JPH0453905A - Polarizing element and its manufacture - Google Patents
Polarizing element and its manufactureInfo
- Publication number
- JPH0453905A JPH0453905A JP2164703A JP16470390A JPH0453905A JP H0453905 A JPH0453905 A JP H0453905A JP 2164703 A JP2164703 A JP 2164703A JP 16470390 A JP16470390 A JP 16470390A JP H0453905 A JPH0453905 A JP H0453905A
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- Prior art keywords
- liquid crystal
- crystal layer
- polarizing element
- linear
- straight line
- Prior art date
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Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明(友 光学機器分野において使用される偏光素子
、特に同心円偏光(または放射偏光)を直線偏光く あ
るいは直線偏光を同心円偏光(または放射偏光)に変換
する偏光素子に関する。[Detailed Description of the Invention] Industrial Application Fields of the Invention Polarizing elements used in the field of optical equipment, particularly converting concentrically polarized light (or radial polarized light) into linearly polarized light, or converting linearly polarized light into concentrically polarized light (or radially polarized light). This invention relates to a converting polarizing element.
従来の技術
従来 光の偏光状態を変換する偏光素子として、光学ヘ
ッド装置等では1/4波長板や1/2波長板等の直線位
相子が用いられてきた力丈 これらは光の偏光状態を全
面にわたって均一に変換するものであった
一−X 主にツイスト・ネマチック液晶(以下、TN
液晶)を用いた表示装置等で1′!、液晶配列を変化さ
せて画素単位で偏光変換を行うh匁 画素の微細化(現
在100〜200μm角程度)にも限界があつ九
しかるに近蝦 光導波路やグレーティング等を組合わせ
た光集積素子において、小面積内で、空間的に異なった
分布をもつ偏光状態を直線偏光等の均質な偏光状態へ
また均質な偏光状態を空間的に分布をもった偏光状態に
変換することが要求されつつある。Conventional technology Conventional linear retarders such as quarter-wave plates and half-wave plates have been used in optical head devices as polarizing elements to convert the polarization state of light. 1-X, which converted uniformly over the entire surface, was mainly used for twisted nematic liquid crystals (hereinafter referred to as TN
1' with display devices using liquid crystal)! In optical integrated devices that combine optical waveguides, gratings, etc., there is a limit to miniaturization of pixels (currently about 100 to 200 μm square). , transform polarization states with spatially different distributions into homogeneous polarization states such as linear polarization within a small area.
Furthermore, there is an increasing demand for converting a homogeneous polarization state into a spatially distributed polarization state.
特級 同心円形状のグレーティングカブラを用いて導波
光を導波路外部に放射する光集積素子の場合、同心円の
接線方向または動径方向に振動面をもつ偏光状態と均質
な偏光状態との変換を行なう必要があった力丈 この様
な偏光変換を実現する素子は過去になかっ九
そこで、本出願人は上記機能を有する偏光素子およびそ
れを用いた光学ヘッド装置を特願平1−246808号
において提示し九
以下これを先行例と称することとし 第5@第6図を用
いて先行例における偏光素子を用いた光学ヘッド装置の
説明を行なう。Special grade In the case of an optical integrated device that uses a concentric grating coupler to radiate guided light to the outside of the waveguide, it is necessary to convert the polarization state with a vibration plane in the tangential direction or radial direction of the concentric circles to a homogeneous polarization state. There has never been an element capable of achieving such polarization conversion in the past.Therefore, the present applicant proposed a polarizing element having the above function and an optical head device using the same in Japanese Patent Application No. 1-246808. This will hereinafter be referred to as a prior example, and an optical head device using a polarizing element in the prior example will be explained using FIG. 5@FIG.
第5図の先行例における光学ヘッド装置の構成図に於い
て、Si基板l上に低屈折率の透明層2が形成され そ
の上に高屈折率の透明層3A、 3Bが形成されていも
透明層3Aは円形tlL 3Bは3Aを取り巻く輪
帯状であム
透明層3A、 3Bの表面には中心軸りに対し同心円状
のグレーティングカブラ4A、4Bが形成されていも
透明層3Aの表面には低屈折率の透明層5Aを挟んで高
屈折率の透明層3cが形成され 透明層3Cは透明層3
Bとそのグレーティングカブラ4Bの内周側に面した領
域で接すム透明層3Cの表面には中心軸りに関し同心円
状のグレーティングカブラ4Cが形成されていも透明層
3Bの表面には低屈折率の透明層5Bが形成されており
、透明層5Bの屈折率は透明層5Aに等しL% Si
基板1には透明層3ん 3B間の断絶部に相当する位置
に光検出器6A、6Bが形成されており、検出器6A、
6Bを覆う形で透明層5A内に反射膜7が形成されて
いも な礼 中心軸り近傍のSi基板1は中空になって
いも半導体レーザー8を出射した直線偏光の光は集光レ
ンズ9により集光され 位相差板19Aおよび偏光素子
10Aによって同心円接線方向(または動径方向)の電
界ベクトルをもつ光11に変換されも この先11が同
心円形状のグレーティング4Cによって導波層3C内に
入力し 層内を外周方向に向かって伝搬するTEモード
(または1Mモード)の導波光12Cとなa
導波光12Cは導波層3cの最外周領域で導波層3Cか
ら導波層3Bに移り導波光12Bとなム導波光12Bは
グレーティングカブラ4Bにより放射され 放射光13
となも 放射光13は導波光12BがTEモードであれ
ば電界ベクトルが同心円接線方向を向く偏光状態(以下
、同心円偏光と称する)の光となり、TMモードであれ
ば電界ベクトルが動径方向を向く偏光状態(以下、放射
偏光と称する)の光となる。In the configuration diagram of the optical head device in the prior example shown in FIG. 5, even though the transparent layer 2 with a low refractive index is formed on the Si substrate 1 and the transparent layers 3A and 3B with high refractive index are formed on it, it is still transparent. The layer 3A is circular tlL, and the layer 3B is annular surrounding 3A.On the surfaces of the transparent layers 3A and 3B, grating covers 4A and 4B are formed concentrically with respect to the center axis.
A transparent layer 3c with a high refractive index is formed on the surface of the transparent layer 3A with a transparent layer 5A with a low refractive index sandwiched therebetween.
Although a concentric grating cover 4C about the center axis is formed on the surface of the transparent layer 3C that contacts B and its grating cover 4B in the area facing the inner circumferential side, the surface of the transparent layer 3B has a low refractive index. A transparent layer 5B is formed, and the refractive index of the transparent layer 5B is equal to that of the transparent layer 5A, and L% Si
Photodetectors 6A and 6B are formed on the substrate 1 at positions corresponding to the discontinuities between the transparent layers 3 and 3B.
Even if the reflective film 7 is formed in the transparent layer 5A to cover the transparent layer 6B, even if the Si substrate 1 near the center axis is hollow, the linearly polarized light emitted from the semiconductor laser 8 is still reflected by the condenser lens 9. The light is focused and converted into light 11 having an electric field vector in the concentric tangential direction (or radial direction) by the retardation plate 19A and the polarizing element 10A.Then, the light 11 is input into the waveguide layer 3C by the concentric grating 4C. The guided light 12C of the TE mode (or 1M mode) propagates toward the outer circumferential direction inside the waveguide layer 3c. Tonamu waveguide light 12B is emitted by grating coupler 4B, and synchrotron radiation 13
If the guided light 12B is in the TE mode, the synchrotron radiation 13 becomes light in a polarization state in which the electric field vector points in the concentric tangential direction (hereinafter referred to as concentric circularly polarized light), and in the TM mode, the electric field vector points in the radial direction. The light is in a polarized state (hereinafter referred to as radiation polarization).
この同心円偏光(または放射偏光)の光131友偏光素
子10Bおよび位相差板19Bを経て直線偏光の光とな
り、光ディスク15の反射面16上の点Fに集光すa
−人 反射面16を反射する光ζよ 再び位相差板19
Bおよび偏光素子10Bを経て同心円偏光(または放射
偏光)の光となり、グレーティングカブラ4A、4Bに
より導波層3A、 3B内に入力し それぞれ層内を外
周方匝 内周方向に向かって伝搬するTEモード(また
はTMモード)の導波光18A、 18Bとなも 導波
光18A、18Bは導波層3A、 3Bの最外端服 最
内端部で放射され それぞれ光検出器6A、 6Bに受
光されも
次へ 偏光素子10Bおよび位相差板19Bを集光点F
とグレーティングカプラ4Bの間に設けることで生ずる
効果について第6図を用いて説明すも
第6図(a)、(b)は同心円形状のグレーティングカ
ブラにより光を集光した場合の集光点での光強度分布断
面図の例を示しており、 (a)は同心円偏光(または
放射偏光)の光 (b)は直線偏光の光であ&(a)と
(b)の比較から明らかなようへ 同心円偏光(または
放射偏光)シヨ 直線偏光に比べて良好な集光性が得
られなし これは電界ベクトルが同心円中心について対
角位置で互いに逆ベクトルをなし 集光点で打消し合う
ためであも 従って偏光素子10Bおよび位相差板19
Bをグレーティングカブラ4Bと集光点との間に配置し
同心円偏光(または放射偏光)を完全な直線偏光に変
換すれば 高い集光性が得られも一人 第5図における
反射光17がグレーティングカブラ4A、 4Bにより
導波路3A、 3B内へ入力する暇 高い入力結合効率
を得るために(よ反射光と放射光の偏光状態が同じであ
ることが望ましく〜 従って、偏光素子10Bおよび位
相差板19Bが可逆的に直線偏光と同心円偏光(または
放射偏光)の変換を行うことか収 反射光の導波路への
入力結合効率を高める効果もあも次へ 第7図を用いて
、先行例における偏光素子10Bと位相差板19Bによ
る光の偏光状態の変化を説明すも 同図(a)!、t、
偏光素子10Bによる偏光変換原理を示す。偏光素
子10Bは1層のTN液晶層で構成され このTN液晶
層は片側(集光点F側)が実線40で示す一方向の直線
状の液晶配置 他面側(グレーティングカプラ4B側)
が破線41で示す円の接線方向の液晶配向を施すことで
形成されていも
このような簡易な液晶配向処理を施すことで、液晶ツイ
スト角θが同心円周上の各位置で連続的に異なる分布を
持ったTN構造の液晶層が得られも すなわ板 同心円
周上で(イ)から(ロ)を経て(八)に至る各位置で、
ツイスト角θはθ=−π/2からθ=0を経てθ=π/
2へと変化しており(ただし紙面上反時計回りのツイス
トを右ねじれとしそのツイスト角を負とする)、(ニ)
から(ネ)を経て(へ)に至る各位置について耘 同様
のTN構造となも
一般にTN構造の液晶層に直線偏光の光が入射すると、
TN構造のねじれに沿って光の電界ベクトルが回転すム
従って、グレーティングカブラ4Bより放射される同
心円偏光の光(破線矢印で示される電界ベクトル42)
ζよ 素子の各位置での液晶ツイスト角とほぼ同じ角度
だけ旋光し 液晶層の直線配向方向に電界ベクトルをも
つ光(実線矢印の電界ベクトル43)となも
な耘 液晶層のねじれの向きが同心円中心を通り直線配
向方向に平行な直線44で分けられる2つの領域A、
Bで互いに逆になるので、電界ベクトル43の向き耘
領域A、 Bで互いに逆向きとなる(すなわち位相
がπだけずれている)。This concentric circularly polarized (or radiation polarized) light 131 becomes linearly polarized light after passing through the polarizing element 10B and the retardation plate 19B, and is focused on a point F on the reflective surface 16 of the optical disc 15. Light ζ, retardation plate 19 again
B and polarizing element 10B, the light becomes concentrically polarized light (or radiation polarized light), enters into waveguide layers 3A and 3B by grating couplers 4A and 4B, and propagates in the respective layers from the outer periphery toward the inner periphery. The guided lights 18A and 18B of the waveguide layers 3A and 3B are emitted from the outermost and innermost ends of the waveguide layers 3A and 3B, and are received by the photodetectors 6A and 6B, respectively. Next Place the polarizing element 10B and retardation plate 19B at the focal point F.
The effect produced by providing it between the grating coupler 4B and the grating coupler 4B will be explained using FIG. An example of a cross-sectional diagram of the light intensity distribution is shown, where (a) is concentrically polarized (or radial polarized) light, (b) is linearly polarized light, and as is clear from the comparison of (a) and (b). Concentric circularly polarized light (or radial polarized light) cannot achieve better light focusing than linearly polarized light. This is because the electric field vectors are opposite to each other at diagonal positions about the center of the concentric circle and cancel each other out at the focal point. Therefore, the polarizing element 10B and the retardation plate 19
If B is placed between the grating coupler 4B and the condensing point and the concentrically polarized light (or radial polarized light) is converted into completely linearly polarized light, high light convergence can be obtained.Reflected light 17 in Figure 5 is the grating coupler. 4A, 4B into the waveguides 3A, 3B. In order to obtain high input coupling efficiency (it is desirable that the polarization state of the reflected light and the emitted light be the same), the polarizing element 10B and the retardation plate 19B Converts reversibly between linearly polarized light and concentric circularly polarized light (or radial polarized light).The effect of increasing the input coupling efficiency of reflected light into the waveguide is also shown in Figure 7. The changes in the polarization state of light due to the element 10B and the retardation plate 19B are explained in the same figure (a)!, t,
The principle of polarization conversion by the polarizing element 10B is shown. The polarizing element 10B is composed of one TN liquid crystal layer, and one side (focusing point F side) of this TN liquid crystal layer has a unidirectional linear liquid crystal arrangement as shown by the solid line 40, and the other side (grating coupler 4B side)
is formed by aligning the liquid crystal in the tangential direction of the circle shown by the broken line 41. However, by performing such a simple liquid crystal alignment process, the distribution of the liquid crystal twist angle θ is continuously different at each position on the concentric circumference. It is possible to obtain a liquid crystal layer with a TN structure with
The twist angle θ is from θ=-π/2 to θ=0 and then θ=π/
2 (however, the counterclockwise twist on the paper is assumed to be a right-handed twist, and the twist angle is negative), (d)
Regarding each position from (ne) to (h), when linearly polarized light is incident on the liquid crystal layer of a similar TN structure,
The electric field vector of the light rotates along the twist of the TN structure. Therefore, the concentric circularly polarized light emitted from the grating coupler 4B (the electric field vector 42 indicated by the dashed arrow)
ζ The light rotates by almost the same angle as the twist angle of the liquid crystal at each position of the element and has an electric field vector in the direction of linear alignment of the liquid crystal layer (electric field vector 43 indicated by a solid line arrow). Two areas A divided by a straight line 44 passing through the center of the concentric circles and parallel to the straight line alignment direction,
Since the electric field vectors 43 are opposite to each other in regions A and B, the directions of the electric field vectors 43 are opposite to each other in regions A and B (that is, the phases are shifted by π).
第7図(b)は先行例における位相差板19Bの位相補
償原理を示し 同心円中心を通り液晶層の直線配向方向
と略平行な直線44 (同図(a)参照)で2っに分け
られた領域ん Bの片側Bに位相差板19Bを構成して
いも
位相差板19Bの屈折率をn1、厚みをd1、レーザー
光の波長をλとすると、位相差板19Bを透過する側の
光と透過しない側の光の位相差力(2π(rz−1)d
+となるようく すなわ板d+=(2k l)λ/2
(n+−1)(k; 自然数)
の関係を満すように作成すれば 領域A、 Bを透過
する光の位相をπだけずらすことができも 従って、液
晶層を通過した光(互いに向きの異なる電界ベクトルa
S、a・の光)は位相差板19Bを透過することで位相
が揃し\ 互いに向きの等しい電界ベクトルam、aマ
の光 すなわち完全な直線偏光の光となム このように
偏光素子10Bと位相差板19Bとを組み合わせるこ
とで領域九Bを通過する光の位相差が補償され同心円偏
光を直線偏光に変換することができも
また これらの変換には可逆性があり、直線偏光から同
心円偏光への変換も同様に行なうことができも
なお 第5図における位相差板19Aおよび偏光素子1
0Aは上記の位相差板19Bおよび偏光素子10Bと同
じ構成であり、同様の原理で半導体レーザー8から出射
する直線偏光の光を完全な同心円偏光に変換することが
できも
発明が解決しようとする課題
以上説明したようへ 同心円形状のグレーティングカプ
ラを用いて高い集光性および高い入力結合効率を実現す
るには可逆的に直線偏光と同心円偏光との変換を行う偏
光素子が必要であり、特願平1−246808において
提案した偏光素子を用いれはこの偏光変換が実現できも
一人 上記先行例の偏光素子において、偏光変換性能を
更に向上させるためには 次のような課題があっち
第8図は先行例の偏光素子におけるTN液晶層のツイス
ト角分布を表わす図であも 第8図で点0は上記の同心
円状配向の円中心を示し 矢印Sは液晶配向面の直線配
向側の配向方向を示す。TN液晶層の液晶配列が理想的
に形成されれば 同心円中心を通り、方向Sに直交する
直線上で液晶ツイスト角θ=0となり、領域Aの点0に
対する方位角α自の直線上では 液晶ツイスト角θがθ
=α1、領域Bの方位角α―の直線上ではθ=α8とな
a (ただし α4、α8ともに時計回り方向を正とす
も )
すなわ杖 点Oを通る直線S方向の直線領域BOでは互
いに逆ねじれ(ツイスト角θ−π/2とθ−−π/2)
のTN構造が隣接する境界線 いわゆるディスクリネー
ションラインが発生すム このディスクリネーションラ
インは幅がきわめて小さい線状の領域であるので、第8
図のようにディスクリネーションラインが同心円中心を
通る直線配向方向の直線と完全に一致していれ(二 偏
光変換性能に大きい影響を及ぼさな(℃
しかしなか収 第9図の偏光素子10Bの平面図に示す
よう&へ 一般にディスクリネーションライン411戴
同心円中心0を通る直線配向方向の直線L4に対し
乱れた状態となも これは液晶住人時の液晶の流動性や
、液晶配向面の表面状態およびツイスト・ネマチック液
晶材料に含まれる旋回性物質の影響により液晶層内のの
弾性エネルギの均衡がくずれていることによム
このようにディスクリネーションライン41が乱れると
、位相差板端面(直線L4に相当)との開にずれた領域
(斜線部F)が生し この領域で偏光素子の変換特性が
劣化すム 特&へ 偏光素子が小さい場合に慰 このデ
ィスクリネーションラインの乱れによる影響は大きいも
のとな4課題を解決するための手段
本発明は上記の問題点を解決する偏光素子とその製造方
法を提供するものであり、以下の手段を用いも
すなわ板 液晶配向面の一方が直線方向 もう一方が同
心円の接線方向の配向である液晶配向面間にツイスト・
ネマチック液晶層を有する偏光素子において、同心円中
心を通り直線配向方向に略平行な直線で分けられる2つ
の領域で液晶層の厚みを異ならせることであム
あるい(よ 直線方向の液晶配向面上へ 同心円中心を
通り前記直線方向に略平行な直線状の領域に凹部または
凸部を設(す、同心円中心を通り直線配向方向に略平行
な直線上で液晶層の厚みが変化する構成とす4
あるいは 同心円中心を通り直線配向方向に略平行な直
線によって分けられる液晶層の2つの領域で直線配向方
向の角度を異ならせも
あるいは 液晶配向面の一方が直線方向 もう一方が同
心円接線方向の配向処理を施した2枚の透明基板間にツ
イスト・ネマチック液晶層を設けてなる偏光素子の製造
において、前記2枚の透明基板間に液晶を封入した抵
液晶をN−I点近傍に加熱したのち冷却を行なう熱処理
を施すことであム
あるい(よ 表面に透明導電膜を有する2枚の透明基板
の一方に直線方向 もう一方に同心円の接線方向の配向
処理を施した後、前記2枚の透明基板間にツイスト・ネ
マチック液晶層を設けた後、液晶層に電圧を印加する。FIG. 7(b) shows the phase compensation principle of the retardation plate 19B in the previous example. Even if the retardation plate 19B is configured on one side B of the area B, if the refractive index of the retardation plate 19B is n1, the thickness is d1, and the wavelength of the laser beam is λ, then the light on the side that passes through the retardation plate 19B is and the phase difference force (2π(rz−1)d) of the light on the non-transmitted side
So that it becomes +, that is, board d+ = (2k l)λ/2
If it is created to satisfy the relationship (n+-1) (k: natural number), it is possible to shift the phase of the light passing through regions A and B by π. Different electric field vector a
The phases of the lights (S, a) are aligned by passing through the retardation plate 19B\ Light with electric field vectors am and a having the same direction, that is, completely linearly polarized light.In this way, the polarizing element 10B By combining the and retardation plate 19B, the phase difference of the light passing through region 9B can be compensated and concentrically polarized light can be converted to linearly polarized light. Furthermore, these conversions are reversible, and linearly polarized light can be converted to concentrically polarized light. Conversion to polarized light can be performed in the same way, but the retardation plate 19A and polarizing element 1 in FIG.
0A has the same configuration as the above-mentioned retardation plate 19B and polarizing element 10B, and the linearly polarized light emitted from the semiconductor laser 8 can be converted into completely concentric circularly polarized light using the same principle. Problems As explained above, in order to achieve high light collection and high input coupling efficiency using a concentric grating coupler, a polarizing element that reversibly converts linearly polarized light to concentrically polarized light is required, and a patent application is filed. It is possible to realize this polarization conversion using the polarizing element proposed in 1991-246808.In order to further improve the polarization conversion performance of the polarizing element of the preceding example, there are the following issues. This is a diagram showing the twist angle distribution of the TN liquid crystal layer in the example polarizing element. In Figure 8, point 0 indicates the center of the circle of the above-mentioned concentric alignment, and arrow S indicates the alignment direction on the linear alignment side of the liquid crystal alignment surface. . If the liquid crystal alignment of the TN liquid crystal layer is ideally formed, the liquid crystal twist angle θ will be 0 on a straight line passing through the center of the concentric circles and orthogonal to the direction S, and the liquid crystal will be on a straight line at the azimuth angle α relative to point 0 in area A. Twist angle θ is θ
= α1, on the straight line of azimuth α- of region B, θ = α8 (however, both α4 and α8 assume that the clockwise direction is positive) In other words, in the straight line region BO in the direction of straight line S passing through point O Reciprocal twists (twist angles θ−π/2 and θ−−π/2)
A so-called disclination line occurs at the boundary line where the TN structures of
As shown in the figure, the disclination line should completely coincide with the straight line in the linear orientation direction passing through the center of the concentric circles (2). As shown in the figure, the disclination line 411 is generally attached to the straight line L4 in the linear orientation direction passing through the concentric center 0.
This is a disordered state. This is due to the fluidity of the liquid crystal when it is inhabited, the surface condition of the liquid crystal alignment surface, and the influence of the rotating substance contained in the twisted nematic liquid crystal material, causing the balance of elastic energy within the liquid crystal layer to collapse. When the disclination line 41 is disturbed in this way, an area (shaded area F) that is deviated from the end face of the retardation plate (corresponding to the straight line L4) is created. In this area, the polarizing element is converted. When the polarizing element is small, the influence of disturbance of this disclination line becomes large.4Means for Solving the ProblemsThe present invention provides a polarizing element and a polarizing element that solves the above-mentioned problems. The present invention provides a method for manufacturing the same, and uses the following means to create a twisted plate between the liquid crystal alignment surfaces in which one of the liquid crystal alignment surfaces is aligned in a straight direction and the other is aligned in a tangential direction of a concentric circle.
In a polarizing element having a nematic liquid crystal layer, the thickness of the liquid crystal layer is made to differ between two regions divided by a straight line passing through the center of concentric circles and approximately parallel to the linear alignment direction (on the liquid crystal alignment surface in the linear direction). A concave portion or a convex portion is provided in a linear region passing through the center of the concentric circles and substantially parallel to the linear direction, and the thickness of the liquid crystal layer is configured to change on a straight line passing through the center of the concentric circles and substantially parallel to the linear alignment direction. 4 Alternatively, the angles of the linear alignment direction may be made different in two areas of the liquid crystal layer separated by a straight line passing through the center of the concentric circle and approximately parallel to the linear alignment direction.Alternatively, one of the liquid crystal alignment planes may be aligned in the linear direction and the other in the concentric circle tangential direction. In manufacturing a polarizing element in which a twisted nematic liquid crystal layer is provided between two treated transparent substrates, a resistor in which a liquid crystal is sealed between the two transparent substrates is used.
By applying a heat treatment to heat the liquid crystal to near the N-I point and then cooling it, one of the two transparent substrates having a transparent conductive film on the surface is applied in a straight direction and the other in the tangential direction of a concentric circle. After alignment treatment, a twisted nematic liquid crystal layer is provided between the two transparent substrates, and then a voltage is applied to the liquid crystal layer.
作用
上記の構成によれば ディスクリネーションラインの位
置を、同心円中心を通る直線配向方向に略平行な直線上
に安定して作成することができるので、TN液晶層の液
晶配列が良好で偏光変換性能の高い偏光素子が得られも
実施例
本発明による偏光素子の実施例について、第1図から第
4図を用いて説明すム な耘 先行例と同じ構成につい
ては同じ番号を用1.% 具体的な説明は省略すも
第1図に本発明の実施例の偏光素子を平面図および断面
構成図で示す。図において、透明基板20Aの内面側の
表面に1よ エツチング等により透明の段差部21が設
けられていも 透明基板20Aおよび段差部21と、透
明基板20Bの表面には液晶を配向させるための液晶配
向膜22、23がそれぞれ形成されており、 22の表
面には段差境界線L+と平行な矢印26方向の直線配向
戟 23の表面にはLi上の点0を中心とする同心円接
線方向(破線矢印27)の配向が施されていもさて、以
上の様に 液晶層24、25は2枚の透明基板20Aお
よび20Bにより挟まれており、同心円中心0を通り直
線L1によって分けられる2つの領域A、 Bのうち
の領域Aに属する液晶層24と、領域Bに属する液晶層
25とでGi 段差部21により液晶層の厚みが異な
っていも このような構成により、先行例と同様 同心
円周上の液晶ツイスト角θパ 領域九 Bでそれぞれθ
=−π/2からθ=π/2まで連続的に分布したTN液
晶層構造が得られ かス 液晶層24と液晶層25は段
差部21の端面部(直線L1に相当)で厚みの変化によ
り明確な不連続性をも1
従って、ディスクリネーションは 段差部21の端面部
(直線L+)上に現れやすくなるので、TN液晶構造が
所望の状態に安定して形成されることになム
また 本実施例の偏光素子でζ友 液晶層24.25を
透過した光は先行例と同様 直線配向方向26の互いに
向きの異なる電界ベクトルの光である力交 2つの領域
A、 Bでその光路長が異なっているた6 A、8
間で位相差が発生ずも しかし先行例における光学ヘッ
ド装置のごとく入力グレーティングカブラ4Cとレーザ
ー光源8との肌および出力グレーティングカブラ4Bと
集光点Fとの間の両方に直線配向方向を一致させて配置
すれば 互いに位相が補償され 完全な直線偏光の光に
変換することができも この場合、位相差板19A、1
9Bは省略できも
次に 第1図の偏光素子により、先行例における偏光素
子10Bと位相差板19Bの組合せと同様 完全な同心
円偏光と直線偏光との変換を行なう場合について考察す
も
一般?−、TN液晶層に入射側液晶分子軸と平行または
直交する電界ベクトルの直線偏光が入射し出射側分子軸
と平行または直交する電界ベクトルの直線偏光が出射す
るときへ ツイスト角θと光の波長λとの関係1i
Gooch−Tarryの式(C9H,Go。Effect: According to the above configuration, the position of the disclination line can be stably created on a straight line passing through the center of the concentric circles and approximately parallel to the straight line alignment direction, so that the liquid crystal alignment of the TN liquid crystal layer is good and polarization conversion is possible. Embodiments in which a polarizing element with high performance can be obtained An embodiment of a polarizing element according to the present invention will be explained with reference to FIGS. % Although detailed explanation will be omitted, FIG. 1 shows a polarizing element according to an embodiment of the present invention in a plan view and a cross-sectional configuration diagram. In the figure, even if a transparent stepped portion 21 is provided on the inner surface of the transparent substrate 20A by etching or the like, the transparent substrate 20A and the stepped portion 21, and the surface of the transparent substrate 20B are provided with a liquid crystal for aligning the liquid crystal. Alignment films 22 and 23 are formed respectively, and the surface of 22 has a linear orientation in the direction of arrow 26 parallel to the step boundary line L+, and the surface of 23 has a concentric circle tangential direction centered on point 0 on Li (broken line). As described above, the liquid crystal layers 24 and 25 are sandwiched between the two transparent substrates 20A and 20B, and are divided into two areas A that pass through the concentric center 0 and are separated by the straight line L1. , B. Even if the liquid crystal layer 24 belonging to area A and the liquid crystal layer 25 belonging to area B of Gi Liquid crystal twist angle θ PA Area 9 B, respectively θ
A TN liquid crystal layer structure continuously distributed from = -π/2 to θ = π/2 is obtained. Therefore, disclination tends to appear on the end face (straight line L+) of the stepped portion 21, which makes it difficult for the TN liquid crystal structure to be stably formed in the desired state. In addition, the light transmitted through the liquid crystal layer 24 and 25 in the polarizing element of this example is the same as in the previous example.The optical path of the light transmitted through the liquid crystal layer 24 and 25 is the same as in the previous example. The lengths are different 6 A, 8
However, as in the optical head device in the previous example, the linear alignment direction is made to match both the input grating cover 4C and the laser light source 8 and the output grating cover 4B and the condensing point F. If the phase difference plates 19A and 1 are arranged as shown in FIG.
9B can be omitted.Next, we will consider the case where the polarizing element shown in FIG. 1 is used to convert completely concentric circularly polarized light to linearly polarized light, similar to the combination of polarizing element 10B and retardation plate 19B in the previous example. −, when linearly polarized light with an electric field vector parallel or orthogonal to the input side liquid crystal molecular axis is incident on the TN liquid crystal layer, and linearly polarized light with an electric field vector parallel or orthogonal to the output side molecular axis is output. Twist angle θ and wavelength of light Relationship with λ1i
Gooch-Tarry formula (C9H, Go.
ch and HoA、Tarry、 ’The o
ptical property of twiste
d nematic 1iquid crystal
5tructures with twist a
ngles<90° ’ 、App1、Phys、、V
o1、8,1975.参照。 ) よ リ、
θ(1+(πdΔnバθλ))” ]’ ”2kyr
(k;整数)・・・(1)
で表わされ、L (1)式で八〇は液晶の屈折率異方
法dは液晶層の厚みを表わす。ch and HoA, Tarry, 'The o
physical property of twist
d nematic 1quid crystal
5 structures with twist a
ngles<90°', App1, Phys,,V
o1, 8, 1975. reference. ) yo ri, θ(1+(πdΔnbaθλ))” ]' “2kyr
(k; integer) (1) In the formula L (1), 80 represents the refractive index difference of the liquid crystal, and d represents the thickness of the liquid crystal layer.
(1)式を変形すると、(2)式のように表わせムλ−
Δnd(4k”−θ”/rr ”)−””
・・・(2)(2)式より、 λはθに対し θ=0
を極小値とした下に凸の曲線を描く。By transforming equation (1), it can be expressed as equation (2), where λ−
Δnd(4k"-θ"/rr")-""
...(2) From equation (2), λ is θ=0 for θ
Draw a downward convex curve with the minimum value.
−X 本発明の偏光素子は液晶層のツイスト角θバ
−π/2≦θ≦π/2の範囲で連続的に分布しているの
六 〇=0のときλは極小値(=λ重)、θ=土π/2
のときλは極大値(=λa)をとも 従って、使用する
光源の波長をλとすると、 λ1≦λ≦λ虚の関係を満
たすように液晶層のΔnd値を設定すればよt〜
すなわ板
θ=0のとき(1)弐Cよ
Δnd(2k)−’−λ (−λ+) (k;自然数
) −−−(3)θ=π/2のとき(1)式は
△nd(4k” −174)−” ”−λ (−λ2)
−−−(4)(k;自然数)
であるので、下記の(5)式の条件を満たすことで良好
な偏光変換が実現できも
(4k”−1/4)”’≦Δnd/λ≦2k
−・(5)(k:自然数)
以上のことか収 第1図に示す偏光素子の液晶層24.
25力丈 それぞれ(6)! (7)式を満足してい
ることが望まししも
(16に+”−1)””≦2△nch/λ≦4に+
−−−(a)(kB自然数)
(18に2”−1)””≦2△nds/λ≦4に2”(
7)(k2;自然数)
さらに 透明段差部21に先行例の位相差板19Bの機
能をもたせるために 位相差板19Bの屈折率を氏 レ
ーザー光の波長をλとすると、段差部21を透過する側
の光と透過しない側の光の位相差力(2yr(n+−n
o)ld+−dalであるか収(n+ −no )ld
+ −d21 = (2kg −1)λ/2 ・−(
8)(k3;自然数)
の関係を満すように作成すれば 領域A、 Bを透過
する光の位相が揃った 完全な同心円偏光と直線偏光へ
の変換ができも
第2図は本発明の他の実施例である偏光素子の断面構成
図であり、図のように2枚の透明基板20A(直線配向
側)、 20B(同心円配向側)の液晶配向面のう−直
線配向側の基板20A上に同心円中心を通る直線配向方
向の直線凹部50また(友 直線凸部51を設けられて
いも このような構成によってL 凹部50または凸部
51により液晶層52の厚みが変化していることでディ
スクリネーシーンラインが凹部50または凸部51に沿
って安定されも
第3図は更に実施例である偏光素子の直線配向面の配向
方法を示す図であも 図において基板31の表面にはポ
リイミド等の有機配向膜がスピンコード等により塗布さ
れていも
この基板31をナイロン製の布などでラビングし 直線
方向の配向処理を施す暇 図のようにま哄 基板31の
半分の領域Aを薄板材30で覆t\薄板材30の直線状
端面L2に対して2〜3 (deg)程度(図中時計回
りを正とする)傾いたPb方向にラビングすム 次にラ
ビングした領域を薄板材30で覆(X 領域Bを直線L
2に対して−2〜−3(deg)程度類いた方向P−に
ラビングする。-X The polarizing element of the present invention has a twist angle θ balance of the liquid crystal layer.
It is continuously distributed in the range of −π/2≦θ≦π/2.When 〇=0, λ is the minimum value (=λ weight), θ=Sat π/2
When λ has a maximum value (=λa), therefore, if the wavelength of the light source used is λ, the Δnd value of the liquid crystal layer should be set so as to satisfy the relationship λ1≦λ≦λimaginary. When plate θ = 0, (1) 2C Δnd (2k) -'-λ (-λ+) (k: natural number) --- (3) When θ = π/2, equation (1) becomes △nd ( 4k"-174)-""-λ (-λ2)
--- (4) (k: natural number), so good polarization conversion can be achieved by satisfying the condition of equation (5) below (4k"-1/4)"'≦Δnd/λ≦ 2k
-.(5) (k: natural number) The above is the conclusion of the liquid crystal layer 24 of the polarizing element shown in FIG.
25 strength lengths (6) each! It is desirable that the formula (7) is satisfied, but (16+”-1)””≦2△nch/λ≦4+
---(a) (kB natural number) (18 to 2"-1)""≦2△nds/λ≦4 to 2" (
7) (k2; natural number) Furthermore, in order to give the transparent stepped portion 21 the function of the retardation plate 19B of the previous example, if the refractive index of the retardation plate 19B is λ and the wavelength of the laser beam is λ, then the laser beam passes through the stepped portion 21. Phase difference force between the light on the side and the light on the non-transparent side (2yr(n+-n
o) Is ld+-dal or is (n+-no)ld
+ -d21 = (2kg -1)λ/2 ・-(
8) If it is created to satisfy the relationship (k3: natural number), it is possible to convert the light passing through areas A and B into completely concentric circularly polarized light and linearly polarized light with the same phase. It is a cross-sectional configuration diagram of a polarizing element that is another example, and as shown in the figure, a substrate 20A on the linear alignment side of the liquid crystal alignment surface of two transparent substrates 20A (linear alignment side) and 20B (concentric alignment side). Even if a linear concave portion 50 or a linear convex portion 51 is provided on the top in the linear alignment direction passing through the center of the concentric circle, the thickness of the liquid crystal layer 52 is changed by the concave portion 50 or the convex portion 51 due to such a configuration. Although the disclination scene line is stabilized along the concave portion 50 or the convex portion 51, FIG. Even if an organic alignment film such as the above is applied using a spin cord or the like, the substrate 31 is rubbed with a nylon cloth or the like to align it in the linear direction. 30, rub in the Pb direction that is inclined by about 2 to 3 degrees (clockwise in the figure is positive) with respect to the linear end surface L2 of the thin plate 30. Next, apply the rubbed area to the thin plate 30. Cover (X area B with straight line L
Rubbing is performed in a direction P- which is approximately -2 to -3 (deg) similar to that of 2.
この紘 基板31を同心円接線方向の配向を施したもう
一枚の基板と貼合わせる際 領域Aと領域Bの境界が同
心円の中心軸と交わるようにアライメントし 液晶材料
シール材を介して貼合わせも 直線配向面にこのよう
な配向処理を施すことで、直線L2上の領域では直線配
向面近傍の液晶分子の向きが不連続であることから直線
Le上にディスクリネーションラインが安定して形成さ
れも一人 先行例の偏光素子について、その製造方法に
工夫を施すことによってk ディスクリネーションライ
ンの位置を安定に作成することができも
第4図は 偏光素子を作成した夜 液晶材料のN−I点
(液晶の光学的異方性が消失する温度)まで液晶を一旦
加熱し その檄 徐冷した場合のディスクリネーション
ラインの変化を示す図であも 同図(a)は加熱前の状
態を示し 同図(b)は加熱後の状態を示す。図のよう
に素子を加賑徐冷することで、液晶注入時の流動性や液
晶配向面の表面等により生じた液晶層の弾性エネルギの
不均衡状態を解除し 液晶を所望の状態に再配列するこ
とができも
また 液晶層を挟む透明基板上にITO等の透明導電膜
を設(す、偏光素子を作成檄 この透明導電膜により液
晶層−に1度または数度にわたり、電圧を印加すること
によっても液晶の再配列により、第4図のごとく直線L
s上にディスクリネーションラインを作成できも
発明の効果
本発明によれば ディスクリネーションラインの位置の
不安定性をなくし 液晶ツイスト角が所定の位置でより
安定した状態で偏光素子を作成することができるので、
高い同心円偏光と直線偏光との偏光変換性能を有する偏
光素子が実現されその効果は非常に太き(tWhen bonding this Hiro substrate 31 to another substrate oriented in the tangential direction of the concentric circles, alignment is made so that the boundary between area A and area B intersects with the center axis of the concentric circle, and the liquid crystal material is bonded via a sealing material. By performing such an alignment treatment on the linearly aligned surface, a disclination line can be stably formed on the straight line Le since the orientation of liquid crystal molecules near the linearly aligned surface is discontinuous in the region on the straight line L2. For the polarizing element of the previous example, by devising the manufacturing method, it was possible to create a stable position of the disclination line. Figure 4 shows the N-I of the liquid crystal material This figure shows the change in the disclination line when the liquid crystal is heated to a point (the temperature at which the optical anisotropy of the liquid crystal disappears) and then slowly cooled. Figure (a) shows the state before heating. Figure (b) shows the state after heating. By heating and slowly cooling the device as shown in the figure, the imbalance in the elastic energy of the liquid crystal layer caused by the fluidity during liquid crystal injection and the surface of the liquid crystal alignment surface is released, and the liquid crystal is rearranged to the desired state. It is also possible to create a polarizing element by providing a transparent conductive film such as ITO on transparent substrates that sandwich a liquid crystal layer.A voltage is applied to the liquid crystal layer once or several times using this transparent conductive film. In particular, due to the rearrangement of the liquid crystal, the straight line L as shown in Figure 4
Effects of the Invention According to the present invention, it is possible to eliminate the instability of the position of the disclination line and create a polarizing element with the liquid crystal twist angle more stable at a predetermined position. Because you can
A polarizing element with high polarization conversion performance between concentric circularly polarized light and linearly polarized light has been realized, and its effect is extremely large (t
第3図は更に他の実施例における配向方法を示す工程説
明医 第4図は本発明の偏光素子の製造方法の一実施例
におけるディスクリネーションラインの変化医 第5図
Cヨ 先行例の偏光素子およびそれを用いた光学ヘッ
ド装置の側断面医 第6図は第5図の光学ヘッド装置の
集光位置での光強度分布医 第7図(友 先行例の偏光
素子の偏光変換性能医 第8図は先行例の偏光素子の液
晶ツイスト角分布l 第9図はディスクリネーションラ
インの変動図であも
■・・・Si基板 2・・・低屈折率の透明# 3A、
3B、3C・・・高屈折率の透明[4A、4B、4C・
・・グレーティングカプラ、 L・・・中心$111
5A、5B、5C・・・低屈折率の透明W/L 6A、
6B・・・光検出銖 7・・・反射風 8・・・半導体
レーザー、 9・・・集光レン、CIOA、 10&
・・・偏光素子、 11・・・入力元 12C,18A
、18B・・・導波光 13・・・放射光 16・・・
光デイスク反射面 17A、17B・・・反射119A
、 19B・・・位相差板21・・・透明段差部 24
、25・・・液晶層 26.27・・・液晶配向方陳
50・・・直線凹脈 51・・・直線5昆
代理人の氏名 弁理士 粟野重孝 はか1名第1図
XIAお8
n、23
N、25
為、27
r
i!1111暮仮
段 惇 部
牽晶配向−
漠晶層
潅晶配置11方呵
1911Q 牲−
第
図
第
図
2−* * 口 卸
51−−− a輪凸部
52− 漬晶壜
0g
0B
第
図
暮
伝
帖
図
り
軸
(り
一)(μm)
−(り
軸)(μm)
第
図FIG. 3 shows a process explanation showing an orientation method in another embodiment. FIG. 4 shows a change in the disclination line in an embodiment of the method for manufacturing a polarizing element of the present invention. FIG. Figure 6 shows the light intensity distribution at the condensing position of the optical head device shown in Figure 5. Figure 7 shows the polarization conversion performance of the polarizing element in the previous example. Figure 8 shows the liquid crystal twist angle distribution l of the polarizing element of the previous example. Figure 9 shows the variation of the disclination line.■...Si substrate 2...Transparent #3A with low refractive index,
3B, 3C...High refractive index transparent [4A, 4B, 4C...
・Grating coupler, L...center $111
5A, 5B, 5C...low refractive index transparent W/L 6A,
6B...Photodetection bolt 7...Reflected wind 8...Semiconductor laser, 9...Condensing lens, CIOA, 10&
...Polarizing element, 11...Input source 12C, 18A
, 18B... Guided light 13... Synchrotron radiation 16...
Optical disk reflective surface 17A, 17B...reflection 119A
, 19B... Retardation plate 21... Transparent stepped portion 24
, 25...Liquid crystal layer 26.27...Liquid crystal alignment direction
50...Straight concave vein 51...Straight line 5Kon Name of agent Patent attorney Shigetaka Awano 1 person Figure 1 XIA 8 n, 23 N, 25 To, 27 r i! 1111 Close-up part Tilt crystal orientation- Obscure crystal layer diagonal crystal arrangement 11 squares 1911Q sacrifice- Figure Figure 2-* Dencho drawing axis (riichi) (μm) - (ritsu axis) (μm) Fig.
Claims (6)
同心円の接線方向の配向である配向面間にツイスト・ネ
マチック液晶層を有する偏光素子であって、前記同心円
の中心を通り前記直線方向に略平行な直線で分けられる
2つの領域で液晶層の厚みが異なることを特徴とする偏
光素子。(1) A polarizing element having a twisted nematic liquid crystal layer between a pair of liquid crystal alignment surfaces, one of which is aligned in a linear direction and the other aligned in a tangential direction of a concentric circle, wherein the straight line passes through the center of the concentric circle. A polarizing element characterized in that a liquid crystal layer has a different thickness in two regions separated by a straight line substantially parallel to the direction.
部を配置することで前記2つの領域間の液晶層の厚みを
異ならせると共に、透明な段差部の屈折率をn、前記ツ
イスト・ネマチック液晶層の屈折率異方性をΔn(=n
_o−n_o)、前記2つの領域の液晶層の厚みをd_
1、d_2、光の波長をλとして、これらの値が (16k_1^2−1)^1^/^≦2Δnd_1/λ
≦4k_1かつ (16k_2^2−1)^1^/^2≦2Δnd_2/
λ≦4k_2かつ |n−n_o||d_2−d_1|=(2k_3−1)
λ/2(または|n−n_o||d_2−d_1|=(
2k_3−1)λ/2)(k_1、k_2、k_3;自
然数) の関係を満たすことを特徴とする請求項1記載の偏光素
子。(2) By arranging a transparent stepped portion adjacent to the liquid crystal layer in one of the two regions, the thickness of the liquid crystal layer between the two regions is made different, and the refractive index of the transparent stepped portion is set to n, The refractive index anisotropy of the twisted nematic liquid crystal layer is expressed as Δn (=n
___o−n_o), the thickness of the liquid crystal layer in the two regions is d_
1, d_2, and the wavelength of light is λ, these values are (16k_1^2-1)^1^/^≦2Δnd_1/λ
≦4k_1 and (16k_2^2-1)^1^/^2≦2Δnd_2/
λ≦4k_2 and |n−n_o||d_2−d_1|=(2k_3−1)
λ/2 (or |n-n_o||d_2-d_1|=(
2k_3-1)λ/2)(k_1, k_2, k_3; natural numbers) The polarizing element according to claim 1, wherein the polarizing element satisfies the following relationship.
同心円の接線方向の配向である液晶配向面間にツイスト
・ネマチック液晶層を有する偏光素子であって、直線配
向面に、同心円中心を通り前記直線配向方向に略平行な
直線状の凹部または凸部を形成したことを特徴とする偏
光素子。(3) A polarizing element having a twisted nematic liquid crystal layer between a pair of liquid crystal alignment surfaces, one of which is oriented in a linear direction and the other in a tangential direction of a concentric circle, with the center of the concentric circle on the linear alignment surface. A polarizing element characterized in that a linear concave portion or convex portion is formed passing through the linear alignment direction and substantially parallel to the linear alignment direction.
同心円の接線方向の配向である液晶配向面間にツイスト
・ネマチック液晶層を有する偏光素子であって、前記同
心円中心を通り前記直線方向に略平行な直線によって分
けられる液晶層の2つの領域で直線配向方向が異なるこ
とを特徴とする偏光素子。(4) A polarizing element having a twisted nematic liquid crystal layer between a pair of liquid crystal alignment surfaces in which one of the liquid crystal alignment surfaces is aligned in a linear direction and the other is aligned in a tangential direction of a concentric circle, wherein the straight line passes through the center of the concentric circle. A polarizing element characterized in that two regions of a liquid crystal layer separated by a straight line substantially parallel to the direction have different linear alignment directions.
同心円の接線方向の配向処理を施した2枚の透明基板間
にツイスト・ネマチック液晶層を設けてなる偏光素子の
製造方法であって、前記2枚の透明基板間に液晶を封入
した後、液晶をN−I点近傍に加熱したのち冷却する熱
処理を施すことを特徴とする偏光素子の製造方法。(5) A method for manufacturing a polarizing element, in which a twisted nematic liquid crystal layer is provided between two transparent substrates that have been subjected to alignment treatment in a linear direction on one of a pair of liquid crystal alignment surfaces and in a concentric tangential direction on the other. A method for manufacturing a polarizing element, comprising: sealing a liquid crystal between the two transparent substrates, and then subjecting the liquid crystal to heat treatment in which the liquid crystal is heated to near the N-I point and then cooled.
に直線方向、もう一方に同心円の接線方向の配向処理を
施した後、前記2枚の透明基板間にツイスト・ネマチッ
ク液晶層を設けてなる偏光素子の製造方法であって、前
記2枚の透明基板間に液晶を封入した後、前記液晶層に
電圧を印加して液晶を再配列させる工程を実施すること
を特徴とする偏光素子の製造方法。(6) After performing alignment treatment on one of two transparent substrates having a transparent conductive film on the surface in a linear direction and in a concentric tangential direction on the other, a twisted nematic liquid crystal layer is placed between the two transparent substrates. A method for manufacturing a polarizing element, comprising: sealing a liquid crystal between the two transparent substrates, and then applying a voltage to the liquid crystal layer to rearrange the liquid crystal. Method of manufacturing elements.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2164703A JPH0453905A (en) | 1990-06-22 | 1990-06-22 | Polarizing element and its manufacture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2164703A JPH0453905A (en) | 1990-06-22 | 1990-06-22 | Polarizing element and its manufacture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0453905A true JPH0453905A (en) | 1992-02-21 |
Family
ID=15798271
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2164703A Pending JPH0453905A (en) | 1990-06-22 | 1990-06-22 | Polarizing element and its manufacture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0453905A (en) |
-
1990
- 1990-06-22 JP JP2164703A patent/JPH0453905A/en active Pending
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