JPH0426822B2 - - Google Patents
Info
- Publication number
- JPH0426822B2 JPH0426822B2 JP57194207A JP19420782A JPH0426822B2 JP H0426822 B2 JPH0426822 B2 JP H0426822B2 JP 57194207 A JP57194207 A JP 57194207A JP 19420782 A JP19420782 A JP 19420782A JP H0426822 B2 JPH0426822 B2 JP H0426822B2
- Authority
- JP
- Japan
- Prior art keywords
- sodium
- inosinate
- salt
- liquid
- concentration
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 235000011194 food seasoning agent Nutrition 0.000 claims description 28
- 239000007788 liquid Substances 0.000 claims description 26
- 150000003839 salts Chemical class 0.000 claims description 18
- AANLCWYVVNBGEE-IDIVVRGQSA-L Disodium inosinate Chemical compound [Na+].[Na+].O[C@@H]1[C@H](O)[C@@H](COP([O-])([O-])=O)O[C@H]1N1C(NC=NC2=O)=C2N=C1 AANLCWYVVNBGEE-IDIVVRGQSA-L 0.000 claims description 16
- 235000013890 disodium inosinate Nutrition 0.000 claims description 16
- 239000004278 EU approved seasoning Substances 0.000 claims description 11
- 239000003349 gelling agent Substances 0.000 claims description 5
- 150000004676 glycans Chemical class 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229920001282 polysaccharide Polymers 0.000 claims description 5
- 239000005017 polysaccharide Substances 0.000 claims description 5
- 108090000623 proteins and genes Proteins 0.000 claims description 5
- 102000004169 proteins and genes Human genes 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 4
- 235000011837 pasties Nutrition 0.000 claims description 2
- 235000002639 sodium chloride Nutrition 0.000 description 22
- 239000013078 crystal Substances 0.000 description 17
- 238000001556 precipitation Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 150000007523 nucleic acids Chemical class 0.000 description 6
- 102000039446 nucleic acids Human genes 0.000 description 6
- 108020004707 nucleic acids Proteins 0.000 description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- 235000019640 taste Nutrition 0.000 description 5
- GRSZFWQUAKGDAV-UHFFFAOYSA-N Inosinic acid Natural products OC1C(O)C(COP(O)(O)=O)OC1N1C(NC=NC2=O)=C2N=C1 GRSZFWQUAKGDAV-UHFFFAOYSA-N 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000000284 extract Substances 0.000 description 4
- 235000013902 inosinic acid Nutrition 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 235000018102 proteins Nutrition 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 150000001413 amino acids Chemical class 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 1
- GRSZFWQUAKGDAV-KQYNXXCUSA-N IMP Chemical compound O[C@@H]1[C@H](O)[C@@H](COP(O)(O)=O)O[C@H]1N1C(NC=NC2=O)=C2N=C1 GRSZFWQUAKGDAV-KQYNXXCUSA-N 0.000 description 1
- 244000294411 Mirabilis expansa Species 0.000 description 1
- 235000015429 Mirabilis expansa Nutrition 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 239000008122 artificial sweetener Substances 0.000 description 1
- 235000021311 artificial sweeteners Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 229940041514 candida albicans extract Drugs 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- -1 cubes Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003778 fat substitute Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000013536 miso Nutrition 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- LPUQAYUQRXPFSQ-DFWYDOINSA-M monosodium L-glutamate Chemical compound [Na+].[O-]C(=O)[C@@H](N)CCC(O)=O LPUQAYUQRXPFSQ-DFWYDOINSA-M 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 239000004223 monosodium glutamate Substances 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 235000021096 natural sweeteners Nutrition 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 235000021264 seasoned food Nutrition 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 235000013555 soy sauce Nutrition 0.000 description 1
- 235000019710 soybean protein Nutrition 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 229940100445 wheat starch Drugs 0.000 description 1
- 239000012138 yeast extract Substances 0.000 description 1
Landscapes
- Seasonings (AREA)
Description
本発明は、液状調味料の製造法に関し、更に詳
しくは、食塩濃度が高い液状調味料における5′−
イノシン酸ナトリウムの結晶析出を遅延乃至は防
止することにより均質かつ安定な液状調味料を製
造する方法に関する。
調味料には、粉末、顆粒、キユーブ、ペース
ト、液体等種々の形態があるが、例えば、動植物
エキス等を含有するものの場合、乾燥による味、
風味等の低下が少ない、吸湿等による物性変化を
考慮しないで済む、或いは、調味料の溶解操作が
容易であり、作業環境を汚染しない等の理由によ
り、液状の調味料が普及している。
液状調味料には、動植物エキス、各種アミノ酸
その塩、各種有機酸、その塩、その他の種々の呈
味、風味成分、香料、香辛料等が配合されている
が、塩味等の呈味機能に加え、液状であるために
特に問題となる保存性を、合成保存料等を用いず
に向上するために、食塩を比較的高濃度で配合す
る方法が有効となる。
このような食塩高濃度の液状調味料に5′−イノ
シン酸及びその塩を配合する場合、5′−イノシン
酸ナトリウムの溶解度が減少するために、製品の
品質安定性、均質性が損われるという問題を生じ
る。
第1図は、食塩と5′−イノシン酸ナトリウムの
溶解度を示すが、食塩濃度が高まるにつれ、5′−
イノシン酸ナトリウムの溶解度は減少し、室温下
では、例えば食塩濃度が5〜10%の場合、5′−イ
ノシン酸ナトリウム溶解度は1〜5%に低下す
る。この5′−イノシン酸ナトリウムの溶解度は多
成分の組合せで調製した液状調味料においても同
傾向にある。従つて常温において5′−イノシン酸
ナトリウムが完全溶解状態である液体調味料が、
低温保存或いは冬場低温下に放置した場合に5′−
イノシン酸ナトリウムの溶解度は低下し、結晶の
析出が起る。
或いは、5′−イノシン酸ナトリウムを高濃度で
含有する場合には、食塩の添加が制限されたり、
常温でも5′−イノシン酸ナトリウムの結晶の析出
が生じるようになる。
温度条件、保存時間によつて結晶の成長は変化
するが、肉眼でも充分観察できる大きさとなり、
条件によつては針状の長い結晶になるため、異物
としてクレームの対象となることも起る。更に、
結晶の大きさはまちまちで、均一混合、分散、浮
遊が困難となる。特に大容量の容器から少量づつ
使用する場合においては、味のバラツキ等が問題
となる。
一般的にこのような場合、温度を上げて5′−イ
ノシン酸ナトリウムを再溶解させてから使用する
方法や、調味液中の食塩濃度を下げて5′−イノシ
ン酸ナトリウムの溶解度を高める方法等が考えら
れるが、いずれも、保存性、使用時の簡便性等か
ら、必ずしも満足できる方法とはいえない。
本発明者らは、このような高食塩濃度下の5′−
イノシン酸ナトリウム含有液状調味料における
5′−イノシン酸ナトリウム結晶析出の解消を図る
べく鋭意検討を重ねた結果、多糖類、蛋白、糊
料、ゲル化剤を0.1%以上添加することにより、
核酸の結晶析出が防止でき、保存安定性及び均質
性に優れた液状調味料が取得できるとの知見に至
り本発明を完成したものである。
本発明で対象となる液状調味料は、食塩及び
5′−イノシン酸ナトリウムを含有する液体乃至ペ
ースト状のものすべてが含まれ、その他の成分の
種類及び数については限定されない。即ち、魚介
エキス、動物エキス、酵母エキス、ボーンエキ
ス、動物蛋白加水分解物(HAP)、植物蛋白加水
分解物(HVP)その他の各種エキス類、グルタ
ミン酸ナトリウムその他のアミノ酸及びその塩、
有機酸及びその塩、天然又は人工甘味料、油脂、
などの中から必要に応じ選択された如何なる成分
で構成されてもよい。
食塩は、食塩として、又は、醤油、味噌その他
の含塩調味料に含まれる食塩として、最終製品濃
度で5%以上25%以下であるが、この濃度であれ
ば、微生物的に安定な液状乃至はペースト状調味
料として提供可能である。
5′−イノシン酸ナトリウムの濃度は5%以下で
ありかつ、その溶解度以上である。
液状調味料に対し、澱粉、天然ガム等の多糖
類、ゼラチン、大豆蛋白、カゼイン等の蛋白、
CMC、アルギン酸ナトリウム等の糊料その他の
ゲル化剤の中から選ばれた1種又は2種以上を併
用して添加する。
これら多糖類、蛋白、糊料、ゲル化剤の添加濃
度は、液状調味料に対し、0.1%以上である。添
加濃度が0.1%以下の場合、核酸の結晶析出遅延
又は防止効果が十分でないが、逆に濃度が高すぎ
ると、味、風味のバランスや物性に悪影響を与え
る場合を生じるため、最適濃度は、0.1〜10.0%
である。
食塩、核酸、多糖類、蛋白、糊料、ゲル化剤並
びに必要に応じて配合されるその他の成分の添加
順序、殺菌方法等は特に限定されず、例えば常法
に従つて添加し、目的とする液状調味料を得る。
本発明方法により得られる液状調味料は、液
体、スラリー、ペースト状等の性状であり、その
ままで又は水、湯等で希釈する等により、飛散、
だまの発生などがなく呈味力の優れた調味料、調
味食品が得られ、流通、保存段階で5′−イノシン
酸ナトリウムの結晶析出も見られず、微生物的に
も安定なため、液状の調味料として、広い用途が
期待できる。
以下、実施例により本発明を更に説明する。
実施例 1
液状調味料(A)の配合
小 麦 澱 粉 3部
食 塩 10部
水 87部
IMP・2Na・7.5H2O 3部
液状調味料(B)の配合
可溶性ゼラチン 3部
食 塩 10部
水 87部
INP・2Na・7.5H2O 3部
対照の配合
食 塩 10部
水 90部
IMP・2Na・7.5H2O 3部
上記の配合に従い食塩−水(−評価物質)の系
に十分に核酸の結晶が溶解し得る温度(80℃)で
核酸の結晶を溶解した後、一定時間、恒温状態
(20℃)に置いた。次に、飽和温度より低い温度
にまで冷却し、冷却開始から結晶が析出し終るま
での時間を測定した。結果を第1表に示す。
The present invention relates to a method for producing a liquid seasoning, and more particularly, to a method for producing a liquid seasoning, and more specifically, the present invention relates to a method for producing a liquid seasoning.
The present invention relates to a method for producing a homogeneous and stable liquid seasoning by delaying or preventing crystal precipitation of sodium inosinate. Seasonings come in various forms such as powders, granules, cubes, pastes, and liquids, but for example, in the case of those containing animal and plant extracts, the taste due to drying,
Liquid seasonings are popular because they cause less deterioration in flavor, do not require consideration of changes in physical properties due to moisture absorption, etc., are easy to dissolve seasonings, and do not contaminate the working environment. Liquid seasonings contain animal and plant extracts, various amino acids, their salts, various organic acids, their salts, and various other tastes, flavor components, fragrances, and spices. In order to improve the storage stability, which is particularly problematic due to the liquid state, without using synthetic preservatives, it is effective to incorporate common salt at a relatively high concentration. When 5'-inosinic acid and its salts are added to such a liquid seasoning with a high salt concentration, the solubility of sodium 5'-inosinate decreases, which impairs the quality stability and homogeneity of the product. cause problems. Figure 1 shows the solubility of common salt and sodium 5'-inosinate; as the salt concentration increases, the 5'-
The solubility of sodium inosinate decreases; at room temperature, for example, when the salt concentration is 5 to 10%, the solubility of sodium 5'-inosinate decreases to 1 to 5%. The solubility of sodium 5'-inosinate tends to be the same even in liquid seasonings prepared with a combination of multiple ingredients. Therefore, a liquid seasoning in which sodium 5'-inosinate is completely dissolved at room temperature is
5′− when stored at low temperatures or left at low temperatures in winter.
The solubility of sodium inosinate decreases and crystal precipitation occurs. Alternatively, if sodium 5'-inosinate is contained at a high concentration, the addition of salt may be limited, or
Crystals of 5'-sodium inosinate begin to precipitate even at room temperature. The growth of crystals changes depending on temperature conditions and storage time, but the crystals grow large enough to be observed with the naked eye.
Depending on the conditions, the crystals may form long needle-like crystals, which may become the subject of claims as foreign substances. Furthermore,
Crystals vary in size, making uniform mixing, dispersion, and floating difficult. Particularly when using small quantities from a large capacity container, variations in taste etc. become a problem. Generally, in such cases, there are methods such as increasing the temperature to redissolve the 5'-sodium inosinate before use, or lowering the salt concentration in the seasoning solution to increase the solubility of the 5'-sodium inosinate. However, none of these methods is necessarily satisfactory in terms of storage stability, ease of use, etc. The present inventors discovered that 5'-
In liquid seasonings containing sodium inosinate
As a result of intensive studies to eliminate the precipitation of sodium 5'-inosinate crystals, we found that by adding 0.1% or more of polysaccharides, proteins, thickeners, and gelling agents,
The present invention was completed based on the finding that a liquid seasoning that can prevent nucleic acid crystal precipitation and has excellent storage stability and homogeneity can be obtained. The liquid seasonings targeted by the present invention include common salt and
All liquids or pastes containing sodium 5'-inosinate are included, and the types and numbers of other ingredients are not limited. Namely, seafood extract, animal extract, yeast extract, bone extract, hydrolyzed animal protein (HAP), hydrolyzed vegetable protein (HVP) and other various extracts, monosodium glutamate and other amino acids and their salts,
Organic acids and their salts, natural or artificial sweeteners, fats and oils,
It may be composed of any component selected from among the following as necessary. Salt, as table salt or as salt contained in soy sauce, miso, and other salt-containing seasonings, has a concentration of 5% to 25% in the final product, but at this concentration, it is in a microbially stable liquid or can be provided as a pasty seasoning. The concentration of sodium 5'-inosinate is less than 5% and greater than its solubility. For liquid seasonings, starch, polysaccharides such as natural gum, proteins such as gelatin, soybean protein, casein, etc.
One or more selected from pastes such as CMC and sodium alginate and other gelling agents are added in combination. The concentration of these polysaccharides, proteins, thickening agents, and gelling agents is 0.1% or more based on the liquid seasoning. If the added concentration is 0.1% or less, the effect of delaying or preventing nucleic acid crystal precipitation will not be sufficient. On the other hand, if the concentration is too high, it may adversely affect the balance of taste and flavor and physical properties. Therefore, the optimal concentration is: 0.1~10.0%
It is. The order of adding salt, nucleic acids, polysaccharides, proteins, thickening agents, gelling agents, and other ingredients added as necessary, as well as the sterilization method, etc., are not particularly limited. Obtain a liquid seasoning. The liquid seasoning obtained by the method of the present invention is in the form of liquid, slurry, paste, etc., and can be used as it is or by diluting with water, hot water, etc. to prevent scattering or
Seasonings and seasoned foods with excellent taste are obtained without the formation of lumps, and no crystal precipitation of sodium 5'-inosinate is observed during the distribution and storage stages, and it is microbially stable. It can be expected to have a wide range of uses as a seasoning. The present invention will be further explained below with reference to Examples. Example 1 Blend of liquid seasoning (A) Wheat Starch 3 parts Salt 10 parts Water 87 parts IMP・2Na・7.5H 2 O 3 parts Blend of liquid seasoning (B) Soluble gelatin 3 parts Salt 10 parts Water 87 parts INP・2Na・7.5H 2 O 3 parts Control mixed food Salt 10 parts Water 90 parts IMP・2Na・7.5H 2 O 3 parts According to the above formulation, add enough water to the salt-water (-evaluation substance) system. After the nucleic acid crystals were dissolved at a temperature (80°C) at which the nucleic acid crystals could be dissolved, the solution was kept at a constant temperature (20°C) for a certain period of time. Next, it was cooled to a temperature lower than the saturation temperature, and the time from the start of cooling until the end of precipitation of crystals was measured. The results are shown in Table 1.
【表】
実施例 2
下記に示した各液体調味料の配合により、25℃
にて調整後5℃にて冷却放置し核酸結晶の析出状
態を顕微鏡で観察した。結果を第2表に示す。[Table] Example 2 By the combination of each liquid seasoning shown below, 25℃
After adjustment at 5° C., the mixture was left to cool at 5° C., and the state of precipitation of nucleic acid crystals was observed using a microscope. The results are shown in Table 2.
【表】【table】
【表】【table】
【表】
第1表及び第2表の結果から明らかなように、
本発明品は5′−イノシン酸ナトリウムの結晶析出
が遅く、安定な物性を示している。[Table] As is clear from the results in Tables 1 and 2,
The product of the present invention exhibits stable physical properties, with slow crystal precipitation of sodium 5'-inosinate.
第1図はIMP・2Na・7.5H2O及び食塩の共通
溶解度を示す。
Figure 1 shows the common solubility of IMP, 2Na, 7.5H 2 O, and common salt.
Claims (1)
リウムを濃度が5%以下でかつその溶解度以上と
なる量含有する液体又はペースト状調味料に、多
糖類、蛋白、糊料及びゲル化剤の中から選ばれた
1種以上を0.01%以上添加することを特徴とする
液状調味料の製法。1. Polysaccharides, proteins, thickening agents, and gelling agents are added to liquid or pasty seasonings with a salt concentration of 5 to 25% and sodium 5'-inosinate in an amount that is less than 5% and greater than its solubility. A method for producing a liquid seasoning characterized by adding 0.01% or more of one or more selected from the following.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57194207A JPS5985270A (en) | 1982-11-05 | 1982-11-05 | Production of liquid seasoning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57194207A JPS5985270A (en) | 1982-11-05 | 1982-11-05 | Production of liquid seasoning |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5985270A JPS5985270A (en) | 1984-05-17 |
| JPH0426822B2 true JPH0426822B2 (en) | 1992-05-08 |
Family
ID=16320732
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57194207A Granted JPS5985270A (en) | 1982-11-05 | 1982-11-05 | Production of liquid seasoning |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5985270A (en) |
-
1982
- 1982-11-05 JP JP57194207A patent/JPS5985270A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5985270A (en) | 1984-05-17 |
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