JPH0465664B2 - - Google Patents

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Publication number
JPH0465664B2
JPH0465664B2 JP61002389A JP238986A JPH0465664B2 JP H0465664 B2 JPH0465664 B2 JP H0465664B2 JP 61002389 A JP61002389 A JP 61002389A JP 238986 A JP238986 A JP 238986A JP H0465664 B2 JPH0465664 B2 JP H0465664B2
Authority
JP
Japan
Prior art keywords
tofu
antifoaming
antifoaming agent
present
defoaming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP61002389A
Other languages
Japanese (ja)
Other versions
JPS62163667A (en
Inventor
Hiroaki Nishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Riken Vitamin Co Ltd
Original Assignee
Riken Vitamin Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Riken Vitamin Co Ltd filed Critical Riken Vitamin Co Ltd
Priority to JP61002389A priority Critical patent/JPS62163667A/en
Publication of JPS62163667A publication Critical patent/JPS62163667A/en
Publication of JPH0465664B2 publication Critical patent/JPH0465664B2/ja
Granted legal-status Critical Current

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Description

【発明の詳細な説明】[Detailed description of the invention]

〔産業上の利用分野〕 本発明は豆腐用消泡剤に関する。 詳しくは大豆、脱脂大豆その他の植物蛋白水溶
液を加熱した時に生ずる泡及び豆乳落下時に生ず
る泡を抑泡消失させる豆腐用消泡剤であつて、カ
ルナバロウ、蜜ロウ、米ヌカロウ等の脂肪酸と高
級アルコールのエステルを含む高融点脂質の単体
又は混合物と炭酸マグネシウムを必須成分として
配合してなる豆腐用消泡剤に関する。 〔従来の技術〕 豆腐業界では、油揚げの廃油などに石灰などを
混合した廃油系消泡剤、グリセリン脂肪酸エステ
ルを主成分としたグリセリン脂肪酸エステル系消
泡剤(特公開58−9430、特公開58−89150)、シリ
コーン樹脂を主成分としたシリコーン系消泡剤が
使用されている(特公昭58−41821)。 このうち廃油系消泡剤は酸価、過酸化物価が高
く、食品である豆腐の製造工程に使用することは
食品衛生上好ましくない。 グリセリン脂肪酸エステル系消泡剤について
は、グリセリン脂肪酸エステルのみでは消泡力が
充分でなく消泡力を高めるためにシリコーン樹脂
などを配合した製剤の形をとつている。 しかしシリコーン樹脂を使うと製品価格が高く
なるなどの問題を抱えている。 〔発明が解決しようとする問題点〕 本発明によると廃油形消泡剤などにみられる酸
価、過酸化物価を抑え、食品衛生上好ましい消泡
剤を得ることができる。 又シリコーン樹脂を原料として使用しなくとも
高い消泡性能が発揮され添加コストも従来のもの
より安価である。 〔問題点を解決するための手段〕 本発明者は前記の問題点を解決すべく鋭意検討
した結果、カルナバロウ、蜜ロウ、米ヌカロウ等
の脂肪酸と高級アルコールのエステルを含む高融
点脂質の単体又は混合物と炭酸マグネシウムを必
須成分として配合することにより良好な消泡性能
を示すことを見い出した。 これは従来の炭酸カルシウムなどのカルシウム
塩類を用いる場合より、はるかに良い消泡性能が
得られることが実験的に証明された。 マグネシウム塩、カルシウム塩など無機塩類の
働きは消泡に必要な成分を表面に吸着し、ご又は
豆乳内に均一に分散させること、そして吸着した
消泡成分を容易に脱着させないことが必要条件と
なるが本発明の高融点脂質と配合した場合炭酸マ
グネシウムがカルシウム塩類より優れていること
が認められた。その優位性は豆腐製造プラントに
おいても実証された。 本発明でいう高融点脂質とは、カルナバロウ、
蜜ロウ、米ヌカロウ等の脂肪酸と高級アルコール
のエステルを含み、酸価が1以上、融点が60℃以
上の固型脂である。 本発明で高融点脂質と炭酸マグネスムとの配合
比は95:5〜50:50の範囲で好ましくは95:5〜
70:30である。炭酸マグネシウムが5以下及び50
以上では消泡力が劣る。 またこのような混合物にさらに動植物油、乳化
剤などを加えてもよい。 動植物油とは、天然の油脂、例えばヤシ油、パ
ーム核油、パーム油、大豆油、綿実油、ナタネ
油、牛脂、ラード、魚油など、またこれらの硬化
油の1種又は2種以上の混合物でもよい。 乳化剤としては、大豆リン脂質、グリセリン脂
肪酸エステル、シヨ糖脂肪酸エステル、ソルビタ
ン脂肪酸エステル、プロピレングリコール脂肪酸
エステルなどであり、これらを添加してもよい。 本発明でいう豆腐用消泡剤は、木綿豆腐、絹ご
し豆腐、ソフト豆腐、充填豆腐などの豆腐類、油
揚、凍豆腐、豆乳飲料などの豆腐類の製造の際使
用できる。 本発明の豆腐用消泡剤の使用量は、原料生大豆
に対し0.1〜1.5%重量%、好ましくは0.2〜0.8重
量%の割合で添加すれば豆腐類製造工程中の発泡
を抑えることができる。 〔実施例〕 以下、実施例によつて本発明を説明する。 実施例 1 表−1に記載した各消泡剤の配合成分は80℃−
90℃に加熱溶融し、均一混合したのち20℃以下の
雰囲気の中に噴霧して粉末(ビーズ)とする。 消泡試験−1 蒸着時の消泡試験方法 各試験当り生大豆7Kgを流水中に10時間浸漬漬
して得た浸漬大豆に水を加えながら磨砕し、42Kg
の〔ご〕を得る。 これに対し表−1に示した本発明品、又は比較
消泡剤をそれぞれ42Kg(生大豆に対し0.6%)加
え、開放釜中で加熱し90℃に達してから6分間加
熱し、その間の釜中の泡の高さの最高値を測定す
る。 消泡試験−2 豆乳落下時の消泡試験法 消泡試験−1終了後の〔ご〕を絞り機で絞り、
得られた豆乳1Kgを1mの高さよりロートを通し
て2000ml容メスシリンダー中に落下させ、落下直
後及び1分後の泡の量(ml)を測定した。 表−1に示した本発明消泡剤及び比較例消泡剤
の試験結果は表−2に示した。 表−2の結果から明らかなように本発明消泡剤
の消泡力が優れていることがわかる。
[Industrial Field of Application] The present invention relates to an antifoaming agent for tofu. More specifically, it is an antifoaming agent for tofu that suppresses and eliminates the foam that occurs when soybeans, defatted soybeans, and other vegetable protein aqueous solutions are heated, and the foam that occurs when soymilk falls. The present invention relates to an antifoaming agent for tofu, which comprises a high melting point lipid alone or a mixture containing an ester of the above and magnesium carbonate as essential components. [Prior art] In the tofu industry, there are waste oil-based defoaming agents made by mixing waste oil from deep-frying with lime, etc., and glycerin fatty acid ester-based defoaming agents whose main component is glycerin fatty acid ester (Japanese Patent Publication No. 58-9430, Japanese Patent Publication No. 58). -89150), silicone antifoaming agents containing silicone resin as the main component are used (Japanese Patent Publication No. 58-41821). Among these, waste oil-based antifoaming agents have high acid values and peroxide values, and their use in the manufacturing process of tofu, which is a food product, is undesirable from the viewpoint of food hygiene. Regarding glycerin fatty acid ester antifoaming agents, glycerin fatty acid esters alone do not have sufficient antifoaming power, and in order to increase the antifoaming power, formulations containing silicone resins and the like are used. However, using silicone resin has problems such as higher product prices. [Problems to be Solved by the Invention] According to the present invention, it is possible to suppress the acid value and peroxide value found in waste oil-type defoaming agents, etc., and to obtain a defoaming agent that is preferable from the viewpoint of food hygiene. Furthermore, high antifoaming performance can be achieved without using silicone resin as a raw material, and the cost of addition is lower than that of conventional products. [Means for Solving the Problems] As a result of intensive studies to solve the above-mentioned problems, the inventors of the present invention have found that a simple substance or a high-melting-point lipid containing an ester of a fatty acid and a higher alcohol such as carnauba wax, beeswax, and rice bran wax, etc. It has been found that good antifoaming performance can be exhibited by blending the mixture with magnesium carbonate as an essential component. This has been experimentally proven to provide much better defoaming performance than conventional calcium salts such as calcium carbonate. The function of inorganic salts such as magnesium salts and calcium salts is to adsorb the components necessary for defoaming on the surface, to disperse them uniformly in the soybean milk, and to prevent the adsorbed defoaming components from being easily desorbed. However, it has been observed that magnesium carbonate is superior to calcium salts when blended with the high melting point lipids of the present invention. Its superiority has also been demonstrated in tofu manufacturing plants. The high melting point lipids in the present invention include carnauba wax,
It is a solid fat containing esters of fatty acids and higher alcohols such as beeswax and rice bran wax, and has an acid value of 1 or higher and a melting point of 60°C or higher. In the present invention, the blending ratio of high melting point lipid and magnesium carbonate is in the range of 95:5 to 50:50, preferably 95:5 to
It is 70:30. Magnesium carbonate is 5 or less and 50
Above this value, the antifoaming power is poor. Moreover, animal and vegetable oils, emulsifiers, etc. may be further added to such a mixture. Animal and vegetable oils include natural fats and oils such as coconut oil, palm kernel oil, palm oil, soybean oil, cottonseed oil, rapeseed oil, beef tallow, lard, and fish oil, as well as one or a mixture of two or more of these hydrogenated oils. good. Examples of emulsifiers include soybean phospholipids, glycerin fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, propylene glycol fatty acid esters, etc., and these may be added. The antifoaming agent for tofu according to the present invention can be used in the production of tofu such as firm tofu, silken tofu, soft tofu, and stuffed tofu, as well as tofu such as fried tofu, frozen tofu, and soy milk drinks. The amount of the antifoaming agent for tofu of the present invention to be used is 0.1 to 1.5% by weight, preferably 0.2 to 0.8% by weight, based on raw raw soybeans to suppress foaming during the tofu manufacturing process. . [Example] The present invention will be described below with reference to Examples. Example 1 The ingredients of each antifoaming agent listed in Table-1 are 80℃-
Melt by heating to 90°C, mix uniformly, and then spray into an atmosphere below 20°C to form powder (beads). Defoaming test-1 Defoaming test method during vapor deposition For each test, 7 kg of raw soybeans were immersed in running water for 10 hours, and the soaked soybeans were ground while adding water.
obtain the [honor] of To this, 42 kg (0.6% based on raw soybeans) of the present invention product or comparative antifoaming agent shown in Table 1 was added, heated in an open pot until the temperature reached 90°C, and then heated for 6 minutes. Measure the maximum height of bubbles in the pot. Defoaming test-2 Defoaming test method when soy milk falls After defoaming test-1, squeeze out the rice with a squeezing machine,
1 kg of the obtained soymilk was dropped from a height of 1 m through a funnel into a 2000 ml graduated cylinder, and the amount of foam (ml) immediately after dropping and 1 minute later was measured. The test results of the antifoaming agent of the present invention and the comparative antifoaming agent shown in Table-1 are shown in Table-2. As is clear from the results in Table 2, it can be seen that the antifoaming agent of the present invention has excellent antifoaming power.

【表】【table】

【表】【table】

【表】【table】

【表】 実施例 2 大豆リン脂質5Kg、米ヌカロウ10Kg、炭酸マグ
ネシウム20Kg、魚油硬化脂65Kgを加熱溶融し(80
〜90℃)、均一混合したのち、20℃以下の雰囲気
の中で噴霧して粉末(ビーズ)を得た。 前記の如く得た粉末(ビーズ)と市販廃油系消
泡剤との比較試験を行なつた。 消泡剤の添加量は生大豆に対し0.6%、豆乳濃
度10.5%で豆腐を製造した。 表−3に消泡試験の結果を示す。 本発明品は蒸着時又は落下時の消泡性に優れ、
良い品質の豆腐が得られた。
[Table] Example 2 Heat and melt 5 kg of soybean phospholipids, 10 kg of rice bran wax, 20 kg of magnesium carbonate, and 65 kg of hydrogenated fish oil (80 kg of hydrogenated fish oil).
~90°C), then mixed uniformly and then sprayed in an atmosphere of 20°C or lower to obtain powder (beads). A comparative test was conducted between the powder (beads) obtained as described above and a commercially available waste oil-based antifoaming agent. The amount of antifoaming agent added was 0.6% to raw soybeans, and tofu was produced with a soymilk concentration of 10.5%. Table 3 shows the results of the defoaming test. The product of the present invention has excellent defoaming properties during vapor deposition or dropping,
Good quality tofu was obtained.

〔発明の効果〕〔Effect of the invention〕

実施例1および2より明らかな如く、本発明品
の消泡効果が優れていることがわかる。豆腐の内
相はきめが細かく、又外観はつやがある。豆腐の
テキスチユアーは弾力があり、好ましい食感であ
る。 又本発明品は油揚製造時にも使用でき、出来上
つた製品の揚げ色は黄金色で、又食感もソフトで
好ましいなど改良効果が認められる。 本発明品は酸価、過酸化物価が低く、食品衛生
上好ましいこと、又シリコーン樹脂を用いずとも
高い消泡性が得られ添加コストも安価である。
As is clear from Examples 1 and 2, it can be seen that the antifoaming effect of the product of the present invention is excellent. Tofu has a fine texture and a shiny exterior. The tofu texture is elastic and has a pleasant texture. The product of the present invention can also be used in the production of fried tofu, and the improved effects of the fried tofu product include a golden yellow color and a soft and pleasant texture. The product of the present invention has a low acid value and peroxide value, which is preferable in terms of food hygiene.Also, high antifoaming properties can be obtained without using silicone resin, and the addition cost is low.

Claims (1)

【特許請求の範囲】 1 カルナバロウ、密ロウ、米ヌカロウ等の脂肪
酸と高級アルコールのエステルを含む高融点脂質
の単体又は混合物と炭酸マグネシウムを必須成分
として配合してなる豆腐用消泡剤。 2 カルナバロウ、密ロウ、米ヌカロウ等の脂肪
酸と高級アルコールのエステルを含む高融点脂質
の単体又は混合物と炭酸マグネシウムとの比が
95:5〜50:50である特許請求の範囲第1項記載
の豆腐用消泡剤。
[Scope of Claims] 1. An antifoaming agent for tofu, comprising a single substance or a mixture of high melting point lipids containing esters of fatty acids and higher alcohols such as carnauba wax, beeswax, and rice bran wax, and magnesium carbonate as essential components. 2. The ratio of a single substance or a mixture of high melting point lipids containing esters of fatty acids and higher alcohols such as carnauba wax, beeswax, and rice bran wax to magnesium carbonate is
The antifoaming agent for tofu according to claim 1, which has a ratio of 95:5 to 50:50.
JP61002389A 1986-01-09 1986-01-09 Antifoaming agent for tofu Granted JPS62163667A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP61002389A JPS62163667A (en) 1986-01-09 1986-01-09 Antifoaming agent for tofu

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP61002389A JPS62163667A (en) 1986-01-09 1986-01-09 Antifoaming agent for tofu

Publications (2)

Publication Number Publication Date
JPS62163667A JPS62163667A (en) 1987-07-20
JPH0465664B2 true JPH0465664B2 (en) 1992-10-20

Family

ID=11527874

Family Applications (1)

Application Number Title Priority Date Filing Date
JP61002389A Granted JPS62163667A (en) 1986-01-09 1986-01-09 Antifoaming agent for tofu

Country Status (1)

Country Link
JP (1) JPS62163667A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101721697B1 (en) * 2016-01-18 2017-03-30 한남대학교 산학협력단 Flow channel design of capacitive deionization unit

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6030595B2 (en) * 2014-03-31 2016-11-24 泰喜物産株式会社 Coagulant composition for tofu and method for producing tofu using the same
JP6600496B2 (en) * 2015-07-01 2019-10-30 理研ビタミン株式会社 Coagulant preparation for tofu
JP6298948B2 (en) * 2015-07-23 2018-03-28 サンノプコ株式会社 Antifoam
US9848617B1 (en) 2016-10-11 2017-12-26 Taiki Product, Inc. Coagulant composition for tofu and method of producing tofu using the same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5915100B2 (en) * 1976-06-30 1984-04-07 株式会社東芝 Glass fiber for optical communication

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101721697B1 (en) * 2016-01-18 2017-03-30 한남대학교 산학협력단 Flow channel design of capacitive deionization unit

Also Published As

Publication number Publication date
JPS62163667A (en) 1987-07-20

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