JPH0471431B2 - - Google Patents

Info

Publication number: JPH0471431B2
Authority: JP; Japan
Prior art keywords: group; dye; copper phthalocyanine; lenses; hours
Prior art date: 1986-05-14
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

JP10860086A

Other languages

English (en)

Japanese (ja)

Other versions

JPS62265357A (ja

Inventor

Takanori Shibata

Yoshitaka Tanyama

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Menicon Co Ltd

Original Assignee

Toyo Contact Lens Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1986-05-14

Filing date

1986-05-14

Publication date

1992-11-13

1986-05-14 Application filed by Toyo Contact Lens Co Ltd filed Critical Toyo Contact Lens Co Ltd

1986-05-14 Priority to JP10860086A priority Critical patent/JPS62265357A/ja

1987-11-18 Publication of JPS62265357A publication Critical patent/JPS62265357A/ja

1992-11-13 Publication of JPH0471431B2 publication Critical patent/JPH0471431B2/ja

Status Granted legal-status Critical Current

Links

RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical class [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 claims description 19
-1 1-methylvinyl group Chemical group 0.000 claims description 6
125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 claims description 6
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
125000000217 alkyl group Chemical group 0.000 claims description 2
125000004432 carbon atom Chemical group C* 0.000 claims description 2
125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
239000000975 dye Substances 0.000 description 24
239000000178 monomer Substances 0.000 description 13
229920000642 polymer Polymers 0.000 description 7
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 6
WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 6
ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
230000015572 biosynthetic process Effects 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
239000000463 material Substances 0.000 description 5
GUAQVFRUPZBRJQ-UHFFFAOYSA-N n-(3-aminopropyl)-2-methylprop-2-enamide Chemical compound CC(=C)C(=O)NCCCN GUAQVFRUPZBRJQ-UHFFFAOYSA-N 0.000 description 5
238000003786 synthesis reaction Methods 0.000 description 5
125000002252 acyl group Chemical group 0.000 description 4
239000007788 liquid Substances 0.000 description 4
239000000203 mixture Substances 0.000 description 4
GNWBLLYJQXKPIP-ZOGIJGBBSA-N (1s,3as,3bs,5ar,9ar,9bs,11as)-n,n-diethyl-6,9a,11a-trimethyl-7-oxo-2,3,3a,3b,4,5,5a,8,9,9b,10,11-dodecahydro-1h-indeno[5,4-f]quinoline-1-carboxamide Chemical compound CN([C@@H]1CC2)C(=O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H](C(=O)N(CC)CC)[C@@]2(C)CC1 GNWBLLYJQXKPIP-ZOGIJGBBSA-N 0.000 description 3
SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 3
230000000694 effects Effects 0.000 description 3
IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 3
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
208000006992 Color Vision Defects Diseases 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
238000000862 absorption spectrum Methods 0.000 description 2
150000001408 amides Chemical class 0.000 description 2
239000001000 anthraquinone dye Substances 0.000 description 2
238000006243 chemical reaction Methods 0.000 description 2
201000007254 color blindness Diseases 0.000 description 2
238000001816 cooling Methods 0.000 description 2
GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 2
UJKWLAZYSLJTKA-UHFFFAOYSA-N edma Chemical compound O1CCOC2=CC(CC(C)NC)=CC=C21 UJKWLAZYSLJTKA-UHFFFAOYSA-N 0.000 description 2
238000010828 elution Methods 0.000 description 2
238000009472 formulation Methods 0.000 description 2
238000000034 method Methods 0.000 description 2
239000002504 physiological saline solution Substances 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
239000000243 solution Substances 0.000 description 2
238000003756 stirring Methods 0.000 description 2
125000000542 sulfonic acid group Chemical group 0.000 description 2
AFXKUUDFKHVAGI-UHFFFAOYSA-N 1-methyl-3-methylidenepyrrolidin-2-one Chemical compound CN1CCC(=C)C1=O AFXKUUDFKHVAGI-UHFFFAOYSA-N 0.000 description 1
NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 1
DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
BONIIQYTWOPUQI-UHFFFAOYSA-N 4-nitroisoindole-1,3-dione Chemical compound [O-][N+](=O)C1=CC=CC2=C1C(=O)NC2=O BONIIQYTWOPUQI-UHFFFAOYSA-N 0.000 description 1
WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
239000004743 Polypropylene Substances 0.000 description 1
239000006096 absorbing agent Substances 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000001252 acrylic acid derivatives Chemical class 0.000 description 1
WKWVTNARZXNZQY-UHFFFAOYSA-N azanide;copper(1+) Chemical compound [Cu]N WKWVTNARZXNZQY-UHFFFAOYSA-N 0.000 description 1
239000001045 blue dye Substances 0.000 description 1
238000004040 coloring Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
238000007796 conventional method Methods 0.000 description 1
230000008878 coupling Effects 0.000 description 1
238000010168 coupling process Methods 0.000 description 1
238000005859 coupling reaction Methods 0.000 description 1
239000012954 diazonium Substances 0.000 description 1
150000001989 diazonium salts Chemical class 0.000 description 1
NQGIJDNPUZEBRU-UHFFFAOYSA-N dodecanoyl chloride Chemical compound CCCCCCCCCCCC(Cl)=O NQGIJDNPUZEBRU-UHFFFAOYSA-N 0.000 description 1
STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
238000007429 general method Methods 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
VHRYZQNGTZXDNX-UHFFFAOYSA-N methacryloyl chloride Chemical compound CC(=C)C(Cl)=O VHRYZQNGTZXDNX-UHFFFAOYSA-N 0.000 description 1
239000003960 organic solvent Substances 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
239000004926 polymethyl methacrylate Substances 0.000 description 1
229920001155 polypropylene Polymers 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000000047 product Substances 0.000 description 1
FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
TVRGPOFMYCMNRB-UHFFFAOYSA-N quinizarine green ss Chemical compound C1=CC(C)=CC=C1NC(C=1C(=O)C2=CC=CC=C2C(=O)C=11)=CC=C1NC1=CC=C(C)C=C1 TVRGPOFMYCMNRB-UHFFFAOYSA-N 0.000 description 1
239000002994 raw material Substances 0.000 description 1
229910052979 sodium sulfide Inorganic materials 0.000 description 1
GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000000967 suction filtration Methods 0.000 description 1
238000012360 testing method Methods 0.000 description 1
239000000984 vat dye Substances 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1

Landscapes

Nitrogen Condensed Heterocyclic Rings (AREA)
Eyeglasses (AREA)

JP10860086A 1986-05-14 1986-05-14 眼用レンズ用染料 Granted JPS62265357A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP10860086A JPS62265357A (ja)	1986-05-14	1986-05-14	眼用レンズ用染料

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP10860086A JPS62265357A (ja)	1986-05-14	1986-05-14	眼用レンズ用染料

Publications (2)

Publication Number	Publication Date
JPS62265357A JPS62265357A (ja)	1987-11-18
JPH0471431B2 true JPH0471431B2 (cs)	1992-11-13

Family

ID=14488910

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP10860086A Granted JPS62265357A (ja)	1986-05-14	1986-05-14	眼用レンズ用染料

Country Status (1)

Country	Link
JP (1)	JPS62265357A (cs)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5944853A (en) *	1992-10-26	1999-08-31	Johnson & Johnson Vision Products, Inc.	Method for preparing halotriazine dye- and vinyl sulfone dye-monomer compounds
NZ248969A (en) *	1992-10-26	1995-08-28	Johnson & Johnson Vision Prod	Tinted contact lens; method of preparation using reactive monomer-halotriazine dye adjunct
JP3234359B2 (ja) *	1993-07-16	2001-12-04	株式会社メニコン	着色されたコンタクトレンズの製法
US5534038A (en) *	1994-06-10	1996-07-09	Pilkington Barnes Hind, Inc.	Tinting hydrogel materials with vat dyes
JP3625097B2 (ja) *	1995-02-07	2005-03-02	セイコーエプソン株式会社	着色コンタクトレンズおよびその製造法
US6149842A (en) *	1998-11-12	2000-11-21	Novartis Ag	Methods and compositions for manufacturing tinted ophthalmic lenses
JP4794089B2 (ja) *	2001-09-17	2011-10-12	株式会社メニコン	眼用レンズのマーキング方法

1986
- 1986-05-14 JP JP10860086A patent/JPS62265357A/ja active Granted

Also Published As

Publication number	Publication date
JPS62265357A (ja)	1987-11-18

Legal Events

Date	Code	Title	Description
2006-05-14	EXPY	Cancellation because of completion of term

Publication	Publication Date	Title
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EP0488145B1 (en)	1999-06-09	Ultraviolet light absorbing intraocular lens
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CS271433B1 (en)	1990-09-12	Hydrophylic copolymer and method of its production
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