JPH04329190A - Thermal transfer recording - Google Patents

Thermal transfer recording

Info

Publication number
JPH04329190A
JPH04329190A JP3126692A JP12669291A JPH04329190A JP H04329190 A JPH04329190 A JP H04329190A JP 3126692 A JP3126692 A JP 3126692A JP 12669291 A JP12669291 A JP 12669291A JP H04329190 A JPH04329190 A JP H04329190A
Authority
JP
Japan
Prior art keywords
image
paper
receiving
layer
receiving paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP3126692A
Other languages
Japanese (ja)
Other versions
JP3088774B2 (en
Inventor
Takao Hirota
広田 隆男
Tsutomu Taki
瀧 勉
Kazuhiro Kato
和広 加藤
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Kasei Corp
Mitsubishi Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Kasei Corp, Mitsubishi Chemical Industries Ltd filed Critical Mitsubishi Kasei Corp
Priority to JP03126692A priority Critical patent/JP3088774B2/en
Publication of JPH04329190A publication Critical patent/JPH04329190A/en
Application granted granted Critical
Publication of JP3088774B2 publication Critical patent/JP3088774B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Thermal Transfer Or Thermal Recording In General (AREA)

Abstract

PURPOSE:To provide thermal transfer recording technique by which to obtain a transferred image having a minimized appearance of roughness, high image quality and high grade. CONSTITUTION:An image-receiving sheet consisting of a cellulose sheet as a base is used for thermal transfer recording (heat-sensitive sublimation technique). The image-receiving sheet is fed under conditions that the tensile breakdown strength ratio or modulus ratio of tensile elasticity of the sheet in a thermal head movement direction against a heating element arrangement direction ranges from 0.01 to 0.9.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】本発明は、基材表面に気化性又は
熱拡散性色素を含有する転写層を設けてなる転写シート
及びセルロース紙等の基材の一方の面に色素を受容する
受像層を設けてなる受像紙を用いた熱転写記録方法に関
するものであり、詳しくは、印画物の画質の改良を図っ
た熱転写記録方法に関するものである。
[Industrial Application Field] The present invention relates to a transfer sheet having a transfer layer containing a vaporizable or heat-diffusible dye on the surface of a base material, and an image receiving layer that receives a dye on one side of a base material such as cellulose paper. The present invention relates to a thermal transfer recording method using a layered image-receiving paper, and more specifically, to a thermal transfer recording method that improves the image quality of printed matter.

【0002】0002

【従来の技術】従来より、ビデオカメラ、スチールビデ
オカメラ、テレビ、ビデオディスク、写真電送装置など
における電気的画像信号から写真のようなハードコピー
の形で画像を再生する方法が盛んに研究されており、そ
の一つの有力な方法として、現在、熱転写記録方法が注
目されている。
BACKGROUND OF THE INVENTION Conventionally, methods for reproducing images in the form of hard copies such as photographs from electrical image signals in video cameras, still video cameras, televisions, video discs, photographic transmission devices, etc. have been actively researched. Thermal transfer recording method is currently attracting attention as one of the promising methods.

【0003】熱転写記録方法は、基材表面に気化性又は
熱拡散性色素を含有する転写層を設けてなる転写シート
及び基材の一方の面に色素を受容する受像層を設けてな
る受像紙を用い、給紙ローラにより、複数の発熱体を配
列してなるサーマルヘッドとプラテンローラとの間に前
記受像紙を供給し、その受像層と前記転写シートの転写
層とを対向させて重ね合わせ、発熱体からの転写シート
への加熱により転写層中の色素を受像層に受容させ、そ
して、発熱体配列方向と略直角方向に受像紙とサーマル
ヘッドとを相対的に移動させて記録を行う熱転写記録方
法である。
The thermal transfer recording method uses a transfer sheet having a transfer layer containing a vaporizable or heat-diffusible dye on the surface of a base material, and an image-receiving paper having an image-receiving layer that receives the dye on one side of the base material. Using a paper feeding roller, the image receiving paper is fed between a thermal head formed by arranging a plurality of heating elements and a platen roller, and the image receiving layer and the transfer layer of the transfer sheet are faced and overlapped. The dye in the transfer layer is received by the image-receiving layer by heating the transfer sheet from the heating element, and recording is performed by relatively moving the image-receiving paper and the thermal head in a direction substantially perpendicular to the direction in which the heating elements are arranged. This is a thermal transfer recording method.

【0004】熱転写記録方法に用いる受像紙の基材には
、種々のものが提案されているが、代表的なものとして
は、セルロース紙またはこれに熱可塑性高分子物質をラ
ミネートしたものが知られている。これらの基材は、プ
ラスチックフィルムなどの合成紙よりなる基材に比べて
安価であり、紙質感が良好であるという特徴を有する。
[0004] Various materials have been proposed for the base material of the image receiving paper used in the thermal transfer recording method, but the typical one is cellulose paper or a material laminated with a thermoplastic polymer material. ing. These base materials have the characteristics that they are cheaper than base materials made of synthetic paper such as plastic film, and have a good paper texture.

【0005】ところで、印画物の画質品位の低下は、各
種の要因、例えば、画像の濃度むら、転写抜け、発熱体
の誤不動によるドット抜け等が複合的に関係して発生し
、従って、その内容と要因との関係を特定することは必
ずしも容易ではない。本出願は、先に、小さい濃度ムラ
や転写抜けに起因するとされている所謂ざらつき感につ
いて詳細に検討し、これの定量方法を提案した(特願平
2−269910号)。上記の提案に係る「ざらつきの
定量化方法」は、特定の指標により、曖昧に評価されて
いたざらつき感を定量的化したものであり、ざらつきの
要因解析を容易なものとして印画物の画質品位の改良に
有用である。
[0005] Incidentally, the deterioration in the image quality of printed matter occurs due to a complex relationship between various factors such as uneven density of the image, missing transfers, missing dots due to incorrect movement of the heating element, etc. It is not always easy to identify the relationship between content and factors. The present application previously conducted a detailed study on so-called roughness, which is said to be caused by small density unevenness and transfer omissions, and proposed a method for quantifying this (Japanese Patent Application No. 2-269910). The ``method for quantifying roughness'' proposed above quantifies the sense of roughness, which had been vaguely evaluated, using a specific index, and aims to simplify the analysis of the causes of roughness by improving the image quality of prints. It is useful for improving.

【0006】[0006]

【発明が解決しようとする課題】本発明者等は、印画物
の画質の一層の改良を図るべく、上記の「ざらつきの定
量化方法」を利用して種々検討を重ねた結果、驚くべき
ことに、セルロース紙等を基材とした受像紙においては
、サーマルヘッドとプラテンローラとの間への給紙方向
により、得られる印画物のざらつき感の程度が異なると
の新規な知見を得た。本発明は、上記の知見を基に完成
されたものであり、その目的は、セルロース紙等を基材
とした受像紙を用いた熱転写記録方法であって、印画物
のざらつき感の問題を解決して画質の改良を図った熱転
写記録方法を提供することにある。
[Problem to be Solved by the Invention] In order to further improve the image quality of prints, the inventors of the present invention have conducted various studies using the above-mentioned "method for quantifying roughness," and have found a surprising result. In addition, we have obtained a new finding that the degree of roughness of the obtained print differs depending on the direction in which the paper is fed between the thermal head and the platen roller in image-receiving paper based on cellulose paper or the like. The present invention was completed based on the above knowledge, and its purpose is to provide a thermal transfer recording method using an image receiving paper based on cellulose paper, etc., and to solve the problem of roughness in prints. An object of the present invention is to provide a thermal transfer recording method that improves image quality.

【0007】[0007]

【課題を解決するための手段】すなわち、本発明の請求
項1記載の発明の要旨は、基材表面に気化性又は熱拡散
性色素を含有する転写層を設けてなる転写シート及びセ
ルロース紙の一方の面に色素を受容する受像層を設けて
なる受像紙を用い、給紙ローラにより、複数の発熱体を
配列してなるサーマルヘッドとプラテンローラとの間に
前記受像紙を供給し、その受像層と前記転写シートの転
写層とを対向させて重ね合わせ、発熱体からの転写シー
トへの加熱により転写層中の色素を受像層に受容させ、
そして、発熱体配列方向と略直角方向に受像紙とサーマ
ルヘッドとを相対的に移動させて記録を行う熱転写記録
方法において、発熱体の配列方向に対するサーマルヘッ
ド移動方向における受像紙の引張破壊強度比または引張
弾性率比が0.01〜0.9の範囲となる条件下に受像
紙の給紙を行うことを特徴とする熱転写記録方法に存し
、請求項2記載の発明は、受像紙として、セルロース紙
と受像層の間に熱可塑性高分子物質のラミネート層を有
する受像紙を使用するものであり、請求項2記載の発明
は、受像紙として、背面処理層を有する受像紙を使用す
るものである。
[Means for Solving the Problems] That is, the gist of the invention as set forth in claim 1 of the present invention is to provide a transfer sheet and a cellulose paper comprising a transfer layer containing a vaporizable or heat-diffusible dye on the surface of a base material. Using an image-receiving paper having an image-receiving layer for receiving dye on one side, the image-receiving paper is fed between a thermal head having a plurality of heating elements arranged and a platen roller by a paper feed roller. The image-receiving layer and the transfer layer of the transfer sheet are stacked facing each other, and the dye in the transfer layer is received by the image-receiving layer by heating the transfer sheet from a heating element,
In a thermal transfer recording method in which recording is performed by moving an image receiving paper and a thermal head relatively in a direction substantially perpendicular to the direction in which the heating elements are arranged, the tensile fracture strength ratio of the image receiving paper in the direction of movement of the thermal head relative to the direction in which the heating elements are arranged is determined. or a thermal transfer recording method characterized in that the image receiving paper is fed under conditions such that the tensile modulus ratio is in the range of 0.01 to 0.9; , an image receiving paper having a laminate layer of a thermoplastic polymer substance between the cellulose paper and the image receiving layer is used, and the invention according to claim 2 uses an image receiving paper having a back side treatment layer as the image receiving paper. It is something.

【0008】以下、本発明を詳細に説明する。図1は、
本発明の熱転写記録方法の概要を示す説明図である。
The present invention will be explained in detail below. Figure 1 shows
FIG. 1 is an explanatory diagram showing an outline of the thermal transfer recording method of the present invention.

【0009】本発明の熱転写記録方法は、基本的には、
従来公知の方法と同様であり、基材表面に気化性又は熱
拡散性色素を含有する転写層を設けてなる転写シート(
1)及びセルロース紙等の基材の一方の面に色素を受容
する受像層を設けてなる受像紙(2)を用い、給紙ロー
ラ(3)、(3′)により、複数の発熱体を配列してな
るサーマルヘッド(4)とプラテンローラ(5)との間
に前記受像紙を供給し、その受像層と前記転写シートの
転写層とを対向させて重ね合わせ、発熱体からの転写シ
ートへの加熱により転写層中の色素を受像層に受容させ
、そして、発熱体配列方向と略直角方向に受像紙とサー
マルヘッドとを相対的に移動させて記録を行う方法より
なる。
The thermal transfer recording method of the present invention basically includes the following steps:
The method is similar to the conventionally known method, and a transfer sheet (
1) and an image receiving paper (2) consisting of a base material such as cellulose paper with an image receiving layer for receiving dye on one side, and a plurality of heating elements by paper feed rollers (3) and (3'). The image receiving paper is supplied between the arranged thermal heads (4) and the platen roller (5), and the image receiving layer and the transfer layer of the transfer sheet are faced and overlapped, and the transfer sheet from the heating element is This method involves heating the transfer layer to cause the dye in the transfer layer to be received by the image-receiving layer, and then recording by relatively moving the image-receiving paper and the thermal head in a direction substantially perpendicular to the direction in which the heating elements are arranged.

【0010】サーマルヘッドには、通常、1mm当り4
〜16ドットの電気発熱体が一列に配置されている。そ
して、これには、画像情報を含む電気信号が入力される
。
[0010] Thermal heads usually have 4
~16 dots of electric heating elements are arranged in a row. An electrical signal containing image information is input to this.

【0011】本発明に用いる受像紙の1つは、セルロー
ス紙を基材とするものである。一般に、セルロース紙は
、広葉樹サルファイトパルプと広葉樹クラフトパルプの
混合パルプを水中で機械的に処理することにより繊維束
を離解し、こう解機により切断し、抄紙機により製造さ
れる。本発明においては、厚さ50μm〜300μmの
範囲のセルロース紙を使用するのが好ましい。
One type of image-receiving paper used in the present invention is based on cellulose paper. In general, cellulose paper is produced by mechanically treating a mixed pulp of hardwood sulfite pulp and hardwood kraft pulp in water to defibrate fiber bundles, cutting the fiber bundles with a disintegrator, and then using a paper machine. In the present invention, it is preferable to use cellulose paper having a thickness in the range of 50 μm to 300 μm.

【0012】本発明に用いる他の受像紙は、熱可塑性高
分子物質をラミネートしたセルロース紙を基材とするも
のである。このようなラミネート品は、通常、RCペー
パー(Reson Coated)と呼ばれている。熱
可塑性高分子物質としては、例えば、高密度ポリエチレ
ン、中密度ポリエチレン、線状低密度ポリエチレン、低
密度ポリエチレン、結晶性ポリプロピレン、結晶性エチ
レン−プロピレン・ブロック共重合体、ポリブテン、ポ
リ−3−メチルブテン−1、ポリ−4−メチルペンテン
−1、エチレン酢酸ビニル共重合体等のポリオレフィン
系樹脂、ポリ塩化ビニル、ポリ塩化ビニリデン、塩化ビ
ニル−酢酸ビニル共重合体等の塩化ビニル系樹脂、ポリ
エチレンテレフタレート、ポリブチレンテレフタレート
等のエステル系樹脂、ナイロン6、ナイロン6−6、ナ
イロン6−10、ナイロン11、ナイロン12等のアミ
ド系樹脂、ポリスチレン、アクリロニトリル−スチレン
共重合体、アクリロニトリル−ブタジエン−スチレン三
元共重合体等のスチレン系樹脂等が挙げられる。これら
は、1種のみを使用してもよいし、公知の方法で2種以
上を混合して使用してもよい。
Another image-receiving paper used in the present invention is based on cellulose paper laminated with a thermoplastic polymer material. Such a laminate product is usually called RC paper (Reson Coated). Examples of thermoplastic polymer substances include high-density polyethylene, medium-density polyethylene, linear low-density polyethylene, low-density polyethylene, crystalline polypropylene, crystalline ethylene-propylene block copolymer, polybutene, and poly-3-methylbutene. -1, polyolefin resins such as poly-4-methylpentene-1, ethylene vinyl acetate copolymer, polyvinyl chloride, polyvinylidene chloride, vinyl chloride resins such as vinyl chloride-vinyl acetate copolymer, polyethylene terephthalate, Ester resins such as polybutylene terephthalate, amide resins such as nylon 6, nylon 6-6, nylon 6-10, nylon 11, and nylon 12, polystyrene, acrylonitrile-styrene copolymer, acrylonitrile-butadiene-styrene ternary copolymer Examples include styrene resins such as polymers. These may be used alone or in combination of two or more using a known method.

【0013】熱可塑性高分子物質のラミネート層の形成
方法としては、押し出しラミネート形成法、高分子フィ
ルムを接着剤にて貼合わせるドライラミネート法等が適
用可能である。押し出しラミネート成形は、公知の方法
および装置を用いて行うことができ、例えば、溶融させ
たラミネート用樹脂を押し出し機のダイから適当な温度
(ポリエチレンの場合では280〜340℃)で押し出
して溶融薄膜となし、該溶融薄膜を圧着ロールに導き、
同様に圧着ロールに導かれたセルロース紙と圧着ラミネ
ートすることにより行われる。そして、セルロース紙の
接着面は、必要に応じて表面活性処理が施される。
[0013] As a method for forming the laminate layer of thermoplastic polymer material, extrusion laminate formation method, dry lamination method in which polymer films are bonded together using an adhesive, etc. can be applied. Extrusion lamination can be performed using known methods and equipment. For example, a molten resin for lamination is extruded through a die of an extruder at an appropriate temperature (280 to 340°C in the case of polyethylene) to form a molten thin film. and guiding the molten thin film to a pressure roll,
Similarly, this is carried out by pressure lamination with cellulose paper guided by a pressure roll. Then, the adhesive surface of the cellulose paper is subjected to surface activation treatment, if necessary.

【0014】熱可塑性高分子物質のラミネート層の厚さ
は、通常5μm 〜40μm の範囲とされ、また、ラ
ミネート層には、通常、酸化チタン、蛍光増白剤、酸化
防止剤等が含有されている。
[0014] The thickness of the laminate layer of thermoplastic polymer material is usually in the range of 5 μm to 40 μm, and the laminate layer usually contains titanium oxide, a fluorescent whitening agent, an antioxidant, etc. There is.

【0015】受像層は、色素染着性の合成樹脂を含有し
て構成される。そして、合成樹脂としては、ポリエステ
ル樹脂、ポリアクリル酸エステル樹脂、ポリカーボネー
ト樹脂、ポリ酢酸ビニル樹脂、スチレンアクリレート樹
脂、ビニルトルエンアクリレート樹脂等のエステル結合
を有する樹脂、ポリウレタン樹脂等のウレタン結合を有
する樹脂、ポリアミド樹脂等のアミド結合を有する樹脂
、尿素樹脂等の尿素結合を有する樹脂、その他、ポリカ
プロラクタン樹脂、スチレン系樹脂、ポリ塩化ビニル樹
脂、塩化ビニル−酢酸ビニル共重合体樹脂、ポリアクリ
ロニトリル樹脂等が挙げられる。また、これらの混合物
や共重合体等も使用できる。
The image-receiving layer contains a dye-dying synthetic resin. Examples of synthetic resins include resins with ester bonds such as polyester resins, polyacrylate resins, polycarbonate resins, polyvinyl acetate resins, styrene acrylate resins, and vinyltoluene acrylate resins, resins with urethane bonds such as polyurethane resins, Resins with amide bonds such as polyamide resins, resins with urea bonds such as urea resins, others, polycaprolactane resins, styrene resins, polyvinyl chloride resins, vinyl chloride-vinyl acetate copolymer resins, polyacrylonitrile resins etc. Moreover, mixtures and copolymers of these can also be used.

【0016】上記の受像層中には、上記合成樹脂の他に
離型剤を含有させてもよい。離型剤としては、ポリエチ
レンワックス、アミドワックス、テフロンパウダー等の
固形ワックス類、弗素系、リン酸エステル系の界面活性
剤、シリコーンオイル類等が挙げられるが、シリコーン
オイル類が好ましい。
The image-receiving layer may contain a release agent in addition to the synthetic resin. Examples of the mold release agent include solid waxes such as polyethylene wax, amide wax, and Teflon powder, fluorine-based and phosphate-based surfactants, and silicone oils, with silicone oils being preferred.

【0017】上記のシリコーンオイル類としては、油状
のものも使用できるが、反応硬化型、光硬化型、触媒硬
化型等の硬化型のものが好ましい。特に、アミノ変性シ
リコーンオイル、エポキシ変性オイル、アルコール変性
シリコーンオイル、カルボキシ変性シリコーンオイル等
の反応硬化型シリコーンオイルが好ましい。離型剤の含
有量は、通常、受像層中の濃度として0.1〜10重量
%の範囲とするのがよい。
As the above-mentioned silicone oils, oily ones can also be used, but curing types such as reaction curing type, photo curing type and catalyst curing type are preferable. In particular, reaction-curing silicone oils such as amino-modified silicone oil, epoxy-modified oil, alcohol-modified silicone oil, and carboxy-modified silicone oil are preferred. The content of the release agent is usually preferably in the range of 0.1 to 10% by weight as a concentration in the image-receiving layer.

【0018】また、上記の受像層中には顔料を含有させ
てもよい。顔料としては、シリカ、炭酸カルシウム、酸
化チタン、酸化亜鉛等の体質顔料が好ましい。顔料の含
有量は、通常、受像層中の濃度として1〜30重量%の
範囲とするのがよい。
[0018] Furthermore, the above image-receiving layer may contain a pigment. As the pigment, extender pigments such as silica, calcium carbonate, titanium oxide, and zinc oxide are preferred. The content of the pigment is usually preferably in the range of 1 to 30% by weight as a concentration in the image-receiving layer.

【0019】また、上記の受像層中には可塑剤を含有さ
せてもよい。可塑剤としては、プラスチック原料の流動
性を改善し、かつ成形品に柔軟性を与える機能を持つも
のが好ましい。このような可塑剤としては、アジピン酸
誘導体、グリコール誘導体、セバシン酸誘導体、フタル
酸誘導体、リン酸誘導体、重合可塑剤などが挙げられる
。可塑剤の含有量は、通常、受像層中の濃度として5〜
30重量%の範囲とするのがよい。
[0019] Furthermore, a plasticizer may be contained in the above image-receiving layer. The plasticizer preferably has the function of improving the fluidity of the plastic raw material and imparting flexibility to the molded product. Examples of such plasticizers include adipic acid derivatives, glycol derivatives, sebacic acid derivatives, phthalic acid derivatives, phosphoric acid derivatives, and polymeric plasticizers. The content of plasticizer is usually 5 to 5 as a concentration in the image receiving layer.
The content is preferably in the range of 30% by weight.

【0020】本発明において、受像層の厚さは、通常0
.5〜20μm の範囲、好ましくは2〜10μm の
範囲とされる。
In the present invention, the thickness of the image-receiving layer is usually 0.
.. The range is 5 to 20 μm, preferably 2 to 10 μm.

【0021】また、本発明においては、受像紙基材の受
像層を設ける側(表側)の反対側(裏側)の面に熱可塑
性高分子物質の背面処理層を設けることが好ましい。背
面処理層は、基材のカール防止性、給紙適性、帯電防止
性等を付与するために設けられる。使用する熱可塑性高
分子物質は、特に制限されないが、RCペーパーのラミ
ネート層に使用した熱可塑性高分子物質層と同様なもの
が好ましい。そして、背面処理層の厚さは、表側のラミ
ネート層とのバランスを考慮して適宜決定される。
Further, in the present invention, it is preferable to provide a back surface treatment layer of a thermoplastic polymer material on the surface of the image-receiving paper base material on the opposite side (front side) to the side on which the image-receiving layer is provided (front side). The back surface treatment layer is provided to impart anti-curl properties, paper feeding suitability, antistatic properties, etc. to the base material. The thermoplastic polymer material used is not particularly limited, but it is preferably the same as the thermoplastic polymer material layer used for the laminate layer of the RC paper. The thickness of the back surface treatment layer is appropriately determined in consideration of the balance with the front side laminate layer.

【0022】また、上記の背面処理層の上には、更に、
次に説明する他の背面処理層を設けてもよい。この背面
処理層は、受像紙に裏移り防止性を付与したり、給紙適
性や帯電防止性等を向上させるために設けられる。ここ
で、裏移りとは、印画した受像紙を複数枚重ねて保存し
た場合、色素の移行により、表側の画像が上に重ねてあ
った受像紙の裏側へ転写し、商品価値が下がることをを
指す。
[0022] Furthermore, on the above-mentioned back surface treatment layer,
Other backside treatment layers described below may also be provided. This back surface treatment layer is provided to impart anti-set-off properties to the image-receiving paper, and to improve paper feeding suitability, antistatic properties, and the like. Here, set-off refers to the fact that when multiple sheets of printed image-receiving paper are stacked and stored, the image on the front side is transferred to the back side of the overlapping image-receiving paper due to dye migration, reducing the product value. refers to

【0023】上記の他の背面処理層は、上記と同様に熱
可塑性高分子物質にて構成され、好適な熱可塑性高分子
物質としては、例えば、ポリビニルアルコール樹脂、ポ
リエステル樹脂、ポリカーボネート樹脂、ポリビニルブ
チラール樹脂等のポリアセタール樹脂、ポリアミド樹脂
等のアミド結合を有する樹脂が挙げられる。また、これ
らの混合物や共重合体等も使用できる。そして、これら
の樹脂に帯電防止剤を添加して帯電防止性能を強化する
こともできる。
[0023] The other back surface treatment layer described above is made of a thermoplastic polymer material in the same manner as described above, and suitable thermoplastic polymer materials include, for example, polyvinyl alcohol resin, polyester resin, polycarbonate resin, and polyvinyl butyral resin. Examples include resins having an amide bond such as polyacetal resins and polyamide resins. Moreover, mixtures and copolymers of these can also be used. The antistatic performance can also be enhanced by adding an antistatic agent to these resins.

【0024】本発明において、受像紙全体の厚さは、5
0μm 〜350μm の範囲とするのが好ましい。
In the present invention, the total thickness of the image receiving paper is 5
It is preferably in the range of 0 μm to 350 μm.

【0025】本発明の特徴は、発熱体の配列方向に対す
るサーマルヘッド移動方向における受像紙の引張破壊強
度比または引張弾性率比が0.01〜0.9の範囲とな
る条件下に受像紙の給紙を行う点にある。
The feature of the present invention is that the tensile strength ratio or tensile modulus ratio of the image receiving paper in the direction of movement of the thermal head with respect to the arrangement direction of the heating elements is in the range of 0.01 to 0.9. The point lies in feeding paper.

【0026】従来、セルロース紙をロールの駆動力を利
用して移動させる場合には、その給紙方向は、機械的物
性の高い方向とするのが慣例である。すなわち、周知の
通り、セルロース紙は、パルプの水スラリーを主原料と
して抄紙工程を含む各工程を得て製造される。そして、
縦方向と横方向とで異方性があり、抄紙機において紙の
進む方向(繊維の流れ方向、すなわち配向方向)である
縦方向とそれと直角の方向の横方向とでは、機械的物性
や寸法安定性が異なる。従って、セルロース紙をロール
の駆動力を利用して移動させる場合には、ロール巻紙、
枚葉紙のいずれでも、その給紙方向は、通常、機械的物
性の高い方向(縦方向)とされている。
Conventionally, when cellulose paper is moved using the driving force of a roll, it is customary to set the paper feeding direction in a direction with high mechanical properties. That is, as is well known, cellulose paper is manufactured using a water slurry of pulp as a main raw material through various steps including a papermaking process. and,
There is anisotropy in the machine direction and the width direction, and the mechanical properties and dimensions are Stability is different. Therefore, when moving cellulose paper using the driving force of a roll, roll paper,
The feeding direction of any sheet of paper is usually the direction (longitudinal direction) with high mechanical properties.

【0027】上記のことは、印刷用途においても例外で
はなく、特に、縦目の紙の場合は、湿度変化による収縮
が横目の紙よりも少ないとされ、縦目の紙の使用が常識
となっている。しかしながら、一般に感熱溶融型と呼ば
れる熱転写記録方法の場合には特に問題とはならないが
、一般に感熱昇華型と呼ばれる本発明のような熱転写記
録方法の場合には、受像紙の給紙方向により、得られる
印画物の画質品位、特に、ざらつき感が著しく異なるこ
とが見出された。
[0027] The above is no exception in printing applications; in particular, vertically grained paper is said to shrink less due to changes in humidity than horizontally grained paper, and it has become common sense to use vertically grained paper. ing. However, this is not a particular problem in the case of a thermal transfer recording method generally called a heat-sensitive melting type, but in the case of a thermal transfer recording method such as the present invention, which is generally called a heat-sensitive sublimation type, the yield may vary depending on the feeding direction of the image-receiving paper. It was found that the image quality of the printed matter, especially the roughness, was significantly different.

【0028】上記の原因は、必ずしも詳らかではないが
、サーマルヘッドの電気発熱体相互の間隔とセルロース
紙の繊維の配向方向のうねりの大きさとが関係している
ものと推定される。すなわち、サーマルヘッドには、前
述のように、通常、1mm当り4〜16ドットの電気発
熱体が給紙方向に対する略垂直方向に一列に配置されて
いる。これに対し、セルロース紙の繊維のうねりは比較
的大きく、50〜60μm 以上もある。
Although the above cause is not necessarily clear, it is presumed that the distance between the electric heating elements of the thermal head and the magnitude of the waviness in the fiber orientation direction of the cellulose paper are related. That is, as described above, in the thermal head, normally, electric heating elements of 4 to 16 dots per mm are arranged in a line in a direction substantially perpendicular to the paper feeding direction. On the other hand, the fibers of cellulose paper have relatively large undulations of 50 to 60 μm or more.

【0029】そして、本発明で使用される受像紙におい
ては、前述のように、基材としてのセルロース紙の厚さ
が通常50μm 〜300μm の範囲であるのに対し
、受像層の厚さは、通常0.5〜20μm の範囲であ
るから、受像紙には、セルロース紙のうねりが反映され
ることになる。また、セルロース紙と受像層の間に熱可
塑性高分子物質層を有し、セルロース紙の受像層を設け
た側と反対側の面に背面処理層を有する受像紙において
も、上記のセルロース紙の厚さに対し、高分子物質層の
厚さは通常5μm 〜40μm の範囲であり、背面層
を含む受像紙全体の厚さは通常50μm 〜350μm
の範囲とされることから、中心的厚さをなすセルロース
紙の前記うねりの問題がある。
In the image-receiving paper used in the present invention, as mentioned above, the thickness of the cellulose paper as the base material is usually in the range of 50 μm to 300 μm, while the thickness of the image-receiving layer is Since it is usually in the range of 0.5 to 20 μm, the undulations of the cellulose paper will be reflected on the image receiving paper. Furthermore, in an image-receiving paper that has a thermoplastic polymer material layer between the cellulose paper and the image-receiving layer, and has a back-treated layer on the side opposite to the side on which the image-receiving layer is provided, the above-mentioned cellulose paper can also be used. Regarding the thickness, the thickness of the polymer material layer is usually in the range of 5 μm to 40 μm, and the thickness of the entire receiver paper including the back layer is usually 50 μm to 350 μm.
There is a problem with the waviness of the cellulose paper having the central thickness.

【0030】従って、発熱体の配列方向に対するサーマ
ルヘッド移動方向における受像紙の機械的物性値比が1
以上の範囲となる条件下に受像紙の給紙を行った場合は
、繊維による表面のうねり方向と発熱体の配列方向とは
平行となる。このような場合は、受像紙のうねりの高低
(山、谷)の差により、高い部分はサーマルヘッドの発
熱体と十分に当接して熱伝達が十分に行われるが、低い
部分は当接が不十分で熱伝達が不十分となり、その結果
、着色せずに白抜けとなってざらつき感が大きくなる。 これに対し、本発明に従って、発熱体の配列方向に対す
るサーマルヘッド移動方向における受像紙の引張破壊強
度比または引張弾性率比が0.01〜0.9の範囲、特
には0.3〜0.7の範囲となる条件下に受像紙の給紙
を行った場合は、繊維による表面のうねり方向と発熱体
の配列方向とは直交する。このような場合は、サーマル
ヘッドの発熱体の一列全体がほぼ同程度のうねりの部分
に当接する結果、全体としてうねりの高い部分および低
い部分のいずれもが良好に着色して白抜けのない印刷と
なり、ざらつき感が小さくなる。
Therefore, the ratio of mechanical properties of the image receiving paper in the direction of movement of the thermal head to the direction in which the heating elements are arranged is 1.
When the image-receiving paper is fed under the above-mentioned conditions, the direction of surface waviness due to the fibers and the direction in which the heating elements are arranged are parallel to each other. In such a case, due to the difference in height (peaks and valleys) of the undulations of the image receiving paper, the high parts make sufficient contact with the heating element of the thermal head and sufficient heat transfer occurs, but the low parts do not make contact. If it is insufficient, heat transfer becomes insufficient, and as a result, white spots are formed without coloring, resulting in a rough texture. On the other hand, according to the present invention, the tensile breaking strength ratio or tensile modulus ratio of the image receiving paper in the thermal head movement direction with respect to the heating element arrangement direction is in the range of 0.01 to 0.9, particularly 0.3 to 0.9. When the image-receiving paper is fed under conditions within the range of 7, the direction of surface waviness due to the fibers and the direction in which the heating elements are arranged are perpendicular to each other. In such a case, the entire row of heating elements of the thermal head comes into contact with the part with approximately the same degree of undulation, and as a result, both the high and low undulation parts are well colored and printing without white spots is achieved. As a result, the roughness is reduced.

【0031】このように、本発明は、受像紙の給紙方向
に関する従来の固定観念を打破したものであり、そして
、従来とは逆方向の給紙方向を採用することにより、熱
転写記録の中でも一般に感熱昇華型と呼ばれる熱転写記
録方法の特有のざらつき感を小さくし、印画物の画質の
改良を図ったものである。
As described above, the present invention breaks down the conventional fixed idea regarding the paper feeding direction of the image receiving paper, and by adopting the paper feeding direction opposite to the conventional paper feeding direction, the present invention achieves an advantage even in thermal transfer recording. The purpose of this method is to reduce the roughness characteristic of a thermal transfer recording method generally called heat-sensitive dye sublimation, and to improve the image quality of prints.

【0032】そして、本発明者等の知見によれば、通常
の熱転写記録装置(プリンター)を使用する限り、本発
明に従って、従来の給紙方向と逆方向に受像紙の給紙を
行っても特別な問題はなく、むしろ、印画物のザラツキ
感が少なく高画質で高品位の転写画像が得られる利益の
方が遙かに大きい。
According to the findings of the present inventors, as long as a normal thermal transfer recording device (printer) is used, even if the image receiving paper is fed in the opposite direction to the conventional paper feeding direction according to the present invention, There is no particular problem; in fact, the benefits of obtaining a high-quality transferred image with less roughness in the printed matter are far greater.

【0033】本発明において、上記のざらつき感は、以
下に説明する、特願平2−269910号にて提案され
た「ざらつきの定量化方法」によって容易に評価するこ
とができる。すなわち、画像品位の低下は、前述の通り
、画像の濃度むら、転写抜け、発熱体の不動によるドッ
ト抜け等が複合的に関係して発生する。上記の「ざらつ
きの定量化方法」は、発熱体の不動によるドット抜け等
により生じる着色していない白い部分を計測することに
より、ざらつき感の定量化を図ったものである。そして
、上記の「ざらつきの定量化方法」は、次の(1)〜(
4)のステップにて構成される。
In the present invention, the above-mentioned roughness can be easily evaluated by the ``method for quantifying roughness'' proposed in Japanese Patent Application No. 2-269910, which will be explained below. That is, as described above, the deterioration of image quality is caused by a complex relationship between uneven image density, missing transfers, missing dots due to immobility of the heating element, and the like. The above-mentioned "method for quantifying roughness" attempts to quantify the feeling of roughness by measuring uncolored white areas caused by missing dots due to immobility of the heating element. The above "method for quantifying roughness" is as follows (1) to (
It consists of steps 4).

【0034】(1)転写シートの背面に一定密度の印画
エネルギーを供給して受像紙上に転写画像を得る。 (2)上記の転写画像を画像処理装置で処理して正規の
色濃度の部分の色濃度レベルのデータを得る。 (3)上記データの色濃度のレベルを上限とし、このレ
ベル未満の各色濃度レベルにおいて二値化し、該色濃度
レベル未満の色濃度の部分の面積、いわゆる白抜け面積
を算出する。 (4)各色濃度レベルをX軸値、白抜け面積の対数をY
軸値とする両者の相関を直線で近似し、該直線とX軸と
Y軸とで構成される三角形の面積(以下「面積指数」と
いう)を求め、これをざらつき感の尺度とする。面積指
数の値が小さい程ざらつき感が小さくて画像品位が高い
。
(1) A transferred image is obtained on image-receiving paper by supplying printing energy at a constant density to the back side of the transfer sheet. (2) The above transferred image is processed by an image processing device to obtain data on the color density level of the portion of normal color density. (3) With the color density level of the above data as the upper limit, each color density level below this level is binarized, and the area of the portion of the color density below the color density level, the so-called white area, is calculated. (4) The density level of each color is the X-axis value, and the logarithm of the white area is Y
The correlation between the two axis values is approximated by a straight line, and the area of a triangle formed by the straight line, the X axis, and the Y axis (hereinafter referred to as "area index") is determined, and this is used as a measure of roughness. The smaller the area index value, the smaller the graininess and the higher the image quality.

【0035】[0035]

【実施例】以下、本発明を実施例により更に詳細に説明
するが、本発明は、その要旨を越えない限り実施例に限
定されるものではない。なお、熱転写用受像紙の引張破
壊強度及び引張弾性率は下記条件で測定した。
[Examples] The present invention will be explained in more detail with reference to Examples below, but the present invention is not limited to the Examples unless the gist thereof is exceeded. The tensile breaking strength and tensile modulus of the thermal transfer image receiving paper were measured under the following conditions.

【0036】(1)引張試験(強伸度)(株)インテス
コ製の引張試験機インテスコモデル2001型を用いて
、温度23℃、湿度50%RHに調節された室内におい
て、長さ50mm、幅15mmの受像紙の試験片を20
0mm/min の速度で引張り、引張応力−ひずみ曲
線より次の各値を求める。■  引張破壊強度は次の式
によって計算する。 σ=F/A ここに、σ=引張破壊強度(Kg/mm2 )F=破壊
時に於ける加重(Kg) A=試験片の元の断面積(mm2 ) ■  引張破壊伸度は次の式によって計算する。 1=(L−L0 )/  L0 ×100ここに、1=
引張破壊伸度(%) L=破壊時の標点間距離(mm) L0 =元の標点間距離(mm)
(1) Tensile test (Strength and elongation) Using a tensile tester Intesco Model 2001 manufactured by Intesco Co., Ltd., a test piece with a length of 50 mm, 20 test pieces of receiver paper with a width of 15 mm
The following values are obtained from the tensile stress-strain curve by pulling at a speed of 0 mm/min. ■ Tensile fracture strength is calculated using the following formula. σ=F/A Where, σ=Tensile fracture strength (Kg/mm2) F=Load at fracture (Kg) A=Original cross-sectional area of test piece (mm2) ■ Tensile fracture elongation is calculated by the following formula. calculate. 1=(L-L0)/L0×100 Here, 1=
Tensile fracture elongation (%) L = Gauge distance at failure (mm) L0 = Original gauge distance (mm)

【0037】(2)引張弾性率 (株)上記と同一の引張試験機用いて、温度23℃、湿
度50%RHに調節された室内において、長さ300m
m、幅20mmの受像紙の試験片を10%/min の
ひずみ速度で引張り、引張応力−ひずみ曲線の初めの直
線部分を用いて次の式によって計算する。 E=Δσ/Δε ここに、E=引張弾性率(Kg/mm2 )Δσ=直線
上の2点間の元の平均断面積による応力差Δε=同じ2
点間のひずみ差
(2) Tensile Elastic Modulus Co., Ltd. Using the same tensile tester as above, a test was conducted for a length of 300 m in a room adjusted to a temperature of 23° C. and a humidity of 50% RH.
A test piece of receiver paper with a width of 20 mm and a width of 20 mm is pulled at a strain rate of 10%/min, and the initial straight line portion of the tensile stress-strain curve is used to calculate the strain according to the following formula. E=Δσ/Δε Where, E=tensile modulus (Kg/mm2) Δσ=stress difference due to original average cross-sectional area between two points on the straight line Δε=same 2
Strain difference between points

【0038】実施例1 広葉樹サルファイトパルプと広葉樹クラフトパルプ1:
1の混合パルプをこう解したのち抄造した。得られたセ
ルロース紙の厚さは190μm であった。次に、上記
のセルロース紙の表面に、低密度ポリエチレンと高密度
ポリエチレンの7:3から成る樹脂組成物を樹脂温度3
30℃で溶融押出コーティングし、厚さ13μm の表
面側ラミネート層を形成した。上記のポリエチレンは、
いずれも、アナターゼ型酸化チタンを10%含有したも
のであり、低密度ポリエチレンとしては、酸化チタン添
加前のポリエチレンの密度が0.92g/m3 、MI
が5のものを使用し、高密度ポリエチレンとしては、酸
化チタン添加前のポリエチレンの密度が0.96g/m
3 、MIが5のものを使用した。次に、表面側ラミネ
ート層と逆の面(裏面)に、酸化チタンを含まない以外
は上記と同様の樹脂組成物を樹脂温度330℃で溶融押
出コーティングし、厚さ13μmの裏面側ラミネート層
を形成した。次に、表面側ラミネート層の表面にコロナ
処理を施して濡れ張力55dyn/cmとした後、下記
の組成の受像層をダイコーターを用いて塗布して乾燥さ
せ、塗布厚5μm の受像層を設けて熱転写用受像紙を
得た。
Example 1 Hardwood sulfite pulp and hardwood kraft pulp 1:
After the mixed pulp of No. 1 was dissolved in this way, it was made into paper. The thickness of the cellulose paper obtained was 190 μm. Next, a resin composition consisting of 7:3 of low-density polyethylene and high-density polyethylene was applied to the surface of the cellulose paper at a resin temperature of 3:3.
Melt extrusion coating was performed at 30°C to form a 13 μm thick surface laminate layer. The above polyethylene is
Both contain 10% anatase-type titanium oxide, and as low-density polyethylene, the density of polyethylene before adding titanium oxide is 0.92 g/m3, MI
The density of the polyethylene before adding titanium oxide is 0.96 g/m as high-density polyethylene.
3, and one with an MI of 5 was used. Next, on the side opposite to the front side laminate layer (back side), a resin composition similar to the above except that it does not contain titanium oxide was melt-extruded coated at a resin temperature of 330°C to form a back side laminate layer with a thickness of 13 μm. Formed. Next, the surface of the front side laminate layer was corona-treated to give a wetting tension of 55 dyn/cm, and then an image-receiving layer having the following composition was applied using a die coater and dried to form an image-receiving layer with a coating thickness of 5 μm. An image receiving paper for thermal transfer was obtained.

【0039】<受像層形成用組成物>     飽和ポリエステル樹脂           
                         
  10重量部    (TP−220:商品名  日
本合成化学工業(株)製)    アミノ変性シリコー
ンオイル                     
         0.5重量部    (KF−39
3:商品名  信越化学工業(株)製)    溶剤(
キシレン/メチルエチルケトン=1/1)      
        30重量部
<Composition for forming image-receiving layer> Saturated polyester resin

10 parts by weight (TP-220: trade name manufactured by Nippon Gosei Kagaku Kogyo Co., Ltd.) Amino-modified silicone oil
0.5 parts by weight (KF-39
3: Product name: Shin-Etsu Chemical Co., Ltd.) Solvent (
xylene/methyl ethyl ketone = 1/1)
30 parts by weight

【0040】上記により得
られた受像紙をA6サイズに断裁し、一方向(B方向)
とこれに直角の他方向(A方向)の機械的物性を測定し
た結果は表1の通りであった。   表1                          
       A方向      B方向      
B/A──────────────────────
──────────────  引張破壊強度(Kg
/mm2 )      4.6      2.8 
     0.61  引張弾性率  (Kg/mm2
 )      273      153     
 0.56  引張破壊伸度(%)         
   3.8      8.3      ────
─────────────────────────
───────────
The image receiving paper obtained above was cut into A6 size and cut in one direction (B direction).
The results of measuring the mechanical properties in the other direction perpendicular to this (direction A) are shown in Table 1. Table 1
A direction B direction
B/A──────────────────────
────────────── Tensile breaking strength (Kg
/mm2) 4.6 2.8
0.61 Tensile modulus (Kg/mm2
) 273 153
0.56 Tensile elongation at break (%)
3.8 8.3 ────
──────────────────────────
────────────

【0041】図1に示す原理の
市販の熱転写記録装置により、上記の受像紙をB方向よ
り給紙ローラに送給し、すなわち、受像紙の引張破壊強
について言えば、発熱体の配列方向に対するサーマルヘ
ッド移動方向における引張破壊強度比が0.61となる
条件下に給紙して印刷を行った。なお、使用した転写シ
ート及び印刷条件は次の通りである。 <転写シート>次の方法により製造した転写シートを使
用した。すなわち、背面に耐熱滑性層を設けた厚さ6μ
m のポリエチレンテレフタレートフイルムの表面にバ
ーコータ−により下記組成の塗料組成物を乾燥後の塗布
厚さが2μm となるように塗布してインク層を形成し
た。     昇華性染料(住友化学工業(株)製スミプラス
レッドFB)      5重量部    エチルセル
ロース(米国ハーキュリーズ製N−7)       
       5重量部    エチルアルコール  
                         
               60重量部    ブ
タノール                     
                         
  30重量部  <印刷条件>     主走査および副走査の線密度        
            6ドット/mm    記録
電力                       
               0.156W/ドット
    ヘッドの加熱時間             
                 8msec
Using a commercially available thermal transfer recording device with the principle shown in FIG. Printing was performed by feeding the paper under conditions such that the tensile strength ratio in the direction of movement of the thermal head was 0.61. The transfer sheet and printing conditions used are as follows. <Transfer sheet> A transfer sheet manufactured by the following method was used. In other words, the thickness is 6 μm with a heat-resistant slippery layer on the back side.
An ink layer was formed by applying a coating composition having the following composition onto the surface of a polyethylene terephthalate film of 2.0 m using a bar coater so that the coating thickness after drying was 2 .mu.m. Sublimation dye (Sumiplus Red FB manufactured by Sumitomo Chemical Co., Ltd.) 5 parts by weight Ethyl cellulose (N-7 manufactured by Hercules, USA)
5 parts by weight ethyl alcohol

60 parts by weight butanol

30 parts by weight <Printing conditions> Main scanning and sub-scanning line density
6 dots/mm recording power
0.156W/dot Head heating time
8msec

【00
42】得られた印画物について、特願平2−26991
0号記載の「ざらつきの定量化方法」に従って、ざらつ
き(面積指数)を測定した結果は、表2に示す通りであ
り、ざらつき感は小さく画質は良好であった。
00
42] Regarding the obtained print, patent application No. 2-26991
The results of measuring roughness (area index) according to the "Method for quantifying roughness" described in No. 0 are as shown in Table 2, and the roughness was small and the image quality was good.

【0043】実施例2〜4 実施例1に準じた方法により、一方向(B方向)とこれ
に直角の他方向(A方向)の機械的物性の異なる受像紙
を得て印刷を行った。すなわち、発熱体の配列方向に対
するサーマルヘッド移動方向における受像紙の引張破壊
強度比と引張弾性率比が表2に示す条件下に受像紙を給
紙して印刷を行った。得られた印画物のざらつき(面積
指数)について、実施例1と同様の方法にて策定し、そ
の結果を表2に示す。いずれの受像紙の場合も、印画物
のざらつき感は小さく画質は良好であった。
Examples 2 to 4 By a method similar to Example 1, image receiving papers having different mechanical properties in one direction (direction B) and the other direction perpendicular thereto (direction A) were obtained and printed. That is, printing was performed by feeding the image-receiving paper under conditions in which the tensile breaking strength ratio and tensile modulus ratio of the image-receiving paper in the thermal head movement direction with respect to the arrangement direction of the heating elements are shown in Table 2. The roughness (area index) of the obtained print was determined in the same manner as in Example 1, and the results are shown in Table 2. In the case of any of the image-receiving papers, the printed matter had little roughness and the image quality was good.

【0044】実施例5 実施例1で得られた厚さ190μm のセルロース紙の
一方の面に実施例1で使用したのと同様の受像層形成用
組成物をダイコーターにより塗布して乾燥させ、塗布厚
5μm の受像層を設けて熱転写用受像紙を得た。実施
例1に準じた方法により、一方向(B方向)とこれに直
角の他方向(A方向)の機械的物性の異なる受像紙を得
て印刷を行った。すなわち、発熱体の配列方向に対する
サーマルヘッド移動方向における受像紙の引張破壊強度
比と引張弾性率比が表2に示す条件下に受像紙を給紙し
て印刷を行った。得られた印画物のざらつき(面積指数
)について、実施例1と同様の方法にて策定し、その結
果を表2に示す。印画物のざらつき感は小さく画質は良
好であった。 比較例1 公知の方法に従って、発熱体の配列方向に対するサーマ
ルヘッド移動方向における受像紙の引張破壊強度比と引
張弾性率比が表2に示す条件下に受像紙を給紙して印刷
を行った。得られた印画物のざらつき(面積指数)を測
定した結果は、表2に示す通りであり、ざらつき感が大
きく画質は不良であった。
Example 5 An image-receiving layer forming composition similar to that used in Example 1 was applied to one side of the 190 μm thick cellulose paper obtained in Example 1 using a die coater and dried. An image-receiving layer with a coating thickness of 5 μm was provided to obtain an image-receiving paper for thermal transfer. By a method similar to Example 1, an image receiving paper having different mechanical properties in one direction (direction B) and the other direction perpendicular to this (direction A) was obtained and printed. That is, printing was performed by feeding the image receiving paper under conditions in which the tensile breaking strength ratio and tensile modulus ratio of the image receiving paper in the thermal head movement direction with respect to the heating element arrangement direction are shown in Table 2. The roughness (area index) of the obtained prints was determined in the same manner as in Example 1, and the results are shown in Table 2. The print had little roughness and the image quality was good. Comparative Example 1 According to a known method, printing was performed by feeding image receiving paper under the conditions that the tensile breaking strength ratio and tensile modulus ratio of the image receiving paper in the direction of movement of the thermal head relative to the direction in which the heating elements were arranged were shown in Table 2. . The results of measuring the roughness (area index) of the obtained print are as shown in Table 2, and the roughness was large and the image quality was poor.

【0045】   表2                 引張破壊強度比  
    引張弾性率比          面積指数─
─────────────────────────
──────────  実施例1        0
.61            0.56      
      6.12  実施例2        ─
───            0.45      
      5.52  実施例3        0
.53            ────      
      5.10  実施例4        ─
───            0.65      
      7.01  実施例5        ─
───            0.51      
      7.53  比較例1        1
.64            1.78      
      8.92───────────────
─────────────────────(注)受
像紙の引張破壊強度比及び引張弾性率比は、発熱体の配
列方向に対すサーマルヘッド移動方向における値である
。
Table 2 Tensile fracture strength ratio
Tensile modulus ratio Area index─
──────────────────────────
────────── Example 1 0
.. 61 0.56
6.12 Example 2 -
─── 0.45
5.52 Example 3 0
.. 53 ────
5.10 Example 4 -
─── 0.65
7.01 Example 5 -
─── 0.51
7.53 Comparative Example 1 1
.. 64 1.78
8.92────────────────
────────────────────── (Note) The tensile breaking strength ratio and tensile modulus ratio of the receiver paper are based on the thermal head movement direction with respect to the heating element arrangement direction. It is a value.

【0046】[0046]

【発明の効果】以上説明した本発明によれば、セルロー
ス紙等を基材とする受像紙の送給を特定の方法で行うこ
とにより、ざらつき感を小さくした、高画質、高品位の
転写画像が得られる。
Effects of the Invention According to the present invention as described above, by feeding an image receiving paper based on cellulose paper or the like in a specific manner, a high-quality, high-quality transferred image with reduced roughness can be obtained. is obtained.

【図面の簡単な説明】[Brief explanation of the drawing]

【図1】本発明の熱転写記録方法の概要を示す説明図で
ある。
FIG. 1 is an explanatory diagram showing an overview of the thermal transfer recording method of the present invention.

【符号の説明】[Explanation of symbols]

(1)        :転写シート (2)        :受像紙 (3)(3′):給紙ローラ (1)        :Transfer sheet (2)        : Image receiving paper (3) (3'): Paper feed roller

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】  基材表面に気化性又は熱拡散性色素を
含有する転写層を設けてなる転写シート及びセルロース
紙の一方の面に色素を受容する受像層を設けてなる受像
紙を用い、給紙ローラにより、複数の発熱体を配列して
なるサーマルヘッドとプラテンローラとの間に前記受像
紙を供給し、その受像層と前記転写シートの転写層とを
対向させて重ね合わせ、発熱体からの転写シートへの加
熱により転写層中の色素を受像層に受容させ、そして、
発熱体配列方向と略直角方向に受像紙とサーマルヘッド
とを相対的に移動させて記録を行う熱転写記録方法にお
いて、発熱体の配列方向に対するサーマルヘッド移動方
向における受像紙の引張破壊強度比または引張弾性率比
が0.01〜0.9の範囲となる条件下に受像紙の給紙
を行うことを特徴とする熱転写記録方法。
Claim 1: Using a transfer sheet comprising a transfer layer containing a vaporizable or heat-diffusible dye on the surface of a base material and an image-receiving paper comprising an image-receiving layer for receiving the dye on one side of cellulose paper, A paper feed roller supplies the image receiving paper between a thermal head having a plurality of heating elements arranged and a platen roller, and the image receiving layer and the transfer layer of the transfer sheet are stacked facing each other, and the heating elements The dye in the transfer layer is received by the image-receiving layer by heating the transfer sheet from
In a thermal transfer recording method in which recording is performed by moving an image receiving paper and a thermal head relatively in a direction approximately perpendicular to the direction in which the heating elements are arranged, the tensile breaking strength ratio or tensile strength of the image receiving paper in the direction of movement of the thermal head relative to the direction in which the heating elements are arranged is A thermal transfer recording method characterized in that image receiving paper is fed under conditions such that the elastic modulus ratio is in the range of 0.01 to 0.9.
【請求項2】  受像紙として、セルロース紙と受像層
の間に熱可塑性高分子物質のラミネート層を有する受像
紙を使用する請求項1記載の熱転写記録方法。
2. The thermal transfer recording method according to claim 1, wherein the image-receiving paper is an image-receiving paper having a laminate layer of a thermoplastic polymer material between the cellulose paper and the image-receiving layer.
【請求項3】  受像紙として、受像層を設けた側と反
対側の面に背面処理層を有する受像紙を使用する請求項
1又は2記載の熱転写記録方法。
3. The thermal transfer recording method according to claim 1, wherein the image-receiving paper is an image-receiving paper having a back surface treatment layer on the side opposite to the side on which the image-receiving layer is provided.
JP03126692A 1991-04-30 1991-04-30 Thermal transfer recording method Expired - Lifetime JP3088774B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP03126692A JP3088774B2 (en) 1991-04-30 1991-04-30 Thermal transfer recording method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP03126692A JP3088774B2 (en) 1991-04-30 1991-04-30 Thermal transfer recording method

Publications (2)

Publication Number Publication Date
JPH04329190A true JPH04329190A (en) 1992-11-17
JP3088774B2 JP3088774B2 (en) 2000-09-18

Family

ID=14941489

Family Applications (1)

Application Number Title Priority Date Filing Date
JP03126692A Expired - Lifetime JP3088774B2 (en) 1991-04-30 1991-04-30 Thermal transfer recording method

Country Status (1)

Country Link
JP (1) JP3088774B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017185735A (en) * 2016-04-07 2017-10-12 凸版印刷株式会社 Thermal transfer image receiving sheet

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017185735A (en) * 2016-04-07 2017-10-12 凸版印刷株式会社 Thermal transfer image receiving sheet

Also Published As

Publication number Publication date
JP3088774B2 (en) 2000-09-18

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