic materials 0.000 description 1
IKZBVTPSNGOVRJ-UHFFFAOYSA-K chromium(iii) phosphate Chemical compound [Cr+3].[O-]P([O-])([O-])=O IKZBVTPSNGOVRJ-UHFFFAOYSA-K 0.000 description 1
239000003245 coal Substances 0.000 description 1
229910052681 coesite Inorganic materials 0.000 description 1
229910052906 cristobalite Inorganic materials 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000012467 final product Substances 0.000 description 1
230000000977 initiatory effect Effects 0.000 description 1
239000011872 intimate mixture Substances 0.000 description 1
238000005342 ion exchange Methods 0.000 description 1
229910052742 iron Inorganic materials 0.000 description 1
238000004949 mass spectrometry Methods 0.000 description 1
229910001463 metal phosphate Inorganic materials 0.000 description 1
ALTWGIIQPLQAAM-UHFFFAOYSA-N metavanadate Chemical compound [O-][V](=O)=O ALTWGIIQPLQAAM-UHFFFAOYSA-N 0.000 description 1
239000003345 natural gas Substances 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
239000011819 refractory material Substances 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
229930195734 saturated hydrocarbon Natural products 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
229910052682 stishovite Inorganic materials 0.000 description 1
239000000126 substance Substances 0.000 description 1
229910052905 tridymite Inorganic materials 0.000 description 1
229910052721 tungsten Inorganic materials 0.000 description 1
229940041260 vanadyl sulfate Drugs 0.000 description 1
238000005303 weighing Methods 0.000 description 1

Landscapes

Catalysts (AREA)

JP3044571A 1991-01-17 1991-01-17 硫化水素の酸化方法 Granted JPH04219306A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP3044571A JPH04219306A (ja)	1991-01-17	1991-01-17	硫化水素の酸化方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP3044571A JPH04219306A (ja)	1991-01-17	1991-01-17	硫化水素の酸化方法

Related Parent Applications (1)

Application Number	Title	Priority Date	Filing Date
JP57018691A Division JPS58156508A (ja)	1982-02-08	1982-02-08	硫化水素の酸化方法

Publications (2)

Publication Number	Publication Date
JPH04219306A true JPH04219306A (ja)	1992-08-10
JPH0581521B2 JPH0581521B2 (da)	1993-11-15

Family

ID=12695193

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP3044571A Granted JPH04219306A (ja)	1991-01-17	1991-01-17	硫化水素の酸化方法

Country Status (1)

Country	Link
JP (1)	JPH04219306A (da)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP4716087B2 (ja) *	2005-02-18	2011-07-06	トヨタ自動車株式会社	排ガス浄化用触媒

1991
- 1991-01-17 JP JP3044571A patent/JPH04219306A/ja active Granted

Also Published As

Publication number	Publication date
JPH0581521B2 (da)	1993-11-15

Publication	Publication Date	Title
US4311683A (en)	1982-01-19	Process for removal of hydrogen sulfide from gas streams
US4314983A (en)	1982-02-09	Catalyst and process for oxidizing hydrogen sulfide
US4382912A (en)	1983-05-10	Selective combusting of hydrogen sulfide in carbon dioxide injection gas
US5891415A (en)	1999-04-06	Process for selective oxidation of hydrogen sulfide to elemental sulfur
US4444908A (en)	1984-04-24	Catalyst and process for oxidizing hydrogen sulfide
NZ243726A (en)	1994-10-26	Conversion of nitrogen oxides incombustion gas to nitrogen, carbon dioxide and water; catalytic conversion in presence of methane and oxygen and using zeolite catalyst
GB1563866A (en)	1980-04-02	Catalytic oxidation of sulphur and sulphur compounds
US4243647A (en)	1981-01-06	Process for removal of hydrogen sulfide from gas streams
US5653953A (en)	1997-08-05	Process for recovering elemental sulfur by selective oxidation of hydrogen sulfide
EP0208434B1 (en)	1990-09-26	Process for removing nitrogen oxides and carbon monoxide simultaneously
EP0768110B1 (en)	2002-02-20	Catalyst and process for converting nitrogen oxide compounds
US4473535A (en)	1984-09-25	Process for reducing nitric oxides
EP0134594B2 (en)	1994-07-27	Process for the oxidation of hydrogen sulphide to elemental sulphur and/or sulphur dioxide
US5597546A (en)	1997-01-28	Selective oxidation of hydrogen sulfide in the presence of bismuth-based catalysts
IE891985L (en)	1989-12-20	New catalyst capable of being used in a process for the¹selective reduction of oxides of nitrogen
US4576814A (en)	1986-03-18	Catalyst and process for oxidizing hydrogen sulfide
US4444742A (en)	1984-04-24	Catalyst and process for oxidizing hydrogen sulfide
US4277458A (en)	1981-07-07	Process for oxidizing sulfur and sulfur compounds
US4528277A (en)	1985-07-09	Catalyst for oxidizing hydrogen sulfide
US4444741A (en)	1984-04-24	Catalyst and process for oxidizing hydrogen sulfide
JPH04219306A (ja)	1992-08-10	硫化水素の酸化方法
JPS6120342B2 (da)	1986-05-21
EP0085213B1 (en)	1990-02-07	Catalyst and process for oxidizing hydrogen sulfide
US5948382A (en)	1999-09-07	Selective oxidation of hydrogen sulfide in the presence of mixed-oxide catalyst containing iron, molybdenum and antimony
WO1994011105A1 (en)	1994-05-26	Process for removing sulphur dioxide from a sulphur dioxide-containing gas stream