JPH048401B2 - - Google Patents
Info
- Publication number
- JPH048401B2 JPH048401B2 JP58150227A JP15022783A JPH048401B2 JP H048401 B2 JPH048401 B2 JP H048401B2 JP 58150227 A JP58150227 A JP 58150227A JP 15022783 A JP15022783 A JP 15022783A JP H048401 B2 JPH048401 B2 JP H048401B2
- Authority
- JP
- Japan
- Prior art keywords
- present
- compound
- test
- crustaceans
- methylisothiazolin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
本発明は陸生の有害甲殻動物の駆除剤に関する
ものであり、更に詳くは、一般式
The present invention relates to a pest control agent for harmful terrestrial crustaceans, and more specifically,
【式】
（但し、Ｒは水素又はハロゲン原子を示す。）
にて示される２−メチルイソチアゾリン−３−オ
ン又は／及びその金属錯塩化合物からなる陸生の
有害甲殻動物駆除剤に係るものである。
陸生の有害甲殻動物、特にダンゴムシ等の甲殻
動物類は、陰湿な場所に樓息し、畑地、温室、庭
園、家屋、青果貯蔵所等のいたるところに出没し
て、諸種の植物類の茎葉、果実、根茎、木材等を
舐食し、多大なる損害を与えている。また、台所
等の湿気ある場所に侵入する場合がある。これに
対し、従来より、種々の誘引剤が使用されている
が、充分な効果をあげ得ない欠点がある。
本発明者等は、陸生の有害甲殻動物であるダン
ゴムシ等の駆除試験を行つた結果、本発明に係る
化合物が駆除効果の極めて高いことを認めた。即
ち本発明の一般式にて示される化合物は、ダンゴ
ムシ等の接触後、短期間のうちに殺滅させること
を認めた。
本発明の一般式に係る化合物は、工業用殺菌剤
として塗料、製紙、切削油、冷却用水素等の場面
において防菌、防黴を目的として、その用途が開
発されている。しかしながら、本発明化合物は陸
生の甲殻動物の駆除作用についての開示は未だみ
られない。
本発明の薬剤は以下に記す如く、種々の形態に
製剤することができ、地形、天候、面積等に影響
をうけることなく容易に処理することができ、ま
た、効果の確実性および効果発現迅速性等の点か
ら実用上極めて有用である。
前記一般式にて示される２−メチルイソチアゾ
リン−３−オン化合物としては、５−クロロ−２
−メチルイソチアゾリン−３−オン、２−メチル
イソチアゾリン−３−オン等が挙げられ、また、
これらと金属錯塩を形成せる金属塩としては、塩
化亜鉛、塩化マグネシウム、塩化カルシウム、硝
酸マグネシウム、硝酸カルシウム、塩化鉄、硫酸
マグネシウム、硫酸銅等が挙げられる。
本発明化合物は、実際に使用するにあたつて、
原体そのものを散布してもよく、通常の製剤の如
く、乳剤、粒剤、水和剤、ペースト、スプレー、
水溶剤あるいは発泡剤などとしても使用できる。
又は、補助剤、例えば展着剤、乳化剤、湿展剤、
固着剤等の界面活性剤を混用して効果の確実を期
することは勿論よい。目的によつて他の殺菌剤、
殺虫剤、除草剤又は肥料等と混用して同時に処
理、施用することも可能である。麦皮、蛋白質生
成物、カゼイン、乾燥酵母及び精油の如き天然及
び合成誘引剤と組合せて誘引性駆除剤とすること
もできる。
実施例 １
鉢もの植木育成場に樓息中のダンゴムシを供試
して散布試験を行つた。
本発明化合物を水で所定濃度に希釈し、小型噴
霧器を用いてダンゴムシの体によくかかるように
散布した。１区10頭とし３区反復した。調査は処
理後24時間目に生きているものの頭数及び死亡し
たものの頭数をかぞえた。試験期間中の気温は20
〜27℃であつた。[Formula] (However, R represents hydrogen or a halogen atom.)
This invention relates to a harmful terrestrial crustacean repellent comprising 2-methylisothiazolin-3-one and/or its metal complex compound shown in the following. Harmful terrestrial crustaceans, especially pill bugs and other crustaceans, live in swampy places and appear everywhere in fields, greenhouses, gardens, houses, fruit and vegetable storage areas, etc., destroying the leaves and leaves of various plants. They lick fruits, rhizomes, wood, etc., causing a great deal of damage. It may also invade humid areas such as the kitchen. To deal with this, various attractants have been used in the past, but they have the drawback of not being sufficiently effective. The present inventors conducted a test for exterminating pill bugs, which are harmful terrestrial crustaceans, and found that the compound according to the present invention has an extremely high extermination effect. That is, it has been confirmed that the compound represented by the general formula of the present invention kills pill bugs and the like within a short period of time after coming into contact with them. The compound according to the general formula of the present invention has been developed for use as an industrial disinfectant for antibacterial and antifungal purposes in paints, paper manufacturing, cutting oil, cooling hydrogen, and the like. However, no disclosure has yet been made regarding the exterminating action of the compound of the present invention on terrestrial crustaceans. The drug of the present invention can be formulated into various forms as described below, can be easily processed without being affected by topography, weather, area, etc., and has a reliable effect and rapid onset of effect. It is extremely useful in practical terms from the viewpoint of performance, etc. The 2-methylisothiazolin-3-one compound represented by the above general formula includes 5-chloro-2
-Methylisothiazolin-3-one, 2-methylisothiazolin-3-one, etc., and
Examples of metal salts that form metal complexes with these include zinc chloride, magnesium chloride, calcium chloride, magnesium nitrate, calcium nitrate, iron chloride, magnesium sulfate, copper sulfate, and the like. When the compound of the present invention is actually used,
The raw material itself may be sprayed, and it can be used in the form of emulsions, granules, wettable powders, pastes, sprays, etc.
It can also be used as a water solvent or a foaming agent.
Or auxiliary agents such as spreading agents, emulsifiers, wetting agents,
It is of course possible to use a surfactant such as a fixing agent in order to ensure the effect. Other fungicides depending on the purpose,
It is also possible to treat and apply the mixture with insecticides, herbicides, fertilizers, etc. at the same time. It can also be combined with natural and synthetic attractants such as wheat bark, protein products, casein, dried yeast and essential oils to form an attractive pest control agent. Example 1 A spraying test was conducted using pill bugs in a potted plant nursery. The compound of the present invention was diluted with water to a predetermined concentration and sprayed using a small sprayer so as to cover the bodies of pill bugs well. The test was repeated for 3 sections with 10 animals per section. The survey counted the number of live and dead animals 24 hours after treatment. The temperature during the test period was 20
It was ~27℃.
【表】【table】
【表】
実施例 ２
本発明化合物のダンゴムシに対する効果試験を
行つた。
供試ダンゴムシには、ダンゴムシ
（Armatillidiumvulgare）を用いた。供試化合物
の所定濃度希釈液をそれぞれ噴霧処理したのち径
９cmの網蓋付き腰高シヤーレに放飼し、処理24時
間後の生死を調査した。対照無処理は水を用いて
散布したのち上記同様シヤーレ内に放飼した。[Table] Example 2 An effect test of the compound of the present invention against pill bugs was conducted. The pill bug (Armatillidium vulgare) was used as the test pill bug. After spraying a diluted solution of the test compound at a predetermined concentration, the animals were released into a waist-high cage with a mesh lid, 9 cm in diameter, and the animals were examined for survival or death 24 hours after the treatment. For the untreated control, the mice were sprayed with water and then released in the same cage as above.
【表】
実施例 ３
本発明化合物の1000倍、2000倍希釈液をシイタ
ケホダ木下に樓息しているダンゴムシに小型手押
噴霧器を用いて散布駆除試験を行つた。調査は散
布後24時間目に行い、散布前の樓息数及び調査時
の樓息数を調べ、これから駆除率を算出した。[Table] Example 3 A 1000-fold and 2000-fold diluted solution of the compound of the present invention was sprayed on pill bugs living under the Shiitake husk tree using a small hand-held sprayer to perform a disinfection test. The survey was conducted 24 hours after spraying, and the number of insects before spraying and the number of insects at the time of the survey were measured, and the eradication rate was calculated from this.
【表】
処理前 処理後
−
棲息数 棲息数
＊ 駆除率＝[Table] Before treatment After treatment
−
Number of habitats Number of habitats
* Extermination rate =
Claims (1)
にて示される２−メチルイソチアゾリン−３−オ
ン又は／及びその金属錯塩化合物を有効成分とし
て含有することを特徴とする陸生の有害甲殻動物
駆除剤。[Claims] 1 General formula [Formula] (However, R represents hydrogen or a halogen atom.)
An agent for controlling harmful terrestrial crustaceans, which contains 2-methylisothiazolin-3-one or/and its metal complex compound as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15022783A JPS6042306A (en) | 1983-08-19 | 1983-08-19 | Agent for controlling noxious crustacean |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15022783A JPS6042306A (en) | 1983-08-19 | 1983-08-19 | Agent for controlling noxious crustacean |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6042306A JPS6042306A (en) | 1985-03-06 |
| JPH048401B2 true JPH048401B2 (en) | 1992-02-17 |
Family
ID=15492319
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15022783A Granted JPS6042306A (en) | 1983-08-19 | 1983-08-19 | Agent for controlling noxious crustacean |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6042306A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110731344A (en) * | 2019-09-30 | 2020-01-31 | 浙江大学 | insecticides and application thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5869510A (en) * | 1993-01-15 | 1999-02-09 | Rohm And Haas Company | Iron stabilizers for 3-isothiazolones |
-
1983
- 1983-08-19 JP JP15022783A patent/JPS6042306A/en active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110731344A (en) * | 2019-09-30 | 2020-01-31 | 浙江大学 | insecticides and application thereof |
| WO2021063177A1 (en) * | 2019-09-30 | 2021-04-08 | 浙江大学 | Use of insecticide in preventing or killing pests |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6042306A (en) | 1985-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20170251655A2 (en) | Compositions and methods for capturing, killing or repelling bed bugs | |
| Libs et al. | Formulation of essential oil pesticides technology and their application | |
| Smith et al. | A compendium of inorganic substances used in European pest control before 1850 | |
| US2853416A (en) | Method of protecting plants by applying a pesticidal amount of a polyvinylpyrrolidone-iodine adduct | |
| KR101387111B1 (en) | Rodents repellent composition containing zeolite | |
| EA003401B1 (en) | Insecticidal composition | |
| CN1306866C (en) | Bioreasonable insecticides/fungicides and methods of application thereof | |
| US6103763A (en) | Methods of killing insects | |
| Unsworth et al. | The battle for a sustainable food supply | |
| JPH048401B2 (en) | ||
| Deshmukh | A Case Study: Traditional Methods of Pest Control in Some Villages of KolhapurDistrict | |
| Roark | Insecticides and fungicides | |
| JPH048402B2 (en) | ||
| DE29802237U1 (en) | Repellent against snails and rodents | |
| Teixeira et al. | Paraffin wax emulsion for increased rainfastness of insecticidal bait to control Rhagoletis pomonella (Diptera: Tephritidae) | |
| United States. Department of Agriculture et al. | Diseases and insects of garden vegetables | |
| WO2020149734A2 (en) | New formulation composition for insecticides | |
| JPH092913A (en) | Whitefly control agent | |
| US5476832A (en) | Alkene aldehyde sulfoxylates as nematocides, insecticides and fungicides | |
| NO151026B (en) | INSECTICID AND AKARICID MIXTURE CONTAINING GELATIN, AND USING THE MIXTURE FOR AA FIGHTING INSECT AND MEDICINE | |
| JPS5852207A (en) | Exterminating method for injurious insect of green pine tree | |
| WO2025093719A1 (en) | Insect control based on pepper | |
| Mahato et al. | Evaluation of insecticides against melon fruit fly Bactrocera cucurbitae Coquillett on cucumber | |
| JPH048403B2 (en) | ||
| MENDUM | livestock production was the dominant interest, and to inventory in-creases of crops and livestock. The cotton farmers in this division, as well as in the South Atlantic division, had much lower returns than in 1925. |