JPH0533268A - Flame-resistant processing of cellulosic fiber web - Google Patents
Flame-resistant processing of cellulosic fiber webInfo
- Publication number
- JPH0533268A JPH0533268A JP21020491A JP21020491A JPH0533268A JP H0533268 A JPH0533268 A JP H0533268A JP 21020491 A JP21020491 A JP 21020491A JP 21020491 A JP21020491 A JP 21020491A JP H0533268 A JPH0533268 A JP H0533268A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- cellulosic fiber
- fiber web
- amidophosphazene
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims abstract description 29
- 229920000768 polyamine Polymers 0.000 claims abstract description 15
- 239000004744 fabric Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 21
- -1 amide phosphazene compound Chemical class 0.000 claims description 10
- 238000002845 discoloration Methods 0.000 abstract description 10
- 238000010438 heat treatment Methods 0.000 abstract description 5
- 238000005406 washing Methods 0.000 abstract description 5
- 229940126062 Compound A Drugs 0.000 abstract 1
- NLDMNSXOCDLTTB-UHFFFAOYSA-N Heterophylliin A Natural products O1C2COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC2C(OC(=O)C=2C=C(O)C(O)=C(O)C=2)C(O)C1OC(=O)C1=CC(O)=C(O)C(O)=C1 NLDMNSXOCDLTTB-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000000243 solution Substances 0.000 description 6
- 150000001408 amides Chemical class 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- GKTNLYAAZKKMTQ-UHFFFAOYSA-N n-[bis(dimethylamino)phosphinimyl]-n-methylmethanamine Chemical compound CN(C)P(=N)(N(C)C)N(C)C GKTNLYAAZKKMTQ-UHFFFAOYSA-N 0.000 description 5
- MCONGYNHPPCHSD-UHFFFAOYSA-N 3-dimethoxyphosphoryl-n-(hydroxymethyl)propanamide Chemical compound COP(=O)(OC)CCC(=O)NCO MCONGYNHPPCHSD-UHFFFAOYSA-N 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 4
- 239000007983 Tris buffer Substances 0.000 description 4
- 239000004480 active ingredient Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000003672 processing method Methods 0.000 description 3
- 239000000985 reactive dye Substances 0.000 description 3
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 2
- 150000004056 anthraquinones Chemical class 0.000 description 2
- 239000004202 carbamide Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000005562 fading Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- YXOLAZRVSSWPPT-UHFFFAOYSA-N Morin Chemical compound OC1=CC(O)=CC=C1C1=C(O)C(=O)C2=C(O)C=C(O)C=C2O1 YXOLAZRVSSWPPT-UHFFFAOYSA-N 0.000 description 1
- WYFRCNZIOOYQHH-UHFFFAOYSA-N N1(CC1)[PH2]=O Chemical compound N1(CC1)[PH2]=O WYFRCNZIOOYQHH-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- NMDGMYNXRRCPGM-UHFFFAOYSA-N dibromo propyl phosphate Chemical compound P(=O)(OBr)(OBr)OCCC NMDGMYNXRRCPGM-UHFFFAOYSA-N 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- UXOUKMQIEVGVLY-UHFFFAOYSA-N morin Natural products OC1=CC(O)=CC(C2=C(C(=O)C3=C(O)C=C(O)C=C3O2)O)=C1 UXOUKMQIEVGVLY-UHFFFAOYSA-N 0.000 description 1
- 235000007708 morin Nutrition 0.000 description 1
- WLKALBXHGZQMSK-UHFFFAOYSA-N n-dimethoxyphosphoryl-n-(hydroxymethyl)propanamide Chemical compound CCC(=O)N(CO)P(=O)(OC)OC WLKALBXHGZQMSK-UHFFFAOYSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000009991 scouring Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- LJRGBERXYNQPJI-UHFFFAOYSA-M sodium;3-nitrobenzenesulfonate Chemical compound [Na+].[O-][N+](=O)C1=CC=CC(S([O-])(=O)=O)=C1 LJRGBERXYNQPJI-UHFFFAOYSA-M 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- ASLWPAWFJZFCKF-UHFFFAOYSA-N tris(1,3-dichloropropan-2-yl) phosphate Chemical compound ClCC(CCl)OP(=O)(OC(CCl)CCl)OC(CCl)CCl ASLWPAWFJZFCKF-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明はアミドホスファゼン系化
合物を用いたセルロース系繊維布帛の防炎加工方法に関
し、より詳細には耐経時変退色に優れたセルロース系繊
維布帛の防炎加工方法に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a flameproofing method for a cellulosic fiber cloth using an amide phosphazene compound, and more particularly to a flameproofing method for a cellulosic fiber cloth excellent in discoloration resistance to aging.
【０００２】[0002]
【従来の技術】セルロース系繊維布帛に、防炎性を付与
する加工は、近年種々の方法で行われてきた。例えばダ
ウ・ケミカル社のＡＰＯ（トリス・１・アジリジニル・
ホスフィンオキシド），ストーファ・ケミカル社のＦｙ
ｒｏｌ ＦＲ−２（トリス・１・３・シクロイソプロピ
ル・ホスフェート），Ｇ．Ｌ．マーチン社のＴＲＩＳ
（トリス・２・３・ジブロモプロピル・ホスフェー
ト），オルブライト・アンド・ウィルソン社のプロバン
加工法（テトラキスヒドロオキシホスホニウムサルフェ
ートを主として用いる），チバ・ガイギー社のピロバテ
ックスＣＰ（Ｎ−メチロールジメチルホスホノプロピオ
ンアミド），アミドホスファゼンを用いる方法等が知ら
れている。そしてＡＰＯ，Ｆｙｒｏｌ ＦＲ−２，ＴＲ
ＩＳは毒性の問題で使用されなくなり、現在セルロース
系繊維布帛に防炎性を付与するには、一般的にプロバン
加工法とピロバテックスＣＰ法とアミドホスファゼン法
が用いられている。2. Description of the Related Art In recent years, various methods have been used to impart flameproofness to cellulosic fiber cloths. For example, APO (Tris 1 aziridinyl
Phosphine oxide), Fy from Stoufa Chemical
rol FR-2 (Tris ・ 1.3 ・ cycloisopropyl phosphate), G.I. L. Martin's TRIS
(Tris ・ 2.3 ・ dibromopropyl phosphate), Provrane processing method of Albright & Wilson (mainly using tetrakishydroxyoxyphosphonium sulfate), Pyrovatex CP (N-methyloldimethylphosphonopropionamide) of Ciba-Geigy ), A method using amidophosphazene, etc. are known. And APO, Fyrol FR-2, TR
IS is no longer used due to toxicity problems, and at present, the Provan processing method, the Pyrovatex CP method and the amide phosphazene method are generally used to impart flame resistance to the cellulosic fiber cloth.
【０００３】しかしながらプロバン加工法はテトラキス
ヒドロオキシホスホニウムサルフェートと尿素の縮合化
合物を防炎剤として用いアンモニアガスで処理する方法
であるので、アンモニアガスで処理する為の別途の設備
が必要で加工コストが高くつくという問題がある。一方
ピロバテックスＣＰ法はピロバテックスＣＰ，メラミン
系樹脂，触媒等の高濃度液を調整し布帛に付与するもの
であるので、調整液の安定性が良くなく防炎性能が安定
しないことや、乾燥工程ではホルマリン臭が発生し作業
環境がよくないという問題がある。アミドホスファゼン
化合物を用いた防炎加工方法は米国特許第２，７８２，
１３３号公報に開示されており、ホルマリンが発生しな
いという長所を有するが、アントラキノン系反応染料で
着色した着色布をアミドホスファゼン系化合物単独で処
理した防炎加工布は時間の経過とともに変退色が発生す
ることが明らかになり、この欠点を改善することが望ま
れている。However, the Provan processing method is a method in which a condensation compound of tetrakishydrooxyphosphonium sulfate and urea is used as a flameproofing agent and is treated with ammonia gas. Therefore, a separate facility for treating with ammonia gas is required and the processing cost is high. There is a problem of being expensive. On the other hand, the Pyrovatex CP method adjusts a high-concentration liquid such as Pyrovatex CP, melamine resin, and catalyst and applies it to the fabric, so the stability of the adjustment liquid is not good and the flameproof performance is not stable, and in the drying process There is a problem that the work environment is not good due to the generation of formalin odor. A flameproofing method using an amidophosphazene compound is disclosed in US Pat. No. 2,782,782.
Although it is disclosed in Japanese Patent Publication No. 133, it has an advantage that formalin does not occur, however, a flameproof processed cloth obtained by treating a colored cloth colored with an anthraquinone reactive dye with an amide phosphazene compound alone causes discoloration over time. Therefore, it is desired to improve this drawback.
【０００４】[0004]
【発明が解決しようとする課題】本発明はアミドホスフ
ァゼン化合物を防炎剤とするセルロース系繊維布帛の防
炎加工方法において、従来における上述の問題点を解決
しうる新規の防炎加工方法の提供を目的とする。DISCLOSURE OF THE INVENTION The present invention provides a novel method for flameproofing a cellulosic fiber cloth using an amidophosphazene compound as a flameproofing agent, which can solve the above-mentioned problems in the prior art. With the goal.
【０００５】[0005]
【課題を解決するための手段】上述の目的を達成するた
めに本発明は次の構成を取る。即ち、第１番目の発明
は、セルロース系繊維布帛を、一般式In order to achieve the above object, the present invention has the following constitution. That is, the first aspect of the present invention is based on the general formula of cellulosic fiber cloth.
【化３】
（式中ｍは３以上である）のアミドホスファゼン化合物
と、ポリアミン系化合物を含む溶液にて処理することを
特徴とするセルロース系繊維布帛の防炎加工方法を要旨
とし、また第２番目の発明は、セルロース系繊維布帛
を、一般式[Chemical 3] A second aspect of the present invention is a method for flameproofing a cellulosic fiber cloth, which is characterized by treating with a solution containing an amidophosphazene compound (wherein m is 3 or more) and a polyamine compound. Is a cellulosic fiber cloth with the general formula
【化４】
（式中ｍは３以上である）のアミドホスファゼン化合物
を含む溶液にて処理し、しかる後ポリアミン系化合物を
含む溶液にて処理することを特徴とするセルロース系繊
維布帛の防炎加工方法を要旨とする。[Chemical 4] A method for flameproofing a cellulosic fiber cloth, which comprises treating with a solution containing an amidophosphazene compound (wherein m is 3 or more), and then with a solution containing a polyamine compound. And
【０００６】以下本発明を詳細に説明する。The present invention will be described in detail below.
【０００７】本発明で云うセルロース系繊維布帛とは
綿，麻等のセルロース系繊維及び／又はビスコースレー
ヨン，銅アンモニアレーヨン等の再生セルロース繊維を
少なくとも５０％以上含有する織物，編物，不織布が挙
げられる。The cellulosic fiber cloth referred to in the present invention includes woven fabrics, knitted fabrics and non-woven fabrics containing at least 50% or more of cellulosic fibers such as cotton and hemp and / or regenerated cellulose fibers such as viscose rayon and copper ammonia rayon. To be
【０００８】本発明で用いられるアミドホスファゼン化
合物はThe amidophosphazene compound used in the present invention is
【化５】
（式中、ｍは３以上である）であり、具体的にはｍ＝３
のヘキサアミドホスファゼン（環状３量体）及びｍ＝４
のオクタアミドホスファゼン（環状４量体）等を挙げる
ことができる。かかるアミドホスファゼンの使用量はセ
ルロース系繊維の種類やセルロース系繊維以外の混用率
やその種類及び要求される性能によって異なるが、繊維
重量に対して１〜２０重量％の割合で有効成分を付着せ
しめるのが好ましい。即ち、１重量％未満では防炎効果
が得られず、また２０重量％を超えると効果の割に経済
的でない。[Chemical 5] (In the formula, m is 3 or more), and specifically, m = 3.
Hexaamidophosphazene (cyclic trimer) and m = 4
Octamidophosphazene (cyclic tetramer) and the like. The amount of the amidophosphazene used varies depending on the type of cellulosic fiber, the mixing ratio of the cellulosic fiber other than the cellulosic fiber, the type thereof, and the required performance, but the active ingredient is attached at a ratio of 1 to 20% by weight based on the fiber weight. Is preferred. That is, if it is less than 1% by weight, the flameproof effect cannot be obtained, and if it exceeds 20% by weight, it is not economical for its effect.
【０００９】本発明で云うポリアミン系化合物とは、ポ
リエチレンポリアミン系化合物，ポリエチレンポリアミ
ン系銅錯塩等が挙げられ、具体的にはアクテックスＦＬ
（モーリン化学（株）社製），サンフィックスＰＡＣ−
７（三洋化成（株）社製），センカフィックスＬＰＮ
（日本染化（株）社製），ダンフィックスＮＣ（日興化
学（株）社製），ネオフィックスＰＰ−７０（日華化学
（株）社製）等が挙げられる。かかるポリアミン系化合
物の使用量は、アミドホスファゼンの使用量によって異
なるが、繊維重量に対して０．１〜３重量％の割合で有
効成分を付着せしめるのが好ましい。即ち、０．１重量
％未満ではアントラキノン系反応性染料の経時的変退色
の防止効果が得られず、また３重量％を越えると効果の
割に経済的でなく好ましくない。Examples of the polyamine-based compound in the present invention include polyethylene polyamine-based compounds, polyethylene polyamine-based copper complex salts and the like, and specifically, Actex FL.
(Morin Chemical Co., Ltd.), Sunfix PAC-
7 (manufactured by Sanyo Kasei Co., Ltd.), Senkafix LPN
(Manufactured by Nippon Dyeing Co., Ltd.), Dunfix NC (manufactured by Nikko Chemical Co., Ltd.), Neofix PP-70 (manufactured by Nikka Chemical Co., Ltd.) and the like. The amount of such a polyamine compound used varies depending on the amount of amide phosphazene used, but it is preferable to deposit the active ingredient at a rate of 0.1 to 3% by weight based on the weight of the fiber. That is, if it is less than 0.1% by weight, the effect of preventing discoloration and fading of the anthraquinone-based reactive dye over time cannot be obtained, and if it exceeds 3% by weight, it is not economical because of its effect, which is not preferable.
【００１０】本発明ではセルロース系繊維布帛に、アミ
ドホスファゼン化合物（Ａ）とポリアミン系化合物
（Ｂ）を同時に、または（Ａ）次いで（Ｂ）の順序で個
別に夫々を含む溶液を付与する。そして上記アミドホス
ファゼン化合物には公知の反応促進剤を含むのが好まし
い。In the present invention, a solution containing the amidophosphazene compound (A) and the polyamine compound (B) at the same time, or individually containing (A) and (B) in this order is applied to the cellulosic fiber cloth. The above-mentioned amide phosphazene compound preferably contains a known reaction accelerator.
【００１１】アミドホスファゼン化合物（Ａ）とポリア
ミン系化合物（Ｂ）を同時にセルロース系繊維布帛に付
与する場合にはパッド−ドライ−ベーク法等を用いる。
熱処理条件としては１５０〜１９０℃で１〜５分行なう
ことが好ましい。熱処理温度が低ければ処理時間は長く
なり、一方熱処理温度が高くなれば処理時間は短くなる
が、高温ではセルロース系繊維の劣化が大きく好ましく
ない。その後湯洗，乾燥して防炎加工製品を得る。When the amidophosphazene compound (A) and the polyamine compound (B) are simultaneously applied to the cellulosic fiber cloth, a pad-dry-bake method or the like is used.
The heat treatment is preferably performed at 150 to 190 ° C. for 1 to 5 minutes. When the heat treatment temperature is low, the treatment time is long, while when the heat treatment temperature is high, the treatment time is short, but at a high temperature, deterioration of the cellulosic fibers is large and not preferable. Then, it is washed with hot water and dried to obtain a flameproof product.
【００１２】先ず、アミドホスファゼン化合物（Ａ）を
セルロース系繊維布帛に付与する場合にはパッド−ドラ
イ−ベーク法等を用いる。熱処理条件としては１５０〜
１９０℃で１〜５分行なうことが好ましい。その後に湯
洗，乾燥を行ない、次に、ポリアミン系化合物（Ｂ）を
セルロース系繊維布帛に付与する場合にはパッド−ドラ
イ法等を適用し、防炎加工製品を得る。First, when the amidophosphazene compound (A) is applied to the cellulosic fiber cloth, a pad-dry-bake method or the like is used. The heat treatment condition is 150 ~
It is preferable to carry out at 190 ° C. for 1 to 5 minutes. After that, it is washed with hot water and dried, and then, when the polyamine compound (B) is applied to the cellulosic fiber cloth, a pad-dry method or the like is applied to obtain a flameproof processed product.
【００１３】[0013]
【作用】本発明は上記の様に構成したので、ポリアミン
系化合物が反応性染料と結合し、見掛けの分子量が大き
くなるので、経時的変退色が少なくなるのである。Since the present invention is constituted as described above, since the polyamine compound is bonded to the reactive dye and the apparent molecular weight is increased, discoloration and fading with time are reduced.
【００１４】[0014]
【実施例】以下、実施例に基づき本発明を詳細に説明す
る。EXAMPLES The present invention will be described in detail below based on examples.
【００１５】尚、防炎性の評価は消防庁告示第１１号に
準じた方法で洗濯を５回行なった後、ＪＩＳ Ｌ−１０
９１に規定されるＡ−１法（４５°ミクロバーナー１分
間加熱）にて燃焼試験を行なった。The flameproofness was evaluated in accordance with Fire Service Agency Notification No. 11 after washing 5 times and then JIS L-10.
A combustion test was conducted by the A-1 method (heated with a 45 ° micro-burner for 1 minute) specified in 91.
【００１６】また引裂強力はＪＩＳ Ｌ−１０９６に規
定されるＤ法（ペンジュラム法）にて行なった。The tear strength was measured by the D method (Pendulum method) specified in JIS L-1096.
【００１７】また、経時的変退色は７０℃飽和蒸気中で
２時間加工布を放置した時の変退色をグレースケールと
比較することにより格付けした。The discoloration with time was graded by comparing the discoloration when the work cloth was allowed to stand in saturated steam at 70 ° C. for 2 hours with a gray scale.
【００１８】実施例１
経糸に２０番手単糸、緯糸に１００番手単糸を用いた経
糸密度１６本／インチ，緯糸密度６０本／インチの綿平
織物を常法により毛焼，糊抜，精練，漂白，シルケット
を施した。Example 1 A cotton plain fabric having a warp density of 20 yarns and a weft yarn of 100 yarns and a warp density of 16 yarns / inch and a weft yarn density of 60 yarns / inch is quilted, desizing and scouring by a conventional method. , Bleached, mercerized.
【００１９】該平織物に、中粘度アルギン酸ソーダ（３
％）８０重量％，ヘキサメタリン酸ソーダ０．１重量
％，ｍ−ニトロベンゼンスルホン酸ソーダ１重量％，尿
素８重量％より成る元糊に、Ｃｉｂａｃｒｏｎ Ｂｌｕ
ｅ ３Ｒ（ＣＩＢＡ−ＧＥＩＧＹ（株）社製）０．４重
量％を溶解して調製した色糊を、フラットスクリーンに
より水玉模様に印捺し、１００℃で３分間の乾燥処理を
行なった。次に、１００℃で８分間スチーミング処理を
施し、捺染処理布を得た。On the plain fabric, a medium viscosity sodium alginate (3
%) 80% by weight, sodium hexametaphosphate 0.1% by weight, sodium m-nitrobenzenesulfonate 1% by weight, and urea 8% by weight to the original paste, Cibacron Blu
e 3R (manufactured by CIBA-GEIGY Co., Ltd.) 0.4% by weight was dissolved to prepare a colored paste, which was printed in a polka dot pattern on a flat screen and dried at 100 ° C. for 3 minutes. Next, a steaming treatment was performed at 100 ° C. for 8 minutes to obtain a textile-printed cloth.
【００２０】この捺染処理布を、アミドホスファゼン化
合物としてアミドホスファゼンＡＡ−１０００（日本曹
達（株）社製，有効成分４２％）４００ｇ／ l，ポリア
ミン系化合物としてネオフィックスＲＰ−７０ ５ｇ／
l（日華化学（株）社製，有効成分７０％），アミドホ
スファゼン化合物の反応促進剤としてアピノン３０１
（三和ケミカル（株）社製）１００ｇ／ l，及び水を一
浴に調整した処理液に浸漬し、ピックアップ率７０％に
絞った。そして１２０℃で１分乾燥後、１５０℃で３分
ベーキングした。次いでこの処理布を６０℃，２分間湯
洗し、乾燥し本発明実施例１の製品を得た。This printing cloth was treated with Amidophosphazene AA-1000 (manufactured by Nippon Soda Co., Ltd., active ingredient 42%) 400 g / l as an amidophosphazene compound and Neofix RP-705 5 g / l as a polyamine compound.
l (Nichika Chemical Co., Ltd., active ingredient 70%), Apinone 301 as a reaction accelerator for amidophosphazene compounds
100 g / l (manufactured by Sanwa Chemical Co., Ltd.) and water were immersed in a treatment solution prepared in one bath, and the pickup rate was reduced to 70%. Then, after drying at 120 ° C. for 1 minute, baking was performed at 150 ° C. for 3 minutes. Then, this treated cloth was washed with hot water at 60 ° C. for 2 minutes and dried to obtain the product of Example 1 of the present invention.
【００２１】実施例２
実施例１の捺染処理布を、アミドホスファゼン化合物と
してアミドホスファゼンＡＡ−１０００ ４００ｇ／
l，反応促進剤としてアピノン３０１ １００ｇ／ l，
及び水を一浴に調整した処理液に浸漬し、ピックアップ
率７０％に絞った。そして１２０℃で１分乾燥後、１５
０℃で３分ベーキングした。次いでこの処理布を６０
℃，２分間湯洗し、乾燥した。Example 2 The textile-printed cloth of Example 1 was treated with amide phosphazene AA-1000 400 g / m as an amide phosphazene compound.
l, Apinone 301 as a reaction accelerator 100 g / l,
And water were immersed in the treatment liquid adjusted to one bath, and the pickup rate was reduced to 70%. Then, after drying at 120 ° C for 1 minute, 15
Baking at 0 ° C. for 3 minutes. This treated cloth is then 60
It was washed with hot water at ℃ for 2 minutes and dried.
【００２２】このアミドホスファゼン処理布を、ネオフ
ィックスＲＰ−７０ ５ｇ／ l，及び水を一浴に調整し
た処理液に浸漬し、ピックアップ率７０％に絞った。そ
して１２０℃で１分乾燥し、本発明実施例２の製品を得
た。This amide phosphazene treated cloth was dipped in Neofix RP-705 (5 g / l) and a treatment solution in which water was adjusted to one bath, and the pickup ratio was reduced to 70%. And it dried at 120 degreeC for 1 minute, and obtained the product of Example 2 of this invention.
【００２３】比較例１
実施例１の捺染処理布を、アミドホスファゼン化合物と
してアミドホスファゼンＡＡ−１０００ ４００ｇ／
l，反応促進剤としてアピノン３０１ １００ｇ／ l，
及び水を一浴に調整した処理液に浸漬し、ピックアップ
率７０％に絞った。そして１２０℃で１分乾燥後、１５
０℃で３分ベーキングした。次いでこの処理布を６０℃
で，２分間湯洗し、乾燥し比較例１の製品を得た。Comparative Example 1 The printing-treated cloth of Example 1 was treated with amide phosphazene AA-1000 400 g / m as an amide phosphazene compound.
l, Apinone 301 as a reaction accelerator 100 g / l,
And water were immersed in the treatment liquid adjusted to one bath, and the pickup rate was reduced to 70%. Then, after drying at 120 ° C for 1 minute, 15
Baking at 0 ° C. for 3 minutes. Then, the treated cloth is treated at 60 ° C.
Then, it was washed with hot water for 2 minutes and dried to obtain the product of Comparative Example 1.
【００２４】実施例１，実施例２及び比較例１で得られ
た製品の引裂強力、洗濯５回後の防炎性及び経時的変退
色を表１に示す。Table 1 shows the tear strength, the flameproof property after 5 times of washing and the discoloration with time of the products obtained in Examples 1, 2 and Comparative Example 1.
【００２５】[0025]
【表１】 [Table 1]
【００２６】表１から明らかなように本発明実施例で得
られた製品は引裂強力、防炎性能に優れ、経時的変退色
が少ない事がわかる。As is apparent from Table 1, the products obtained in the examples of the present invention are excellent in tear strength, flameproof performance and little discoloration with time.
【００２７】[0027]
【発明の効果】以上詳述したように、本発明方法によっ
て処理された布帛は、きわめて良好な耐洗濯性を有する
防炎効果を示し引裂強力の低下も少なく、また経時的変
退色も少なく、カーテン等のインテリア用品，ワーキン
グウェア，シーツ，パジャマ等の着衣品，寝具品等に頗
る有用である。更に加工コストが高いなどの欠点もなく
工業生産に非常に有用である。As described above in detail, the fabric treated by the method of the present invention has a very good washing resistance, exhibits a flameproof effect, shows little decrease in tear strength, and has little discoloration with time. It is useful for interior items such as curtains, working wear, sheets, clothes such as pajamas, and bedding. Further, it is very useful for industrial production without any drawbacks such as high processing cost.
Claims (2)
と、ポリアミン系化合物を含む溶液にて処理することを
特徴とするセルロース系繊維布帛の防炎加工方法。1. A cellulosic fiber cloth is represented by the general formula: A flameproofing method for a cellulosic fiber cloth, which comprises treating with a solution containing an amide phosphazene compound represented by the formula (m is 3 or more) and a polyamine compound.
を含む溶液にて処理し、しかる後ポリアミン系化合物を
含む溶液にて処理することを特徴とするセルロース系繊
維布帛の防炎加工方法。2. A cellulosic fiber cloth having a general formula: A flameproofing method for a cellulosic fiber cloth, comprising treating with a solution containing an amide phosphazene compound (wherein m is 3 or more), and then treating with a solution containing a polyamine compound.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21020491A JPH0533268A (en) | 1991-07-25 | 1991-07-25 | Flame-resistant processing of cellulosic fiber web |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21020491A JPH0533268A (en) | 1991-07-25 | 1991-07-25 | Flame-resistant processing of cellulosic fiber web |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0533268A true JPH0533268A (en) | 1993-02-09 |
Family
ID=16585517
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP21020491A Pending JPH0533268A (en) | 1991-07-25 | 1991-07-25 | Flame-resistant processing of cellulosic fiber web |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0533268A (en) |
-
1991
- 1991-07-25 JP JP21020491A patent/JPH0533268A/en active Pending
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