JPH04362148A - Gold alloy for ornamentation - Google Patents

Gold alloy for ornamentation

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Publication number
JPH04362148A
JPH04362148A JP16369991A JP16369991A JPH04362148A JP H04362148 A JPH04362148 A JP H04362148A JP 16369991 A JP16369991 A JP 16369991A JP 16369991 A JP16369991 A JP 16369991A JP H04362148 A JPH04362148 A JP H04362148A
Authority
JP
Japan
Prior art keywords
gold
gold alloy
alloy
cobalt
manganese
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP16369991A
Other languages
Japanese (ja)
Inventor
Yoshihiko Isobe
礒部 芳彦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NIPPON KOGYO GINKOU KK
Original Assignee
NIPPON KOGYO GINKOU KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NIPPON KOGYO GINKOU KK filed Critical NIPPON KOGYO GINKOU KK
Priority to JP16369991A priority Critical patent/JPH04362148A/en
Publication of JPH04362148A publication Critical patent/JPH04362148A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To develop on alloy having excellent hardness and elasticity as well as a color tone similar to that of an Au-Ag-Cu ternary alloy by adding Co and Mn or Ni to the Au-Ag-Cu alloy. CONSTITUTION:An Au-Ag-Cu alloy consisting of 75wt.% Au, 5-8wt.% Ag and 7-12wt.% Cu is alloyed with 1-6wt.% Co and 1-6wt.% Mn or 1-4wt.% Ni to obtain an alloy for ornamentation having excellent hardness and elasticity, high scratch resistance and toughness as a sheet while maintaining a color tone peculiar to the 18-k. gold alloy.

Description

【発明の詳細な説明】[Detailed description of the invention]

【0001】0001

【産業上の利用分野】この発明は高硬度、高弾性を有す
る装飾用金合金、特にマンガンとコバルト又はマンガン
とニッケルとを合金の添加元素とした装飾用金合金の提
供に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a decorative gold alloy having high hardness and high elasticity, and particularly to a decorative gold alloy containing manganese and cobalt or manganese and nickel as additive elements.

【0002】0002

【従来の技術】装飾用の金合金は、典型的には18K金
合金等が装飾性、加工性等の面から一般に広く用いられ
ている。しかしながら、この種の18K金合金は比較的
柔かく、変形し易い不都合を有すると共に、靭性が低く
、機能性をもった装飾具の成形には稍々難があった。か
ゝる点から、近時白金又はニッケルを添加元素とした金
合金が装飾用金合金として用いられるにいたっている。
2. Description of the Related Art Decorative gold alloys, typically 18K gold alloys, are widely used in view of their decorative properties and workability. However, this type of 18K gold alloy has the disadvantage of being relatively soft and easily deformed, and has low toughness, making it somewhat difficult to mold into functional ornaments. From this point of view, gold alloys containing platinum or nickel as an additive element have recently come to be used as decorative gold alloys.

【0003】0003

【発明が解決しようとする課題】かゝる白金又はニッケ
ルを添加元素とする金合金は、装飾材に要請される硬さ
と充分な弾性とを有する反面、色調が白地基調となる傾
向を示し金合金に特有の色調が喪われる不都合があった
。かゝる点については、金−銀−銅の三元合金に前記の
白金又はニッケル以外の貴金属あるいは卑金属を添加し
て得られる金合金が白地基調の色調となることゝして一
般に認識されている。
[Problems to be Solved by the Invention] Although such gold alloys containing platinum or nickel as an additive element have the hardness and sufficient elasticity required for decorative materials, they tend to have a white background color and are There was an inconvenience that the color tone peculiar to the alloy was lost. Regarding this point, it is generally recognized that gold alloys obtained by adding noble metals or base metals other than platinum or nickel to a ternary alloy of gold-silver-copper have a white background color. There is.

【0004】かゝる装飾用金合金の不都合を解消するた
めに、一般的な手段として、ニッケル又は白金を添加合
金元素として得られた金合金の表面に再度メッキ処理を
施して色調の調整をすることが試みられている。しかし
ながら、かゝるメッキ処理では金合金としての価値を充
分に発揮することができず、装飾具としての価値を著し
く減ずる不都合があった。
[0004] In order to eliminate such inconveniences of decorative gold alloys, as a general method, the surface of the gold alloy obtained by adding nickel or platinum as an alloying element is plated again to adjust the color tone. An attempt is being made to do so. However, such plating treatment has the disadvantage that it cannot fully demonstrate its value as a gold alloy, and its value as a decorative tool is significantly reduced.

【0005】本発明は、かゝる従来の金合金材における
不都合に鑑み、金−銀−銅合金に近い色調を有すると共
に高硬度、且つ高弾性の装飾用金合金材の提供を目的と
している。
In view of the disadvantages of conventional gold alloy materials, it is an object of the present invention to provide a decorative gold alloy material that has a color tone similar to that of a gold-silver-copper alloy, has high hardness, and has high elasticity. .

【0006】[0006]

【課題を解決するための手段】本発明はかゝる目的を達
成するものとして、選択的に添加されるマンガン1〜6
wt%又はニッケル1〜4wt%のいずれか一種と、コ
バルト1〜6wt%とを、18K金合金である金75w
t%、銀5〜8wt%、銅7〜12wt%の添加合金元
素として含めて装飾用金合金としてある。
[Means for Solving the Problems] The present invention achieves the above object by adding selectively added manganese 1 to 6.
wt% or 1 to 4 wt% of nickel and 1 to 6 wt% of cobalt to gold 75w, which is an 18K gold alloy.
t%, 5 to 8 wt% of silver, and 7 to 12 wt% of copper as additional alloying elements to form a decorative gold alloy.

【0007】[0007]

【作用】金−銀−銅の三元合金にコバルト1〜6wt%
と、マンガン1〜6wt%又はニッケル1〜4wt%を
添加合金元素として添加することによって前記三元合金
の色調が維持されると共に合金の靭性と硬さとが増し、
装飾用金合金としてスクラッチに強く、薄板としての強
靭性が保持される。
[Action] 1 to 6 wt% cobalt in gold-silver-copper ternary alloy
and by adding 1 to 6 wt% of manganese or 1 to 4 wt% of nickel as an additive alloying element, the color tone of the ternary alloy is maintained and the toughness and hardness of the alloy are increased,
As a decorative gold alloy, it is resistant to scratches and maintains its toughness as a thin plate.

【0008】[0008]

【実施例】以下、本発明に係る典型的な装飾用金合金に
ついて詳細に説明する。本発明に係る第1の装飾用金合
金は金75wt%、銀5〜8wt%、銅7〜1 2wt
%と、コバルト1〜6wt%、マンガン1〜6wt%の
範囲で添加されてなる合金である。
EXAMPLES A typical decorative gold alloy according to the present invention will be explained in detail below. The first decorative gold alloy according to the present invention has 75 wt% gold, 5 to 8 wt% silver, and 7 to 12 wt% copper.
%, cobalt in the range of 1 to 6 wt%, and manganese in the range of 1 to 6 wt%.

【0009】この実施例の装飾用金合金は、時効々果理
論にもとづいて析出基材としてコバルト、マンガンを用
い、時効処理により300Hv の高硬度材を得る。更
に、得られた金合金に熱処理を施すことによって硬度並
びに弾性の改良をする。
The decorative gold alloy of this example uses cobalt and manganese as precipitation base materials based on the aging theory, and is aged to obtain a material with a high hardness of 300 Hv. Furthermore, the obtained gold alloy is heat treated to improve its hardness and elasticity.

【0010】この実施例で、金75wt%、銀5〜8w
t%、銅7〜12wt%、コバルト1〜6wt%、マン
ガン1〜6wt%の配合率のいずれでも18K金合金に
近い色調を有しながら高硬度且つ高弾性の金合金を得る
ことができるが、金75wt%、6〜8wt%、銅10
〜12wt%、コバルト1〜6wt%、マンガン1〜6
wt%の比率が色調の点からより好ましい金合金となる
ことが認められる。
[0010] In this example, gold 75wt%, silver 5~8w
It is possible to obtain a gold alloy with high hardness and high elasticity while having a color tone close to that of an 18K gold alloy at any blending ratio of 7 to 12 wt% copper, 1 to 6 wt% cobalt, and 1 to 6 wt% manganese. , gold 75wt%, 6-8wt%, copper 10
~12wt%, cobalt 1-6wt%, manganese 1-6
It is recognized that the ratio of wt% results in a more preferable gold alloy from the viewpoint of color tone.

【0011】次いで典型的な実施例と、硬度との関係を
明らかにする。 実施例1 金75wt%、銀8wt%、銅10wt%、コバルト1
.4 wt%、マンガン5.6 wt%からなる金合金
を得た。こゝで得られた金合金は300Hv の硬度を
有し高い靭性を有していた。 又、得られた金合金は18K金合金に近い赤味のある色
調を有し、この18K金合金と比較しても何等の遜色が
無かった。
Next, typical examples and their relationship with hardness will be explained. Example 1 Gold 75wt%, silver 8wt%, copper 10wt%, cobalt 1
.. A gold alloy containing 4 wt% of manganese and 5.6 wt% of manganese was obtained. The gold alloy thus obtained had a hardness of 300 Hv and high toughness. Further, the obtained gold alloy had a reddish color tone similar to that of 18K gold alloy, and was not inferior in any way when compared with this 18K gold alloy.

【0012】実施例2 金75wt%、銀8wt%、銅10wt%、コバルト3
.5 wt%、マンガン3.5 wt%からなる金合金
を得た。こゝで得られた金合金は靭性が稍々少ないもの
ゝ300Hv の硬度を有し、18K金合金に近い色調
を有しており実用に充分に用いることができた。
Example 2 Gold 75wt%, silver 8wt%, copper 10wt%, cobalt 3
.. A gold alloy containing 5 wt% of manganese and 3.5 wt% of manganese was obtained. The gold alloy thus obtained had a hardness of 300 Hv, although its toughness was somewhat low, and had a color tone close to that of 18K gold alloy, so it could be used satisfactorily for practical use.

【0013】実施例3 金75wt%、銀8wt%、銅10wt%、コバルト5
.6 wt%、マンガン1.4 wt%からなる金合金
を得た。こゝで得られた金合金は靭性が稍々少ないもの
ゝ300Hv の硬度を有し、18K金合金と似た色調
を有しており実用に充分用いることができた。。
Example 3 Gold 75wt%, silver 8wt%, copper 10wt%, cobalt 5
.. A gold alloy containing 6 wt% of manganese and 1.4 wt% of manganese was obtained. The gold alloy thus obtained had a hardness of 300 Hv, although its toughness was somewhat low, and had a color tone similar to that of an 18K gold alloy, so it could be used satisfactorily for practical use. .

【0014】比較例1 金75wt%、銀12.5wt%、銅12.5wt%の
三元合金の鋳放し硬度は140Hv 、加工硬度は18
0 〜200Hv であり、硬度及び靭性に難があった
Comparative Example 1 The as-cast hardness of a ternary alloy of 75 wt% gold, 12.5 wt% silver, and 12.5 wt% copper was 140 Hv, and the working hardness was 18
0 to 200 Hv, and the hardness and toughness were poor.

【0015】比較例2 金75wt%、銀8wt%、銅12wt%、コバルト4
.5 wt%、マンガン0.5 wt%からなる金合金
を得た。こゝで得られた金合金は色調も良く充分な硬度
を有するものゝ、得られた合金の靭性が少なく、装飾用
金合金に適していなかった。
Comparative Example 2 Gold 75wt%, silver 8wt%, copper 12wt%, cobalt 4
.. A gold alloy containing 5 wt% of manganese and 0.5 wt% of manganese was obtained. Although the gold alloy obtained here had good color and sufficient hardness, the obtained alloy had low toughness and was not suitable as a decorative gold alloy.

【0016】比較例3 金75wt%、銀8wt%、銅8wt%、コバルト0.
5 wt%、マンガン8.5 wt%からなる金合金を
得た。こゝで得られた金合金は充分な硬度と靭性とを有
するものゝ、色調に難があり、18K金合金特有の色調
を有していなかった。
Comparative Example 3 Gold: 75 wt%, silver: 8 wt%, copper: 8 wt%, cobalt: 0.
A gold alloy containing 5 wt% of manganese and 8.5 wt% of manganese was obtained. Although the gold alloy thus obtained had sufficient hardness and toughness, it had poor color tone and did not have the color tone characteristic of 18K gold alloy.

【0017】比較例4 金75wt%、銀8wt%、銅12wt%、コバルト0
.5 wt%、マンガン4.5 wt%からなる金合金
を得た。こゝで得られた金合金は強い赤味を呈し、18
K金合金に近い色調を示したが装飾材として要請される
充分な硬さを有していなかった。
Comparative Example 4 Gold 75wt%, silver 8wt%, copper 12wt%, cobalt 0
.. A gold alloy containing 5 wt% of manganese and 4.5 wt% of manganese was obtained. The gold alloy obtained here has a strong reddish color and is 18
Although it exhibited a color tone similar to K gold alloy, it did not have sufficient hardness required as a decorative material.

【0018】以上の実施例と比較例とから、金75wt
%、銀5〜8wt%、銅7〜12wt%に対しコバルト
1〜6wt%、マンガン1〜6wt%添加して金合金を
得ることが望ましく、マンガンの添加量の少ない場合、
得られる金合金の靭性に難があり、又コバルトの添加量
の少ない場合、得られる金合金に充分な硬さがもたらさ
れない不都合が認められる。又、マンガンとコバルトと
の添加量が6wt%以上である場合、得られた金合金の
加工性と色調に難を生ずることが認められる。
From the above examples and comparative examples, it is clear that 75wt of gold
It is desirable to obtain a gold alloy by adding 1 to 6 wt% of cobalt and 1 to 6 wt% of manganese to 5 to 8 wt% of silver and 7 to 12 wt% of copper, and when the amount of manganese added is small,
The toughness of the obtained gold alloy is poor, and when the amount of cobalt added is small, there are disadvantages in that the obtained gold alloy does not have sufficient hardness. Moreover, when the amount of manganese and cobalt added is 6 wt% or more, it is recognized that the processability and color tone of the obtained gold alloy are impaired.

【0019】かゝる点から金75wt%、銀5〜8wt
%、銅7〜12wt%に、マンガンを1〜6wt%の範
囲で添加して金合金を得るのが望ましい。
[0019] From this point, gold is 75 wt% and silver is 5 to 8 wt%.
%, it is desirable to obtain a gold alloy by adding manganese in the range of 1 to 6 wt% to 7 to 12 wt% of copper.

【0020】次いで第2の装飾用金合金について説明す
る。この第2の装飾用金合金は、金75wt%、銀5〜
8wt%、銅7〜12wt%、コバルト1〜6wt%、
ニッケル1〜4wt%からなるものである
Next, the second decorative gold alloy will be explained. This second decorative gold alloy contains 75 wt% gold and 5 to 5 wt% silver.
8wt%, copper 7-12wt%, cobalt 1-6wt%,
It consists of 1 to 4 wt% nickel.

【0021】このコバルトとニッケルとを合金の添加元
素とする金合金は、先のコバルトとマンガンとを合金の
添加元素とする金合金に比較して更に高い硬度と靭性と
を有する反面、色調が稍々白っぽい傾向を示している。 特にコバルト、ニッケルの添加量を増した場合に、かゝ
る色調特性が顕著に生ずることから、コバルトは6wt
%未満、ニッケルは4wt%未満に添加量を抑制する必
要がある。
This gold alloy containing cobalt and nickel as additive elements has higher hardness and toughness than the gold alloy containing cobalt and manganese as additive elements, but has a poor color tone. It shows a slightly whitish tendency. In particular, when the amount of cobalt and nickel added is increased, such color tone characteristics are noticeable, so cobalt is 6wt.
%, and the amount of nickel added needs to be suppressed to less than 4 wt%.

【0022】実施例4 金75wt%、銀8wt%、銅11wt%、コバルト5
wt%、ニッケル1wt%からなる金合金を得た。こゝ
で得られた金合金は327.4Hv の硬度を有し、や
ゝ白味を帯びた18K金合金の色調を有していた。
Example 4 Gold 75wt%, silver 8wt%, copper 11wt%, cobalt 5
A gold alloy containing 1 wt% of nickel and 1 wt% of nickel was obtained. The gold alloy thus obtained had a hardness of 327.4 Hv and a slightly whitish color of 18K gold alloy.

【0023】実施例5 金75wt%、銀8wt%、銅10.2wt%、コバル
ト6wt%、ニッケル1wt%からなる金合金を得た。 こゝで得られた金合金は314Hv の硬度を有し、白
基調ながら18K金合金特有の色調を有していた。
Example 5 A gold alloy consisting of 75 wt% gold, 8 wt% silver, 10.2 wt% copper, 6 wt% cobalt, and 1 wt% nickel was obtained. The gold alloy thus obtained had a hardness of 314 Hv, and although it was white in color, it had a color characteristic of 18K gold alloy.

【0024】実施例6 金75wt%、銀7wt%、銅11.2wt%、コバル
ト6wt%、ニッケル1wt%からなる金合金を得た。 こゝで得られた金合金は314Hv の硬度を有し、僅
かに白味を帯びた18K金合金特有の色調を有していた
Example 6 A gold alloy consisting of 75 wt% gold, 7 wt% silver, 11.2 wt% copper, 6 wt% cobalt, and 1 wt% nickel was obtained. The gold alloy thus obtained had a hardness of 314 Hv and a slightly whitish color characteristic of 18K gold alloy.

【0025】実施例7 金75wt%、銀5wt%、銅12wt%、コバルト4
wt%、ニッケル4wt%からなる金合金を得た。こゝ
で得られた金合金は380Hv の硬度を有し、僅かに
白基調を残した18K金合金特有の色調を有していた。
Example 7 Gold 75wt%, silver 5wt%, copper 12wt%, cobalt 4
A gold alloy containing 4 wt% of nickel and 4 wt% of nickel was obtained. The gold alloy thus obtained had a hardness of 380 Hv and a color tone characteristic of 18K gold alloy with a slight white tone.

【0026】比較例5 金75wt%、銀7wt%、銅8wt%、コバルト5w
t%、ニッケル5wt%からなる金合金を得た。こゝで
得られた金合金は充分な硬さと靭性を有する反面、色調
が特に白く、18K金合金の趣きが全く見受けられず加
工性にも難があった。
Comparative Example 5 Gold 75wt%, silver 7wt%, copper 8wt%, cobalt 5w
A gold alloy containing 5 wt% of nickel and 5 wt% of nickel was obtained. Although the gold alloy thus obtained had sufficient hardness and toughness, it was particularly white in color, had no appearance of 18K gold alloy, and had difficulty in workability.

【0027】比較例6 金75wt%、銀8wt%、銅11.5wt%、コバル
ト5wt%、ニッケル0.5wt %からなる金合金を
得た。こゝで得られた金合金は18K金合金に近い色調
を有しているものゝ、硬度、靭性に難が認められた。
Comparative Example 6 A gold alloy consisting of 75 wt% gold, 8 wt% silver, 11.5 wt% copper, 5 wt% cobalt, and 0.5 wt% nickel was obtained. The gold alloy thus obtained had a color tone similar to that of 18K gold alloy, but it was found to have poor hardness and toughness.

【0028】[0028]

【発明の効果】本発明に係る金合金は18K金合金に対
しコバルト1〜6wt%とマンガン1〜6wt%とを添
加し、又はコバルト1〜6wt%とニッケル1〜4wt
%とを添加することで得られる高硬度、高弾性で、しか
も18K金合金に特有の色調を損うことのない装飾材向
きの金合金を提供できる特長を有している。即ち、金−
銀−銅の三元合金の有する色調を維持しながら、硬さと
弾性とを高め、スクラッチに強く、薄板として強靭性を
有する機能性の高い装飾用金合金となし得る特長を有し
ている。かゝる点から金合金による各種の止金具類の作
成並びに、スプリング材等の作成を可能とし、プレス材
、時計用材等として多方面に用い得る金合金とされる特
長を有している。
Effects of the Invention The gold alloy according to the present invention is made by adding 1 to 6 wt% of cobalt and 1 to 6 wt% of manganese to the 18K gold alloy, or adding 1 to 6 wt% of cobalt and 1 to 4 wt% of nickel.
%, it has the advantage of providing a gold alloy suitable for decorative materials that has high hardness and high elasticity and does not impair the color tone characteristic of 18K gold alloy. That is, gold-
While maintaining the color tone of the silver-copper ternary alloy, it has the characteristics of increasing hardness and elasticity, being resistant to scratches, and being tough as a thin plate, making it a highly functional decorative gold alloy. From this point of view, gold alloys can be used to make various types of fasteners, spring materials, etc., and have the characteristics of gold alloys that can be used in a variety of ways, such as press materials and watch materials.

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】  金75wt%、銀5〜8wt%、銅7
〜12wt%、コバルト1〜6wt%と、マンガン1〜
6wt%又はニッケル1〜4wt%の一種とよりなるこ
とを特徴とする装飾用金合金。
[Claim 1] Gold 75wt%, silver 5-8wt%, copper 7%
~12wt%, cobalt 1-6wt%, and manganese 1~
A decorative gold alloy comprising 6 wt% or 1 to 4 wt% of nickel.
JP16369991A 1991-06-07 1991-06-07 Gold alloy for ornamentation Pending JPH04362148A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16369991A JPH04362148A (en) 1991-06-07 1991-06-07 Gold alloy for ornamentation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16369991A JPH04362148A (en) 1991-06-07 1991-06-07 Gold alloy for ornamentation

Publications (1)

Publication Number Publication Date
JPH04362148A true JPH04362148A (en) 1992-12-15

Family

ID=15778936

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16369991A Pending JPH04362148A (en) 1991-06-07 1991-06-07 Gold alloy for ornamentation

Country Status (1)

Country Link
JP (1) JPH04362148A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001335861A (en) * 2000-05-26 2001-12-04 Tokuriki Honten Co Ltd Gold alloy for ornament
US6576187B2 (en) * 2000-10-06 2003-06-10 Cookson Metaux Precieux Sa 18 carat grey gold alloy, without nickel and without palladium, for jewellery
CN115109962A (en) * 2022-06-24 2022-09-27 有研工程技术研究院有限公司 Wear-resistant high-hardness gold-based alloy material for collector ring and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63259042A (en) * 1987-04-15 1988-10-26 Ijima Kingin Kogyo Kk Gold alloy having excellent abrasion resistance and toughness

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63259042A (en) * 1987-04-15 1988-10-26 Ijima Kingin Kogyo Kk Gold alloy having excellent abrasion resistance and toughness

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001335861A (en) * 2000-05-26 2001-12-04 Tokuriki Honten Co Ltd Gold alloy for ornament
US6576187B2 (en) * 2000-10-06 2003-06-10 Cookson Metaux Precieux Sa 18 carat grey gold alloy, without nickel and without palladium, for jewellery
CN115109962A (en) * 2022-06-24 2022-09-27 有研工程技术研究院有限公司 Wear-resistant high-hardness gold-based alloy material for collector ring and preparation method thereof
CN115109962B (en) * 2022-06-24 2023-10-13 有研工程技术研究院有限公司 Wear-resistant high-hardness gold-based alloy material for bus ring and preparation method thereof

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