JPH0446919A - Unsaturated polyester resin molding material - Google Patents
Unsaturated polyester resin molding materialInfo
- Publication number
- JPH0446919A JPH0446919A JP15607190A JP15607190A JPH0446919A JP H0446919 A JPH0446919 A JP H0446919A JP 15607190 A JP15607190 A JP 15607190A JP 15607190 A JP15607190 A JP 15607190A JP H0446919 A JPH0446919 A JP H0446919A
- Authority
- JP
- Japan
- Prior art keywords
- unsaturated polyester
- polyester resin
- resin
- molding material
- resin molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920006337 unsaturated polyester resin Polymers 0.000 title claims abstract description 20
- 239000012778 molding material Substances 0.000 title claims abstract description 17
- 229920005989 resin Polymers 0.000 abstract description 13
- 239000011347 resin Substances 0.000 abstract description 13
- 239000003365 glass fiber Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract description 3
- 125000005442 diisocyanate group Chemical group 0.000 abstract description 2
- 239000000945 filler Substances 0.000 abstract description 2
- 239000000654 additive Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000002787 reinforcement Effects 0.000 abstract 1
- 239000012779 reinforcing material Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 1
- 150000001735 carboxylic acids Chemical group 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は住宅機器用、建築部材用、衛生機器用等、特に
強度、耐久性が要求される成形品に用いられるシート状
の不飽和ポリエステル樹脂成形材料に関するものである
。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a sheet-like unsaturated polyester used in molded products that particularly require strength and durability, such as for housing equipment, building materials, sanitary equipment, etc. This invention relates to resin molding materials.
従来、不飽和ポリエステル樹脂成形材料は、樹脂として
末端カルボン酸不飽和ポリエステル樹脂を用いているが
、樹脂粘度が高く、補強材としてガラス繊維を多量に用
いるシート状成形材料ではガラス繊維と樹脂との濡れが
悪く、強度向上を阻害する欠点があった。Conventionally, unsaturated polyester resin molding materials use unsaturated polyester resins with terminal carboxylic acids as the resin, but the resin viscosity is high, and sheet molding materials that use a large amount of glass fiber as a reinforcing material are difficult to combine with the glass fiber and resin. It had the disadvantage of poor wetting, which hindered strength improvement.
従来の技術で述べたようにシート状成形材料に用いられ
ている末端カルボン酸不飽和ポリエステル樹脂は高粘度
で高強度成形品が得られない９本発明は従来の技術にお
ける上述の問題点に鑑みてなされたもので、その目的と
するところは高強度成形品が得られるシート状の不飽和
ポリエステル樹脂成形材料を提供することにある。As described in the prior art section, the terminal carboxylic acid unsaturated polyester resin used in sheet molding materials has a high viscosity and high strength molded products cannot be obtained9.The present invention was developed in view of the above problems in the prior art. The purpose is to provide a sheet-like unsaturated polyester resin molding material from which high-strength molded products can be obtained.
本発明はウレタン変性不飽和ポリエステル樹脂を含有し
たことを特徴とするシート状の不飽和ポリエステル樹脂
成形材料のため、樹脂粘度が低く、ガラス繊維と樹脂と
の濡れがよくなり高強度成形品を得ることができたもの
で、以下本発明の詳細な説明する。The present invention is a sheet-shaped unsaturated polyester resin molding material characterized by containing a urethane-modified unsaturated polyester resin, so the resin viscosity is low, and the wetting of the glass fiber and resin is good, resulting in a high-strength molded product. The present invention will now be described in detail.
本発明に用いるウレタン変性不飽和ポリエステル樹脂は
好ましくは不飽和ポリエステル樹脂の末端が水酸基から
なり、ジイソシアネートでウレタン変性できるものが望
ましいが、特に限定するものではない、ウレタン変性不
飽和ポリエステル樹脂の添加量は成形材料の樹脂全量で
もよいが好ましくは５０−１００重量％（以下単に％と
記す）であることが望ましい、即ち５０％未満では樹脂
としての粘度が低粘度になり難いからである。成形材料
全量中の樹脂量は２０〜６０％が好ましい、補強材とし
てはガラス繊維、合成繊維、炭素繊維、セラミック繊維
、天然繊維等を用いることができ全量中の補強材量は４
０〜８０％が好ましい、充填剤としては炭酸カルシウム
、クレー、シリカ、タルク、水酸化アルミニウム等の無
機粉末充填剤を必要に応じて添加することができる。架
橋剤、離型剤、着色剤、界面活性剤等については通常用
いられているものをそのまま用いることができ、これら
配合材料を混合、混練後、シート状にして不飽和ポリエ
ステル樹脂成形材料とするものである。The urethane-modified unsaturated polyester resin used in the present invention preferably has a hydroxyl group at the terminal end and is desirably one that can be urethane-modified with diisocyanate, but the amount of the urethane-modified unsaturated polyester resin added is not particularly limited. may be the total amount of the resin in the molding material, but it is preferably 50-100% by weight (hereinafter simply referred to as %); that is, if it is less than 50%, the viscosity of the resin is difficult to decrease. The amount of resin in the total amount of molding material is preferably 20 to 60%.As the reinforcing material, glass fiber, synthetic fiber, carbon fiber, ceramic fiber, natural fiber, etc. can be used, and the amount of reinforcing material in the total amount is 4%.
The amount is preferably 0 to 80%, and inorganic powder fillers such as calcium carbonate, clay, silica, talc, and aluminum hydroxide can be added as necessary. Commonly used crosslinking agents, mold release agents, coloring agents, surfactants, etc. can be used as they are, and after mixing and kneading these compounded materials, they are made into a sheet to form an unsaturated polyester resin molding material. It is something.
以下本発明を実施例にもとづいて説明する。The present invention will be explained below based on examples.
実施例１及び２と比較例１及び２
第１表の配合表にもとづいて各材料をニーダ−で混線後
、シート化して不飽和ポリエステル樹脂成形材料を得、
該成形材料を金型温度１５０°Ｃ１成形圧力２５０ ｋ
ｇ／ｃｉｉで加熱加圧成形して不飽和ポリエステル樹脂
成形品を得た。Examples 1 and 2 and Comparative Examples 1 and 2 Based on the recipe in Table 1, each material was mixed in a kneader and then formed into a sheet to obtain an unsaturated polyester resin molding material.
The molding material was molded at a mold temperature of 150°C and a molding pressure of 250 k.
A molded article of unsaturated polyester resin was obtained by heat-pressing molding at g/cii.
注
＊１アジツク株式会社製、品番ＡＧＵ
＊２品番エボ品番タボラックＨＶ
＊３アジツク株式会社製、品番ＡＣＩ
＊４化薬アクゾ株式会社、品番トリボノックス２ＬＳ５
０
実施例１及び２と比較例１及び２の成形材料及びその成
形品の性能は第２表のようである。Note *1 Manufactured by Ajitsu Co., Ltd., product number AGU *2 Product number Evo Product number Tavolac HV *3 Manufactured by Ajitsu Co., Ltd., product number ACI *4 Kayaku Akzo Co., Ltd., product number Tribonox 2LS5
0 The performance of the molding materials and molded products of Examples 1 and 2 and Comparative Examples 1 and 2 are shown in Table 2.
第 ２ 表
〔発明の効果〕
本発明は上述した如く構成されている。特許請求の範囲
に記載した構成を有するシート状の不飽和ポリエステル
樹脂成形材料においてはガラス繊維の樹脂含浸性がよく
、成形品強度が向上する効果を有している。Table 2 [Effects of the Invention] The present invention is constructed as described above. In the sheet-shaped unsaturated polyester resin molding material having the structure described in the claims, the resin impregnation of the glass fibers is good, and the strength of the molded product is improved.
Claims (1)
ことを特徴とするシート状の不飽和ポリエステル樹脂成
形材料。(1) A sheet-shaped unsaturated polyester resin molding material characterized by containing a urethane-modified unsaturated polyester resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15607190A JPH0446919A (en) | 1990-06-14 | 1990-06-14 | Unsaturated polyester resin molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15607190A JPH0446919A (en) | 1990-06-14 | 1990-06-14 | Unsaturated polyester resin molding material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0446919A true JPH0446919A (en) | 1992-02-17 |
Family
ID=15619671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15607190A Pending JPH0446919A (en) | 1990-06-14 | 1990-06-14 | Unsaturated polyester resin molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0446919A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5744816A (en) * | 1996-09-04 | 1998-04-28 | Premix, Inc. | Low pressure sheet molding compounds |
| CN1300249C (en) * | 2005-08-10 | 2007-02-14 | 北京玻钢院复合材料有限公司 | Modified unsaturated polyester composition material and its preparing method |
| CN110408185A (en) * | 2019-07-11 | 2019-11-05 | 安徽金九鼎复合材料有限公司 | A kind of high-strength low-temperature-resistant glass reinforced plastic and preparation method thereof |
-
1990
- 1990-06-14 JP JP15607190A patent/JPH0446919A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5744816A (en) * | 1996-09-04 | 1998-04-28 | Premix, Inc. | Low pressure sheet molding compounds |
| US5998510A (en) * | 1996-09-04 | 1999-12-07 | Premix, Inc. | Low pressure sheet molding compounds |
| CN1300249C (en) * | 2005-08-10 | 2007-02-14 | 北京玻钢院复合材料有限公司 | Modified unsaturated polyester composition material and its preparing method |
| CN110408185A (en) * | 2019-07-11 | 2019-11-05 | 安徽金九鼎复合材料有限公司 | A kind of high-strength low-temperature-resistant glass reinforced plastic and preparation method thereof |
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