JPH04220193A - Al-mg-si series alloy brazing filler metal - Google Patents

Abstract

PURPOSE:To prevent shortage defect of the brazing filler metal and to improve brazability when an aluminum heat exchanger having a hollow structure is manufactured by the vacuum brazing method. CONSTITUTION:This brazing filler metal contains 0.6-1.8wt.% Mg and 6.0-20.0wt.% Si, or further, 0.01-0.2wt.% Bi, and the content of Fe is specified to be <=0.3% in weight and the balance is Al and unavoidable impurities. This brazing filler metal has >=1000/mm<2> of Mg2Si grains having 2-5mum circular equivalent diameters and >=3000/mm<2> of <=6mum Si grains in the metallic structure.

Description

[Detailed description of the invention]

0001

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an Al-Mg-Si alloy brazing material having excellent vacuum brazing properties and suitable for manufacturing aluminum heat exchangers having a hollow structure.

0002

[Prior Art and Problems to be Solved by the Invention] In recent years, a vacuum brazing method that does not require flux has been developed for brazing aluminum structures, and it has become popular as there is no concern about pollution. Ta. Vacuum brazing is a method of brazing in vacuum using a brazing sheet with an aluminum alloy core and one or both sides clad with aluminum alloy brazing material as a skin material, and is suitable for brazing various structures such as heat exchangers. It is used in For vacuum brazing sheets, various aluminum alloys for core materials and aluminum alloy brazing materials for skin materials have been developed and are currently standardized by JIS Z 3263.

[0003] For vacuum brazing sheets used in heat exchangers, JIS A 3003, JI
SA 3005, JIS A 3105, JIS
A 6951 alloy is used, and the skin material is JIS BA 4004, AA 4104 with the composition shown in Table 1.
An alloy brazing filler metal is usually used. The plate thickness is 0.
5-1.2mm, brazing metal cladding ratio 5-15 on one side
% is used as a brazing sheet for single-sided or double-sided brazing metal cladding.

0004

[Table 1]

[0005] As aluminum heat exchangers having a hollow structure using such a vacuum brazing sheet, Dron cup type evaporators, oil coolers, radiators, etc. are manufactured. For example, a Dron cup type evaporator has a member (1) as shown in Figure 4.
A corrugated fin (2) is arranged between the laminated members (1), and a pressure of 10-5 to 10-4 Torr is applied.
It is manufactured by heating it to 600℃ and brazing it in a vacuum on a stand. In this vacuum brazing, the Mg added to the brazing sheet brazing material (JISBA4004, AA 4104 alloy, etc.) starts to evaporate gradually from around 400℃, and the oxidizing gas in the furnace is changed to H2O + Mg → Mg.
O+H2, O2 +2Mg→2MgO getter reaction removes Mg in the brazing material when melting the brazing material.
g evaporates rapidly, causing destruction of the oxide film on the surface of the brazing material, making brazing possible. Further, Si has the effect of lowering the melting point of the solder and lowering the brazing temperature to improve brazing properties.

By the way, when a furnace is used for a long period of time, the degree of vacuum decreases due to contamination of the furnace, etc. In such a case, the wettability of the wax decreases and fillets of the wax are not formed.
Brazing properties deteriorate. In other words, a defect phenomenon called solder breakage phenomenon occurs.

[0007]

[Means for Solving the Problems] As a result of various studies to solve this problem, the present invention has found that brazing properties and brazing breakage phenomena are caused by Mg2Si particles and We also obtained the knowledge that Fe content is related to the size and number of Si particles, and that the Fe content is related to the formation of an oxide film on the surface of the brazing material during brazing heating, which affects brazing properties. . Based on these findings, the brazing filler metal of the present invention has A
This is a l-Mg-Si based alloy brazing filler metal developed.

That is, one of the brazing materials of the present invention has a brazing temperature of 0.6 to 1
．． A brazing material containing 8 wt% Mg and 6.0 to 20.0 wt% Si, with the Fe content being regulated to 0.3 wt% or less, and the balance consisting of Al and inevitable impurities, Mg with an equivalent circle diameter of 2 to 5 μm in the metal structure
2 Si particles are 1000 pieces/mm2 or more and 6 μm
It is characterized by the presence of 3000 or more Si particles/mm2 as shown below.

Another brazing filler metal of the present invention is 0.6
Contains ~1.8 wt% Mg, 6.0-20.0 wt% Si and 0.01-0.2 wt% Bi,
In addition, the content of Fe is specified to be 0.3 wt% or less, the balance is Al and unavoidable impurities, and the metal structure contains 1000 Mg2Si particles/mm2 with an equivalent circle diameter of 2 to 5 μm. It is characterized by the presence of 3,000 or more Si particles/mm2 with a size of 6 μm or less.

0010

[Operation] First, the chemical composition of the brazing filler metal alloy according to the present invention will be explained. The brazing filler metal contains 0.6-1.8 wt% M
g and 6.0 to 20.0 wt% Si, F
The content of e is specified to be 0.3 wt% or less, and an Al-Mg-Si alloy consisting of the remainder Al and inevitable impurities is used.

[0011] Mg in the brazing material evaporates during brazing and has the effect of improving the degree of vacuum due to getter action, and has the effect of destroying the oxide film by evaporation. However, the amount is 0.6w
If it is less than 1.8 wt%, the above effect will not occur sufficiently and the brazing properties will deteriorate, and if it exceeds 1.8 wt%, M will be lost during brazing heating.
On the contrary, the g-based oxide film increases and reduces brazing properties.

[0012] Si in the brazing material is an additive element that lowers the melting point of the alloy and makes brazing possible. However, if the amount added is less than 6.0 wt% or more than 20.0 wt%, the melting point of the solder increases and brazability deteriorates. F in brazing filler metal
e promotes the growth of an oxide film during brazing heating. However, if the amount of Fe exceeds 0.3 wt%, the amount of film growth increases, so that the film is not sufficiently destroyed during Mg evaporation, resulting in poor brazing properties.

The above is the composition of the brazing alloy of the first invention, but the second invention further contains 0.01 to 0.2 wt of Bi.
% is added. In this case, Bi has the function of improving the fluidity of the wax, promoting the evaporation of Mg, and making the film more susceptible to destruction. However, when the amount of Bi added is less than 0.01 wt%, the above effect is not sufficient, and 0
．． If it exceeds 2 wt%, the rollability of the brazing filler metal decreases, making it difficult to manufacture brazing sheets.

Next, a method for measuring particle size will be explained. Particles present inside the brazing material were observed using a backscattered electron image using a scanning electron microscope. In the observed backscattered electron image, those that appeared black were determined to be Mg2Si particles, and those that appeared white were determined to be Si particles, and image analysis was performed to determine their equivalent circle diameters.

Now, as mentioned above, in the present invention, the reason why the number of Mg2Si particles in the metal structure is set to 1000 particles/mm2 or more in the range of equivalent circle diameter from 2 to 5 μm is because the particle size is 5 μm.
If it exceeds m, the amount of Mg evaporated in the early stage of vacuum brazing heating will be reduced, the function as a getter will be reduced, and the expected effect will not be obtained. On the other hand, if the particle size is smaller than 2 μm, the breaking force of the oxide film on the surface of the brazing material decreases when Mg evaporates. Therefore, in the present invention, it is necessary to have a sufficient amount of Mg2Si particles with a particle size of 2 to 5 μm. That is, if the number of Mg2Si particles with a particle size within the above range is 100
When the number is less than 0 pieces/mm2, the ability to destroy the oxide film on the surface of the brazing material due to Mg evaporation is reduced, and the function as a getter becomes insufficient. Therefore, the particle size is 2-5μ
The number of Mg2Si particles in m should be limited to 1000 pieces/mm2 or more. The upper limit of the number of Mg2Si particles is preferably as large as possible;
The following are the limits.

Furthermore, in the present invention, the number of Si particles present in the brazing material is 3000 particles/mm2 with an equivalent circle diameter of 6 μm or less.
The reason for the above is that in the case of Si particles having a particle size exceeding 6 μm, a long time is required for the solder to melt, and as a result, the brazing time must be lengthened or the brazing temperature must be increased. Therefore, in the present invention, the Si particles must be 6 μm or less. Also, Si of the size in that range
If the number of particles is less than 3000/mm2, the desired effect cannot be obtained in the above action. Therefore, the particle size is 6 μm
By limiting the number of Si particles below to 3000 pieces/mm2 or more, the brazing properties are further improved.

In the present invention, the number of Mg2Si particles with a particle size of 2 to 5 μm existing in the metal structure inside the brazing material is 1
By limiting the number to 000 pieces/mm2 or more, the destruction of the oxide film on the surface of the brazing material by Mg vapor progresses sufficiently,
In addition, it acts as a getter to improve the discharge of oxidizing gases, and furthermore, by limiting the number of Si particles with a particle size of 6 μm or less to 3000 pieces/mm2 or more, the brazing time is shortened. This has the effect of lowering the brazing temperature and improving brazing properties.

[0018] Regarding the conventional brazing filler metal, similarly to the above, the number of Mg2Si particles with a particle size of 2 to 5 μm in the metal structure,
When the number of Si particles with a particle size of 6 μm or less was investigated, as shown in Table 3, the number of Mg2 Si particles was 946 pieces/mm2.
, the number of Si particles was 10,528/mm2.

In order to obtain the predetermined Mg2Si particle distribution and Si particle distribution in the present invention, casting of the brazing filler metal,
Soaking, hot rolling, and intermediate annealing conditions can be controlled.

[0020]

EXAMPLES Next, the present invention will be explained in more detail based on examples. For the core material and brazing filler metal, filler fillers A and B having compositions according to the present invention and filler fillers C and D having conventional compositions as shown in Table 2 were used, and the plate thickness was 0.6 mm. 15% cladding rate) shown in Table 3. 1~N
o. Twelve brazing sheets were produced.

At this time, conventional brazing sheet No.
No. 12 first casts the brazing material (skin material), then soaking the brazing material at 485°C for 3 hours, and then heating the Al alloy core material and skin material together (485°C x 3 hours). Hot rolling, intermediate annealing (360°C x 2 hours), and further cold rolling to a plate thickness of 0.6 mm, and then 3
Final annealing at 60°C for 2 hours to a thickness of 0.6mm.
The annealed material was manufactured.

[0022] Another brazing sheet No. 1~N
o. Sample No. 11 was manufactured by changing the soaking treatment conditions, combined heating conditions, hot rolling conditions, and annealing conditions of the brazing filler metal to change the presence state of Mg2Si particles and Si particles in the brazing filler metal. That is, these brazing sheets N
o. 1~No. 11, first cast the brazing material (skin material),
After soaking this brazing material at 520°C or higher for 3 hours, the Al alloy core material and skin material were combined and heated at 520°C or higher for 3 hours, and then hot rolled and cold rolled to reduce the plate thickness to 0. 6 mm, and then final annealing was performed at 330° C. for 2 hours to produce an annealed material with a thickness of 0.6 mm.

Next, this brazing sheet is press-molded to form a cup (
3) was created. In the figure, (4) is the exhaust port. A test hollow structure (5) shown in FIG. 3 was created by stacking the cups formed by press-molding the brazed sheets in this manner by vacuum brazing, and was tested. In the figure, (3) is a cup with an exhaust port, (6) is a cup without an exhaust port, and (7) is a cup with an exhaust port.
) is the exhaust stack.

The brazing test conditions are 5×10−
60°C at a heating rate of 30°C/min in a vacuum of 5 Torr.
After reaching 0°C, the temperature was maintained for 10 min. Evaluation was performed based on the degree of fillet formation after brazing on the mating surfaces of the cups, and the incidence of solder breakage was determined for 100 tests. The results are also listed in Table 3.

[0025]

[Table 2]

[0026]

[Table 3]

[0027] From Table 3, it can be seen that the fillet forming ability of the example of the present invention was significantly improved compared to the results of the conventional example and the comparative example.
It can be seen that the brazing properties are stable.

[0028]

Effects of the Invention As described above, according to the present invention, Al-Mg-
It is possible to improve the brazing properties of the Si-based alloy brazing material, thereby making it possible to significantly reduce the defective rate, and achieving stable operations, which has significant industrial effects.

[Brief explanation of the drawing]

FIG. 1 is a plan view showing an example of a heat exchanger cup.

FIG. 2 is a sectional view as well.

FIG. 3 is a side sectional view showing a test hollow structure with stacked cups.

FIG. 4 is a perspective view showing an example of a drone cup type evaporator.

[Explanation of symbols]

1 part material 2 Corrugated fin 3 Cup 4 Exhaust port 5 Hollow structure for testing 6 Cup without exhaust port 7 Exhaust stack

Claims (2)

[Claims] Claim 1: Contains 0.6 to 1.8 wt% Mg and 6.0 to 20.0 wt% Si, and F
The content of e is defined as 0.3 wt% or less, and the balance is Al and unavoidable impurities, and the metal structure contains 1000 Mg2Si particles with an equivalent circle diameter of 2 to 5 μm.
30 Si particles/mm2 or more and 6 μm or less
Al- characterized by the presence of 00 pieces/mm2 or more
Mg-Si alloy brazing filler metal. 2. 0.6 to 1.8 wt% Mg,
6.0-20.0wt% Si and 0.01-0.2
Contains wt% Bi and Fe content 0.3
wt% or less, the balance is Al and unavoidable impurities, and the metal structure has an equivalent circle diameter of 2 to 5 μm.
m of Mg2Si particles is 1000 pieces/mm2 or more,
An Al-Mg-Si alloy brazing filler metal, characterized in that Si particles of 6 μm or less are present at 3000 pieces/mm 2 or more.