JPH044695B2 - - Google Patents
Info
- Publication number
- JPH044695B2 JPH044695B2 JP58017926A JP1792683A JPH044695B2 JP H044695 B2 JPH044695 B2 JP H044695B2 JP 58017926 A JP58017926 A JP 58017926A JP 1792683 A JP1792683 A JP 1792683A JP H044695 B2 JPH044695 B2 JP H044695B2
- Authority
- JP
- Japan
- Prior art keywords
- glass tube
- filament
- light bulb
- bromine
- inert gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011521 glass Substances 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 13
- 229910052736 halogen Inorganic materials 0.000 claims description 12
- 150000002367 halogens Chemical class 0.000 claims description 12
- 239000011261 inert gas Substances 0.000 claims description 10
- 239000007769 metal material Substances 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 8
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 3
- 229910052786 argon Inorganic materials 0.000 claims description 2
- 150000002366 halogen compounds Chemical class 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 10
- 229910052794 bromium Inorganic materials 0.000 description 10
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- QGLKJKCYBOYXKC-UHFFFAOYSA-N nonaoxidotritungsten Chemical compound O=[W]1(=O)O[W](=O)(=O)O[W](=O)(=O)O1 QGLKJKCYBOYXKC-UHFFFAOYSA-N 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 229910001930 tungsten oxide Inorganic materials 0.000 description 9
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 8
- 239000001257 hydrogen Substances 0.000 description 7
- 229910052739 hydrogen Inorganic materials 0.000 description 7
- FJBFPHVGVWTDIP-UHFFFAOYSA-N dibromomethane Chemical compound BrCBr FJBFPHVGVWTDIP-UHFFFAOYSA-N 0.000 description 5
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 229910052796 boron Inorganic materials 0.000 description 4
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 4
- MOWNZPNSYMGTMD-UHFFFAOYSA-N oxidoboron Chemical compound O=[B] MOWNZPNSYMGTMD-UHFFFAOYSA-N 0.000 description 4
- 150000002431 hydrogen Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- SKCGKQHUYTYMSL-UHFFFAOYSA-N [W].BrOBr Chemical compound [W].BrOBr SKCGKQHUYTYMSL-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- -1 bromine hydrocarbon Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01K—ELECTRIC INCANDESCENT LAMPS
- H01K1/00—Details
- H01K1/50—Selection of substances for gas fillings; Specified pressure thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B20/00—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、ハロゲン電球の製造方法に関するも
のである。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a method for manufacturing a halogen light bulb.
従来例の構成とその問題点
臭素または塩素を用いたハロゲン電球を作る場
合、ガラス管内に酸素が残存すると短寿命とな
る。Conventional structure and problems When making a halogen light bulb using bromine or chlorine, if oxygen remains in the glass tube, the lifespan will be shortened.
従つて、極力、電球内から酸素を取り除く必要
がある。従来、一般には、排気工程の途中でガラ
ス管内に水素を数パーセント含む不活性ガスを封
入し、ガラス管を外部からバーナ等により加熱す
るとともに、フイラメントを点灯し、それらの熱
によつてガラス管内の金属材料を還元する方法が
とられていた。しかし、このような方法では十分
にガラス管内の金属材料を還元することができな
いため、ガラス管内に酸素が残存することとな
り、短寿命が発生する原因となつていた。 Therefore, it is necessary to remove oxygen from the bulb as much as possible. Conventionally, in the course of the exhaust process, an inert gas containing a few percent of hydrogen was filled into the glass tube, the glass tube was heated from the outside with a burner, etc., and a filament was lit, and the heat generated inside the glass tube A method of reducing metal materials was used. However, since such a method cannot sufficiently reduce the metal material inside the glass tube, oxygen remains inside the glass tube, causing a short life.
発明の目的
本発明はこのような問題を解決するもので、ガ
ラス管内に酸素を残存させず、長寿命のハロゲン
電球を得ることのできる製造方法を提供するもの
である。OBJECTS OF THE INVENTION The present invention solves these problems, and provides a manufacturing method that allows a long-life halogen light bulb to be obtained without leaving oxygen in the glass tube.
発明の構成
本発明は、排気工程中でガラス管内に不活性ガ
スとジボランを含むガスを封入することにより、
ガラス管内の金属材料の酸化物をジボランによつ
て還元するようにしたものである。Composition of the Invention The present invention has the following features: By filling a glass tube with a gas containing an inert gas and diborane during the evacuation process,
The oxide of the metal material inside the glass tube is reduced by diborane.
実施例の説明
以下本発明の一実施例を図面を参照して説明す
る。DESCRIPTION OF EMBODIMENTS An embodiment of the present invention will be described below with reference to the drawings.
図は一般照明に用いる100V500Wの一端形のハ
ロゲン電球であつて、１は石英などからなるガラ
ス管、２は封止部、３はガラス管１の内部に設け
られた２重コイル形のタングステンからなるフイ
ラメント、４および５は内部導入線、６はフイラ
メント支持線をそれぞれ示す。フイラメント支持
線６と内部導入線４および５は、それらの基部を
加熱加工によつてガラス製の棒状体７に埋込んで
ある。８および９はモリブデン箔、１０および１
１は外部導入線である。 The figure shows a 100V, 500W single-ended halogen bulb used for general lighting, in which 1 is a glass tube made of quartz, 2 is a sealing part, and 3 is a double-coiled tungsten bulb installed inside the glass tube 1. 4 and 5 indicate internal lead-in lines, and 6 indicates a filament support line, respectively. The bases of the filament support wire 6 and the internal lead-in wires 4 and 5 are embedded in a glass rod-shaped body 7 by heat processing. 8 and 9 are molybdenum foils, 10 and 1
1 is an external lead-in line.
このような構成のハロゲン電球において、ガラ
ス製の棒状体７にフイラメント支持線６、内部導
入線４および５を加熱加工によつて埋込む際にフ
イラメント支持線６、内部導入線４および５が酸
化することが多い。その酸化は、化学研摩や電解
研摩によつて取り除かれるが、完全に取り除くこ
とは困難である。このような酸化を残したまま封
止、排気を行い、封入ガスとして不活性ガスとと
もに微量のハロゲン化合物を封入しハロゲン電球
を完成させた場合、このハロゲン電球は早期黒化
を起したり、短寿命となつたりする。 In a halogen light bulb with such a configuration, when the filament support wire 6 and the internal lead-in wires 4 and 5 are embedded in the glass rod-shaped body 7 by heat processing, the filament support wire 6 and the internal lead-in wires 4 and 5 are oxidized. There are many things to do. The oxidation can be removed by chemical polishing or electrolytic polishing, but it is difficult to completely remove it. If a halogen light bulb is completed by sealing and exhausting with such oxidation remaining, and filling a small amount of halogen compound with an inert gas as the sealed gas, this halogen light bulb may cause early blackening or short life. It becomes a lifespan.
これらの問題を解決するためには、ガラス管内
に残留する酸素をガラス管外に取り除く必要があ
る。 In order to solve these problems, it is necessary to remove the oxygen remaining inside the glass tube to the outside of the glass tube.
前述したとおり、一般には、排気工程中でガラ
ス管内に水素を数パーセント含む不活性ガスを封
入し、ガラス管を外部からバーナ等により加熱す
るとともにフイラメントを点灯し、それらの熱に
よつてガラス管内の金属材料を還元しようとする
方法がとられていたが、ガラス管内の酸化してい
る金属材料を水素で還元するにはそれらの金属材
料を1000℃以上の温度にする必要がある。しか
し、実際にはフイラメント以外の金属材料を1000
℃以上に加熱することは困難である。 As mentioned above, in general, during the evacuation process, the glass tube is filled with an inert gas containing several percent hydrogen, the glass tube is heated from the outside with a burner, etc., and a filament is turned on. However, in order to reduce the oxidized metal materials inside the glass tube with hydrogen, it is necessary to bring the metal materials to a temperature of 1000°C or higher. However, in reality, 1000 metal materials other than filament are used.
It is difficult to heat above ℃.
そこで、もつと低い温度で酸化を除去する方法
について検討を行つた。 Therefore, we investigated a method to remove oxidation at a lower temperature.
発明者は、まず排気工程中で不活性ガスに微量
の臭化メチレンを加えたガスを封入し、その封入
ガス中でフイラメントを点灯することを検討し
た。臭化メチレンは熱を加えると分解し、炭素と
臭化水素となる。さらに高温になると、臭化水素
は分解して水素と臭素に別れる。この臭素が酸化
タングステンと化合すると、オキシ臭化タングス
テンとなる。オキシ臭化タングステンは蒸発温度
が低く、フイラメントからの熱およびガラス管の
外部からのバーナ等による熱によつて容易に蒸発
するので、排気工程中にガラス管外に排気するこ
とが可能であると考えられた。しかし、実際に試
作検討を行つてみると、期待通りに行かないこと
が判明した。その原因は臭化メチレンの分解によ
つてできた臭化水素がほとんど分解しないため、
酸化タングステンを蒸発させるに必要な臭素が十
分得られないことによることが判明した。 The inventor first investigated the idea of filling an inert gas with a small amount of methylene bromide in the exhaust process and lighting the filament in the filled gas. When heated, methylene bromide decomposes into carbon and hydrogen bromide. At higher temperatures, hydrogen bromide decomposes into hydrogen and bromine. When this bromine combines with tungsten oxide, it becomes tungsten oxybromide. Tungsten oxybromide has a low evaporation temperature and is easily evaporated by heat from the filament and heat from a burner, etc. from outside the glass tube, so it is possible to exhaust it outside the glass tube during the exhaust process. it was thought. However, when we actually investigated the prototype, we found that it did not work as expected. The reason for this is that hydrogen bromide produced by the decomposition of methylene bromide hardly decomposes.
It turned out that this was due to not being able to obtain enough bromine to evaporate tungsten oxide.
臭素の量を多くする目的で、封入ガス中の臭化
メチレンの量を増加したところ、酸化タングステ
ンを蒸発させることに対しては望ましい方向に進
んだが、臭化メチレンが分解したときに出る炭素
がフイラメントに付着し、フイラメントをぜい化
させたり、管壁黒化を起し、実用に供することが
できなかつた。 When the amount of methylene bromide in the filler gas was increased to increase the amount of bromine, progress was made in the desired direction for evaporating tungsten oxide, but the carbon released when methylene bromide decomposed was It adhered to the filament and caused brittleness of the filament and blackening of the tube wall, making it impossible to put it to practical use.
臭素の炭化水素を用いず、不活性ガス中に臭素
を封入した封入ガスの場合には、十分、酸化タン
グステンを蒸発させることが可能であつたが、排
気機が臭素に侵食されるため、実用に供すること
ができなかつた。 It was possible to sufficiently evaporate tungsten oxide using a sealed gas containing bromine in an inert gas without using a bromine hydrocarbon, but the exhaust machine would be attacked by the bromine, making it impractical. It was not possible to offer it to the public.
そこで、発明者は、臭素を用いずに酸化タング
ステンを還元する方法について検討した。 Therefore, the inventor investigated a method for reducing tungsten oxide without using bromine.
排気工程中でガラス管内に封入するガスとし
て、窒素、アルゴンまたはそれらの混合ガスから
なる不活性ガスとともに、微量のジボランを用い
る検討を行つた。ジボランはガラス管内のフイラ
メントを点灯すると、その熱によつて容易に分解
し、BHと水素となる（（）式）。 We investigated the use of a small amount of diborane as well as an inert gas consisting of nitrogen, argon, or a mixture thereof as gases sealed in the glass tube during the evacuation process. When the filament inside the glass tube is turned on, diborane easily decomposes due to the heat and becomes BH and hydrogen (formula ()).
B2H6→2BH＋2H2 ……（）
BHが酸素や酸化タングステンに会うと化合し
て一酸化ほう素となる（（）式）。 B 2 H 6 → 2BH + 2H 2 ... () When BH meets oxygen or tungsten oxide, it combines to form boron monoxide (formula ()).
2BH＋WO2→Ｗ＋2BO＋H2 ……（）
一酸化ほう素は不活性ガスとともにガラス管外
に排気される。 2BH+WO 2 →W+2BO+H 2 ...() Boron monoxide is exhausted to the outside of the glass tube along with inert gas.
臭化水素の場合には臭素と水素の結合が強いた
め、酸化タングステンを還元することができない
が、ほう素と水素の化合物（BH）は、ほう素と
酸素の親和力が強いため、水素との結合がきれ、
ほう素はタングステンから酸素をうばつて酸化ほ
う素となるので、酸化タングステンを還元するこ
とができる。 Hydrogen bromide cannot reduce tungsten oxide because the bond between bromine and hydrogen is strong, but a compound of boron and hydrogen (BH) has a strong affinity for boron and oxygen, so it cannot reduce tungsten oxide. The bond is broken,
Since boron removes oxygen from tungsten and becomes boron oxide, it can reduce tungsten oxide.
ジボランの不活性ガス中への封入量について実
験した結果、0.1容量％より少ない量ではガラス
管内の酸化物が取り切れず、早期黒化を起した
り、短寿命となるハロゲン電球が発生した。ま
た、2.5容量％より多い場合には、タングステン
フイラメントの中にほう素が拡散する量が多くな
りすぎ、フイラメントサグ等の問題を生じ好まし
くなかつた。 As a result of experiments on the amount of diborane sealed in an inert gas, it was found that if the amount was less than 0.1% by volume, the oxides inside the glass tube could not be removed, causing early blackening and shortening the lifespan of halogen bulbs. Moreover, when the amount is more than 2.5% by volume, the amount of boron diffused into the tungsten filament becomes too large, which is not preferable because problems such as filament sag occur.
発明の効果
以上説明したように、本発明はガラス管内に酸
素が残存せず、長寿命のハロゲン電球を得ること
のできる製造方法を提供することができるもので
ある。Effects of the Invention As explained above, the present invention can provide a manufacturing method that allows a long-life halogen light bulb without oxygen remaining in the glass tube.
図は本発明にかかるハロゲン電球の一例を示す
正面図である。
１……ガラス管、３……フイラメント、４，５
……内部導入線、６……フイラメント支持線、７
……棒状体。
The figure is a front view showing an example of a halogen light bulb according to the present invention. 1...Glass tube, 3...Filament, 4,5
...Internal introduction line, 6...Filament support line, 7
...A rod-shaped body.
Claims (1)
内に窒素、アルゴンまたはそれらの混合ガスにジ
ボランを含むガスを封入し、前記ガラス管内の金
属材料をフイラメントの点灯により加熱するとと
もに、前記ガラス管の外部から加熱して、前記ガ
ラス管内の金属材料の酸化物を前記ジボランによ
つて還元し、生成した酸化物を前記ガラス管外に
排気したのち、前記ガラス管内に不活性ガスおよ
びハロゲン化合物からなるガスを封入することを
特徴とするハロゲン電球の製造方法。1. In the exhaust process of a halogen light bulb, a gas containing diborane in nitrogen, argon, or a mixture thereof is sealed in a glass tube, and the metal material in the glass tube is heated by lighting a filament, and the metal material is heated from the outside of the glass tube. After reducing the oxide of the metal material in the glass tube with the diborane and exhausting the generated oxide outside the glass tube, a gas consisting of an inert gas and a halogen compound is sealed in the glass tube. A method for manufacturing a halogen light bulb, characterized by:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58017926A JPS59143236A (en) | 1983-02-04 | 1983-02-04 | Method for manufacturing halogen lamp |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58017926A JPS59143236A (en) | 1983-02-04 | 1983-02-04 | Method for manufacturing halogen lamp |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59143236A JPS59143236A (en) | 1984-08-16 |
| JPH044695B2 true JPH044695B2 (en) | 1992-01-29 |
Family
ID=11957370
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58017926A Granted JPS59143236A (en) | 1983-02-04 | 1983-02-04 | Method for manufacturing halogen lamp |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59143236A (en) |
-
1983
- 1983-02-04 JP JP58017926A patent/JPS59143236A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59143236A (en) | 1984-08-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2883571A (en) | Electric incandescent lamp | |
| US3091718A (en) | Constant lumen maintenance lamp | |
| US5034656A (en) | Tungsten halogen lamp including phosphorous and bromine | |
| US3475072A (en) | Getter for incandescent lamps and similar devices | |
| US3821585A (en) | Tungsten halogen incandescent lamp with group iva metal getter and method of manufacture | |
| US3263113A (en) | Tungsten filament lamp comprising hexafluoride gas at partial pressure not exceeding 10 torrs | |
| US3585435A (en) | Electric incandescent lamp | |
| US3728572A (en) | Incandescent lamp with regenerative cycle | |
| JPH044695B2 (en) | ||
| US3364376A (en) | Iodine cycle incandescent lamp including carbon monoxide | |
| CA1042976A (en) | Bromine lamp with molybdenum parts | |
| US4237401A (en) | Low-pressure mercury vapor discharge lamp | |
| JPH0430141B2 (en) | ||
| US3453476A (en) | Halogen regenerative cycle incandescent lamp | |
| US4015157A (en) | Iodine lamp with molybdenum parts | |
| JPS59143237A (en) | Method for manufacturing halogen lamp | |
| JPS58126638A (en) | Manufacturing method of tungsten halogen lamp | |
| EP0328065B1 (en) | Improved getter for incandescent lamps | |
| US3831053A (en) | Differential output lamp containing chlorine and hydrogen | |
| JPS622448A (en) | Halogen lamp filling gas mixture for low operation temperature of halogen cycle | |
| US4032808A (en) | Electric incandescent lamp | |
| US4898558A (en) | Getter for incandescent lamps | |
| US4810221A (en) | Method for gettering incandescent lamps | |
| JPS58126639A (en) | Manufacturing method of tungsten halogen lamp | |
| US1647591A (en) | Gaseous-discharge lamp |