JPH04237183A - Distorted quantum well laser - Google Patents

Distorted quantum well laser

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Publication number
JPH04237183A
JPH04237183A JP580991A JP580991A JPH04237183A JP H04237183 A JPH04237183 A JP H04237183A JP 580991 A JP580991 A JP 580991A JP 580991 A JP580991 A JP 580991A JP H04237183 A JPH04237183 A JP H04237183A
Authority
JP
Japan
Prior art keywords
quantum well
active layer
substrate
laser
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP580991A
Other languages
Japanese (ja)
Inventor
Toshiaki Fukunaga
敏明 福永
Kenji Watanabe
賢司 渡辺
Takeshi Takamori
高森 毅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oki Electric Industry Co Ltd
Original Assignee
Oki Electric Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Oki Electric Industry Co Ltd filed Critical Oki Electric Industry Co Ltd
Priority to JP580991A priority Critical patent/JPH04237183A/en
Publication of JPH04237183A publication Critical patent/JPH04237183A/en
Withdrawn legal-status Critical Current

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  • Semiconductor Lasers (AREA)

Abstract

PURPOSE:To obtain a semiconductor laser where a distorted quantum well large in tolerance to stress induced in a manufacturing process and laser oscilla tion is made to serve as an active layer by a method wherein the active layer is made to grow on a stepped substrate of inverted mesa structure, whereby it grows discontinuous. CONSTITUTION:A distorted quantum well laser is provided with an N-GaAs (100) stepped substrate 11 of inverted mesa structure and an InvGa1-vAs quantum well active layer 15 formed on the stepped substrate 11 through a molecular beam epitaxial growth method, where the active layer 15 is severed through the stepped part of the substrate 11 and in result enhanced in tolerance to stress which acts on it near a light emitting region.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は、化合物半導体の光・電
子デバイスの高性能化に大きく寄与する歪み量子井戸レ
ーザの製造方法に関するものである。2種類のバンドギ
ャップの違う半導体から構成され、エネルギーギャップ
が大きい半導体によって他方の半導体が包み込まれ、活
性層となる量子井戸が基板と格子定数が異なり歪むこと
を特徴とした歪み量子井戸レーザに関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for manufacturing a strained quantum well laser, which greatly contributes to improving the performance of compound semiconductor opto-electronic devices. Concerning a strained quantum well laser that is composed of two types of semiconductors with different band gaps, in which the other semiconductor is surrounded by the semiconductor with a large energy gap, and the quantum well that serves as the active layer has a different lattice constant from the substrate and is distorted. It is.

【0002】0002

【従来の技術】従来、このような分野の技術としては、
例えば A.Lasson,S.Forouhar,J.Cod
y  and  R.J.Lang:「980nmで発
振する高信頼性狭ストライプ・プッシュドモーフィック
・単一量子井戸レーザの高出力動作」(High−Po
wer  Operation  of  Highl
y  Reliable  Narrow  Stri
pePseudomorphic  Single  
Quantum  WellLasers  Emit
ting  at  980  nm)IEEE  P
HOTONICS  TECHNOLOGY  LET
TERS  VOL.2,No.5,MAY,1990
年  P.307−309に記載されるものがあった。
[Prior Art] Conventionally, technologies in this field include:
For example, A. Lasson, S. Forouhar, J. Cod
y and R. J. Lang: "High-power operation of a highly reliable narrow stripe pushed morphic single quantum well laser oscillating at 980 nm" (High-Po
Were Operation of High
y Reliable Narrow Stri
pePseudomorphic Single
Quantum Well Lasers Emit
ting at 980 nm) IEEE P
HOTONICS TECHNOLOGY LET
TERS VOL. 2, No. 5, MAY, 1990
Year P. There was one described in 307-309.

【0003】図2はかかる従来の分子線エピタキシャル
成長InGaAs/GaAs/AlGaAs  GRI
N−SCH  SQWの組成プロファイル及び層厚を示
す図、図3はかかる歪み量子井戸レーザの断面図である
。 これらの図に示すように、この種の歪み量子井戸レーザ
の製造方法としては、分子線エピタキシャル成長によっ
て、n−GaAs基板1上にn−AlGaAsクラッド
層2、AlGaAs  GRIN−SCH(Grate
d  IndexSeparate  Confine
ment  Heterostracture)+In
GaAs  SQW(Single  Quantum
  Well)層3、p−AlGaAsクラッド層4、
p−GaAsコンタクト層5を積層した後、3μm程度
のストライプの領域を残し、屈折率導波機構を形成する
ため、活性層近傍までドライエッチングあるいは化学エ
ッチングでp−GaAsコンタクト層5、p−AlGa
Asクラッド層4の大部分を除去し、リッジ構造を形成
し、その後、絶縁膜6を用い電流狭窄を行っていた。
FIG. 2 shows such conventional molecular beam epitaxial growth InGaAs/GaAs/AlGaAs GRI.
FIG. 3, which is a diagram showing the composition profile and layer thickness of N-SCH SQW, is a cross-sectional view of such a strained quantum well laser. As shown in these figures, the method for manufacturing this type of strained quantum well laser is to form an n-AlGaAs cladding layer 2 and an AlGaAs GRIN-SCH (Grate) on an n-GaAs substrate 1 by molecular beam epitaxial growth.
dIndexSeparate Confine
ment Heterostructure)+In
GaAs SQW (Single Quantum
Well) layer 3, p-AlGaAs cladding layer 4,
After laminating the p-GaAs contact layer 5, the p-GaAs contact layer 5 and the p-AlGa are deposited by dry etching or chemical etching to the vicinity of the active layer, leaving a stripe region of about 3 μm and forming a refractive index waveguide mechanism.
Most of the As cladding layer 4 was removed to form a ridge structure, and then an insulating film 6 was used to perform current confinement.

【0004】0004

【発明が解決しようとする課題】しかしながら、上記し
た従来の歪み量子井戸レーザの製造方法では、基板と格
子整合しないInGaAsを全面に成長しており、発振
波長を長くする時、転位を発生させないで成長できる限
界に近い厚みの活性層を必要とするので、製造プロセス
中や高出力発振時にストレスに起因する欠陥が生じ易く
、レーザ素子が劣化するという欠点があった。
[Problems to be Solved by the Invention] However, in the conventional strained quantum well laser manufacturing method described above, InGaAs, which is not lattice-matched to the substrate, is grown on the entire surface, and when the oscillation wavelength is lengthened, it is difficult to generate dislocations. Since it requires an active layer with a thickness close to the growth limit, it has the disadvantage that defects due to stress are likely to occur during the manufacturing process or during high-output oscillation, and the laser device deteriorates.

【0005】本発明は、以上に述べた活性層の全面にか
かったストレスが素子を劣化させるという問題点を除去
し、特性の向上を図り、信頼性の高い歪み量子井戸レー
ザを提供することを目的としている。
The present invention aims to eliminate the above-mentioned problem that stress applied to the entire surface of the active layer deteriorates the device, improve the characteristics, and provide a highly reliable strained quantum well laser. The purpose is

【0006】[0006]

【課題を解決するための手段】本発明は、上記目的を達
成するために、歪み量子井戸レーザにおいて、逆メサ構
造の段差付き基板と、該段差付き基板上に分子線エピタ
キシャル成長法により形成される活性層とを具備し、前
記基板の段差により活性層のつながりを断ち、発光領域
近傍の活性層にかかるストレスの許容度を大きくするよ
うにしたものである。
[Means for Solving the Problems] In order to achieve the above object, the present invention provides a strained quantum well laser that includes a stepped substrate having an inverted mesa structure and a structure formed on the stepped substrate by molecular beam epitaxial growth. The active layer is separated from the active layer by the step of the substrate, thereby increasing the tolerance of stress applied to the active layer near the light emitting region.

【0007】[0007]

【作用】本発明は、上記したように、分子線エピタキシ
ャル成長装置を用いて、逆メサの段差付き基板上に半導
体レーザ構造を形成し、段差により活性層のつながりを
断ち、発振領域近傍にかかるストレスの許容度を増大さ
せることができる。従って、従来のように、活性層の全
面にかかるストレスにより、素子を劣化させることはな
くなり、信頼性の高い歪み量子井戸レーザを得ることが
できる。
[Operation] As described above, the present invention uses a molecular beam epitaxial growth apparatus to form a semiconductor laser structure on a substrate with an inverted mesa step, and the step breaks the connection between the active layers and causes stress in the vicinity of the oscillation region. Tolerance can be increased. Therefore, unlike in the prior art, stress applied to the entire surface of the active layer does not cause deterioration of the device, and a highly reliable strained quantum well laser can be obtained.

【0008】[0008]

【実施例】以下、本発明の実施例を図面を用いて詳細に
説明する。図1は本発明の実施例を示す歪み量子井戸レ
ーザの製造工程断面図である。まず、図1(a)に示す
ように、分子線エピタキシャル成長により、通常のリソ
グラフィ技術と化学エッチングにより、<011>方向
に、幅10μm程度のストライプに逆メサの段差付きn
−GaAs(100)基板11上に、n−GaAsバッ
ファ層12(0.5μm程度)、n−AlX Ga1−
X Asクラッド層13(約1μm)、AlY Ga1
−Y As光導波層14(約100nm)、InV G
a1−V As量子井戸活性層15、AlY Ga1−
Y As光導波層16(約100nm)、p−AlX 
Ga1−X Asクラッド層17(約1μm)、p−G
aAsコンタクト層18(約0.5μm)を積層する。
Embodiments Hereinafter, embodiments of the present invention will be explained in detail with reference to the drawings. FIG. 1 is a sectional view showing the manufacturing process of a strained quantum well laser according to an embodiment of the present invention. First, as shown in FIG. 1(a), by molecular beam epitaxial growth, ordinary lithography technology and chemical etching, a stripe with a width of about 10 μm is formed in the <011> direction with an inverted mesa step.
- On a GaAs (100) substrate 11, an n-GaAs buffer layer 12 (about 0.5 μm), an n-AlX Ga1-
X As cladding layer 13 (approximately 1 μm), AlY Ga1
-Y As optical waveguide layer 14 (about 100 nm), InV G
a1-V As quantum well active layer 15, AlY Ga1-
YAs optical waveguide layer 16 (about 100 nm), p-AlX
Ga1-X As cladding layer 17 (approximately 1 μm), p-G
An aAs contact layer 18 (approximately 0.5 μm) is laminated.

【0009】設定された発振波長で、閾値電流を最小に
するという条件で、InV Ga1−V As量子井戸
活性層15の厚みと組成が決まる。AlY Ga1−Y
 As光導波層14、16の組成は、活性層でY〜0.
2程度とし、AlX Ga1−X Asクラッド層でY
=Xとなるように直線的に変化させる。次に、図1(b
)に示すように、通常のリソグラフィ技術とドライエッ
チング技術を用いて逆メサの上の中央部に約3μm程度
の幅のストライプを<011>方向に形成し、ストライ
プ領域以外の領域をエッチングし、リッジ構造を形成す
る。このエッチング深さは、AlY Ga1−Y As
光導波層14に到達せず、かつ、屈折率導波機構が作り
付けられるようにする。絶縁膜19を形成し、通常のリ
ソグラフィ技術を用いて、p−GaAsコンタクト層1
8上の絶縁膜を取り除き、p側電極20を形成する。次
に、裏面にn側電極21を形成し、ドライエッチングあ
るいは、へき開によって、レーザ端面を形成する。
The thickness and composition of the InV Ga1-V As quantum well active layer 15 are determined on the condition that the threshold current is minimized at the set oscillation wavelength. AlYGa1-Y
The composition of the As optical waveguide layers 14 and 16 is Y~0.
2, and Y in the AlX Ga1-X As cladding layer.
=X. Next, Figure 1(b
), a stripe with a width of about 3 μm is formed in the <011> direction at the center of the inverted mesa using normal lithography and dry etching techniques, and the area other than the stripe area is etched. Forms a ridge structure. This etching depth is AlYGa1-YAs
The optical waveguide layer 14 is not reached and a refractive index waveguide mechanism is built. An insulating film 19 is formed, and a p-GaAs contact layer 1 is formed using a normal lithography technique.
The insulating film on 8 is removed, and p-side electrode 20 is formed. Next, an n-side electrode 21 is formed on the back surface, and a laser end face is formed by dry etching or cleaving.

【0010】上記した実施例では、n−GaAs基板上
での成長について説明を行ったが、不純物の選択によっ
て、p−GaAs基板上でも構わない。また、逆メサ上
以外のエピタキシャル成長領域もエッチングにより、取
り除いてもよい。更に、GaSb基板上へのInGaS
b量子井戸レーザ、GaP基板上へのGaInP量子井
戸レーザの形成等についても応用できる。
In the above embodiments, growth on an n-GaAs substrate was explained, but growth on a p-GaAs substrate may be used depending on the selection of impurities. Furthermore, the epitaxial growth regions other than those on the inverted mesa may also be removed by etching. Furthermore, InGaS on GaSb substrate
It can also be applied to the formation of b-quantum well lasers, GaInP quantum well lasers on GaP substrates, etc.

【0011】なお、本発明は上記実施例に限定されるも
のではなく、本発明の趣旨に基づいて種々の変形が可能
であり、これらを本発明の範囲から排除するものではな
い。
It should be noted that the present invention is not limited to the above embodiments, and various modifications can be made based on the spirit of the present invention, and these are not excluded from the scope of the present invention.

【0012】0012

【発明の効果】本発明によれば、逆メサ構造の段差付き
基板上に活性層を成長させることによって、段差により
活性層のつながりを断ち、製造工程及びレーザ発振時に
生じるストレスに対して許容度の大きい歪み量子井戸を
活性層とする半導体レーザを作製することにより、信頼
性の高い歪み量子井戸半導体レーザを得ることができる
。そして、本発明は、超高速な光情報処理及び通信等の
広い分野に適用することができる。
Effects of the Invention According to the present invention, by growing an active layer on a substrate with steps having an inverted mesa structure, the connection between the active layers is severed by the steps, and the tolerance to stress generated during the manufacturing process and laser oscillation is improved. A highly reliable strained quantum well semiconductor laser can be obtained by manufacturing a semiconductor laser having a strained quantum well as an active layer with a large strained quantum well. The present invention can be applied to a wide range of fields such as ultra-high speed optical information processing and communication.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明の実施例を示す歪み量子井戸レーザの製
造工程断面図である。
FIG. 1 is a cross-sectional view showing the manufacturing process of a strained quantum well laser according to an embodiment of the present invention.

【図2】従来の分子線エピタキシャル成長InGaAs
/GaAs/AlGaAs  GRIN−SCH  S
QWの組成プロファイル及び層厚を示す図である。
[Figure 2] Conventional molecular beam epitaxial growth InGaAs
/GaAs/AlGaAs GRIN-SCH S
It is a figure which shows the composition profile and layer thickness of QW.

【図3】従来の歪み量子井戸レーザの断面図である。FIG. 3 is a cross-sectional view of a conventional strained quantum well laser.

【符号の説明】[Explanation of symbols]

11    逆メサの段差付きn−GaAs(100)
基板12    n−GaAsバッファ層 13    n−AlX Ga1−X Asクラッド層
14    AlY Ga1−Y As光導波層15 
   InV Ga1−V As量子井戸活性層16 
   AlY Ga1−Y As光導波層17    
p−AlX Ga1−X Asクラッド層18    
p−GaAsコンタクト層19    絶縁膜 20    p側電極 21    n側電極
11 Inverted mesa stepped n-GaAs (100)
Substrate 12 n-GaAs buffer layer 13 n-AlX Ga1-X As cladding layer 14 AlY Ga1-Y As optical waveguide layer 15
InV Ga1-V As quantum well active layer 16
AlY Ga1-Y As optical waveguide layer 17
p-AlX Ga1-X As cladding layer 18
p-GaAs contact layer 19 insulating film 20 p-side electrode 21 n-side electrode

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】(a)逆メサ構造の段差付き基板と、(b
)該段差付き基板上に分子線エピタキシャル成長法によ
り形成される活性層とを具備し、 (c)前記基板の段差により活性層のつながりを断ち、
発光領域近傍の活性層にかかるストレスの許容度を大き
くすることを特徴とする歪み量子井戸レーザ。
Claim 1: (a) A substrate with steps having an inverted mesa structure; (b)
) an active layer formed by molecular beam epitaxial growth on the stepped substrate; (c) the active layer is disconnected by the stepped substrate;
A strained quantum well laser characterized by increasing the tolerance of stress applied to the active layer near the light emitting region.
JP580991A 1991-01-22 1991-01-22 Distorted quantum well laser Withdrawn JPH04237183A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP580991A JPH04237183A (en) 1991-01-22 1991-01-22 Distorted quantum well laser

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP580991A JPH04237183A (en) 1991-01-22 1991-01-22 Distorted quantum well laser

Publications (1)

Publication Number Publication Date
JPH04237183A true JPH04237183A (en) 1992-08-25

Family

ID=11621413

Family Applications (1)

Application Number Title Priority Date Filing Date
JP580991A Withdrawn JPH04237183A (en) 1991-01-22 1991-01-22 Distorted quantum well laser

Country Status (1)

Country Link
JP (1) JPH04237183A (en)

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Effective date: 19980514