JPH0437620A - Casting device for glass ceramics and its casting method - Google Patents
Casting device for glass ceramics and its casting methodInfo
- Publication number
- JPH0437620A JPH0437620A JP2140511A JP14051190A JPH0437620A JP H0437620 A JPH0437620 A JP H0437620A JP 2140511 A JP2140511 A JP 2140511A JP 14051190 A JP14051190 A JP 14051190A JP H0437620 A JPH0437620 A JP H0437620A
- Authority
- JP
- Japan
- Prior art keywords
- casting
- temperature
- crucible
- casting material
- platinum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005266 casting Methods 0.000 title claims abstract description 104
- 239000002241 glass-ceramic Substances 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims description 19
- 239000000463 material Substances 0.000 claims abstract description 61
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 59
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 30
- 238000010438 heat treatment Methods 0.000 claims description 32
- 238000009750 centrifugal casting Methods 0.000 claims description 6
- 238000002844 melting Methods 0.000 abstract description 5
- 230000008018 melting Effects 0.000 abstract description 5
- 239000013078 crystal Substances 0.000 abstract description 3
- 230000003247 decreasing effect Effects 0.000 abstract 2
- 238000003466 welding Methods 0.000 abstract 1
- 238000010586 diagram Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000007769 metal material Substances 0.000 description 3
- 238000001514 detection method Methods 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
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- Dental Prosthetics (AREA)
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野]
本発明は、ガラスセラミックなどを鋳造材料として用い
る高周波遠心鋳造装置とその鋳造方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a high-frequency centrifugal casting apparatus and a casting method thereof using glass ceramic or the like as a casting material.
(従来の技術〕
一般に、金、白金などの金属材料を加熱コイルの軸線上
に配設されたルツボ内に収納して誘導電流を利用して熔
解し、その溶融した金属を遠心力を利用して鋳型に注湯
して鋳造する高周波遠心鋳造装置に関する文献として、
例えば実公昭56−26728号公報がある。(Prior art) In general, metal materials such as gold and platinum are stored in a crucible placed on the axis of a heating coil and melted using induced current, and the molten metal is then melted using centrifugal force. As a literature on high frequency centrifugal casting equipment that pours metal into a mold and casts,
For example, there is Japanese Utility Model Publication No. 56-26728.
この公報に開示されている技術は、鋳造材料を所定温度
まで加熱し、その温度をこのあと一定時間保持したのち
遠心鋳造するという方法である。The technique disclosed in this publication is a method of heating a casting material to a predetermined temperature, maintaining that temperature for a certain period of time, and then performing centrifugal casting.
上記方法による装置は、装置が回転操作される支持棒に
バランス重りと釣り合うように装着されたルツボおよび
型材と、ルツボ内の金属材料を加熱コイルで溶融する高
周波加熱回路と、上記ルツボ内の溶融金属温度を検出す
る検出手段とを設けて検出値に応じて上記加熱コイルと
高周波加熱回路を一定時間オン・オフ制御するタイマー
回路を有する温度制御部から構成されているものである
。The apparatus according to the above method includes a crucible and a mold material mounted on a support rod on which the apparatus is rotated so as to be balanced with a balance weight, a high-frequency heating circuit for melting the metal material in the crucible with a heating coil, and a high-frequency heating circuit for melting the metal material in the crucible using a heating coil. The temperature control section includes a detection means for detecting metal temperature, and a timer circuit for controlling the heating coil and the high-frequency heating circuit on and off for a certain period of time according to the detected value.
従って、上記構成であるから溶融後の溶融金属は、一定
時間所定温度に保持されているので溶融金属の過熱を防
止すると共に、充分攪拌された良質の鋳造材料があたえ
られるというものである。Therefore, with the above structure, the molten metal after melting is maintained at a predetermined temperature for a certain period of time, which prevents overheating of the molten metal and provides a sufficiently stirred, high-quality casting material.
上記した公報の技術においては、その所定温度が低く設
定されると鋳造材料の粒子が充分溶融されずに得られた
鋳造物の結晶状態が不均一であったり、鋳造を繰り返す
うちにルツボの注ぎ口にその材料が固着し注湯がスムー
ズに注がれないという問題点があり、また所定温度が高
く設定されるとその鋳造材料が型材と反応し融合するな
どの問題があった。In the technique disclosed in the above-mentioned publication, if the predetermined temperature is set low, the particles of the casting material may not be sufficiently melted, resulting in uneven crystallization of the resulting casting, or the crucible may become unstable during repeated castings. There was a problem in that the material stuck to the spout and the pouring material could not be poured smoothly, and if the predetermined temperature was set high, the casting material reacted with the mold material and fused.
本発明は、上記問題点に鑑みてなされたもので、鋳造材
料が完全に溶融され、得られた鋳造物の結晶状態が均一
になり、更に鋳造を繰り返すうちに、ルツボの注ぎ口に
その材料が固着するというようなことの無い鋳造温度よ
り高い温度まで加熱し、一定時間保持するようにし、更
には鋳造材料が鋳型と反応し融合しないように高温状態
から所定の鋳造温度まで下降させ、ルツボに接続された
熱電対の出力値を検出し高周波加熱回路を一定時間PI
DIIIIIする温度制御部により行うガラスセラミッ
クなどの鋳造装置とその鋳造方法とを提供することを目
的とするものである。The present invention was made in view of the above-mentioned problems.The casting material is completely melted, the crystalline state of the obtained casting is made uniform, and as the casting is repeated, the material is poured into the spout of the crucible. The crucible is heated to a temperature higher than the casting temperature at which the material will not stick and held for a certain period of time, and then lowered from the high temperature state to the specified casting temperature to prevent the casting material from reacting with the mold and fusing. Detects the output value of the thermocouple connected to the high frequency heating circuit for a certain period of time.
It is an object of the present invention to provide an apparatus for casting glass ceramics, etc., and a method for casting the same, using a temperature control section that performs DIII.
本発明は、ガラスセラミックなどの鋳造材料を収納して
加熱する白金系熱電対を接続した白金系ルツボを設けた
ルツボユニットと、上記白金系ルツボ内の鋳造材料を加
熱する加熱コイルを設けた高周波加熱手段と、上記ルツ
ボユニットに設けた上記加熱コイルへの移送と上記加熱
溶融した鋳造材料を鋳型に注湯とを行う駆動手段と、上
記鋳型に注湯した鋳造材料を遠心回転にて鋳造する遠心
駆動手段と、上記白金系ルツボ内の鋳造材料の温度の検
出と温度調節と設定温度切換などを制御する温度制御部
とを具備したガラスセラミックなどの鋳造装置である。The present invention provides a crucible unit equipped with a platinum-based crucible connected to a platinum-based thermocouple that houses and heats a casting material such as glass ceramic, and a high-frequency unit equipped with a heating coil that heats the casting material in the platinum-based crucible. a heating means, a driving means for transferring the melt to the heating coil provided in the crucible unit and pouring the heated and melted casting material into a mold, and casting the casting material poured into the mold by centrifugal rotation. This is a casting apparatus for glass ceramics, etc., which is equipped with a centrifugal drive means, and a temperature control unit that controls temperature detection, temperature adjustment, and setting temperature switching of the casting material in the platinum-based crucible.
[作 用]
上g己構成による鋳造方法(作用)は、まず白金名ルツ
ボ内の鋳造材料を所定の鋳造温度より高い温度まで加熱
する加熱工程と、この高温度を所定時間保持する高温保
持工程と、この高温度より所定の鋳造温度まで下降する
下降温度工程と、上記鋳造温度にて鋳造材料を鋳型にて
注湯し遠心回転にて鋳造する遠心工程とよりなるガラス
セラミ。[Function] The casting method (action) using the above-mentioned structure consists of a heating process in which the casting material in the platinum crucible is heated to a temperature higher than the predetermined casting temperature, and a high-temperature holding process in which this high temperature is maintained for a predetermined time. A glass-ceramic glass ceramic comprising: a lowering temperature step in which the temperature is lowered from this high temperature to a predetermined casting temperature; and a centrifugal step in which the casting material is poured into a mold at the above casting temperature and cast by centrifugal rotation.
りなどの鋳造方法である。This is a casting method such as casting.
(実 施 例〕 本発明を実施例に基づいて説明する。(Example〕 The present invention will be explained based on examples.
図面中において、各実施例の共通構成および共通機構に
ついては、最初の実施例にその説明を行い後の実施例に
おいては省略する。In the drawings, common configurations and common mechanisms of each embodiment will be explained in the first embodiment and will be omitted in subsequent embodiments.
(第1実施例)
第1図は、本発明に係わるガラスセラミンクの鋳造装置
の概要を示す概略図である。(First Embodiment) FIG. 1 is a schematic diagram showing an outline of a glass-ceramink casting apparatus according to the present invention.
第2図は、第1図に示す温度制御部の構成を示すブロッ
ク図である。FIG. 2 is a block diagram showing the configuration of the temperature control section shown in FIG. 1.
第3図は、本発明に係わるガラスセラミックなどの鋳造
方法の第1実施例における温度制御プロファイルを示す
グラフ図である。FIG. 3 is a graph diagram showing a temperature control profile in the first embodiment of the method for casting glass-ceramics, etc. according to the present invention.
第1図に示す符号1は、ガラスセラミックなどの鋳造材
料を加熱熔融するための白金系熱電対7を接続した白金
系ルツボである。この白金系ルツボ1にはカバー、断熱
部材なと′により構成されたルツボユニット3と、この
ルツボユニット3には鋳造材料を加熱熔融する高周波加
熱回路6に設けた加熱コイル2内に搬入出移動と、加熱
溶融した鋳造材料を鋳型11に注湯作動とを行うルツボ
ユニ7)駆動部4とが連設されている。上記加熱コイル
2により加熱された鋳造材料を置場収納した鋳型11お
よび鋳型11と釣り合うように天秤状に装着されたバラ
ンサ12とを遠心回転にて鋳造する遠心駆動部5が設け
られている。Reference numeral 1 shown in FIG. 1 is a platinum-based crucible to which a platinum-based thermocouple 7 is connected for heating and melting a casting material such as glass ceramic. This platinum-based crucible 1 has a crucible unit 3 composed of a cover and a heat insulating member, and this crucible unit 3 is moved in and out of a heating coil 2 provided in a high frequency heating circuit 6 that heats and melts the casting material. and a crucible unit 7) drive unit 4 that performs an operation of pouring heated and melted casting material into the mold 11. A centrifugal drive unit 5 is provided which casts by centrifugal rotation a mold 11 storing the casting material heated by the heating coil 2 and a balancer 12 mounted in a scale shape to balance the mold 11.
また、上記白金系ルツボ1内の鋳造材料の温度を白金系
熱電対7の出力で検出し、その温度を2段階にPIDI
!It御できる温度調整器8と、設定された温度を切換
る切換回路9とを有する温度制御部10が構成されてい
る。In addition, the temperature of the casting material in the platinum crucible 1 is detected by the output of the platinum thermocouple 7, and the temperature is divided into two stages by PIDI.
! A temperature control unit 10 is configured, which includes a temperature regulator 8 that can control the temperature, and a switching circuit 9 that switches the set temperature.
上記構成の本実施例の製造工程を説明する。The manufacturing process of this embodiment having the above configuration will be explained.
まず、白金系ルツボ1内にガラスセラミックなどの鋳造
材料を入れる。続いて鋳造材料を収納した白金系ルツボ
1をルツボユニット駆動部4の駆動にて高周波加熱回路
6に設けた加熱コイル2内に挿入し所定の高温度まで加
熱される。この場合の高い温度とは第3図に示すように
例えば、1450’C(A)と鋳造温度より高い温度ま
で加熱される。この高温を鋳造材料を完全に溶融するた
めに、所定時間(例えば1分間)保持される。上記高温
度保持時間を絆ねった白金系ルツボ1内の鋳造材料は、
鋳造材料と白金系ルツボ1とが融合するのを防ぐために
鋳造温度まで下降される。この場合の鋳造温度とは第3
図に示すように例えば、1250’C(B)に下げられ
る。所定の鋳造温度に下降された白金系ルツボl内の鋳
造材料は、ルツボユニット駆動部4の駆動により、鋳型
11内に注湯される。First, a casting material such as glass ceramic is placed in a platinum-based crucible 1. Subsequently, the platinum-based crucible 1 containing the casting material is inserted into the heating coil 2 provided in the high-frequency heating circuit 6 by the drive of the crucible unit drive section 4, and is heated to a predetermined high temperature. The high temperature in this case is, for example, 1450'C (A), which is higher than the casting temperature, as shown in FIG. This high temperature is maintained for a predetermined time (for example, 1 minute) to completely melt the casting material. The cast material in the platinum-based crucible 1 that has been kept at the high temperature for the above-mentioned time is
The temperature is lowered to the casting temperature to prevent the casting material and the platinum-based crucible 1 from fusing. The casting temperature in this case is the third
For example, as shown in the figure, it is lowered to 1250'C (B). The casting material in the platinum-based crucible 1, which has been lowered to a predetermined casting temperature, is poured into the mold 11 by driving the crucible unit driving section 4.
鋳造材料を注湯された鋳型11は、バランサ12と天秤
的に釣り合うように遠心駆動部5に装着されて遠心回転
にて鋳造される。The mold 11 into which the casting material has been poured is mounted on the centrifugal drive unit 5 so as to be balanced with the balancer 12, and cast by centrifugal rotation.
上記において、高温加熱と、鋳造温度および高温保持時
間は、温度制御部10により制御される。In the above, the high temperature heating, casting temperature, and high temperature holding time are controlled by the temperature control section 10.
また上記温度設定と保持時間の設定は、鋳造される材料
によって所望の温度および時間に切り換え、または変更
される。Further, the temperature setting and holding time setting described above are switched or changed to a desired temperature and time depending on the material to be cast.
上記構成の装置と、製造方法とによる本実施例によれば
、鋳造材料を完全に加熱溶融でき、また鋳造材料と白金
系ルツボ1とは融合することがないので品質のよい高周
波遠心鋳造ができる。According to this embodiment using the apparatus and manufacturing method having the above configuration, the casting material can be completely heated and melted, and the casting material and the platinum crucible 1 do not fuse, so high-frequency centrifugal casting with high quality can be performed. .
(第2実施例)
本実施例の鋳造装置の構成は、上記第1実施例と同一に
つき省略する。従って、その鋳造方法についてのみ説明
する。(Second Embodiment) The configuration of the casting apparatus of this embodiment is the same as that of the first embodiment, so a description thereof will be omitted. Therefore, only the casting method will be described.
第4図は、本発明に係わるガラスセラミックなどの鋳造
方法の第2実施例における温度制御プロファイルを示す
グラフ図である。FIG. 4 is a graph diagram showing a temperature control profile in a second embodiment of the method for casting glass-ceramics, etc. according to the present invention.
まず白金系ルツボl内にガラスセラミックなどの鋳造材
料を入れる。続いて鋳造材料を収納した白金系ルツボ1
をルツボユニット駆動部4の駆動にて高周波加熱回路6
に設けた加熱コイル2内に挿入し所定の高温度まで加熱
される。この場合の高温度とは、第4に示すように例え
ば1450°C(A)と予め設定された鋳造温度より高
い温度まで加熱される。この高温度に加熱された鋳造部
材を完全に熔融するために1分間保持される。First, a casting material such as glass ceramic is placed in a platinum-based crucible l. Next, platinum crucible 1 containing casting materials
The high frequency heating circuit 6 is driven by the crucible unit drive unit 4.
The device is inserted into a heating coil 2 installed in a heating coil 2 and heated to a predetermined high temperature. The high temperature in this case means heating to a temperature higher than the preset casting temperature, for example, 1450° C. (A), as shown in the fourth section. The cast member heated to this high temperature is held for 1 minute to completely melt it.
上記高温度の保持時間を終わった白金系ルツボ1内の鋳
造材料は、鋳造材料と白金系ルツボ1とが融合するを防
くため第4図に示すように鋳造温度まで下降される。こ
の場合の鋳造温度とは、例えば1250°C(B)に下
げられる。更に、この鋳造温度に下降された白金ルツボ
1内の鋳造材料は、予め設定された1分間同一温度にて
保持される。After the high-temperature holding time, the casting material in the platinum-based crucible 1 is lowered to the casting temperature as shown in FIG. 4 in order to prevent the casting material and the platinum-based crucible 1 from fusing. The casting temperature in this case is lowered to, for example, 1250°C (B). Furthermore, the casting material in the platinum crucible 1 that has been lowered to this casting temperature is held at the same temperature for a preset one minute.
上記温度時間を終わった白金系ルツボ1内の鋳造材料は
、ルツボユニット駆動部4の駆動により鋳型11内に注
湯される。The casting material in the platinum-based crucible 1 after the above-mentioned temperature period is poured into the mold 11 by driving the crucible unit driving section 4 .
鋳造材料を注湯された鋳型11は、バランサ12と天秤
的に釣り合うように遠心駆動部5に装着されて遠心回転
に鋳造される。The mold 11 into which the casting material has been poured is mounted on the centrifugal drive unit 5 so as to be balanced with the balancer 12, and centrifugally rotated for casting.
上記においても上記第1実施例と同様に高温加熱と鋳造
温度および高温度保持時間と鋳造温度保持時間は、温度
制御部10により制御される。また上記温度設定と温度
保持時間の設定は、鋳造される鋳造材料によって所望の
温度および時間に可変される。In the above case as well, the high temperature heating, the casting temperature, the high temperature holding time, and the casting temperature holding time are controlled by the temperature control section 10, as in the first embodiment. Furthermore, the temperature settings and temperature holding time settings can be varied to desired temperatures and times depending on the casting material to be cast.
上記構成の装置と製造方法とによる本実施例によれば、
鋳造条件が良好でt源変動や外乱に対しても安定した高
周波遠心鋳造ができる。According to this embodiment using the apparatus and manufacturing method having the above configuration,
High-frequency centrifugal casting is possible under good casting conditions and stable against source fluctuations and disturbances.
上記構成と方法により本発明によれば、鋳造材料が高温
で充分に熔融されるので結晶状態が均一になり、更にル
ツボから鋳型に注湯する際に、注ぎ口に材料が固まり付
くことのない、また高い温度に加熱し、かつ一定時間保
持する工程を設けたことにより鋳造材料を完全に熔融さ
せるので良質な鋳造ができる。また高温状態から鋳造温
度まで下降することにより鋳造材料とルツボとが融合す
ることが防げるなどの効果を奏する。According to the present invention, with the above structure and method, the casting material is sufficiently melted at high temperature, so that the crystal state becomes uniform, and furthermore, when pouring from the crucible into the mold, the material does not solidify at the pouring spout. In addition, by providing a step of heating to a high temperature and holding it for a certain period of time, the casting material is completely melted, resulting in high-quality casting. Further, by lowering the temperature from the high temperature state to the casting temperature, it is possible to prevent the casting material and the crucible from fusing.
第1図は、本発明に係わるガラスセラミックなどの鋳造
装置の概要を示す概念図。
第2図は、第1図に示す温度制御部の構成を示すブロッ
ク図。
第3図は、本発明に係わるガラスセラミックなどの鋳造
方法の第1実施例における温度制御プロファイルを示す
グラフ図。
第4図は、本発明に係わるガラスセラミックなどの鋳造
方法の第2実施例における温度制御プロファイルを示す
グラフ図。
第5図は、従来の高周波遠心装置における温度制御のプ
ロファイルを示すグラフ図。
2・・・加熱コイル
3・・・ルツボユニット
4・・・ルツボユニット駆動部
5・・・遠心駆動部
6・・・高周波加熱回路
7・・・白金系熱電対
8・・・温度調節器
9・・・設定温度切換回路
10・・・温度制御部
11・・・鋳型
12・・・バランサFIG. 1 is a conceptual diagram showing an overview of a casting apparatus for glass ceramics, etc., according to the present invention. FIG. 2 is a block diagram showing the configuration of the temperature control section shown in FIG. 1. FIG. 3 is a graph diagram showing a temperature control profile in the first embodiment of the method for casting glass-ceramics, etc. according to the present invention. FIG. 4 is a graph diagram showing a temperature control profile in a second embodiment of the method for casting glass-ceramics, etc. according to the present invention. FIG. 5 is a graph diagram showing a temperature control profile in a conventional high-frequency centrifugal device. 2... Heating coil 3... Crucible unit 4... Crucible unit drive section 5... Centrifugal drive section 6... High frequency heating circuit 7... Platinum thermocouple 8... Temperature controller 9 ... Set temperature switching circuit 10 ... Temperature control section 11 ... Mold 12 ... Balancer
Claims (2)
する白金系熱電対を接続した白金系ルツボを設けたルツ
ボユニットと、上記白金系ルツボ内の鋳造材料を加熱す
る加熱コイルを設けた高周波加熱手段と、上記ルツボユ
ニットに設けられ、上記加熱コイルへの移送と上記加熱
溶融した鋳造材料を鋳型に注湯とを行う駆動手段と、上
記鋳型に注湯した鋳造材料を遠心回転にて鋳造する遠心
駆動手段と、上記白金系ルツボ内の鋳造材料の温度の検
出と、温度調節と設定温度切換などを制御する温度制御
部とを具備したことを特徴とするガラスセラミックなど
の鋳造装置。(1) A crucible unit equipped with a platinum-based crucible connected to a platinum-based thermocouple that houses and heats a casting material such as glass ceramic, and a high-frequency heating system equipped with a heating coil that heats the casting material inside the platinum-based crucible. means, a driving means provided in the crucible unit for transferring the heated and melted casting material to the heating coil and pouring the heated and melted casting material into the mold, and casting the casting material poured into the mold by centrifugal rotation. 1. A casting apparatus for glass-ceramics, etc., comprising a centrifugal drive means, a temperature control unit that detects the temperature of the casting material in the platinum-based crucible, and controls temperature adjustment, setting temperature switching, etc.
高い温度まで加熱する加熱工程と、この高温度を所定時
間保持する高温保持工程と、この高温度より所定の鋳造
温度まで下降する下降温度工程と、上記鋳造温度にて鋳
造材料を鋳型に注湯し、遠心回転にて鋳造する遠心鋳造
工程とよりなることを特徴とするガラスセラミックなど
の鋳造方法。(2) A heating process in which the casting material in the platinum-based crucible is heated to a temperature higher than the predetermined casting temperature, a high-temperature holding process in which this high temperature is maintained for a predetermined time, and a descending process in which the high temperature is lowered to the predetermined casting temperature. A method for casting glass ceramics, etc., comprising a temperature step and a centrifugal casting step in which a casting material is poured into a mold at the above-mentioned casting temperature and cast by centrifugal rotation.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2140511A JPH0437620A (en) | 1990-05-30 | 1990-05-30 | Casting device for glass ceramics and its casting method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2140511A JPH0437620A (en) | 1990-05-30 | 1990-05-30 | Casting device for glass ceramics and its casting method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0437620A true JPH0437620A (en) | 1992-02-07 |
Family
ID=15270350
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2140511A Pending JPH0437620A (en) | 1990-05-30 | 1990-05-30 | Casting device for glass ceramics and its casting method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0437620A (en) |
-
1990
- 1990-05-30 JP JP2140511A patent/JPH0437620A/en active Pending
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