JPH04316633A - Continuous filament-reinforced thermoplastic resin molding material - Google Patents
Continuous filament-reinforced thermoplastic resin molding materialInfo
- Publication number
- JPH04316633A JPH04316633A JP3108545A JP10854591A JPH04316633A JP H04316633 A JPH04316633 A JP H04316633A JP 3108545 A JP3108545 A JP 3108545A JP 10854591 A JP10854591 A JP 10854591A JP H04316633 A JPH04316633 A JP H04316633A
- Authority
- JP
- Japan
- Prior art keywords
- thermoplastic resin
- fibers
- woven fabric
- fiber
- molding material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
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- Treatment Of Fiber Materials (AREA)
- Woven Fabrics (AREA)
Abstract
Description
【0001】0001
【産業上の利用分野】本発明は、補強用連続繊維と熱可
塑性樹脂繊維とからなる織物によって構成した連続繊維
補強熱可塑性樹脂成形材料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a continuous fiber-reinforced thermoplastic resin molding material composed of a woven fabric made of reinforcing continuous fibers and thermoplastic resin fibers.
【0002】0002
【従来の技術】従来、連続繊維補強熱可塑性樹脂成形体
を作るための成形材料として、補強用連続繊維を引き揃
え、溶融した熱可塑性樹脂中に浸漬させることによって
その補強用連続繊維に樹脂を含浸させ、その後樹脂を冷
却、固化することによって作ったシート状材料が知られ
ている。しかしながら、この成形材料は、常温ではきわ
めて硬く、そのままではドレープ性(型なじみ性)が悪
いので、成形する時は、これをオーブンなどで加熱し柔
軟性をもたせてプレスなどで加圧賦形しなければならず
、作業性が悪く、しかも成形体に微妙な形状を求められ
る場合、その対応は極めて困難であった。更に、ポリエ
ーテルエーテルケトンのような高融点の熱可塑性樹脂を
用いる場合には、その熱可塑性樹脂を補強用連続繊維に
含浸させる際の酸化を防ぐために熱可塑性樹脂を不活性
ガス雰囲気中で溶融しその中に連続繊維を浸漬させると
いうような配慮をしなければならず、装置が大型化し、
コスト高となる等の問題もあった。[Prior Art] Conventionally, as a molding material for making a continuous fiber-reinforced thermoplastic resin molded article, continuous reinforcing fibers are aligned and immersed in a molten thermoplastic resin to inject resin into the reinforcing continuous fibers. Sheet-like materials made by impregnating resin and then cooling and solidifying the resin are known. However, this molding material is extremely hard at room temperature and has poor drape properties (mold conformability) if left as is, so when molding it, it must be heated in an oven to make it flexible and then pressurized with a press. However, when the molded article is required to have a delicate shape, it is extremely difficult to handle it. Furthermore, when using a thermoplastic resin with a high melting point such as polyetheretherketone, the thermoplastic resin is melted in an inert gas atmosphere to prevent oxidation when impregnating the reinforcing continuous fibers with the thermoplastic resin. Care must be taken to immerse the continuous fibers in the shiso, which increases the size of the equipment.
There were also problems such as high costs.
【0003】これに対応するため、熱可塑性樹脂を繊維
化し、これを補強用の連続繊維と一緒に織り込んて得た
交織織物、或いは、糸の段階で両者をなんらかの方法で
混合しておき、これを製織して得た混織織物を成形材料
とする方法(ファイバーマトリクス法)が知られている
。このようなファイバーマトリクス法に使用する織物は
柔軟であるためドレープ性が良いという利点を有してい
る。[0003] In order to deal with this, thermoplastic resin is made into fibers and this is woven together with reinforcing continuous fibers to obtain a mixed woven fabric, or the two are mixed in some way at the yarn stage. A method is known in which a blended fabric obtained by weaving is used as a molding material (fiber matrix method). The fabric used in such a fiber matrix method has the advantage of good drapability because it is flexible.
【0004】0004
【発明が解決しようとする課題】しかしながら、ファイ
バーマトリクス法に使用する織物は、撚りのほとんどか
かっていない繊維糸を縦糸、横糸として、粗い織り目を
形成するように製織したものであるので、柔軟で切断性
が悪く、しかも、その切断時に繊維がほつれてしまい、
作業性が極めて悪いという問題があった。また、その織
物を成形のために型内にセットした際に目曲がりを生じ
やすく、そのため、成形体中の補強繊維が曲がっていて
外観が悪いとか補強効果が低い等の問題もあった。[Problems to be Solved by the Invention] However, the fabrics used in the fiber matrix method are woven with almost untwisted fiber yarns as the warp and weft to form a coarse weave, so they are not flexible. It has poor cutting properties, and the fibers fray when cutting.
There was a problem that workability was extremely poor. In addition, when the woven fabric is set in a mold for molding, it tends to bend, and as a result, the reinforcing fibers in the molded article are bent, resulting in problems such as poor appearance and poor reinforcing effect.
【0005】本発明はかかる従来の問題点に鑑みてなさ
れたもので、ドレープ性が良く、切断時にほつれを生じ
ることなく容易に切断でき、しかも目曲がりを生じにく
い織物からなる連続繊維補強熱可塑性樹脂成形材料を提
供することを目的とする。The present invention has been made in view of such conventional problems, and provides a continuous fiber-reinforced thermoplastic fabric made of a fabric that has good drapability, can be easily cut without fraying when cut, and is less prone to bending. The purpose is to provide resin molding materials.
【0006】[0006]
【課題を解決するための手段】本発明者等は上記問題点
を解決すべく鋭意検討の結果、補強用連続繊維と熱可塑
性樹脂繊維とからなる織物を加熱、加圧することにより
、その熱可塑性樹脂繊維をそれに交差する糸に対して熱
接着させたり、或いは熱可塑性樹脂繊維を含む縦糸或い
は横糸等をリボン状としそれに交差する糸に対して接着
或いは含浸させることができ、それにより切断時の繊維
のほつれや型内にセットした際の目曲がりを防止できる
ことを見出し、本発明を完成した。[Means for Solving the Problems] As a result of intensive studies to solve the above-mentioned problems, the present inventors have devised a thermoplastic resin by heating and pressurizing a fabric made of reinforcing continuous fibers and thermoplastic resin fibers. Resin fibers can be thermally bonded to the threads that cross them, or warp or weft threads containing thermoplastic resin fibers can be made into a ribbon shape and the threads that cross them can be bonded or impregnated. The present invention was completed based on the discovery that it is possible to prevent fibers from fraying and bending when set in a mold.
【0007】すなわち、本願第一の発明は、補強用連続
繊維と熱可塑性樹脂繊維からなる織物で構成され、織物
内の熱可塑性樹脂繊維が、それに交差している糸に対し
て熱接着していることを特徴とする連続繊維補強熱可塑
性樹脂成形材料を要旨とする。That is, the first invention of the present application is composed of a woven fabric made of reinforcing continuous fibers and thermoplastic resin fibers, and the thermoplastic resin fibers in the woven fabric are thermally bonded to the threads intersecting with the woven fabric. The subject matter is a continuous fiber-reinforced thermoplastic resin molding material characterized by:
【0008】また、本願第二の発明は、補強用連続繊維
と熱可塑性樹脂繊維からなる織物で構成され、その織物
内の熱可塑性樹脂繊維を含む糸が熱溶融によりリボン状
となり、それに交差している糸に対して接着或いは含浸
していることを特徴とする連続繊維補強熱可塑性樹脂成
形材料を要旨とする。Further, the second invention of the present application is composed of a woven fabric made of reinforcing continuous fibers and thermoplastic resin fibers, and the threads containing the thermoplastic resin fibers in the woven fabric are thermally melted into a ribbon shape and intersected with the woven fabric. The gist of the invention is a continuous fiber-reinforced thermoplastic resin molding material, which is characterized by being adhesively bonded to or impregnated with fibers.
【0009】以下、本発明を詳細に説明する。本発明に
使用する織物は、補強用連続繊維と熱可塑性樹脂繊維と
からなるものであればよく、織物内における繊維の配列
については特に制限されるものではない。すなわち、本
発明に使用する織物としては、補強用連続繊維の配列に
関して大別すれば、補強用連続繊維が縦糸又は横糸のい
ずれか一方のみに配置されている一方向性補強成形体用
織物と、補強用連続繊維が縦糸及び横糸のいずれにも配
置されている両方向性補強成形体用織物を挙げることが
できる。更に、これらの織物内において、補強用連続繊
維及び熱可塑性樹脂繊維は、それぞれが別個に糸を構成
し、縦糸及び/又は横糸として使用されてもよいし、或
いは、補強用連続繊維と熱可塑性樹脂繊維とを混合して
1本の糸とし、それを縦糸及び/又は縦糸として使用し
てもよい。以下に本発明に使用しうる織物の代表的な具
体例を列挙すると共に図3、図4に概略的に示す。The present invention will be explained in detail below. The woven fabric used in the present invention may be made of reinforcing continuous fibers and thermoplastic resin fibers, and the arrangement of the fibers within the woven fabric is not particularly limited. That is, the woven fabrics used in the present invention can be broadly classified into woven fabrics for unidirectional reinforced molded bodies in which reinforcing continuous fibers are arranged only in either the warp or the weft, and , bidirectional reinforced fabrics for molded bodies in which reinforcing continuous fibers are arranged in both the warp and the weft. Furthermore, within these fabrics, the reinforcing continuous fibers and the thermoplastic resin fibers may each constitute separate threads and be used as warp and/or weft threads, or the reinforcing continuous fibers and the thermoplastic resin fibers may be used as warp and/or weft threads. It is also possible to mix the fibers with resin fibers to form a single thread and use it as the warp and/or warp thread. Typical examples of textiles that can be used in the present invention are listed below and are schematically shown in FIGS. 3 and 4.
【0010】(1)一方向性補強成形用織物(図3参照
)
(a)図3(a)に示すように、縦糸と横糸のいずれか
一方を、補強用連続繊維のみからなる糸(補強用連続繊
維糸という)1、他方を熱可塑性樹脂繊維のみからなる
糸(熱可塑性樹脂繊維糸という)2とした交織織物。こ
の場合には、補強用連続繊維糸1を縦糸として使用する
ことが好適である。
(b)図3(b)に示すように、縦糸と横糸のいずれか
一方を、補強用連続繊維糸1と熱可塑性樹脂繊維糸2と
し、他方を熱可塑性樹脂繊維糸2とした交織織物。この
場合にも、補強用連続繊維糸は縦糸として使用すること
が好適である。なお、図面では平行に配列された補強用
連続繊維糸1と熱可塑性樹脂繊維糸2とを同数使用し、
交互に配置しているが、使用本数の比率、配列等は適宜
変更可能である。
(c)図3(c)に示すように、縦糸と横糸のいずれか
一方を、補強用連続繊維と熱可塑性樹脂繊維とを混合し
た糸(混合糸という)3とし、他方を熱可塑性樹脂繊維
糸2とした混織織物。この場合にも、補強用連続繊維を
含んだ混合糸3は縦糸に使用することが好適である。(1) Unidirectional reinforced fabric for forming (see Figure 3) (a) As shown in Figure 3(a), either the warp or the weft is replaced with a yarn consisting only of reinforcing continuous fibers (reinforcing A mixed woven fabric in which one yarn (referred to as a continuous fiber yarn) and the other yarn (referred to as a thermoplastic resin fiber yarn) 2 are made of only thermoplastic resin fibers. In this case, it is preferable to use the reinforcing continuous fiber yarn 1 as the warp. (b) As shown in FIG. 3(b), a mixed woven fabric in which one of the warp and weft is a reinforcing continuous fiber yarn 1 and a thermoplastic resin fiber yarn 2, and the other is a thermoplastic resin fiber yarn 2. In this case as well, it is preferable to use the reinforcing continuous fiber yarn as the warp yarn. In addition, in the drawing, the same number of reinforcing continuous fiber yarns 1 and thermoplastic resin fiber yarns 2 arranged in parallel are used,
Although they are arranged alternately, the ratio of the number used, arrangement, etc. can be changed as appropriate. (c) As shown in Fig. 3(c), one of the warp and weft is a yarn (referred to as mixed yarn) 3 that is a mixture of reinforcing continuous fibers and thermoplastic resin fibers, and the other is a thermoplastic resin fiber. Blended fabric with 2 threads. In this case as well, it is preferable to use the mixed yarn 3 containing reinforcing continuous fibers as the warp yarn.
【0011】(2)両方向性補強成形用織物(図4参照
)
(a)図4(a)に示すように、補強用連続繊維糸1と
熱可塑性樹脂繊維糸2とを、それぞれ縦糸、横糸の両方
に使用した交織織物。
(b)図4(b)に示すように、縦糸と横糸のいずれか
一方を、補強用連続繊維糸1と熱可塑性樹脂繊維糸2と
し、他方を補強用連続繊維糸1とした交織織物。
(c)図4(c)に示すように、縦糸と横糸のいずれか
一方を、補強用連続繊維と熱可塑性樹脂繊維とを混合し
た混合糸3とし、他方を補強用連続繊維糸1とした混織
織物。
(d)図4(d)に示すように、縦糸と横糸のいずれか
一方を、混合糸3とし、他方を補強用連続繊維糸1と熱
可塑性樹脂繊維糸2とした混織織物。
(e)図4(e)に示すように、縦糸と横糸の両方を、
混合糸3とした混織織物。(2) Bidirectional reinforcing molding fabric (see FIG. 4) (a) As shown in FIG. Mixed woven fabric used for both. (b) As shown in FIG. 4(b), a mixed woven fabric in which one of the warp and weft is a reinforcing continuous fiber yarn 1 and a thermoplastic resin fiber yarn 2, and the other is a reinforcing continuous fiber yarn 1. (c) As shown in Fig. 4(c), one of the warp and weft yarns is a mixed yarn 3 made of a mixture of reinforcing continuous fibers and thermoplastic resin fibers, and the other is a reinforcing continuous fiber yarn 1. Blended fabric. (d) As shown in FIG. 4(d), a blended fabric in which one of the warp and weft is a mixed yarn 3, and the other is a reinforcing continuous fiber yarn 1 and a thermoplastic resin fiber yarn 2. (e) As shown in Figure 4(e), both warp and weft threads are
A blended fabric with 3 mixed yarns.
【0012】本発明に使用する織物の織り組織は、通常
は、図3、図4に示す平織りが使用されるが、これに限
らず、他の織り組織、例えば斜文織り、朱子織り、なな
こ織り等を使用してもよい。なお、縦糸、横糸の両方向
に補強用連続繊維を配列する場合には、特開昭64−4
5841号公報(特願昭62−200905号)に示す
ように、熱可塑性樹脂繊維を溶融した後においても、補
強用連続繊維のみで織り組織を構成するような織り組織
とすることが好ましい。The weave structure of the fabric used in the present invention is usually the plain weave shown in FIGS. 3 and 4, but is not limited to this, and other weave structures such as diagonal weave, satin weave, and nanako weave are also used. Weaving or the like may also be used. In addition, when arranging reinforcing continuous fibers in both the warp and weft directions, Japanese Patent Application Laid-Open No. 64-4
As shown in Japanese Patent Application No. 5841 (Japanese Patent Application No. 62-200905), it is preferable to have a woven structure in which the woven structure is composed only of reinforcing continuous fibers even after the thermoplastic resin fibers are melted.
【0013】本発明に使用する補強用連続繊維としては
、ガラス繊維、カーボン繊維、アラミド繊維、アルミナ
繊維、金属繊維等、使用する熱可塑性樹脂繊維糸よりも
高融点のものであれば、特に限定されない。補強用連続
繊維としてガラス繊維を用い、かつ多数の集束したガラ
ス繊維からなる糸を縦糸或いは横糸として使用する場合
、そのモノフィラメントの直径は、通常3〜23μmに
、望ましくは、5〜15μmであり、集束本数は、望ま
しくは、100〜800本である。The reinforcing continuous fibers used in the present invention are not particularly limited as long as they have a higher melting point than the thermoplastic resin fiber yarn used, such as glass fibers, carbon fibers, aramid fibers, alumina fibers, metal fibers, etc. Not done. When glass fiber is used as the reinforcing continuous fiber and a thread consisting of a large number of bundled glass fibers is used as the warp or weft, the diameter of the monofilament is usually 3 to 23 μm, preferably 5 to 15 μm, The number of convergence is preferably 100 to 800.
【0014】本発明に使用する熱可塑性樹脂繊維として
は、ポリプロピレン、ポリエチレン、ポリアミド、ポリ
エステル、ポリカーボネート、ポリアセタール、ポリサ
ルフォン、ポリエーテルサルフォン、ポリエーテルエー
テルケトン、ポリエーテルケトン、ポリエーテルイミド
、ポリフェニレンサルファイド等、繊維状にできるもの
であれば特に限定されない。その繊維の形態は、長繊維
を集束したものであっても、或いはステープル糸であっ
てもよい。そのモノフィラメント直径は、通常10〜2
00μm、望ましくは、40〜80μmに選択される。Thermoplastic resin fibers used in the present invention include polypropylene, polyethylene, polyamide, polyester, polycarbonate, polyacetal, polysulfone, polyethersulfone, polyetheretherketone, polyetherketone, polyetherimide, polyphenylene sulfide, etc. It is not particularly limited as long as it can be made into a fibrous form. The fibers may be in the form of bundles of long fibers or staple yarns. The monofilament diameter is usually 10-2
00 μm, preferably 40 to 80 μm.
【0015】本発明に使用する織物内における補強用連
続繊維と熱可塑性樹脂繊維との割合は、それによって製
造する成形体中における補強材の含有率を考慮して定め
るものであり、補強用連続繊維が体積含有率で、通常3
0〜65%、好ましくは45〜60%に選定される。The ratio of reinforcing continuous fibers and thermoplastic resin fibers in the woven fabric used in the present invention is determined by taking into account the reinforcing material content in the molded article produced thereby. The fiber volume content is usually 3
It is selected to be 0 to 65%, preferably 45 to 60%.
【0016】本願第一の発明になる成形材料は、上記し
た補強用連続繊維と熱可塑性樹脂繊維とからなる織物に
おいて、熱可塑性樹脂繊維を、それに交差している糸に
対して熱接着したことを特徴としている。例えば、図3
、図4に示す織物において、熱可塑性樹脂繊維糸2及び
熱可塑性樹脂繊維を含む混合糸3を、それに交差する他
の糸(補強用連続繊維糸1、熱可塑性樹脂繊維糸2、混
合糸3)に熱接着している。この熱可塑性樹脂繊維の熱
接着は、織物に加熱加圧加工を施すことにより得られる
。その織物の加熱加圧加工には、図5に示すように、織
物5を、表面温度を所定温度に昇温させている熱ロール
6と、その熱ロール6に対して適当な圧力で押し付けら
れている押えロール7の間に通し、これらのロール6、
7によって加熱加圧する方法を採ることが好ましい。こ
のような熱ロールを用いた方法では、織物5を原反8か
ら繰り出し、熱ロール6と押えロール7の間を通した後
、巻取ロール9として巻き取るという連続的な処理を行
うことが可能であり、かつ熱ロール6の表面温度を制御
することにより織物の熱可塑性樹脂繊維の加熱温度を制
御でき、温度制御が容易となる利点が得られる。
なお、織物の加熱加圧に用いる熱ロール6としては、通
常金属ロールが用いられ、押えロール7にはゴムロール
が用いられるが、必要に応じ押えロール7としても金属
ロールを用い、またそれを加熱するようにしてもよい。
また、図5では、織物5を熱ロール6と押えロール7の
間に直線状に走行させているが、必要に応じ織物5を熱
ロール6の外周面に適当な角度にわたって接触させ、予
熱するようにしてもよいし、熱ロール6の上流に別の熱
ロールを配置し、織物を予熱するようにしてもよい。[0016] The molding material according to the first invention of the present application is obtained by thermally bonding the thermoplastic resin fibers to the intersecting threads of the above-mentioned woven fabric consisting of reinforcing continuous fibers and thermoplastic resin fibers. It is characterized by For example, Figure 3
In the fabric shown in FIG. 4, a thermoplastic resin fiber yarn 2 and a mixed yarn 3 containing thermoplastic resin fiber are combined with other yarns (reinforcing continuous fiber yarn 1, thermoplastic resin fiber yarn 2, mixed yarn 3) that intersect therewith. ) is thermally bonded to the This thermal adhesion of thermoplastic resin fibers is obtained by subjecting the fabric to heating and pressure processing. As shown in FIG. 5, the heating and pressure processing of the textile fabric involves pressing the textile fabric 5 against a heating roll 6 whose surface temperature is raised to a predetermined temperature with an appropriate pressure. These rolls 6,
It is preferable to adopt a heating and pressurizing method according to step 7. In the method using such a hot roll, it is possible to carry out a continuous process in which the fabric 5 is unwound from the raw fabric 8, passed between the hot roll 6 and the presser roll 7, and then wound up as a take-up roll 9. This is possible, and by controlling the surface temperature of the heat roll 6, the heating temperature of the thermoplastic resin fibers of the fabric can be controlled, and the advantage is that temperature control becomes easy. Note that a metal roll is usually used as the heat roll 6 used for heating and pressing the fabric, and a rubber roll is used as the presser roll 7, but if necessary, a metal roll can also be used as the presser roll 7, and it can also be heated. You may also do so. Further, in FIG. 5, the fabric 5 is run linearly between the heat roll 6 and the presser roll 7, but if necessary, the fabric 5 may be brought into contact with the outer peripheral surface of the heat roll 6 at an appropriate angle to preheat it. Alternatively, another heating roll may be placed upstream of the heating roll 6 to preheat the fabric.
【0017】織物内の熱可塑性樹脂繊維をそれに交差し
ている糸に対して熱接着させるための加熱温度としては
、通常、その熱可塑性樹脂繊維糸の融点以下でかつガラ
ス転移点以上とする。この温度で織物を加熱加圧すると
、織物中の樹脂繊維は完全には溶融しないが、粘性が発
現し、このため、樹脂繊維は繊維形態を残した状態で隣
接した繊維同士に熱接着し、更にそれに交差する糸の繊
維に対しても熱接着する。The heating temperature for thermally adhering the thermoplastic resin fibers in the fabric to the threads crossing them is usually below the melting point of the thermoplastic resin fiber threads and above the glass transition point. When the woven fabric is heated and pressurized at this temperature, the resin fibers in the woven fabric do not completely melt, but they develop viscosity, and as a result, the resin fibers thermally bond to adjacent fibers while retaining their fiber form. Furthermore, it is also thermally bonded to the fibers of the threads that intersect with it.
【0018】上記した加熱加圧加工を行うに際し、使用
する織物が一方向性補強成形体用織物の場合には、補強
用連続繊維を織物の縦糸方向に配列しておき、且つ図5
に示すように熱ロール6で加工する際、織物の縦糸方向
(織物の進行方向)に大きい張力を、幅方向に均一に付
与することが好適である。このように張力を付与しなが
ら加熱加圧加工を行うと、得られた成形材料において補
強用連続繊維を含んだ縦糸が引き延ばされて比較的平坦
となる。例えば、図1は縦糸に補強用連続繊維糸1を、
横糸に熱可塑性樹脂繊維糸2を用いた織物に、縦糸方向
に張力を付与しながら加熱加圧処理を施して得た成形材
料10を示すもので、(a)はその平面図、(b)、(
c)はそれぞれ(a)のB−B矢視図、C−C矢視図で
ある。この(b)、(c)に示すように、縦糸である補
強用連続繊維糸1が引っ張られたために、横糸である熱
可塑性樹脂繊維糸2との交差部分において形成されてい
た湾曲が引き延ばされ、従って、補強用連続繊維糸1は
ほぼ直線状に延びた状態となり、熱可塑性樹脂繊維糸2
のみが湾曲している。この構成の成形材料10は、補強
用連続繊維糸が湾曲を有していないので、成形に際し熱
可塑性樹脂繊維糸2を溶融した時に補強用連続繊維糸に
たるみが生じて目曲がりを生じるということがなく、こ
のため得られた成形品の外観が良好となる。なお、縦糸
を引き延ばした分、横糸に大きい湾曲が生じることとな
るがこの横糸は成形時に溶融するので何ら支障はない。
補強用連続繊維を縦糸,横糸の両方に含んだ両方向性補
強成形体用織物の場合には、縦糸に張力をかけて引っ張
ると横糸の補強用連続繊維の湾曲が大きくなるので、好
ましくなく、従って、この場合には織物の加熱加圧加工
時に織物に強い張力を掛ける必要はない。When carrying out the above-mentioned heating and pressing process, if the fabric used is a fabric for a unidirectional reinforced molded article, reinforcing continuous fibers are arranged in the warp direction of the fabric, and as shown in FIG.
As shown in FIG. 2, when processing with the hot roll 6, it is preferable to apply a large tension in the warp direction of the fabric (travel direction of the fabric) and uniformly in the width direction. When heat and pressure processing is performed while applying tension in this manner, the warp yarns containing reinforcing continuous fibers in the obtained molding material are elongated and become relatively flat. For example, in Fig. 1, reinforcing continuous fiber yarn 1 is inserted into the warp.
It shows a molding material 10 obtained by subjecting a woven fabric using thermoplastic resin fiber threads 2 as wefts to heat and pressure treatment while applying tension in the warp direction, (a) is a plan view thereof, (b) ,(
c) is a BB arrow view and a CC arrow view of (a), respectively. As shown in (b) and (c), since the reinforcing continuous fiber yarn 1, which is the warp yarn, is stretched, the curve formed at the intersection with the thermoplastic resin fiber yarn 2, which is the weft yarn, is stretched and stretched. Therefore, the reinforcing continuous fiber yarn 1 is in a substantially linearly extended state, and the thermoplastic resin fiber yarn 2
Only the edges are curved. In the molding material 10 having this configuration, since the reinforcing continuous fiber yarn does not have any curvature, when the thermoplastic resin fiber yarn 2 is melted during molding, the reinforcing continuous fiber yarn sag and bends. Therefore, the appearance of the obtained molded product is good. Note that the stretching of the warp yarns causes a large curvature in the weft yarns, but since the weft yarns are melted during molding, there is no problem at all. In the case of a fabric for bidirectional reinforcing molded articles containing reinforcing continuous fibers in both the warp and weft, pulling the warp with tension will increase the curvature of the reinforcing continuous fibers in the weft, which is undesirable. In this case, there is no need to apply strong tension to the fabric during heating and pressure processing of the fabric.
【0019】本願第二の発明になる成形材料は、上記し
た補強用連続繊維と熱可塑性樹脂繊維とからなる織物に
おいて、熱可塑性樹脂繊維を含む糸を熱溶融によりリボ
ン状とし、それに交差している糸に対して接着或いは含
浸させていることを特徴とする。この成形材料も、上記
した本願第一の発明になる成形材料と同様に、織物に対
して加熱加圧処理を施すことにより得られる。ただし、
この場合には、織物の加熱温度を、織物内の熱可塑性樹
脂繊維の融点以上とする。この温度で加熱、加圧すると
、織物中の樹脂繊維が溶融し、1本の縦糸或いは横糸を
構成する熱可塑性樹脂繊維糸或いは混合糸がリボン状(
フィルム状)となり、それに交差する糸に対して接着或
いは含浸する。例えば、図3、図4に示す織物において
、熱可塑性樹脂繊維糸2及び熱可塑性樹脂繊維を含む混
合糸3が熱溶融してリボン状となり、それに交差する熱
可塑性樹脂繊維糸2及び混合糸3(これらもリボン状と
なっている)に接着し、また、補強用連続繊維糸1に対
して含浸する。この際、含浸の度合いとしては、リボン
状の樹脂が補強用連続繊維糸の片面のみに含浸し、反対
面までは達しない状態としても、或いは反対面まで達す
るようにしてもよい。これらの含浸の程度は、加熱温度
、加熱時間、加圧力等の条件で調整しうる。[0019] The molding material according to the second invention of the present application is a fabric made of the above-mentioned reinforcing continuous fibers and thermoplastic resin fibers. It is characterized by being bonded to or impregnated with the yarn. This molding material, like the molding material according to the first invention of the present application described above, can also be obtained by subjecting a textile to a heating and pressurizing treatment. however,
In this case, the heating temperature of the woven fabric is set to be higher than the melting point of the thermoplastic resin fibers within the woven fabric. When heated and pressurized at this temperature, the resin fibers in the fabric melt, and the thermoplastic resin fiber yarns or mixed yarns constituting one warp or weft become ribbon-like (
(film-like) and adheres to or impregnates the threads that intersect with it. For example, in the fabrics shown in FIGS. 3 and 4, thermoplastic resin fiber threads 2 and mixed threads 3 containing thermoplastic resin fibers are thermally melted into a ribbon shape, and thermoplastic resin fiber threads 2 and mixed threads 3 intersect therewith. (These are also ribbon-shaped) and impregnated into the reinforcing continuous fiber yarn 1. At this time, the degree of impregnation may be such that the ribbon-shaped resin impregnates only one side of the reinforcing continuous fiber yarn and does not reach the opposite side, or may reach the opposite side. The degree of these impregnations can be adjusted by controlling heating temperature, heating time, pressing force, and other conditions.
【0020】熱可塑性樹脂繊維を含む糸をリボン状に熱
溶融する加工工程においても、使用する織物が一方向性
補強成形体用織物の場合には、補強用連続繊維を織物の
縦糸方向に配列し、縦糸方向に大きい張力を付与するこ
とが好適である。図2は縦糸に補強用連続繊維糸1を、
横糸に熱可塑性樹脂繊維糸2を用いた織物に、縦糸方向
に張力を付与しながら加熱加圧処理を施して得た成形材
料11を示すもので、(a)はその平面図、(b)、(
c)はそれぞれ(a)のB−B矢視図、C−C矢視図で
ある。この(b)、(c)に示すように、縦糸である補
強用連続繊維糸1はほぼ直線状に引き延ばされており、
その上下面に、熱溶融してリボン状となった熱可塑性樹
脂繊維糸2が部分的に含浸している。この成形材料11
も図1に示す成形材料10と同様に、成形体中の補強用
連続繊維糸に曲がりのない、外観の良い成形体を作るこ
とができる。なお、図2では、リボン状となった熱可塑
性樹脂繊維糸2を互いに離れた状態で示しているが、こ
れは説明のためであって、実際には加熱加圧加工される
際に偏平に押しつぶされ、隣接するリボン同士は若干接
着してしまうことがあるが、特に支障はない。Even in the process of heat-melting yarn containing thermoplastic resin fibers into a ribbon shape, if the fabric used is a fabric for a unidirectional reinforced molded article, the reinforcing continuous fibers are arranged in the warp direction of the fabric. However, it is preferable to apply a large tension in the warp direction. Figure 2 shows reinforcing continuous fiber yarn 1 in the warp.
It shows a molding material 11 obtained by subjecting a woven fabric using thermoplastic resin fiber threads 2 as wefts to heat and pressure treatment while applying tension in the warp direction, (a) is a plan view thereof, (b) ,(
c) is a BB arrow view and a CC arrow view of (a), respectively. As shown in (b) and (c), the reinforcing continuous fiber yarn 1, which is the warp, is stretched almost linearly,
The upper and lower surfaces thereof are partially impregnated with a thermoplastic resin fiber thread 2 which has been thermally melted into a ribbon shape. This molding material 11
Similarly to the molding material 10 shown in FIG. 1, it is possible to produce a molded product with a good appearance in which the reinforcing continuous fiber yarns in the molded product are not bent. Note that although the ribbon-shaped thermoplastic resin fiber yarns 2 are shown separated from each other in FIG. 2, this is for the purpose of explanation; Adjacent ribbons may adhere to each other slightly due to crushing, but there is no particular problem.
【0021】[0021]
【作用】本願第一の発明の成形材料は、補強用連続繊維
と熱可塑性樹脂繊維とからなる織物において、前記熱可
塑性樹脂繊維を、それに交差している糸に対して熱接着
しているので、織物中に含まれる補強用連続繊維が熱可
塑性樹脂繊維をバインダーとして固定されており、この
ため裁断時にほつれが生じることがなく、裁断が容易で
ある。しかも、本材料を用いて成形する場合、目曲がり
が生じることがない。更に、熱可塑性樹脂繊維は完全に
は溶融しておらず、従って繊維としての形態を保ってい
るので、柔軟性があり、良好なドレープ性を保っている
。このため、複雑な形状にも適用でき、良好な外観の製
品を得ることができる。[Operation] The molding material of the first invention of the present application is a woven fabric consisting of reinforcing continuous fibers and thermoplastic resin fibers, in which the thermoplastic resin fibers are thermally bonded to the threads crossing them. The reinforcing continuous fibers contained in the woven fabric are fixed using thermoplastic resin fibers as a binder, so that no fraying occurs during cutting, and cutting is easy. Furthermore, when molding using this material, bending of the mesh does not occur. Furthermore, since the thermoplastic resin fibers are not completely melted and therefore maintain their fiber form, they are flexible and maintain good drape properties. Therefore, it can be applied to complex shapes and products with good appearance can be obtained.
【0022】また、本願第二の発明の成形材料は、補強
用連続繊維と熱可塑性樹脂繊維とからなる織物において
、前記熱可塑性樹脂繊維を含む糸をリボン状とし、それ
に交差している糸に対して接着或いは含浸させているの
で、やはり,補強用連続繊維が熱可塑性樹脂のリボンを
バインダーとして固定されており、裁断時にほつれが生
じることがなく、裁断が容易である。しかも、本材料を
用いて成形する場合、目曲がりが生じることがない。
なお、熱可塑性樹脂繊維を含む糸が溶融してリボン状と
なり、それに交差する糸に含浸されているので、元の織
物に比べると柔軟性が低下するが、熱可塑性樹脂繊維を
含む糸をリボン状となるように溶融しただけであり、織
物内の熱可塑性樹脂繊維が全体として1枚のシートとな
るようには溶融していないので、柔軟性が保たれており
、ドレープ性が良く、複雑な形状にも適用でき、良好な
外観の製品を得ることができる。更に、この成形材料で
は、補強用連続繊維間に熱可塑性樹脂が一部含浸してい
るので、成形時の含浸速度が早く、成形サイクルを短縮
できる。[0022] In addition, the molding material of the second invention of the present application is a woven fabric consisting of reinforcing continuous fibers and thermoplastic resin fibers, in which the threads containing the thermoplastic resin fibers are formed into a ribbon shape, and the intersecting threads are formed into a ribbon shape. On the other hand, since the reinforcing continuous fibers are bonded or impregnated, the reinforcing continuous fibers are fixed using the thermoplastic resin ribbon as a binder, so that no fraying occurs during cutting, and cutting is easy. Moreover, when molding using this material, no bending of the mesh occurs. Note that the threads containing thermoplastic resin fibers are melted into a ribbon shape, and the intersecting threads are impregnated, so the flexibility is lower than the original fabric, but the threads containing thermoplastic resin fibers are made into ribbons. The thermoplastic resin fibers in the fabric are not melted to form a single sheet, so it maintains flexibility, has good drapability, and has a complex shape. It can be applied to any shape, and it is possible to obtain a product with a good appearance. Furthermore, in this molding material, since the thermoplastic resin is partially impregnated between the reinforcing continuous fibers, the impregnation speed during molding is fast, and the molding cycle can be shortened.
【0023】[0023]
【実施例】以下、本発明の実施例を説明する。[Examples] Examples of the present invention will be described below.
【0024】実施例1
下記仕様の交織織物を製織した。
縦糸:炭素繊維糸(1K、67Tex)、密度22本/
25mm
横糸:ナイロン6糸(32Tex)、 密度22
本/25mm
織り組織:平織り
炭素繊維体積含有率:55%
この交織織物を、図5に示すように熱ロール6、押えロ
ール7を用い、下記条件で加熱加圧加工して、成形材料
を得た。
温度(熱ロール表面温度):190°C圧力(ロール間
圧力):6kg/cm
加工速度:0.5m/minExample 1 A mixed woven fabric having the following specifications was woven. Warp: Carbon fiber yarn (1K, 67Tex), density 22/
25mm Weft: Nylon 6 thread (32Tex), density 22
Texture/25mm Weave structure: Plain weave Carbon fiber Volume content: 55% This mixed woven fabric was subjected to heating and pressure processing under the following conditions using a heat roll 6 and a presser roll 7 as shown in Fig. 5 to obtain a molding material. Ta. Temperature (heat roll surface temperature): 190°C Pressure (pressure between rolls): 6 kg/cm Processing speed: 0.5 m/min
【0025】実施例2
下記仕様の交織織物を製織した。
縦糸:炭素繊維糸(3K、198Tex)、密度20本
/25mm
横糸:ポリエーテルエーテルケトン糸(150Tex)
、密度13.5本/25mm
織り組織:平織り
炭素繊維体積含有率:60%
この交織織物を、熱ロールの温度を300°Cとした以
外は、実施例1と同じ条件で加熱加圧加工して、成形材
料を得た。Example 2 A mixed woven fabric having the following specifications was woven. Warp: Carbon fiber yarn (3K, 198Tex), density 20/25mm Weft: Polyetheretherketone yarn (150Tex)
, density 13.5 pieces/25 mm Weave structure: Plain weave carbon fiber volume content: 60% This mixed woven fabric was heat-pressed under the same conditions as Example 1, except that the temperature of the hot roll was 300°C. A molding material was obtained.
【0026】実施例3
下記仕様の交織織物を製織した。
縦糸:ガラス繊維糸(ECG37 1/0、135T
ex)、密度25本/25mm
横糸:ポリエーテルイミド糸(78Tex)、密度15
本/25mm
織り組織:平織り
ガラス繊維体積含有率:55%
この交織織物を、熱ロールの温度を230°Cとした以
外は、実施例1と同じ条件で加熱加圧加工して、成形材
料を得た。Example 3 A mixed woven fabric having the following specifications was woven. Warp: Glass fiber thread (ECG37 1/0, 135T
ex), density 25 threads/25mm Weft: polyetherimide thread (78Tex), density 15
Texture/25mm Weave structure: Plain weave Glass fiber Volume content: 55% This mixed woven fabric was heated and pressurized under the same conditions as in Example 1, except that the temperature of the heat roll was 230°C, and the molding material was Obtained.
【0027】実施例4
下記仕様の交織織物を製織した。
縦糸:炭素繊維糸(1K、67Tex)、密度22本/
25mm
横糸:ナイロン12糸(26Tex)、 密度22本
/25mm
織り組織:平織り
炭素繊維体積含有率:60%
この交織織物を、熱ロールの温度を200°Cとした以
外は、実施例1と同じ条件で加熱加圧加工して、成形材
料を得た。Example 4 A mixed woven fabric having the following specifications was woven. Warp: Carbon fiber yarn (1K, 67Tex), density 22/
25mm Weft: 12 nylon threads (26Tex), density 22 threads/25mm Weave structure: Plain weave carbon fiber volume content: 60% This mixed woven fabric was the same as Example 1 except that the temperature of the heat roll was 200°C. A molding material was obtained by heat-pressing processing under the following conditions.
【0028】実施例5
下記仕様の交織織物を製織した。
縦糸:ガラス繊維糸(ECG37 1/0、135T
ex)、密度20本/25mm
ナイロン6糸(85Tex)、密度20本/25mm横
糸:ガラス繊維糸(ECG37 1/0、135Te
x)、密度18本/25mm
ナイロン6糸(85Tex)、密度18本/25mm織
り組織:2/2正則ななこ織り
ガラス繊維体積含有率:40%
この交織織物を、熱ロールの温度を200°Cとした以
外は、実施例1と同じ条件で加熱加圧加工して、成形材
料を得た。Example 5 A mixed woven fabric having the following specifications was woven. Warp: Glass fiber thread (ECG37 1/0, 135T
ex), Density 20/25mm Nylon 6 thread (85Tex), Density 20/25mm Weft: Glass fiber thread (ECG37 1/0, 135Te
x), Density 18 threads/25mm Nylon 6 threads (85Tex), Density 18 threads/25mm Weaving structure: 2/2 Regular Nako weave Glass fiber volume content: 40% This mixed woven fabric was heated at a temperature of 200°C on a heat roll. A molding material was obtained by heating and pressing under the same conditions as in Example 1 except for the following.
【0029】実施例6
下記仕様の交織織物を製織した。
縦糸:ガラス繊維糸(ECG37 1/0、135T
ex)、密度20本/25mm
ポリエーテルイミド糸(90Tex)、密度20本/2
5mm
横糸:ガラス繊維糸(ECG37 1/0、135T
ex)、密度18本/25mm
ポリエーテルイミド糸(90Tex)、密度18本/2
5mm
織り組織:2/2正則ななこ織り
ガラス繊維体積含有率:40%
この交織織物を、熱ロールの温度を320°Cとした以
外は実施例1と同じ条件で加熱加圧加工して、成形材料
を得た。Example 6 A mixed woven fabric having the following specifications was woven. Warp: Glass fiber thread (ECG37 1/0, 135T
ex), density 20 threads/25mm Polyetherimide thread (90Tex), density 20 threads/2
5mm Weft: Glass fiber thread (ECG37 1/0, 135T
ex), density 18 threads/25mm Polyetherimide thread (90Tex), density 18 threads/2
5mm Weave texture: 2/2 regular Nanako weave Glass fiber volume content: 40% This mixed woven fabric was heated and pressurized under the same conditions as Example 1 except that the temperature of the hot roll was 320°C, and then molded. I got the material.
【0030】比較例1〜6
実施例1〜6で用意した織物で、加熱加圧加工しないも
のを、比較例1〜6の成形材料とした。Comparative Examples 1 to 6 The fabrics prepared in Examples 1 to 6 but not subjected to heating and pressure processing were used as molding materials for Comparative Examples 1 to 6.
【0031】以上の実施例1〜6、比較例1〜6で用意
した成形材料を用い、成形テストを行い、作業時の目曲
がり、切断時のほつれ等を目視検査した。また、各成形
材料を3枚重ね合わせ、オートクレーブ成形により平板
に成形し、その成形板における補強糸の目曲がり状態及
び外観を見て、外観を判定した。その結果を表1に示す
。A molding test was conducted using the molding materials prepared in Examples 1 to 6 and Comparative Examples 1 to 6, and visual inspection was conducted for bending during work, fraying during cutting, etc. In addition, three sheets of each molding material were stacked together and molded into a flat plate by autoclave molding, and the appearance was judged by looking at the bent state of the reinforcing threads and the appearance on the molded plate. The results are shown in Table 1.
【0032】[0032]
【表1】[Table 1]
【0033】表1の結果より明らかなように、本発明の
実施例による成形材料はいずれも、作業時の目曲がりや
切断時のほつれが生じにくく、従って、成形作業が極め
て容易となっている。また、得られた成形板の外観も良
好である。As is clear from the results in Table 1, all of the molding materials according to the examples of the present invention are less prone to bending during work or fraying during cutting, making molding work extremely easy. . Moreover, the appearance of the obtained molded plate is also good.
【0034】[0034]
【発明の効果】以上に説明したように、本願第一の発明
の連続繊維補強熱可塑性樹脂成形材料は、補強用連続繊
維と熱可塑性樹脂繊維からなる織物において、その熱可
塑性樹脂繊維を、それに交差している糸に対して熱接着
したことを特徴とするものであるので、成形材料内にお
いて、補強用連続繊維が熱可塑性樹脂繊維をバインダー
として拘束されており、このため、切断時にほつれが生
じたり、成形型にセットする際に目曲がりが生じること
がなく、しかも、熱可塑性樹脂繊維は繊維の形態を保っ
ているので適度な柔軟性を有しており、このため、ドレ
ープ性が良く、成形作業が容易で、複雑な形状の成形に
も適用でき、しかも、得られた成形品の外観が良好であ
るという効果を有している。Effects of the Invention As explained above, the continuous fiber-reinforced thermoplastic resin molding material of the first invention of the present application can be used in fabrics made of reinforcing continuous fibers and thermoplastic resin fibers. Since it is characterized by being thermally bonded to the intersecting threads, the reinforcing continuous fibers are bound within the molding material using thermoplastic resin fibers as a binder, which prevents them from fraying when cut. In addition, thermoplastic resin fibers retain their fiber form and have appropriate flexibility, resulting in good drapability. It has the advantage that the molding operation is easy, it can be applied to molding of complicated shapes, and the appearance of the obtained molded product is good.
【0035】また、本願第二の発明の連続繊維補強熱可
塑性樹脂成形材料は、補強用連続繊維と熱可塑性樹脂繊
維からなる織物において、熱可塑性樹脂繊維を含む糸を
熱溶融してリボン状とし、それに交差している糸に対し
て接着或いは含浸させたことを特徴とするものであるの
で、成形材料内において、補強用連続繊維が熱可塑性樹
脂繊維をバインダーとして拘束されており、このため、
切断時にほつれが生じたり、成形型にセットする際に目
曲がりが生じることがなく、しかも、熱可塑性樹脂繊維
を含む糸は単にリボン状となるのみであるので元の織物
状態に比べると硬化しているがかなりの柔軟性は有して
おり、このため、ドレープ性が良く、成形作業が容易で
、複雑な形状の成形にも適用でき、しかも、得られた成
形品の外観が良好であるという効果を有している。また
、樹脂が補強用連続繊維間に部分的に含浸しているので
、成形時における含浸速度が早く、成形時間を短縮でき
るという効果も有している。[0035] Furthermore, the continuous fiber reinforced thermoplastic resin molding material of the second invention of the present application can be used in a woven fabric made of reinforcing continuous fibers and thermoplastic resin fibers by thermally melting the threads containing the thermoplastic resin fibers into a ribbon shape. , the reinforcing continuous fibers are bound with thermoplastic resin fibers as a binder within the molding material, and therefore,
There is no fraying when cutting or bending when setting in a mold, and since the thread containing thermoplastic resin fibers simply forms a ribbon, it is less hardened than the original woven fabric. However, it has considerable flexibility, so it has good drape properties, is easy to mold, and can be applied to molding complex shapes, and the resulting molded product has a good appearance. It has this effect. In addition, since the resin is partially impregnated between the reinforcing continuous fibers, the impregnation speed during molding is fast and the molding time can be shortened.
【図1】本発明の1実施例による成形材料を示すもので
、
(a)はその概略平面図
(b)は(a)のB−B矢視図
(c)は(a)のC−C矢視図FIG. 1 shows a molding material according to one embodiment of the present invention, (a) is a schematic plan view thereof, (b) is a view taken along line B-B in (a), and (c) is a view taken along C--C in (a). C arrow view
【図2】本発明の他の実施例による成形材料を示すもの
で、
(a)はその概略平面図
(b)は(a)のB−B矢視図
(c)は(a)のC−C矢視図FIG. 2 shows a molding material according to another embodiment of the present invention, (a) is a schematic plan view thereof, (b) is a view taken along the line B-B in (a), and (c) is a C-C view in (a). -C arrow view
【図3】(a)、(b)、(c)はそれぞれ、本発明に
使用する一方向性補強成形体用織物の例を示す概略平面
図FIG. 3 (a), (b), and (c) are schematic plan views each showing an example of a woven fabric for a unidirectional reinforced molded body used in the present invention.
【図4】(a)、(b)、(c)、(d)、(e)はそ
れぞれ、本発明に使用する両方向性補強成形体用織物の
例を示す概略平面図FIG. 4 (a), (b), (c), (d), and (e) are schematic plan views each showing an example of a fabric for a bidirectional reinforced molded body used in the present invention.
【図5】織物を加熱加圧加工する方法の1例を示す概略
側面図[Fig. 5] A schematic side view showing an example of a method for heating and pressurizing textiles.
1 補強用連続繊維糸
2 熱可塑性樹脂繊維糸
3 補強用連続繊維と熱可塑性樹脂繊維とを混合した
混合糸
5 織物
6 熱ロール
7 押えロール
10、11 成形材料1 Reinforcing continuous fiber yarn 2 Thermoplastic resin fiber yarn 3 Mixed yarn of reinforcing continuous fiber and thermoplastic resin fiber 5 Fabric 6 Heat roll 7 Presser rolls 10, 11 Molding material
Claims (4)
らなる織物で構成され、織物内の熱可塑性樹脂繊維が、
それに交差している糸に対して熱接着していることを特
徴とする連続繊維補強熱可塑性樹脂成形材料。Claim 1: Consisting of a woven fabric made of reinforcing continuous fibers and thermoplastic resin fibers, the thermoplastic resin fibers in the woven fabric are
A continuous fiber-reinforced thermoplastic resin molding material characterized by being thermally bonded to the intersecting threads.
らなる織物で構成され、その織物内の熱可塑性樹脂繊維
を含む糸が熱溶融によりリボン状となり、それに交差し
ている糸に対して接着或いは含浸していることを特徴と
する連続繊維補強熱可塑性樹脂成形材料。[Claim 2] Consisting of a woven fabric made of reinforcing continuous fibers and thermoplastic resin fibers, the threads containing the thermoplastic resin fibers in the woven fabric are melted into a ribbon shape and bonded to the threads that intersect with it. Alternatively, a continuous fiber-reinforced thermoplastic resin molding material characterized by being impregnated with it.
横糸のいずれか一方のみに含んでいる一方向性補強成形
体用織物であることを特徴とする請求項1又は2記載の
連続繊維補強熱可塑性樹脂成形材料。3. The continuous fiber according to claim 1 or 2, wherein the woven fabric is a woven fabric for a unidirectional reinforced molded body containing reinforcing continuous fibers only in either the warp or the weft. Reinforced thermoplastic molding material.
横糸のいずれにも含んでいる両方向性補強成形体用織物
であることを特徴とする請求項1又は2記載の連続繊維
補強熱可塑性樹脂成形材料。4. The continuous fiber-reinforced thermoplastic according to claim 1 or 2, wherein the woven fabric is a woven fabric for a bidirectionally reinforced molded body containing reinforcing continuous fibers in both warp and weft. Resin molding material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3108545A JPH04316633A (en) | 1991-04-12 | 1991-04-12 | Continuous filament-reinforced thermoplastic resin molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3108545A JPH04316633A (en) | 1991-04-12 | 1991-04-12 | Continuous filament-reinforced thermoplastic resin molding material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04316633A true JPH04316633A (en) | 1992-11-09 |
Family
ID=14487544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3108545A Pending JPH04316633A (en) | 1991-04-12 | 1991-04-12 | Continuous filament-reinforced thermoplastic resin molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04316633A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06346337A (en) * | 1993-06-07 | 1994-12-20 | Yamaha Corp | Sleeve for fiber-reinforced thermoplastic resin |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61287936A (en) * | 1985-06-17 | 1986-12-18 | Toray Ind Inc | Unidirectional prepreg and its production |
| JPS63315638A (en) * | 1987-06-15 | 1988-12-23 | 東レ株式会社 | Resin refinforcing fabric |
-
1991
- 1991-04-12 JP JP3108545A patent/JPH04316633A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61287936A (en) * | 1985-06-17 | 1986-12-18 | Toray Ind Inc | Unidirectional prepreg and its production |
| JPS63315638A (en) * | 1987-06-15 | 1988-12-23 | 東レ株式会社 | Resin refinforcing fabric |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06346337A (en) * | 1993-06-07 | 1994-12-20 | Yamaha Corp | Sleeve for fiber-reinforced thermoplastic resin |
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