JPH045321A - Civil engineering work method using foaming resin - Google Patents
Civil engineering work method using foaming resinInfo
- Publication number
- JPH045321A JPH045321A JP10700690A JP10700690A JPH045321A JP H045321 A JPH045321 A JP H045321A JP 10700690 A JP10700690 A JP 10700690A JP 10700690 A JP10700690 A JP 10700690A JP H045321 A JPH045321 A JP H045321A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- chamber
- plate unit
- beads
- resin beads
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005989 resin Polymers 0.000 title claims abstract description 30
- 239000011347 resin Substances 0.000 title claims abstract description 30
- 238000005187 foaming Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title description 6
- 239000012508 resin bead Substances 0.000 claims abstract description 34
- 239000011324 bead Substances 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 239000011148 porous material Substances 0.000 claims description 10
- 238000009415 formwork Methods 0.000 claims description 5
- 238000012407 engineering method Methods 0.000 claims description 3
- 239000006260 foam Substances 0.000 abstract description 29
- 239000000919 ceramic Substances 0.000 abstract description 9
- 239000000463 material Substances 0.000 abstract description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000007547 defect Effects 0.000 description 3
- 238000007664 blowing Methods 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Landscapes
- Investigation Of Foundation Soil And Reinforcement Of Foundation Soil By Compacting Or Drainage (AREA)
- Pit Excavations, Shoring, Fill Or Stabilisation Of Slopes (AREA)
- Road Paving Structures (AREA)
Abstract
Description
本発明は、発泡性樹脂を現場で必要形状に発泡させて盛
土9人工地盤の形成、道路の拡幅工事等を行う際、発泡
状態及び圧縮強度が均一な樹脂発泡体を得る土木工法に
関する。The present invention relates to a civil engineering method for foaming a foamable resin into a required shape on site to obtain a resin foam with a uniform foamed state and compressive strength when forming an artificial ground embankment 9, widening a road, etc.
【従来の技術1
発泡樹脂の軽量性を活かして、窪地を埋めたり人工地盤
の一部とする試みが従来から行われていたとえば、発泡
性樹脂を工場で所定形状の発泡体ブロックに成形し、こ
の発泡体ブロックを盛土しようとする原地盤に積み上げ
、表層面にコンクリート床板や壁面保護材等を張って仕
上げている。
また、内部に鉄筋等の補強材を配置して、構造的な強度
を向上させることも行われている。
このように発泡体を積み重ねて人工地盤を形成するとき
、発泡体ブロック相互の間にズレが生じ易い。そこで、
実開昭63−81941号公報。
実開昭63−81942号公報等においては、このズレ
をなくすため、発泡体ブロックの表面に凹凸を形成し、
この凹凸を噛み合わせることが紹介されている。
ところが、工場で発泡させた後の発泡体ブロックを現場
まで運搬し、所定の形状に積み上げる方式では、運搬や
取扱いに手数がかかる。たとえば、この種のブロックと
して2XIX0.5m程度の大型ブロックを使用してい
るが、このような大型のものにあっては、軽量であるに
も拘らず、運搬に人手を要する。また、その運搬は、実
質的には空気を運搬しているようなものであり、無駄が
多い。しかも、ブロックが大型になるほど、盛土等の作
業を施そうとする原地盤を平にして敷き詰められたブロ
ックとの間に隙間が形成されないようにすることが必要
となる。
また、特開昭47−19617号公報では、窪地又は路
床上にウレタン、塩化ビニル、スチレン等の未発泡樹脂
を散布した後、発泡反応を行わせて、窪地等の充填を行
うことが開示されている。
しかし、当該公報には、樹脂をどのように発泡させるか
に関して具体的に教示するところがない。
ところで、単に樹脂を発泡させるだけでは、不均一な発
泡等に起因して発泡後の樹脂体表面が必要とする輪郭を
持たないことが多い。また、自由界面で発泡させると、
発泡体の表面強度が充分でなく、踏圧が加わったとき窪
み等が生じ易くなる。
【発明が解決しようとする課題1
本発明者等は、現場施工の利点を活かしながら、必要と
する強度をもつ人工地盤等を形成する工法として、型枠
で仕切られた原地盤に発泡性樹脂のビーズを散布し、加
熱気体によって樹脂ビーズを発泡させることにより人工
地盤を構築する方法を開発した。
ところで、樹脂ビーズを発泡させて地盤を構築するとき
、樹脂ビーズの不均一な発泡が起こりがちである。その
結果、発泡後の樹脂体表面での凹凸発生や内部の空洞発
生等の欠陥が生じることになる。このような欠陥は、樹
脂ビーズの発泡雰囲気の変動に起因するものと推察され
る。
そこで、本発明は、樹脂ビーズに対して加熱気体を均一
に接触させることにより、樹脂ビーズを均一に発泡させ
、均一な発泡組織及び圧縮強度をもつ樹脂発泡体製の地
盤を構築することを目的とする。
【課題を解決するための手段1
本発明の土木工法は、この目的を達成するため、原地盤
の上方に多孔質材料製の板体或いは多数の細孔が穿設さ
れた板体を配置して前記原地盤と前記板体との間にチャ
ンバーを形成し、前記板体の上に樹脂ビーズを散布し、
該ビーズの上方に空間を介して型枠を配置し、前記チャ
ンバーに供給された加熱気体を前記板体を透過さ、せて
前記樹脂ビーズに接触させて加熱・発泡させることを特
徴とする。
【作 用】
チャンバーに供給された水蒸気等の加熱気体は。
多孔質材料製の板体或いは多数の細孔が穿設された板体
を介して樹脂ビーズに供給される。このとき、給気間を
介してボイラー等から供給された加熱気体は、チャンバ
ーで供給圧から一旦解放された後、板体の多孔質材料製
いは細孔を経由して、樹脂ビーズに向けて流れる。その
ため、加熱気体は、板体の全面にわたって均一な流量分
布をもって樹脂ビーズに接触し、樹脂ビーズの発泡が全
面にわたって一様に行われる。したがって、発泡反応が
局部的に発生することが抑えられ、均一な発泡状態をも
った樹脂発泡体が得られる。[Prior art 1] Attempts have been made to take advantage of the lightweight nature of foamed resin to fill depressions or make it part of artificial ground. These foam blocks are piled up on the original ground that is to be embanked, and the surface is finished with concrete floor plates, wall protection materials, etc. Additionally, reinforcing materials such as reinforcing bars are placed inside to improve structural strength. When forming an artificial ground by stacking foams in this manner, misalignment is likely to occur between the foam blocks. Therefore,
Utility Model Application No. 63-81941. In Japanese Utility Model Application Publication No. 63-81942, etc., in order to eliminate this misalignment, unevenness is formed on the surface of the foam block,
It is introduced that these irregularities can be interlocked. However, the method of transporting foam blocks that have been foamed in a factory to the site and stacking them into a predetermined shape requires time and effort to transport and handle. For example, a large block of about 2XIX 0.5 m is used as this type of block, but such a large block requires manpower to transport, although it is lightweight. Furthermore, the transportation is essentially like transporting air, which is wasteful. Moreover, as the blocks become larger, it becomes necessary to flatten the original ground on which work such as embankment is to be performed so that no gaps are formed between the blocks and the laid blocks. Furthermore, Japanese Patent Application Laid-open No. 47-19617 discloses that after spraying an unfoamed resin such as urethane, vinyl chloride, or styrene onto a depression or roadbed, a foaming reaction is caused to fill the depression. ing. However, this publication does not specifically teach how to foam the resin. By the way, if the resin is simply foamed, the surface of the resin body after foaming often does not have the required contour due to non-uniform foaming or the like. In addition, when foaming occurs at the free interface,
The surface strength of the foam is insufficient, and dents are likely to occur when treading pressure is applied. Problem to be Solved by the Invention 1 The present inventors have developed a method for forming artificial ground with the required strength while taking advantage of on-site construction. We have developed a method to construct artificial ground by scattering resin beads and foaming the resin beads with heated gas. By the way, when building a foundation by foaming resin beads, non-uniform foaming of the resin beads tends to occur. As a result, defects such as unevenness on the surface of the foamed resin body and internal cavities occur. It is presumed that such defects are caused by fluctuations in the foaming atmosphere of the resin beads. Therefore, the purpose of the present invention is to uniformly foam the resin beads by uniformly bringing heated gas into contact with the resin beads, and to construct a base made of resin foam that has a uniform foam structure and compressive strength. shall be. [Means for solving the problem 1] In order to achieve this objective, the civil engineering method of the present invention arranges a plate made of a porous material or a plate with many pores bored above the original ground. forming a chamber between the original ground and the plate body, and scattering resin beads on the plate body,
A mold is placed above the beads with a space therebetween, and heated gas supplied to the chamber is passed through the plate and brought into contact with the resin beads to heat and foam them. [Operation] Heated gas such as water vapor supplied to the chamber. The resin beads are supplied through a plate made of porous material or a plate with a large number of pores. At this time, the heated gas supplied from a boiler etc. through the air supply gap is once released from the supply pressure in the chamber, and then directed to the resin beads via the porous material or pores of the plate. It flows. Therefore, the heated gas contacts the resin beads with a uniform flow rate distribution over the entire surface of the plate, and the foaming of the resin beads is performed uniformly over the entire surface. Therefore, local occurrence of a foaming reaction is suppressed, and a resin foam having a uniform foamed state can be obtained.
以下、図面を参照しながら、傾斜面の盛土に適用した実
施例により、本発明を具体的に説明する。
本実施例においては、第1図に示すように原地盤1の傾
斜面2に所定の盛土をする。
下側地面3の上方に通気性板体4を配置し、下側地面3
と板体4との間にチャンバー5を形成する。通気性板体
4は、たとえば多孔質状態に焼結したセラミックス、発
泡コンクリート、多数の細孔を穿設した金属板等が使用
される。この通気性板体4は、下側地面3に打ち込まれ
た杭5によって支持され、下側地面3から所定の高さに
維持されている。
通気性板体4の上には、適量の樹脂ビーズ7が均等な厚
みで散布される。樹脂ビーズ7としては、発泡性のある
スチレン樹脂、ウレタン樹脂、ユリア樹脂等、種々のも
のが知られている。たとえば、樹脂発泡体の材料として
広範な分野で使用されているスチレン樹脂にあっては、
約35〜45倍の発泡倍率で膨張する。
そこで、この発泡後の容積を見込んだ位置に、型枠8を
配置しておく。型枠8の内容積は、自由状態で樹脂ビー
ズ7を発泡させたときに得られる体積よりも若干小さく
しておくことが好ましい。
これにより、樹脂ビーズの発泡末期において、型枠8に
よる拘束力、すなわち圧力が加わり、樹脂発泡体の表面
層が緻密なものとなる。
チャンバー5には、給気管9が開口している。
この給気管9は、給気ポンプ10を介してボイラー11
等の加熱気体源に接続されている。
次いで、この装置を使用して樹脂発泡体により地盤を形
成する手順を説明する。
樹脂ビーズとして、平均粒径0.9mmのスチレン樹脂
を使用した。この樹脂は、第2図に示すように温度及び
時間との関係で発泡反応を開始し、反応終了時に発泡倍
率30〜45倍程度の発泡体に膨張し、発泡後の密度が
約0.015g/cm3となるものであった。
傾斜面2としては、1 m X 1 mの断面積で段差
80cmのものを用意した。この傾斜面2の下側地面3
から10cmの高さに、板厚5cmの多孔質セラミック
ス板4を配置した。そして、下側地面3と多孔質セラミ
ックス板4との間に生じたチャンバー5に、内径30m
mの給気管9を開口させた。なお、多孔質セラミックス
板4は、下側地面3に4Qセンチの深さで打ち込んだ杭
6によって支持した。そして、多孔質セラミックス板4
の上に、厚み23mmで樹脂ビーズ5を散布した。
この状態で、ボイラー11から給気管9に温度100℃
の水蒸気を毎分0 、1 m 3の流量で供給した。水
蒸気は、チャンバー5で一旦膨張した後、多孔質セラミ
ックス板4を透過して、均一な流量分布をもった流れと
なって樹脂ビーズ7に接触した。水蒸気の吹込みを15
分継続したところ、樹脂ビーズ5は、多孔質セラミック
ス板4の表面から65cmの高さまで膨張した。
樹脂ビーズ5は更に発泡を継続して膨張しようとするが
、その外郭が型枠8で拘束されている。
そのため、この膨張しようとする力は、樹脂発泡体に反
力として作用し、樹脂発泡体の表面が緻密なものとなっ
た。
次いで、型枠8を取り外し、形成した樹脂発泡体を傾斜
面2から取り出し、垂直方向及び水平方向に裁断して、
内部の発泡状態を観察した。その結果、両方向共にほぼ
均一な発泡組織となっていることが判った。また、この
発泡体から試験片を切り出し圧縮強度を測定したところ
、4%の圧縮歪を与えるときの圧縮応力値が1.5〜2
.0kg/Cm2の範囲にあった。このことから、車輌
走行時に加わる平均的な踏圧である0、5kg/cm2
よりも充分に大きな強度をもつ地盤が獲られていること
が判る。この樹脂発泡体に100kgの移動荷重を繰り
返し加える試験を10時間継続した後、樹脂発泡体の表
面状態を調べたところ、陥没等の欠陥は何等検出されな
かった。
他方、多孔質セラミックス板4を設けずに樹脂ビーズ5
に水蒸気を直接吹き出して加熱・発泡を行わせたところ
、得られた樹脂発泡体は、発泡状態にむらがあり、圧縮
強度も0.5〜2.5 k g/cm2と大きくばらつ
いていた。これは、供給された水蒸気の流量が、ガス吹
込み方向に関して変動し、且つ樹脂ビーズ7の間に形成
されるガス通路の抵抗にばらつきがあることに起因する
ものと考えられる。このような発泡状態の不均一性及び
圧縮強度のばらつきによって、得られた樹脂発泡体の上
に移動荷重を同様に繰り返し加えたところ、局部的に陥
没した箇所が検出された。
以上の実施例では、傾斜面2の盛土を例にとって説明し
ているが、同様の方法によって窪地の盛土や路幅の拡張
等に本発明を適用することもできる。また、形成された
樹脂発泡体の上に更に通気性板体を設け、その通気性板
体の上で樹脂ビーズの加熱・発泡を再度行わせることに
よって、多層に樹脂発泡体を積み重ね、深い窪地や段差
の大きな傾斜面や道路側面等に対する盛土を行うことも
できる。
【発明の効果1
以上に説明したように、本発明においては、樹脂ビーズ
の発泡を現場で行って地盤を構築する際に、水蒸気等の
加熱気体を多孔質材料性の板体或いは多数の細孔を穿設
した板体を介して樹脂ビーズに供給している。これによ
って、樹脂ビーズと加熱気体との接触が均一に行われ、
発泡後の樹脂の内部及び外部がほぼ−様な発泡状態とな
り、局部的に圧縮強度が低下することがなくなる。この
ようにして、本発明によるとき、踏圧に耐える充分な強
度をもった地盤を簡単に構築することができる。Hereinafter, the present invention will be specifically described by way of an example applied to an embankment on a slope, with reference to the drawings. In this embodiment, as shown in FIG. 1, a predetermined embankment is placed on a slope 2 of the original ground 1. A breathable plate 4 is arranged above the lower ground 3, and the lower ground 3
A chamber 5 is formed between the plate body 4 and the plate body 4. The air permeable plate 4 is made of, for example, porous sintered ceramics, foamed concrete, a metal plate with a large number of pores, or the like. This breathable plate 4 is supported by stakes 5 driven into the lower ground 3 and maintained at a predetermined height from the lower ground 3. An appropriate amount of resin beads 7 are spread on the air-permeable plate 4 with an even thickness. Various resin beads 7 are known, such as foamable styrene resin, urethane resin, and urea resin. For example, styrene resin is used in a wide range of fields as a material for resin foam.
It expands at a foaming ratio of about 35 to 45 times. Therefore, the formwork 8 is placed at a position that takes into account the volume after foaming. It is preferable that the internal volume of the mold 8 is slightly smaller than the volume obtained when the resin beads 7 are foamed in a free state. As a result, at the final stage of foaming the resin beads, a restraining force, ie, pressure, is applied by the mold 8, and the surface layer of the resin foam becomes dense. An air supply pipe 9 opens into the chamber 5 . This air supply pipe 9 is connected to a boiler 11 via an air supply pump 10.
connected to a heated gas source such as Next, a procedure for forming a ground using resin foam using this device will be explained. Styrene resin with an average particle size of 0.9 mm was used as the resin beads. As shown in Figure 2, this resin starts a foaming reaction depending on the temperature and time, and at the end of the reaction it expands into a foam with an expansion ratio of about 30 to 45 times, and the density after foaming is about 0.015 g. /cm3. As the inclined surface 2, one with a cross-sectional area of 1 m x 1 m and a step difference of 80 cm was prepared. The lower ground 3 of this slope 2
A porous ceramic plate 4 with a thickness of 5 cm was placed at a height of 10 cm from the base. Then, a chamber 5 formed between the lower ground 3 and the porous ceramic plate 4 has an inner diameter of 30 m.
The air supply pipe 9 of m was opened. Note that the porous ceramic plate 4 was supported by stakes 6 driven into the lower ground 3 at a depth of 4Q cm. And porous ceramic plate 4
Resin beads 5 were sprinkled on top to a thickness of 23 mm. In this state, the temperature from the boiler 11 to the air supply pipe 9 is 100°C.
of water vapor was supplied at a flow rate of 0.1 m3 per minute. After once expanding in the chamber 5, the water vapor passed through the porous ceramic plate 4 and came into contact with the resin beads 7 as a flow with a uniform flow rate distribution. 15 minutes of water vapor injection
After continuing for several minutes, the resin beads 5 expanded to a height of 65 cm from the surface of the porous ceramic plate 4. The resin beads 5 continue to foam and try to expand, but their outer shells are restrained by the formwork 8. Therefore, this expanding force acts on the resin foam as a reaction force, and the surface of the resin foam becomes dense. Next, the formwork 8 is removed, the formed resin foam is taken out from the inclined surface 2, and cut vertically and horizontally.
The foaming state inside was observed. As a result, it was found that the foamed structure was substantially uniform in both directions. In addition, when a test piece was cut out from this foam and its compressive strength was measured, the compressive stress value when applying a compressive strain of 4% was 1.5 to 2.
.. It was in the range of 0 kg/Cm2. From this, the average pedal pressure applied when the vehicle is running is 0.5kg/cm2.
It can be seen that ground with sufficiently greater strength has been obtained. After a test in which a moving load of 100 kg was repeatedly applied to this resin foam for 10 hours, the surface condition of the resin foam was examined, and no defects such as depressions were detected. On the other hand, the resin beads 5 are not provided with the porous ceramic plate 4.
When heating and foaming was carried out by directly blowing out water vapor, the resulting resin foams had uneven foaming states, and their compressive strengths varied widely, ranging from 0.5 to 2.5 kg/cm2. This is considered to be due to the fact that the flow rate of the supplied water vapor varies with respect to the gas blowing direction and that the resistance of the gas passage formed between the resin beads 7 varies. Due to the non-uniformity of the foamed state and the variation in compressive strength, when moving loads were similarly repeatedly applied to the obtained resin foam, localized areas were detected. In the above embodiments, the embankment of the slope 2 is explained as an example, but the present invention can also be applied to embankment of a depression, expansion of road width, etc. by a similar method. In addition, by further providing a breathable plate on top of the formed resin foam and heating and foaming the resin beads again on the breathable plate, the resin foam can be stacked in multiple layers and deep depressions can be created. It is also possible to carry out embankments on slopes with large differences in level, road sides, etc. Effects of the Invention 1 As explained above, in the present invention, when constructing the ground by foaming resin beads on-site, heated gas such as water vapor is applied to a porous material plate or a large number of fine particles. The resin beads are supplied through a plate with holes. This ensures uniform contact between the resin beads and the heated gas.
After foaming, the inside and outside of the resin will be in a substantially -like foamed state, and the compressive strength will not locally decrease. In this way, according to the present invention, it is possible to easily construct a ground having sufficient strength to withstand treading pressure.
第1図は本発明を傾斜面の造成に適用した実施例を説明
するための図、第2図は発泡状態を温度及び時間との関
係で表したグラフである。
1・・・原地盤 2・・・傾斜面3・・・下側
地面 4・・・通気性板体5・・・チャンバー
6・・・杭
7・・・樹脂ビーズ 8・・・型枠9・・・給気管
10・・・給気ポンプ11・・・ボイラー
則 郵 ρFIG. 1 is a diagram for explaining an embodiment in which the present invention is applied to the creation of an inclined surface, and FIG. 2 is a graph showing the foaming state in relation to temperature and time. 1...Original ground 2...Sloped surface 3...Lower ground 4...Breathable plate 5...Chamber
6...Pile 7...Resin beads 8...Formwork 9...Air supply pipe 10...Air supply pump 11...Boiler rule ρ
Claims (1)
穿設された板体を配置して前記原地盤と前記板体との間
にチャンバーを形成し、前記板体の上に樹脂ビーズを散
布し、該ビーズの上方に空間を介して型枠を配置し、前
記チャンバーに供給された加熱気体を前記板体を透過さ
せて前記樹脂ビーズに接触させて加熱・発泡させること
を特徴とする発泡樹脂を使用した土木工法。A plate made of a porous material or a plate with a large number of pores is arranged above the original ground to form a chamber between the original ground and the plate, and a chamber is formed above the plate. Resin beads are dispersed, a formwork is placed above the beads with a space therebetween, and heated gas supplied to the chamber is passed through the plate and brought into contact with the resin beads to cause heating and foaming. A civil engineering method that uses foamed resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10700690A JP2772994B2 (en) | 1990-04-23 | 1990-04-23 | Civil engineering method using foamable resin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10700690A JP2772994B2 (en) | 1990-04-23 | 1990-04-23 | Civil engineering method using foamable resin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH045321A true JPH045321A (en) | 1992-01-09 |
| JP2772994B2 JP2772994B2 (en) | 1998-07-09 |
Family
ID=14448106
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10700690A Expired - Lifetime JP2772994B2 (en) | 1990-04-23 | 1990-04-23 | Civil engineering method using foamable resin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2772994B2 (en) |
-
1990
- 1990-04-23 JP JP10700690A patent/JP2772994B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JP2772994B2 (en) | 1998-07-09 |
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