JPH0480032A - Composite sheet with design characteristics - Google Patents
Composite sheet with design characteristicsInfo
- Publication number
- JPH0480032A JPH0480032A JP19395490A JP19395490A JPH0480032A JP H0480032 A JPH0480032 A JP H0480032A JP 19395490 A JP19395490 A JP 19395490A JP 19395490 A JP19395490 A JP 19395490A JP H0480032 A JPH0480032 A JP H0480032A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- mica
- titanium
- thickness
- thermoplastic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 11
- 239000010445 mica Substances 0.000 claims abstract description 27
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 27
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010936 titanium Substances 0.000 claims abstract description 15
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 15
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002834 transmittance Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 12
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 11
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 7
- 239000006185 dispersion Substances 0.000 claims abstract description 6
- 239000002245 particle Substances 0.000 claims abstract description 4
- 229920005989 resin Polymers 0.000 abstract description 17
- 239000011347 resin Substances 0.000 abstract description 17
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 15
- 239000000049 pigment Substances 0.000 description 10
- 239000003086 colorant Substances 0.000 description 7
- 238000004040 coloring Methods 0.000 description 7
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 241000255777 Lepidoptera Species 0.000 description 3
- 241000907681 Morpho Species 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- BQJCRHHNABKAKU-KBQPJGBKSA-N morphine Chemical compound O([C@H]1[C@H](C=C[C@H]23)O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4O BQJCRHHNABKAKU-KBQPJGBKSA-N 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 241000501044 Buprestidae Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 235000019733 Fish meal Nutrition 0.000 description 1
- 244000061354 Manilkara achras Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 241000519995 Stachys sylvatica Species 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004467 fishmeal Substances 0.000 description 1
- 230000014509 gene expression Effects 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はモル７オ蝶、ンジミ蝶、黄金虫、玉虫などの何
色光彩色の美麗な色彩をプラスチックシートで表現した
文具、家具、室内表層、自動車内表層等の表層材として
近年の高級化、差別化、個性化傾向に対応した意匠性複
合シートに関するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention is a stationery, furniture, and interior surface layer in which the beautiful colors of various colors such as mole butterflies, yellow butterflies, golden bugs, and iridescent butterflies are expressed using plastic sheets. This invention relates to a decorative composite sheet that is used as a surface layer material for automobile interiors, etc., and is compatible with recent trends toward luxury, differentiation, and individualization.
（従来の技術）
モルフオ蝶、玉虫に代表される有色光彩色を有し、かつ
見る角度によるその色合いか変化する色彩表現は従来か
ら検討されて来た。例えば魚粉、メタル片、マイカ粉（
以下パール顔料という）を用いたインクを用い黒色もし
くは有色の基材に印刷する方法やパール顔料に有色の顔
料を加え基材に印刷する方法が用いられてきた。いずれ
の方法もインクの厚みがさほど厚くできず上述した天然
の有色光彩色の深み、鮮やかさ、色の変化の点で劣って
いた。又、プラスチックの中にパール顔料もしくは有色
顔料を添加したパール顔料を加え、／−ト状もしくは成
形体として用いる場合も見受けられるが、いずれもパー
ルの白つぼさが勝ち逆に安っぽいイメージしか表現でき
なかった。(Prior Art) Color expressions such as Morpho butterflies and jewel beetles, which have colored luminous colors and whose hue changes depending on the viewing angle, have been studied for some time. For example, fish meal, metal pieces, mica powder (
A method of printing on a black or colored base material using ink using pearl pigment (hereinafter referred to as pearl pigment), and a method of printing on a base material by adding a colored pigment to pearl pigment have been used. In either method, the ink could not be made very thick, and the depth, vividness, and color change of the above-mentioned natural colored glow colors were inferior. In addition, there are cases in which pearl pigments or colored pigments are added to plastic and used in the form of a tote or a molded body, but in either case, the white spots of the pearl prevail and, on the contrary, only give a cheap impression. There wasn't.
（発明が解決しようとする課題）
その目的とするところは、従来の技術では表現できなか
った有色光彩色を天然のものに近付けた意匠性複合／−
トを提供するものである。(Problem to be solved by the invention) The purpose of the invention is to bring the chromatic radiance, which could not be expressed using conventional techniques, closer to that of natural materials.
It is intended to provide the following information.
（課題を解決する手段）
本発明は、全光線透過率か厚み１ｍｍの場合６０％以上
の熱可塑性樹脂（以下透明樹脂という）に微薄片状でそ
の厚みか０，０５〜２．０μｍである雲母の表面上に３
０〜５００ｍμｍの膜厚の二酸化チタンを被覆したチク
／マイカ粒子を分散させた第１層、及び全光線透過率か
５０％以下であって白色、黒色もしくは有彩色の熱可塑
性樹脂（以下不透明樹脂という）の第２層からなる複合
ソートであり、かつ第１層の厚みＡ （ｍｍ）と第１層
に分散したチタンマイカの分散比率Ｂ（％）との関係が
帆０１／Ａ≦Ｂ≦０゜５／Ａであることを特徴とする意
匠性複合／−トである。(Means for Solving the Problems) The present invention is a thermoplastic resin (hereinafter referred to as a transparent resin) having a total light transmittance of 60% or more when the thickness is 1 mm, and the thickness thereof is 0.05 to 2.0 μm. 3 on the surface of mica
A first layer in which chiku/mica particles coated with titanium dioxide with a film thickness of 0 to 500 mm are dispersed, and a white, black or chromatic thermoplastic resin (hereinafter referred to as opaque resin) with a total light transmittance of 50% or less. ), and the relationship between the thickness A (mm) of the first layer and the dispersion ratio B (%) of titanium mica dispersed in the first layer is 01/A≦B≦ It is a design composite/-t characterized by 0°5/A.
ここで言う透明樹脂とは押出製膜、カレンダー製膜等の
製膜法でフィルム化可能な全光線透過率か厚み１闘の場
合６０％以上の熱可塑性樹脂であればよく、例えばポリ
塩化ビニル、ポリスチレン、ポリプロピレン、ポリエス
テル、ポリウレタン等の樹脂を挙げることができる。The transparent resin referred to here may be any thermoplastic resin that can be made into a film by extrusion film forming, calendar film forming, etc., and has a total light transmittance of 60% or more when the thickness is 1 cm, such as polyvinyl chloride. , polystyrene, polypropylene, polyester, polyurethane, and other resins.
第１層に用いる透明樹脂の全光線透過率か６０％未満で
あるとチタンでイカの光彩性、干渉発色性か減ぜられる
ため、目的か達成されない。ただし透明樹脂には着色剤
を添加して透明有彩色にすることもできる。If the total light transmittance of the transparent resin used for the first layer is less than 60%, the titanium will reduce the squid's brilliance and interference coloring properties, making it impossible to achieve the objective. However, a coloring agent can be added to the transparent resin to make it transparent and chromatic.
二酸化チタンを被覆したマイカ即ちチタンマイカの特徴
は、透明樹脂ノートに分散した場合マイカ表面で反射す
る光と二酸化チタン表面で反射する光とか干渉し発現す
る。そのために二酸化チタンの膜厚を雲母の厚みにより
その発色する色が決まると共に、ソートを透過する光に
ついては該チタンマイカに反射されずに透過する波光の
光についてのみ見え、反射光と通過光かお互いに補色の
関係を持ち、かつ反射光は光彩色を持つこととなる。The characteristics of mica coated with titanium dioxide, that is, titanium mica, occur when the light reflected on the mica surface and the light reflected on the titanium dioxide surface interfere when dispersed in a transparent resin notebook. For this reason, the color produced is determined by the thickness of the titanium dioxide film and the mica.As for the light that passes through the sort, only the wave light that is transmitted without being reflected by the titanium mica is visible, and there is a difference between reflected light and passing light. The colors are complementary to each other, and the reflected light has a chromatic color.
チタンマイカの第１層への分散添加量Ｂ％か第１層厚み
Ａｍｍに対しＢ ＜０．０１／ Ａであると干渉発色性
が減ぜられるため、目的を達成できない。又Ｂ＞０．５
／Ａであると第２層の着色状況を充分に確認できず変化
のある有色光彩色を得ることができない。If B<0.01/A with respect to the dispersed addition amount of titanium mica to the first layer B% or the first layer thickness Amm, the interference coloring property will be reduced and the objective cannot be achieved. Also B>0.5
/A, the coloring state of the second layer cannot be sufficiently confirmed and it is not possible to obtain a varying colored glow color.
該ヤイカチタンを透明樹脂に分散したフィルムま押出法
、共押出法、カレンダー法、溶液キャスト法、二軸延伸
法等の一般的な製膜法で得ることができる。全光線透過
率か５０％以下である白色、黒色もしぐは有彩色の熱可
塑性樹脂層は一般に二酸化チタン等の白色顔料、カーボ
ンブラック等の黒色顔料、ペンカラ、７りロシアニング
等の有機もしくは無機有色顔料を熱可塑性樹脂に分散さ
せ着色した樹脂をフィルム化したものを用いる。製膜は
チタンマイカ分散シート層と同様の方法で得ることかで
きる。第１層のチタンマイカ分散シート層と第２層の着
色ンヘトのラミネートは、ドライラミネート法、押出ラ
ミネート法、黙ラミネート法、共押出ラミネート法等の
手法を用いる。It can be obtained by a general film forming method such as a film extrusion method, a coextrusion method, a calendar method, a solution casting method, a biaxial stretching method, etc., in which the Yaika titanium is dispersed in a transparent resin. White, black or chromatic thermoplastic resin layers with a total light transmittance of 50% or less are generally made of white pigments such as titanium dioxide, black pigments such as carbon black, organic or inorganic pigments such as pen color, 7-lysyanning, etc. A colored resin film made by dispersing colored pigments in a thermoplastic resin is used. The film can be formed in the same manner as the titanium-mica dispersed sheet layer. The first titanium mica dispersion sheet layer and the second colored sheet are laminated using methods such as dry lamination, extrusion lamination, silent lamination, and coextrusion lamination.
（作用）
第１層のヘース樹脂となる透明樹脂は、分散されたチタ
ンマイカの干渉発色性、光彩発色性を生かす働きをして
おり、特定添加量のチタンマイカは干渉発色性、光彩発
色性そのものの働きと第２層の着色層の色会いを見る角
度ｌこより微妙に変化させる働きを持ち、第２層の着色
層は本発明複合ノートの基調となる色合いを例えは、黒
基調、赤基調、緑基調を決める働さを持つ。(Function) The transparent resin that becomes the first layer of Heath resin has the function of making use of the interference coloring and luminous coloring properties of the dispersed titanium mica, and the titanium mica added in a specific amount has the interference coloring and luminous coloring properties. It has the function of subtly changing the viewing angle of the color of the second colored layer. It has the function of determining the basic tone and green tone.
（実施例）
（実施例Ｉ）
硬質塩化ビニル樹脂に安定剤、滑剤、補強剤を添加し、
硬質塩化ビニル透明樹脂ベースを作製した。該硬質塩化
ビニル透明樹脂ベース１００に対し、メルク社製イリオ
ジン２３５を１％添加した後、カレンダーにより０，１
闘厚みのシートを作製した。(Example) (Example I) Adding stabilizers, lubricants, and reinforcing agents to hard vinyl chloride resin,
A hard vinyl chloride transparent resin base was made. After adding 1% of Iriodin 235 manufactured by Merck Co., Ltd. to the hard vinyl chloride transparent resin base 100, 0.1
A thick sheet was made.
別にカーボンブラックを０．５％添加した全光線透過率
１．２％の黒色塩化ビニルシートを同しくカレンダー法
により Ｑ、１ｍｍのソートを得た。次に熱ラミネート
機で上記２種のシートを熱ラミネートし０．２ｍｍの複
合シートを得た。得られたシートをチタンマイカを分散
／−ト側から見ると、緑色の干渉光彩色が反射光として
得られ見る角度によっては緑色が減じ下地の黒色が強く
認識できあたかもモルフオ蝶のような色合いのシートか
得られた。Separately, a black vinyl chloride sheet with a total light transmittance of 1.2% to which 0.5% of carbon black was added was similarly calendered to obtain a sort of Q, 1 mm. Next, the above two types of sheets were thermally laminated using a thermal laminating machine to obtain a 0.2 mm composite sheet. When the resulting sheet is viewed from the side where the titanium mica is dispersed, a green interference chromatic color is obtained as reflected light. Got a sheet.
（実施例２）
実施例１と同様にメルク社製イリオジン２３５を０．５
％を添加した硬質塩化ヒニル／々ト０．２ｍｍを得た。(Example 2) Similarly to Example 1, 0.5% of Iriodin 235 manufactured by Merck & Co.
0.2 mm of hard vinyl chloride/metal was obtained.
別に赤色顔料を添加した厚みＯ，１ｍｍ全光線透過率３
％の赤色塩化ヒニルノートをカレンタ法により得た。か
つこの２種の／−トをウレタン系接着剤でドライラミネ
ートし、 ０ 、３ｍｍの複合ソートを得た。得られた
シートをチタンマイカ分散シート側から見ると緑色の干
渉光彩色が得られ見る角度によっては下地の赤色が強く
感じられる特異な色合いのシートが得られた。Separately added red pigment, thickness 0, 1mm total light transmittance 3
% of red hinyl chloride notes were obtained by the Calendar method. These two kinds of sheets were dry-laminated with a urethane adhesive to obtain a composite sort of 0.3 mm. When the obtained sheet was viewed from the titanium mica dispersion sheet side, a green interference chromatic color was obtained, and depending on the viewing angle, a sheet with a unique coloration in which the underlying red color was strongly felt was obtained.
（実施例３）
メチルメタアクリレート樹脂にメルク社製イリオジン２
３５を０．５％添加してチタンマイカ分散メチルメタア
クリレート樹脂を得た。別にカーボン顔料を１．０％添
加した黒色メチルメタアクリレート樹脂を得た。２種の
樹脂を二層共押出設備で共押出製膜し、チタンマイカ層
０．１ｍｍ、黒色層０．２ｍｍ合計０．３ｍｍ厚みの複
合ソートを得た。得られたシートは実施例１とと同様に
モルフオ蝶の如き黒縁色光彩色ノートが得られた。(Example 3) Merck's Iriodin 2 was added to methyl methacrylate resin.
35 was added in an amount of 0.5% to obtain a titanium-mica-dispersed methyl methacrylate resin. Separately, a black methyl methacrylate resin to which 1.0% of carbon pigment was added was obtained. Two types of resins were coextruded into a film using a two-layer coextrusion facility to obtain a composite sort with a total thickness of 0.3 mm, including a titanium mica layer of 0.1 mm and a black layer of 0.2 mm. The sheet obtained had a black-rimmed, luminous colored note similar to that of Example 1, resembling a morpho butterfly.
（発明の効果）
本発明の意匠性複合／−トは、モルフオ蝶、／７゛ミ蝶
、黄金虫、玉虫なとの有色光彩色の奇麗な色彩を天然の
ものに近付けた意匠性ををするソートであって、文具、
家具、室内表層、自動車内表層等の表層材として用いら
れる。(Effects of the Invention) The design composite of the present invention brings the beautiful colors of the morpho butterfly, /7mm butterfly, golden bug, and iridescent butterfly closer to those of nature. sorting, stationery,
Used as surface material for furniture, interior surfaces, automobile interior surfaces, etc.
第１図は本発明の意匠性複合ソートの模式断面図である
。FIG. 1 is a schematic cross-sectional view of the design composite sort of the present invention.
Claims (1)
塑性樹脂に微薄片状でその厚みが０．０５〜２．０μｍ
である雲母の表面上に３０〜５００ｍμｍの膜厚の二酸
化チタンを被覆したチタンマイカ粒子を分散させた第１
層、及び全光線透過率が５０％以下であって白色、黒色
もしくは有彩色の熱可塑性樹脂の第２層からなる複合シ
ートであり、かつ第１層の厚みＡ（ｍｍ）と第１層に分
散したチタンマイカの分散比率Ｂ（％）との関係が０．
０１／Ａ≦Ｂ≦０．５／Ａであることを特徴とする意匠
性複合シート。(1) When the total light transmittance is 1 mm thick, the thermoplastic resin has a total light transmittance of 60% or more and is in the form of fine flakes with a thickness of 0.05 to 2.0 μm.
The first method is to disperse titanium mica particles coated with titanium dioxide with a film thickness of 30 to 500 mμm on the surface of mica.
It is a composite sheet consisting of a second layer of white, black or chromatic thermoplastic resin with a total light transmittance of 50% or less, and the thickness of the first layer is A (mm). The relationship with the dispersion ratio B (%) of dispersed titanium mica is 0.
A design composite sheet characterized in that 01/A≦B≦0.5/A.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19395490A JPH0480032A (en) | 1990-07-24 | 1990-07-24 | Composite sheet with design characteristics |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19395490A JPH0480032A (en) | 1990-07-24 | 1990-07-24 | Composite sheet with design characteristics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0480032A true JPH0480032A (en) | 1992-03-13 |
| JPH0583372B2 JPH0583372B2 (en) | 1993-11-25 |
Family
ID=16316524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19395490A Granted JPH0480032A (en) | 1990-07-24 | 1990-07-24 | Composite sheet with design characteristics |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0480032A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5859079A (en) * | 1981-10-05 | 1983-04-07 | 三菱樹脂株式会社 | Metallic glossy film or tube |
| JPS6140200A (en) * | 1984-08-01 | 1986-02-26 | 小島プレス工業株式会社 | Molded shape having printed pattern and manufacture thereof |
| JPS6144829U (en) * | 1984-08-24 | 1986-03-25 | 株式会社 ほくさん | Vapor phase epitaxial growth equipment using thermal decomposition of Group 3-5 compound semiconductors |
| JPS62101676A (en) * | 1985-10-30 | 1987-05-12 | Nippon Carbide Ind Co Ltd | Translucent synthetic resin adhesive sheet |
-
1990
- 1990-07-24 JP JP19395490A patent/JPH0480032A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5859079A (en) * | 1981-10-05 | 1983-04-07 | 三菱樹脂株式会社 | Metallic glossy film or tube |
| JPS6140200A (en) * | 1984-08-01 | 1986-02-26 | 小島プレス工業株式会社 | Molded shape having printed pattern and manufacture thereof |
| JPS6144829U (en) * | 1984-08-24 | 1986-03-25 | 株式会社 ほくさん | Vapor phase epitaxial growth equipment using thermal decomposition of Group 3-5 compound semiconductors |
| JPS62101676A (en) * | 1985-10-30 | 1987-05-12 | Nippon Carbide Ind Co Ltd | Translucent synthetic resin adhesive sheet |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0583372B2 (en) | 1993-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR860001943B1 (en) | Plastic cardard with metallic luster | |
| EP0298603B1 (en) | Simulated mother-of-pearl | |
| EP1162059B1 (en) | Coloring structure for producing colors | |
| US5008143A (en) | Decorative objects with multi-color effects | |
| HUP0100370A2 (en) | Ink composition comprising first and second optically variable pigments and combination and security document | |
| CN109348660A (en) | Decorative sheets and covers for consumer electronics | |
| JP2003266610A (en) | Decorative sheet and decorative material | |
| JPH0480032A (en) | Composite sheet with design characteristics | |
| JPH03167238A (en) | Decorative sheet | |
| JP2000062081A (en) | Decorative sheet | |
| JP2002103777A (en) | Printed matter for preventing forgery and method for producing the same | |
| JPH0811436B2 (en) | Designable composite sheet | |
| JPH0468030A (en) | Decorative sheet | |
| EP0298604B1 (en) | Decorative objects with multicolor effects | |
| JPH0687201A (en) | Makeup film | |
| JP2501238B2 (en) | Manufacturing method of design sheet | |
| JPS6130849Y2 (en) | ||
| JP2509735B2 (en) | Patterned sheet | |
| JP2003312192A (en) | Eraser | |
| JPH03173626A (en) | Manufacture of design sheet | |
| JPH0948102A (en) | Designed composite mirror surface sheet | |
| JP3098586B2 (en) | Decorative sheet with concealment | |
| JP2584650B2 (en) | Metallic film | |
| JPH0636863U (en) | Reversible thermochromic laminate | |
| JPH0468031A (en) | Patterned sheet |