JPH0434497B2 - - Google Patents
Info
- Publication number
- JPH0434497B2 JPH0434497B2 JP19484184A JP19484184A JPH0434497B2 JP H0434497 B2 JPH0434497 B2 JP H0434497B2 JP 19484184 A JP19484184 A JP 19484184A JP 19484184 A JP19484184 A JP 19484184A JP H0434497 B2 JPH0434497 B2 JP H0434497B2
- Authority
- JP
- Japan
- Prior art keywords
- fabric
- parts
- moisture permeability
- stretchable
- moisture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004744 fabric Substances 0.000 claims description 34
- 230000035699 permeability Effects 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 19
- 239000000853 adhesive Substances 0.000 claims description 8
- 230000001070 adhesive effect Effects 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 8
- 239000012982 microporous membrane Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 description 16
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 13
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 239000011347 resin Substances 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- 239000005871 repellent Substances 0.000 description 10
- 230000002940 repellent Effects 0.000 description 9
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 6
- 229910052731 fluorine Inorganic materials 0.000 description 6
- 239000011737 fluorine Substances 0.000 description 6
- 238000007756 gravure coating Methods 0.000 description 5
- 239000004677 Nylon Substances 0.000 description 4
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 230000032683 aging Effects 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- 150000003673 urethanes Chemical class 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003495 polar organic solvent Substances 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、優れた透湿性と防水性とを有する、
風合の柔軟な、ストレツチ性を有する透湿性防水
性伸縮布帛に関する。
従来の技術、発明が解決しようとする問題点
従来、防水性透湿性布帛として、ウレタン重合
体、ポリアクリル酸エステル樹脂、四フツ化エチ
レン樹脂等を繊維基布にコーテイングもしくはラ
ミネートしたものが多数提案されているが、最近
になつてこれらの布帛が有する諸機能以外に、繊
維自体の伸縮性を保持し、しかも防水性及び透湿
性を有するものへのニーズが高まつてきている。
かかるニーズに対応した提案として、撥水処理を
施したタフタ上にナイフオーバーロールコーター
にてウレタン重合体を塗布し、次いで伸縮性基布
を無荷重及び無張力の状態で貼り合わせ、しかる
のち水浴中に浸漬して微多孔質皮膜を得、次いで
タフタを剥離して製品とする方法、あるいは伸縮
性基布上に四フツ化エチレン樹脂をグラビアロー
ルにて点状にコーテイングして得る方法、またポ
リアミノ酸変性ウレタンを伸縮基布とラミネート
して得る方法等がある。これらのいずれかの方法
においても防水性は得られるものの、充分な透湿
性は得難いという欠点がある。本発明は、このよ
うな従来技術における欠点を解消し、防水性及び
透湿性の両者に優れた伸縮布帛を提供しようとす
るものである。
問題点を解決するための手段
本発明は、即ち透湿性防水性伸縮布帛を提供す
るものである。本発明の布帛は、伸縮性を有する
繊維基布の少なくとも片面上に、高分子材料から
なる微多孔質膜を、ポリウレタンからなる接着剤
で点状に接着してなる透湿性防水性伸縮布帛であ
つて、前記接着剤が1μmの厚さのフイルムに成膜
したときに4000g/m2/24時間以上の透湿度を示
すことを特徴とするものである。
本発明は、即ち、伸縮性の基布上に高分子材料
からなる微多孔質膜を接着する如き伸縮布帛の構
成において、ポリウレタン接着剤を用いて点状に
接着したことを特徴とするのであつて、その透湿
度が4000g/m2/24時間以上であり、耐水圧が
900mmH2O/cm2であり、剥離強度が200g/cm以上
であるのが好ましい。
本発明の透湿性防水性伸縮布帛の製造に際して
透湿性及び防水性を有する微多孔質膜を与える高
分子材料としては、例えば、ポリエステル系ウレ
タン重合体やポリエール系重合体の他に、ポリア
クリル酸重合体、アミノ酸変性ウレタン重合体等
があるが、微多孔質皮膜を形成する機能を有する
ものであれば如何なるものでも採用できる。然し
ながら、本発明にあつては、透湿性及び防水性を
与える為にきわめて微少な小孔を有する皮膜を形
成させると同時に、該皮膜内部に均一なセルを形
成させ必要がある。従つて、微多孔質膜を形成す
るにはポリウレタン重合体を湿式凝固法により成
膜する方法が一般的であるが、この場合上記の目
的の為にポリウレタン重合体を主体とする塗布溶
液を特別に調製する必要がある。例えば、ポリウ
レタン重合体100重量部を含有するジメチルホル
ムアミドによつて代表される極性有機溶媒の溶液
にフツ素系撥水剤0.5〜2重合部及び水酸化アル
ミニウム5〜20重合部を配合した調合液が良好な
結果を与える。
撥水剤の添加は、得られる布帛に耐久撥水性を
与える効果があり、好ましい。撥水剤の含有量が
0.5重量部より少ない場合には充分な撥水性が得
られず、一方2重量部より多い場合には湿式凝固
に際して湿式成膜性や微多孔質皮膜の不均一性を
招く傾向になる。
水酸化アルミニウムの添加は湿式フイルムのブ
ロツキング性を良好にする効果を与え、皮膜内部
に均一なセルを形成させる効果もある。さらに安
価であることは樹脂コストの低下につながる。水
酸アルミニウムの添加量は5重量部以下では適度
のブロツキング性は得られず、20重量部以上では
微多孔質皮膜の透湿度の低下を招く。
上記調合液の塗布方法としてはナイフオーバー
ロールコーターその他の通常のコーテイング機を
使用し、任意の厚さに均一に塗布する。次に、こ
の微多孔質膜上にポリウレタンからなる接着剤を
グラビア塗工機、ロータリースクリーン捺染機な
どの適当な手段により点状に塗布し、次いで伸縮
性基布を無荷重、無張力の状態で貼り合せる。こ
の場合、このポリウレタン接着剤は、これを1μm
の厚さのフイルムに形成したとき4000g/m2/
24hr以上の透湿度を示すような材料であることが
必要である。本発明に有用なかかるポリウレタン
接着剤の例としては、ポリアミノ酸変性ウレタン
樹脂や親水性を有するポリエチレングリコールな
どから得られるウレタン樹脂、もしくはケミカル
発泡、機械発泡等で得られる多孔性の樹脂などを
挙げることができる。ドツドの形状及び形態は特
に限定されないが、透湿性の保持と剥離強度の向
上の面より、ドツドの大きさは0.01〜10mm2であ
るのが適当である。0.01mm2以下の大きさでは十
分な剥離強度を得られず、10mm2以上では透湿性
の低下を招く結果となることがある。
発明の効果
このようにして得られる本発明の布帛は、風合
の低下もなく、防水性に優れ、高い透湿性を有す
る、ストレツチ性に富んだ布帛となる。
実施例
以下、本発明を具体例を挙げて説明する。尚、
以下の説明において、部および%は特にことわり
のない限り重量に関するものである。
実施例 1
ナイロンタフタにシリコーン系撥水剤処理を施
す。このように処理されたタフタ上の片面に下記
組成の樹脂液をナイフオーバーロールコーター方
式により約230g/m2塗布し、水中凝固後脱溶媒
を行い、次いで乾燥し、微多孔質を得た。
クリスボン8006(大日本インキ製ポリエステル
型ウレタン重合体) 100部
DMF(N,N′−ジメチルホルムアミド) 80部
水酸化アルミニウムL−308(住友アルミニウム
製) 15部
フツ素系撥水剤(明成化学製アサヒガード
AG710) 2部
次に下記組成の樹脂液をグラビア塗工機にて、
40メツシユのドツトで、前述のウレタン塗布面上
に印捺し、伸縮性ニツト基布を無荷重、無張力の
状態で貼り合わせた。エージング工程を終えたの
ち、ナイロンタフタを剥離した。尚、この樹脂液
から得られた厚さ1μmのフイルムの透湿度は5000
であつた。
ラツクスキンu−682(セイコー化成製アミノ酸
変性二液ウレタン重合体) 70部
ラツクスキンu−678(セイコー化成製アミノ酸
変性一液ウレタン重合体) 30部
MEK(メチルエチルケトン) 15部
架橋剤(イソシアネート) 5部
さらに撥水性能を付与する為布帛をエマルジヨ
ンタイプのフツ素系撥水剤(アサヒガード
AG710)の水溶液に浸漬し、パデイング後乾燥
し、キユアリングを行つた。
比較例 1
実施例1と同様にウレタン重合体の微多孔質膜
をナイロンタフタ上に作製したものを、下記のよ
うに透湿性の低い樹脂液をグラビア塗工機にて、
40メツシユのドツトで印捺したのち、実施例1と
同一の伸縮性ニツト基布を無荷重、無張力の状態
で貼り合わせ、エージング工程を経て、ナイロン
タフタを剥離した。尚、この樹脂液から得られた
厚さ1μmのフイルムの透湿度は900であつた。
クリスボン5010(大日本インキ製セミ一液型ウ
レタン重合体) 70部
クリスボン4010(大日本インキ製二液型ウレタ
ン重合体) 30部
MEK 50部
DMF 10部
架橋剤(イソシアネート) 5部
さらに布帛をエナルジヨンタイプのフツ素系撥
水剤(アサヒガードAG710)の水溶液に浸漬し、
パデイング後乾燥し、キユアリングを行つた。こ
れを実施例1の布帛と比較した。
実施例 2
実施例1で得られた2層の伸縮性透湿性布帛の
ウレタン面上にさらに下記の樹脂液をグラビア塗
工機にて20メツシユのドツトで印捺し、伸縮性ニ
ツト基布を無荷重、無張力の状態で貼り合わせ、
3層の伸縮性布帛を得た。エツチング工程を経
て、フツ素系撥水剤(アサヒガードAG710)の
水溶液で撥水性能を付与した。
ラツクスキンu−682(セイコー化成製アミノ酸
変性二液ウレタン重合体) 100部
MEK 30部
架橋剤(イソシアネート) 5部
比較例 2
比較例1で得られた布帛のウレタン重合体面上
に比較例1で使用したと同じ透湿性の低い樹脂の
液をグラビア塗工機にて20メツシユのドツトで印
捺したものに、実施例2と同一の伸縮性ニツト基
布を無荷重、無張力の状態で貼り合わせ、3層の
伸縮性布帛を得た。エージング工程を終えたの
ち、フツ素系撥水剤(アサヒガードAG710)の
水溶液で撥水性能を付与した。これを比較例2と
した。
実施例1及び2並びに比較例1及び2の各例で
得られた製品の透湿性及び耐水圧並びに剥離強度
を測定し、結果を第1表に示す。本発明による実
施例は、比較例と比較し、透湿度の点で向上して
おり、しかも実用に耐える剥離強度を有している
ことがわかる。
【表】DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention provides a method of using a
The present invention relates to a breathable, waterproof, stretchable fabric with a soft texture and stretch properties. Conventional technology and problems to be solved by the invention In the past, many waterproof and breathable fabrics have been proposed in which urethane polymers, polyacrylic acid ester resins, tetrafluoroethylene resins, etc. are coated or laminated on fiber base fabrics. However, recently there has been an increasing need for fabrics that not only have the various functions that these fabrics have, but also maintain the elasticity of the fibers themselves, as well as having waterproofness and moisture permeability.
As a proposal to meet these needs, we applied a urethane polymer to water-repellent taffeta using a knife-over roll coater, then attached a stretchable base fabric under no load and no tension, and then bathed it in water. A method in which a microporous film is obtained by dipping the taffeta into a product, and then the taffeta is peeled off to obtain a product, or a method in which a polytetrafluoroethylene resin is coated in dots on a stretchable base fabric using a gravure roll, There are methods such as laminating a polyamino acid-modified urethane with a stretchable base fabric. Although waterproof properties can be obtained with any of these methods, there is a drawback that sufficient moisture permeability is difficult to obtain. The present invention aims to eliminate such drawbacks in the prior art and provide a stretchable fabric that is excellent in both waterproofness and moisture permeability. Means for Solving the Problems The present invention provides a moisture-permeable waterproof elastic fabric. The fabric of the present invention is a moisture-permeable, waterproof, stretchable fabric in which a microporous membrane made of a polymeric material is adhered in dots on at least one side of a stretchable fiber base fabric with an adhesive made of polyurethane. The adhesive exhibits a moisture permeability of 4000 g/m 2 /24 hours or more when formed into a film with a thickness of 1 μm. That is, the present invention is characterized in that, in the construction of a stretchable fabric in which a microporous membrane made of a polymeric material is bonded onto a stretchable base fabric, the membrane is bonded in dots using a polyurethane adhesive. Its moisture permeability is 4000g/m 2 /24 hours or more, and its water pressure resistance is
It is preferable that the peel strength is 900 mmH 2 O/cm 2 and the peel strength is 200 g/cm or more. In the production of the moisture-permeable waterproof elastic fabric of the present invention, examples of polymeric materials that provide a microporous membrane having moisture permeability and waterproof properties include polyester-based urethane polymers, polyale-based polymers, and polyacrylic acid. There are polymers, amino acid-modified urethane polymers, etc., but any material can be used as long as it has the function of forming a microporous film. However, in the present invention, it is necessary to form a film having extremely small pores in order to provide moisture permeability and waterproofness, and at the same time to form uniform cells inside the film. Therefore, in order to form a microporous membrane, it is common to form a film using a wet coagulation method using a polyurethane polymer. It is necessary to prepare the For example, a liquid preparation is prepared by blending 0.5 to 2 parts of a fluorine-based water repellent and 5 to 20 parts of aluminum hydroxide into a solution of a polar organic solvent such as dimethylformamide containing 100 parts by weight of a polyurethane polymer. gives good results. Addition of a water repellent is preferable because it has the effect of imparting durable water repellency to the resulting fabric. Water repellent content
When the amount is less than 0.5 parts by weight, sufficient water repellency cannot be obtained, while when it is more than 2 parts by weight, wet film formability and non-uniformity of the microporous film tend to occur during wet coagulation. Addition of aluminum hydroxide has the effect of improving the blocking properties of the wet film and also has the effect of forming uniform cells inside the film. Furthermore, being inexpensive leads to a reduction in resin cost. If the amount of aluminum hydroxide added is less than 5 parts by weight, adequate blocking properties cannot be obtained, and if it is more than 20 parts by weight, the moisture permeability of the microporous film will be reduced. The above-mentioned liquid mixture is coated uniformly to a desired thickness using a knife-over-roll coater or other conventional coating machine. Next, an adhesive made of polyurethane is applied dotted onto this microporous membrane using an appropriate means such as a gravure coating machine or a rotary screen printing machine, and then the elastic base fabric is placed in a no-load, no-tension state. Paste it with In this case, this polyurethane adhesive
When formed into a film with a thickness of 4000g/m 2 /
The material must have a moisture permeability of 24 hours or more. Examples of such polyurethane adhesives useful in the present invention include urethane resins obtained from polyamino acid-modified urethane resins, hydrophilic polyethylene glycol, etc., and porous resins obtained by chemical foaming, mechanical foaming, etc. be able to. Although the shape and form of the dots are not particularly limited, from the viewpoint of maintaining moisture permeability and improving peel strength, it is appropriate that the size of the dots is 0.01 to 10 mm 2 . If the size is less than 0.01 mm 2 , sufficient peel strength cannot be obtained, and if it is more than 10 mm 2 , this may result in a decrease in moisture permeability. Effects of the Invention The fabric of the present invention thus obtained is a fabric with excellent waterproofness, high moisture permeability, and high stretchability without any deterioration in feel. Examples Hereinafter, the present invention will be explained by giving specific examples. still,
In the following description, parts and percentages are by weight unless otherwise specified. Example 1 Nylon taffeta is treated with a silicone water repellent. Approximately 230 g/m 2 of a resin liquid having the following composition was coated on one side of the taffeta thus treated using a knife over roll coater method, and after coagulating in water, the solvent was removed and then dried to obtain a microporous material. Crisbon 8006 (polyester type urethane polymer manufactured by Dainippon Ink) 100 parts DMF (N,N'-dimethylformamide) 80 parts Aluminum hydroxide L-308 (manufactured by Sumitomo Aluminum) 15 parts Fluorine-based water repellent (manufactured by Meisei Chemical Co., Ltd.) asahi guard
AG710) 2 parts Next, apply the resin liquid with the following composition using a gravure coating machine.
40 mesh dots were printed on the urethane coated surface described above, and the stretchable knit base fabric was bonded under no load and no tension. After completing the aging process, the nylon taffeta was peeled off. Furthermore, the moisture permeability of a 1 μm thick film obtained from this resin liquid is 5000.
It was hot. Luxkin U-682 (Seiko Kasei's amino acid-modified two-component urethane polymer) 70 parts Luxkin u-678 (Seiko Kasei's amino acid-modified one-component urethane polymer) 30 parts MEK (methyl ethyl ketone) 15 parts Crosslinking agent (isocyanate) 5 parts Emulsion-type fluorine-based water repellent (Asahi Guard) is used to add water repellency to fabrics.
AG710), padded, dried, and cured. Comparative Example 1 A microporous membrane of urethane polymer was prepared on nylon taffeta in the same manner as in Example 1, and a resin liquid with low moisture permeability was coated with a gravure coating machine as shown below.
After printing with 40 mesh dots, the same stretchable knit base fabric as in Example 1 was laminated under no load and no tension, and after an aging process, the nylon taffeta was peeled off. Note that the moisture permeability of a 1 μm thick film obtained from this resin liquid was 900. Crisbon 5010 (semi-one-component urethane polymer manufactured by Dainippon Ink) 70 parts Crisbon 4010 (two-component urethane polymer manufactured by Dainippon Ink) 30 parts MEK 50 parts DMF 10 parts Crosslinking agent (isocyanate) 5 parts Immerse it in an aqueous solution of a fluorine-based water repellent (Asahi Guard AG710).
After padding, it was dried and cured. This was compared with the fabric of Example 1. Example 2 On the urethane surface of the two-layer stretchable, moisture-permeable fabric obtained in Example 1, the following resin solution was further printed in 20 mesh dots using a gravure coating machine, leaving no stretchable knit base fabric. Laminated under no load or tension,
A three-layer stretch fabric was obtained. After an etching process, water repellency was imparted using an aqueous solution of a fluorine-based water repellent (Asahi Guard AG710). Luxkin U-682 (Seiko Kasei's amino acid-modified two-part urethane polymer) 100 parts MEK 30 parts Crosslinking agent (isocyanate) 5 parts Comparative Example 2 Used in Comparative Example 1 on the urethane polymer surface of the fabric obtained in Comparative Example 1 The same stretchable knit base fabric as in Example 2 was pasted under no load and no tension to the same resin liquid with low moisture permeability printed with 20 mesh dots using a gravure coating machine. , a three-layer stretch fabric was obtained. After completing the aging process, water repellency was imparted with an aqueous solution of a fluorine-based water repellent (Asahi Guard AG710). This was designated as Comparative Example 2. The moisture permeability, water pressure resistance, and peel strength of the products obtained in Examples 1 and 2 and Comparative Examples 1 and 2 were measured, and the results are shown in Table 1. It can be seen that the examples according to the present invention are improved in moisture permeability as compared to the comparative examples, and have a peel strength that is suitable for practical use. 【table】
Claims (1)
に、高分子材料からなる微多孔質膜を、ポリウレ
タンからなる接着剤で点状に接着してなる透湿性
防水性伸縮布帛であつて、前記接着剤が1μmの厚
さのフイルムに成膜したときに4000g/m2/24時
間以上の透湿度を示すことを特徴とする透湿性防
水性伸縮布帛。 2 透湿度が4000g/m2/24時間以上であり、耐
水圧が900mmH2O/cm2以上であり、剥離強度が
200g/cm以上である特許請求の範囲第1項記載
の透湿性防水性伸縮布帛。[Scope of Claims] 1. A moisture-permeable, waterproof, stretchable fabric in which a microporous membrane made of a polymeric material is adhered in dots on at least one side of a stretchable fiber base fabric with an adhesive made of polyurethane. A moisture permeable waterproof stretchable fabric, characterized in that the adhesive exhibits a moisture permeability of 4000 g/m 2 /24 hours or more when formed into a film with a thickness of 1 μm. 2 Moisture permeability is 4000g/m 2 /24 hours or more, water pressure resistance is 900mmH 2 O/cm 2 or more, and peel strength is
The moisture permeable waterproof elastic fabric according to claim 1, which has a weight of 200 g/cm or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19484184A JPS6172543A (en) | 1984-09-19 | 1984-09-19 | Permeable waterproof stretch fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19484184A JPS6172543A (en) | 1984-09-19 | 1984-09-19 | Permeable waterproof stretch fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6172543A JPS6172543A (en) | 1986-04-14 |
| JPH0434497B2 true JPH0434497B2 (en) | 1992-06-08 |
Family
ID=16331160
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19484184A Granted JPS6172543A (en) | 1984-09-19 | 1984-09-19 | Permeable waterproof stretch fabric |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6172543A (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0630442Y2 (en) * | 1986-08-08 | 1994-08-17 | セーレン株式会社 | Breathable waterproof fabric |
| JPH0444355Y2 (en) * | 1986-09-24 | 1992-10-20 | ||
| JPS6377731U (en) * | 1986-11-07 | 1988-05-23 | ||
| CA2097630A1 (en) * | 1992-12-29 | 1994-06-30 | Ann Louise Mccormack | Stretch-pillowed, bulked laminate |
| ZA9510307B (en) * | 1994-12-20 | 1996-06-11 | Kimberly Clark Co | Mechanically compatibilized film/non-woven laminates |
| CA2221136A1 (en) * | 1995-06-06 | 1996-12-12 | Kimberly-Clark Worldwide, Inc. | Microporous film containing a microbial adsorbent |
| AU5882296A (en) * | 1995-06-06 | 1996-12-24 | Kimberly-Clark Worldwide, Inc. | Microporous fabric containing a microbial adsorbent |
| GB2470572A (en) * | 2009-05-27 | 2010-12-01 | Sealskinz Ltd | A waterproof windprrof breathable and stretchable laminate |
-
1984
- 1984-09-19 JP JP19484184A patent/JPS6172543A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6172543A (en) | 1986-04-14 |
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