JPH0441586A - Increase and control of heat recovery in coke dry quenching facility - Google Patents

Increase and control of heat recovery in coke dry quenching facility

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Publication number
JPH0441586A
JPH0441586A JP14739090A JP14739090A JPH0441586A JP H0441586 A JPH0441586 A JP H0441586A JP 14739090 A JP14739090 A JP 14739090A JP 14739090 A JP14739090 A JP 14739090A JP H0441586 A JPH0441586 A JP H0441586A
Authority
JP
Japan
Prior art keywords
prechamber
amount
gas
combustible gas
coke dry
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP14739090A
Other languages
Japanese (ja)
Inventor
Koichi Nagasaki
長崎 幸一
Hideyuki Saito
英之 斉藤
Hiroyuki Iida
洋行 飯田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Nippon Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Corp filed Critical Nippon Steel Corp
Priority to JP14739090A priority Critical patent/JPH0441586A/en
Publication of JPH0441586A publication Critical patent/JPH0441586A/en
Pending legal-status Critical Current

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  • Coke Industry (AREA)

Abstract

PURPOSE:To keep the amt. of steam generation of a coke dry quenching facility at the highest level within a set range by controlling the pressure in a prechamber. CONSTITUTION:When recovered heat capacity is increased by burning flammable gas in a cycling gas 7 in a coke dry quenching facility, the amt. of flammable gas formation based on the intaken gas (through a pumping pipe 17) into a prechamber 3 or the amt. of discharge of the flammable gas (through the pumping pipe 17) from the prechamber 3 is controlled and adjusted by controlling 12 the pressure 10 in the prechamber 3 within a specified range based on the analytical values of the cycling gas ingredients (measured with an ingredient measuring instrument 14).

Description

【発明の詳細な説明】 産業上の利用分野 本発明はコークス乾式消火設備における回収熱量増量制
御方法、具体的には蒸気発生量を設定範囲内で最高レベ
ルに維持するために、プレチャンバ−内で可燃ガスを生
成あるいは放散制御する方法に関する。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for controlling the increase in the amount of recovered heat in coke dry extinguishing equipment, specifically, to maintain the amount of steam generated at the highest level within a set range. This invention relates to a method for generating or controlling the release of combustible gas.

従来の技術 ]−クス乾式消火設備において、装入された赤熱コーク
スより不可避的に発生する可燃ガスの自動制御方法につ
いては、空気導入による可燃ガス燃焼、窒素吹き込みに
よる希釈、循環ガスの放散等による方法が知られている
(特開昭53−5201号、特開昭54−10302号
、特開昭58−1591号)。
[Prior art] - Automatic control methods for combustible gas inevitably generated from charged red-hot coke in coke dry fire extinguishing equipment include combustion of combustible gas by introducing air, dilution by blowing nitrogen, and dissipation of circulating gas. Methods are known (JP-A-53-5201, JP-A-54-10302, JP-A-58-1591).

これらの可燃ガス成分の自動制御は系内での爆発防止、
高価な窒素ガス使用量低減等を目的とした可燃ガス成分
低下にもとづく制御法である。
Automatic control of these combustible gas components prevents explosions within the system.
This is a control method based on reducing combustible gas components with the aim of reducing the amount of expensive nitrogen gas used.

また、赤熱コークスより可燃ガスを得る方法としては、
チャン/へ一部への空気、水の吹き込み装置が開示され
ている(特開昭52−85203号、特公平1−283
98号)。
In addition, as a method of obtaining flammable gas from red-hot coke,
A device for blowing air and water into a part of a chamber/tube is disclosed (Japanese Unexamined Patent Publication No. 52-85203, Japanese Patent Publication No. 1-283).
No. 98).

しかしながら、上記方法は、既存のコークス乾式消火設
備に新たに設備を設置する必要がある。
However, the above method requires new equipment to be installed in the existing coke dry extinguishing equipment.

発明が解決しようとする課題 本発明は、プレチャンバ−内圧力を制御することにより
、新規設備を設置することなく、コークス乾式消火設備
の蒸気発生量を設定範囲内で最高レベルに維持しながら
循環ガス中の可燃ガス濃度を一定範囲に維持しようとす
るものである。
Problems to be Solved by the Invention The present invention enables circulation while maintaining the amount of steam generated in coke dry extinguishing equipment at the highest level within a set range, without installing new equipment, by controlling the pressure inside the prechamber. The aim is to maintain the combustible gas concentration in the gas within a certain range.

ところが、プレチャンバ−内の赤熱コークスの堆積量は
時々刻々と変化する。コークス炉で製造された赤熱コー
クスはパケットによってプレチャンバ−へ装入するので
パッチ装入となる。一方、乾式消火されたコークスはコ
ークス乾式消火設備より連続的に排出される。このバッ
チ操作と連続操作との整合と採る手段としてプレチャン
バ−が設けられているものであるが、プレチャンバ−へ
の赤熱コークス装入から次の装入までの間はその堆積量
は減少する。
However, the amount of red-hot coke deposited in the prechamber changes from moment to moment. Red-hot coke produced in a coke oven is charged into the prechamber in packets, resulting in patch charging. On the other hand, the dry extinguished coke is continuously discharged from the coke dry extinguishing equipment. A pre-chamber is provided as a means of matching batch operation and continuous operation, but the amount of red-hot coke deposited in the pre-chamber decreases from one charge to the next charge. .

本発明は、この堆積赤熱コークス量の変動するプレチャ
ンバ−内で、回収熱量増量分に相当する量の可燃ガスを
生成制御しようとするものである。
The present invention attempts to control the production of combustible gas in an amount corresponding to the increased amount of recovered heat in the prechamber where the amount of red-hot coke deposited varies.

課題を解決するための手段 本発明は、コークス乾式消火設備における循環ガス中の
可燃ガスを燃焼させて回収熱量を増量するに際して、循
環ガス成分分析値に基づいてブレチャンバー内圧力を所
定範囲内で制御することによって、プレチャンバ−への
吸入空気による可燃ガスの生成量あるいはプレチャンバ
−からの可燃ガス放散量を加減調整することを特徴とす
るコークス乾式消火設備における回収熱量増量制御方法
、である。
Means for Solving the Problems The present invention aims to increase the amount of recovered heat by burning combustible gas in circulating gas in coke dry extinguishing equipment, by controlling the internal pressure of the bleed chamber within a predetermined range based on the circulating gas component analysis value. 1. A method for controlling an increase in the amount of recovered heat in coke dry extinguishing equipment, characterized in that the amount of combustible gas produced by air taken into a prechamber or the amount of combustible gas released from a prechamber is adjusted by controlling .

作用 コークス乾式消火設備はコークス炉から排出された赤熱
コークスを粉塵を発生させることなく消火できると共に
、赤熱コークスが保有する顕熱を循環ガスを介して廃熱
ボイラーで蒸気エネルギーに変換して有効に利用するこ
とができる。
Working Coke dry extinguishing equipment can extinguish the red hot coke discharged from the coke oven without generating dust, and also effectively converts the sensible heat held by the red hot coke into steam energy in the waste heat boiler via circulating gas. can be used.

この廃熱ボイラーの安定操業を図るため、循環ガス中の
可燃ガス(H2、CO)成分の含有量を0.5〜15マ
O1%、好ましくは1マロ1%以下に制御することが望
まれている。
In order to ensure stable operation of this waste heat boiler, it is desirable to control the content of combustible gas (H2, CO) components in the circulating gas to 0.5 to 15 mmO1%, preferably 1 mmO1% or less. ing.

本発明者等はコークス乾式消火設備の操業の経験におい
て、プレチャンバ−内圧力が上昇すると可燃ガス濃度が
減少し、逆にプレチャンバ−内圧力が低下すると可燃ガ
ス濃度が増加する傾向が見られるとの知見に基づき、プ
レチャンバ−に吸排管を設けるのみで、プレチャンバ−
内圧力を、例えば、−50〜+201腸^qの範囲内で
、積極的に加減調節することによってプレチャンバ−内
で可燃ガスを生成させ、あるいは過剰の可燃ガスをプレ
チャンノー一から放散することができ、回収熱量の増量
に相当する量の可燃ガスを確保することができる。
The inventors have found in their experience in operating coke dry extinguishing equipment that when the prechamber internal pressure increases, the combustible gas concentration tends to decrease, and conversely, when the prechamber internal pressure decreases, the combustible gas concentration tends to increase. Based on the knowledge that
Combustible gas is generated within the pre-chamber or excess combustible gas is released from the pre-chamber by actively adjusting the internal pressure within the range of -50 to +201 mm, for example. This makes it possible to secure an amount of combustible gas corresponding to the increase in the amount of recovered heat.

プレチャンバ−内圧力を所定の範囲に維持する手段とし
ては、循環ガスの放散量の調節によって行うことができ
る。
The prechamber internal pressure can be maintained within a predetermined range by adjusting the amount of circulating gas released.

例えば、可燃ガス濃度が目標値より高い場合は、循環ガ
スの放散量を減少してプレチャンバ−内圧力を正圧とし
、プレチャンバ−に設けた吸排管より可燃ガスを放散す
る。一方、可燃ガス濃度が目標値より低い場合は、循環
ガスの放散量を増大してプレチャンバ−内圧力を負圧と
し、プレチャンバ−に設けた吸排管より空気を導入し、
プレチャンバ−内の赤熱コークスとの反応により可燃ガ
スを生成する。
For example, when the combustible gas concentration is higher than the target value, the amount of released circulating gas is reduced to make the pre-chamber internal pressure positive, and the combustible gas is released from the intake and exhaust pipes provided in the pre-chamber. On the other hand, if the combustible gas concentration is lower than the target value, the amount of dissipation of circulating gas is increased to make the pressure inside the prechamber negative, and air is introduced from the intake and exhaust pipe provided in the prechamber.
Combustible gas is produced by reaction with red-hot coke in the prechamber.

上記プレチャンバ−内圧力制御範囲としては、炉特性に
よって異なるが例えば、−50〜+20+smAqの範
囲を採用できる。前記したように、プレチャンバ−内の
赤熱コークスの堆積量は変動1.ており、導入空気で生
成できる可燃ガスの量は赤熱コークス量に依存している
ので、生成される可燃ガス量は変動する0例えば、プレ
チャンバ−内圧力と特定の値に保持し、一定量の空気を
導入した場合、赤熱コークスの堆積量が少ないと可燃ガ
スの生成に寄与するに充分な接触時間が採れないことか
ら、その一部はプレチャンバ−の下端(チャンバーの上
端)を通過する循環ガス中に余剰空気として流出する。
The prechamber internal pressure control range may vary depending on the furnace characteristics, but may be in the range of -50 to +20+smAq, for example. As mentioned above, the amount of red-hot coke deposited in the prechamber varies.1. The amount of combustible gas that can be generated with the introduced air depends on the amount of red-hot coke, so the amount of combustible gas that is generated varies. When air is introduced, if the amount of red-hot coke deposited is small, there will not be enough contact time to contribute to the generation of combustible gas, so some of it will pass through the lower end of the prechamber (upper end of the chamber). Excludes as excess air into the circulating gas.

この現象は循環ダクト内での異常燃焼を伴い、熱回収設
備であるボイラーチューブを損傷することとなる。
This phenomenon is accompanied by abnormal combustion within the circulation duct and damages the boiler tube, which is heat recovery equipment.

従って、本発明は、循環ガス成分分析値に基づいて可燃
ガス成分の含有量を0.5〜15マof%、好ましくは
1マロ1%以下に制御すると共に酸素濃度を監視し、循
環ガスの放散量を調節してプレチャンバ−内圧力を修正
制御するものである。
Therefore, the present invention controls the content of combustible gas components to 0.5 to 15% of combustible gas, preferably 1% or less, based on the analysis value of the circulating gas components, and monitors the oxygen concentration. This is to correct and control the prechamber internal pressure by adjusting the amount of radiation.

循環ガスの成分測定は熱回収ボイラーの出側から、チャ
ンバー入側までの間であればよい。
The components of the circulating gas may be measured between the outlet side of the heat recovery boiler and the inlet side of the chamber.

以下図面にもとすいて本発明を具体的に説明する。The present invention will be specifically explained below with reference to the drawings.

第1図に示すように、コークス乾式消火設備は、冷却塔
工の上部に装入口2を有するプレチャンバ−3を、中間
にクーリングチャンバー4を、その底部に循環ガス吹き
込み口5及び消火コークス切り出し装置6を備え、クー
リングチャンバー4の上端部に環状に配置した部位から
循環ガス7を排出して廃熱ボイラー8へ導入し、赤熱コ
ークスの保有熱を循環ガス7を介して蒸気9として回収
する。!3は廃熱ボイラー8へ導入される循環ガス7の
温度検出器。
As shown in Fig. 1, the coke dry extinguishing equipment includes a prechamber 3 having a charging port 2 at the top of the cooling tower structure, a cooling chamber 4 in the middle, and a circulating gas inlet 5 and extinguishing coke cutout at the bottom. Equipped with a device 6, circulating gas 7 is discharged from a part arranged annularly at the upper end of the cooling chamber 4 and introduced into a waste heat boiler 8, and the heat retained in the red-hot coke is recovered as steam 9 via the circulating gas 7. . ! 3 is a temperature detector for the circulating gas 7 introduced into the waste heat boiler 8;

回収蒸気9は工場内の熱源、発電等として工業的に使用
するので、蒸気発生量は設定範囲内で最高レベルに維持
することが望まれる。そのために、コークス乾式消火設
備の操業時に各種の原因で発生する熱量変動に対応して
、回収熱量増量分に対応する可燃ガスをプレチャンバ−
3内でタイムリーに生成するものである。
Since the recovered steam 9 is used industrially as a heat source in a factory, for power generation, etc., it is desirable to maintain the amount of steam generation at the highest level within a set range. To this end, in response to heat fluctuations that occur due to various causes during the operation of coke dry fire extinguishing equipment, combustible gas corresponding to the increased amount of recovered heat is pumped into the prechamber.
It is generated in a timely manner within 3 days.

具体的には、プレチャンバー3の上部には吸排管17が
設けである。プレチャンバー3の圧力測定器10の測定
値と、自動運転制御用計算機12から設定される目標圧
力値に基づいて圧力調節計11は循環ガス放散管18に
設けた弁13の開度を制御する。
Specifically, a suction and exhaust pipe 17 is provided in the upper part of the pre-chamber 3. Based on the measured value of the pressure measuring device 10 of the pre-chamber 3 and the target pressure value set from the automatic operation control computer 12, the pressure regulator 11 controls the opening degree of the valve 13 provided in the circulating gas diffusion pipe 18. .

自動運転制御用計算機12には、循環ガス7成分測定器
14で測定された可燃ガス濃度15および導入空気量1
6が入力されており、測定可燃ガス濃度が設定濃度より
濃い場合は、プレチャンバ−3内圧力を上昇させてプレ
チャンバー3に設けた吸排管17より吸引される空気量
を減少あるいはブレチャンバー3内圧力を正圧以上とな
し吸排管17より可燃ガスを放散する。逆に、測定可燃
ガス濃度が設定濃度より薄い場合は、プレチャンバ−3
内圧力を低下させてプレチャンバ−3に設けた吸排管1
7より放散する可燃ガスを減少あるいはブレチャンバー
3内圧力を負圧となし吸排管17より大気を吸引し、C
O1■2の可燃ガスを生成させる。
The automatic operation control computer 12 contains the combustible gas concentration 15 measured by the circulating gas 7 component measuring device 14 and the introduced air amount 1.
6 is input and the measured combustible gas concentration is higher than the set concentration, the pressure inside the pre-chamber 3 is increased to reduce the amount of air sucked through the suction and exhaust pipe 17 provided in the pre-chamber 3, or the pre-chamber 3 The internal pressure is made higher than the positive pressure and combustible gas is released from the intake and exhaust pipe 17. Conversely, if the measured combustible gas concentration is lower than the set concentration, the pre-chamber 3
Suction and exhaust pipe 1 installed in prechamber 3 to reduce internal pressure
Reduce the combustible gas emitted from 7 or make the internal pressure of the brake chamber 3 a negative pressure, and suck the atmosphere through the suction and exhaust pipe 17.
Generates combustible gas of O1 and 2.

上記ブレチャンバー3内に大気を吸引して可燃ガスを生
成する状態下では、循環ガス7成分測定器14で測定さ
れた酸素濃度に基づいて、自動運転制御用計算機12は
可燃ガス生成可否判断を行い。
Under the condition where air is sucked into the above-mentioned breech chamber 3 and combustible gas is generated, the automatic operation control computer 12 determines whether or not combustible gas can be generated based on the oxygen concentration measured by the circulating gas 7 component measuring device 14. conduct.

酸素濃度が設定値まで増加すると、プレチャンバー 3
内圧力設定値を一定量、例えば、1(lsmAp程度の
設定替え指示をし、ブレチャンバー3内の赤熱コークス
堆積量に対応した吸入空気量となるようにプレチャンバ
−3内圧力制御値を設定する。
When the oxygen concentration increases to the set value, the prechamber 3
Instruct to change the internal pressure set value by a certain amount, for example, about 1 (lsmAp), and set the pre-chamber 3 internal pressure control value so that the intake air amount corresponds to the amount of red-hot coke deposited in the pre-chamber 3. do.

実施例 第1図に示すコークス乾式消火設備において、赤熱コー
クスの移送経路に発生したトラブル処理時間に対応する
ため、消火コークスの切り出し量を75%低減させた。
Example In the coke dry extinguishing equipment shown in FIG. 1, the amount of extinguishing coke cut out was reduced by 75% in order to cope with the time required to resolve troubles that occurred in the red-hot coke transfer route.

第2図はその時の制御イメージを示しており、その結果
、循環ガス7の温度は低下することとなるが、循環ガス
7の一部150008m3/Hが放散され、第2図(ロ
)図に示すように、ブレチャンバー3内圧力が一20m
mAq低下され、吸排管17より大気が吸引されて40
0ONm3/H可燃ガスが生成され、第2図(ハ)図に
示すように、廃熱ボイラー8における回収熱量の低下は
抑制された。トラブル復旧(約10分)後に消火コーク
スの切り出し量を定常値に戻したら、ブレチャンバー内
圧力は徐々に上昇し、トラブル前とほぼ同等の圧力−1
0脂mAqとなった。
Figure 2 shows the control image at that time.As a result, the temperature of the circulating gas 7 will decrease, but a part of the circulating gas 7, 150008 m3/H, will be dissipated, and as shown in Figure 2 (b). As shown, the pressure inside the brake chamber 3 is 120m
The mAq is lowered, and the atmosphere is sucked through the suction and exhaust pipe 17.
0ONm3/H combustible gas was generated, and as shown in FIG. 2(c), a decrease in the amount of heat recovered in the waste heat boiler 8 was suppressed. After the problem is resolved (about 10 minutes), the amount of extinguishing coke cut out is returned to the normal value, and the pressure inside the breech chamber gradually increases until it reaches -1, which is almost the same as before the problem.
0 fat mAq.

第2図(ニ)図は、上記同様の操業においてブレチャン
バー3内圧力を制御することなく操業したケース(比較
例)におけるボイラー人ロガス温度の変化の一例である
FIG. 2(d) is an example of a change in the boiler log gas temperature in a case (comparative example) in which the operation was performed without controlling the internal pressure of the boiler chamber 3 in the same operation as described above.

発明の効果 以上のように、本発明はコークス乾式消火設備過程で随
時可燃ガスを生成し、またその閂を制御できるので、廃
熱ボイラーの設定温度の上限近傍で操業でき、」−記発
生量は設定範囲内の最高レベルでの操業が達成されるの
でその経済的効果は大きい。
Effects of the Invention As described above, the present invention generates combustible gas at any time during the process of coke dry fire extinguishing equipment, and can control the bolts, so it can operate near the upper limit of the set temperature of the waste heat boiler, and the amount of gas generated can be reduced. The economic effect is large because the operation is achieved at the highest level within the set range.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明の実施例装置の一例の説明図。 第2図は本発明制御法と比較例の操業推移を示すグラフ
である。 1・・・冷却塔、2・争・装入口、3・争・ブレチャン
パー、4・・串クーリング・チャン/ヘー5・・・循環
ガス吹き込み口、6・・・切り出し装置、7・・・循環
ガス、8・・會廃熱ボイラー9・・・蒸気、10・・・
圧力測定器、11・・・圧力調節器、12会・会自動運
転制御用計算機、13・・・放散弁、14・・・成分測
音器、15Φ会φ可燃ガス濃度値、16・・・空気量、
17・・−吸排管、18・・・放散ガス、19番・・温
度測定器。
FIG. 1 is an explanatory diagram of an example of an embodiment device of the present invention. FIG. 2 is a graph showing the operational trends of the control method of the present invention and the comparative example. DESCRIPTION OF SYMBOLS 1...Cooling tower, 2.Charging port, 3.Brenchamper, 4.Skewer cooling chamber/he 5..Circulating gas inlet, 6..Cutting device, 7.. Circulating gas, 8... Company waste heat boiler 9... Steam, 10...
Pressure measuring device, 11... Pressure regulator, 12... Automatic operation control computer, 13... Diffusion valve, 14... Component sound meter, 15 Φ meeting φ combustible gas concentration value, 16... air volume,
No. 17: Suction and exhaust pipe, No. 18: Diffusion gas, No. 19: Temperature measuring device.

Claims (1)

【特許請求の範囲】[Claims]  コークス乾式消火設備における循環ガス中の可燃ガス
を燃焼させて回収熱量を増量するに際して、循環ガス成
分分析値に基づいてプレチャンバー内圧力を所定範囲内
で制御することによって、プレチャンバーへの吸入空気
による可燃ガスの生成量あるいはプレチャンバーからの
可燃ガス放散量を加減調整することを特徴とするコーク
ス乾式消火設備における回収熱量増量制御方法。
When increasing the amount of recovered heat by burning combustible gas in the circulating gas in coke dry extinguishing equipment, the intake air to the prechamber is A method for controlling an increase in the amount of recovered heat in a coke dry fire extinguishing equipment, the method comprising adjusting the amount of combustible gas produced by or the amount of combustible gas released from a pre-chamber.
JP14739090A 1990-06-07 1990-06-07 Increase and control of heat recovery in coke dry quenching facility Pending JPH0441586A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP14739090A JPH0441586A (en) 1990-06-07 1990-06-07 Increase and control of heat recovery in coke dry quenching facility

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP14739090A JPH0441586A (en) 1990-06-07 1990-06-07 Increase and control of heat recovery in coke dry quenching facility

Publications (1)

Publication Number Publication Date
JPH0441586A true JPH0441586A (en) 1992-02-12

Family

ID=15429182

Family Applications (1)

Application Number Title Priority Date Filing Date
JP14739090A Pending JPH0441586A (en) 1990-06-07 1990-06-07 Increase and control of heat recovery in coke dry quenching facility

Country Status (1)

Country Link
JP (1) JPH0441586A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5410302A (en) * 1977-06-24 1979-01-25 Nippon Kokan Kk <Nkk> Method of extinguishing coke in dry extinguishing system and device therefor
JPS54124002A (en) * 1978-03-20 1979-09-26 Kawatetsu Kagaku Kk Recovery of excess circulating gas in dry type coke extingoishing method
JPS591591A (en) * 1982-06-28 1984-01-06 Ishikawajima Harima Heavy Ind Co Ltd Method for adjusting gas components in pre-chamber in coke dry extinguishing equipment

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5410302A (en) * 1977-06-24 1979-01-25 Nippon Kokan Kk <Nkk> Method of extinguishing coke in dry extinguishing system and device therefor
JPS54124002A (en) * 1978-03-20 1979-09-26 Kawatetsu Kagaku Kk Recovery of excess circulating gas in dry type coke extingoishing method
JPS591591A (en) * 1982-06-28 1984-01-06 Ishikawajima Harima Heavy Ind Co Ltd Method for adjusting gas components in pre-chamber in coke dry extinguishing equipment

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