JPH0533295A - Non-slip coating composition - Google Patents
Non-slip coating compositionInfo
- Publication number
- JPH0533295A JPH0533295A JP20226291A JP20226291A JPH0533295A JP H0533295 A JPH0533295 A JP H0533295A JP 20226291 A JP20226291 A JP 20226291A JP 20226291 A JP20226291 A JP 20226291A JP H0533295 A JPH0533295 A JP H0533295A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- coating composition
- parts
- silicone oil
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000008199 coating composition Substances 0.000 title claims abstract description 18
- 229920002545 silicone oil Polymers 0.000 claims abstract description 19
- 229920000642 polymer Polymers 0.000 claims abstract description 14
- 230000009477 glass transition Effects 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000010954 inorganic particle Substances 0.000 claims description 6
- 239000004815 dispersion polymer Substances 0.000 claims 1
- 229910052714 tellurium Inorganic materials 0.000 claims 1
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 22
- 239000000377 silicon dioxide Substances 0.000 abstract description 11
- 230000000903 blocking effect Effects 0.000 abstract description 4
- 239000006185 dispersion Substances 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 description 13
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
- 238000000034 method Methods 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000839 emulsion Substances 0.000 description 7
- 239000004698 Polyethylene Substances 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000012748 slip agent Substances 0.000 description 5
- 239000004721 Polyphenylene oxide Substances 0.000 description 4
- 229920000570 polyether Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 3
- APJIKHNEQAQSEH-UHFFFAOYSA-N 5-methylheptyl prop-2-enoate Chemical compound CCC(C)CCCCOC(=O)C=C APJIKHNEQAQSEH-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- TYIUEFYPIHUHTD-UHFFFAOYSA-N 4-ethylhexyl prop-2-enoate Chemical compound CCC(CC)CCCOC(=O)C=C TYIUEFYPIHUHTD-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 239000004831 Hot glue Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- -1 dimethylsiloxane Chemical class 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 229920006300 shrink film Polymers 0.000 description 1
- 229920006302 stretch film Polymers 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Paper (AREA)
Abstract
Description
【０００１】[0001]
【産業上の利用分野】本発明は段ボ−ルシ−トまたは板
紙等の表面に塗工して用いられる防滑性塗料組成物に関
する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an anti-slip coating composition which is used by coating on the surface of corrugated sheet or paperboard.
【０００２】[0002]
【従来の技術】パレット等に積まれた段ボ−ル箱の荷崩
れを防止する方法としては、紐やバンドで縛ったり、
シュリンクフイルムやストレッチフィルムで覆ったりす
る機械的方法、上下の箱をホットメルト接着剤で点接
着する方法、箱の表面に防滑剤を塗布する方法等が知
られている。しかし、の方法は荷造り・荷解きの作業
が煩雑であり、の方法は接着剤の跡が箱の表面に残
り、美観を著しく損う不都合がある。こうした事情か
ら、現在ではの方法が最も広く採用され、なかでも段
ボ−ルシ−トを形成する前の、例えばライナ−原紙の印
刷工程で、防滑剤を塗工する、いわゆるプレプリント方
式が注目されている。2. Description of the Related Art As a method for preventing the collapse of cargo in a corrugated box packed on a pallet or the like, tie it with a string or band,
Known methods include a mechanical method of covering with a shrink film or a stretch film, a method of spot-bonding upper and lower boxes with a hot-melt adhesive, and a method of applying an anti-slip agent on the surface of the boxes. However, the method of (1) is complicated in packing and unpacking work, and the method of (1) has a disadvantage that a trace of the adhesive remains on the surface of the box and the appearance is significantly impaired. Under these circumstances, the present method is most widely adopted, and among them, the so-called pre-printing method in which the anti-slip agent is applied in the printing process of the liner base paper before forming the corrugated ball sheet, for example, has attracted attention. Has been done.
【０００３】プレプリント方式に使用される従来の防滑
剤の一つに、重合体水分散液と無機粒子との混合物から
なる防滑性塗料組成物がある。しかし、この塗料組成物
は塗装に汚れが付着し易い欠点があり、特に冬場でも満
足な防滑性能が得られるように、ガラス転移温度が０℃
以下の重合体を使用した場合には、塗面の汚れが著し
い。One of the conventional anti-slip agents used in the preprint system is an anti-slip coating composition comprising a mixture of a polymer aqueous dispersion and inorganic particles. However, this coating composition has a drawback that dirt is liable to adhere to the coating, and the glass transition temperature is 0 ° C. so that satisfactory anti-slip performance can be obtained especially in winter.
When the following polymers are used, stains on the coated surface are remarkable.
【０００４】[0004]
【発明が解決しようとする課題】本発明はガラス転移温
度が０℃以下である重合体の水分散液と、無機粒子との
混合物からなる防滑剤塗料組成物に於いて、その塗面の
汚れ付着を防止することを目的とする。DISCLOSURE OF THE INVENTION The present invention relates to an anti-slip agent coating composition comprising a mixture of an aqueous dispersion of a polymer having a glass transition temperature of 0 ° C. or lower and inorganic particles, which stains the coated surface. The purpose is to prevent adhesion.
【０００５】[0005]
【課題を解決するための手段】本発明は上記の課題を解
決するための手段として、重合体の水分散液と無機粒子
との混合物からなる防滑性塗料組成物に於いて、前記重
合体としてガラス転移温度が０℃以下の重合体を使用
し、かつポリエ−テル変性シリコ−ンオイルを重合体の
０．１〜２重量％配合する。Means for Solving the Problems As a means for solving the above problems, the present invention provides an anti-slip coating composition comprising a mixture of an aqueous dispersion of a polymer and inorganic particles. A polymer having a glass transition temperature of 0 ° C. or lower is used, and 0.1 to 2% by weight of the polymer is blended with a polyether-modified silicone oil.
【０００６】本発明で使用する重合体、すなわち、ガラ
ス転移温度が０℃以下である重合体それ自体は、当業界
で公知であって、例えば、エチルアクリレ−ト、ブチル
アクリレ−ト、イソプロピルアクリレ−ト、２−エチル
ヘキシルアクリレ−ト、ヒドロキシエチルアクリレ−ト
等のアクリル酸エステルの単独重合体を使用することが
できる外、上記モノマ−と他のビニル系モノマ−との共
重合体が使用できる。また、スチレン・ブタジエン共重
合体、エチレン・酢酸ビニル共重合体も、本発明の重合
体として使用することができる。The polymer used in the present invention, that is, the polymer having a glass transition temperature of 0 ° C. or lower is known in the art, and examples thereof include ethyl acrylate, butyl acrylate and isopropyl acrylate. It is possible to use homopolymers of acrylic acid esters such as vinyl ether, 2-ethylhexyl acrylate, hydroxyethyl acrylate, etc., as well as copolymers of the above-mentioned monomers and other vinyl-based monomers. it can. Further, a styrene / butadiene copolymer and an ethylene / vinyl acetate copolymer can also be used as the polymer of the present invention.
【０００７】ガラス転移温度が０℃以下である重合体を
防滑剤成分に使用した場合には、耐ブロッキング性を向
上させる必要がある関係で、本発明ではシリカその他の
無機粒子を併用する。典型的にはシリカである無機粒子
の防滑性塗料組成物に対する配合量は、全固形分の２０
〜６０重量％の範囲とするのが通常である。When a polymer having a glass transition temperature of 0 ° C. or lower is used as the anti-slip agent component, silica and other inorganic particles are used in combination in the present invention in order to improve the blocking resistance. The amount of the inorganic particles, which is typically silica, in the anti-slip coating composition is 20% of the total solid content.
It is usually in the range of 60 to 60% by weight.
【０００８】塗装面の汚れ防止の目的で本発明の組成物
に混合するポリエ−テル変性シリコ−ンオイルは、次の
化１又は化２で示され、その配合量は重合体固形分の
０．１〜２重量％の範囲とするのが好ましい。The polyether-modified silicone oil mixed with the composition of the present invention for the purpose of preventing stains on the coated surface is represented by the following chemical formula 1 or chemical formula 2, and the compounding amount thereof is 0. It is preferably in the range of 1 to 2% by weight.
【０００９】[0009]
【化１】 [Chemical 1]
【００１０】[0010]
【化２】 [Chemical 2]
【００１１】式中、Ｒはアルキル基を、Ｐ１はポリエチ
レンオキシド基、ポリプロピレンオキシド基又はこれら
が混合したポリアルキレンオキシド基であり、ジメチル
シロキサンのメチル基の置換の度合は３０〜８０モル程
度である。Ｐ２はＰ１と同一であるか、もしくはエポキ
シ基、アミノ基、カルボキシル基及びヒドロキシル基か
ら選ばれる官能基である。変性の度合はｙ１＝１〜１
０、ｙ２＝１〜１０、ｙ１＋ｙ２＝２〜２０である。In the formula, R is an alkyl group, P1 is a polyethylene oxide group, a polypropylene oxide group or a polyalkylene oxide group in which these are mixed, and the substitution degree of the methyl group of dimethylsiloxane is about 30 to 80 mol. .. P2 is the same as P1 or is a functional group selected from an epoxy group, an amino group, a carboxyl group and a hydroxyl group. The degree of denaturation is y1 = 1 to 1
0, y2 = 1-10, y1 + y2 = 2-20.
【００１２】上記ポリエ−テル変性シリコ−ンオイルの
分子量は、約１０００〜３００００程度であり、粘度は
５０〜３０００ｃｐｓ程度であれば良い。The molecular weight of the above polyether modified silicone oil is about 1000 to 30,000, and the viscosity is about 50 to 3000 cps.
【００１３】[0013]
【作用】無変性のシリコ−ンオイルは防滑塗装面の粘着
性を軽減する作用を有しているが、汚れを防止する能力
に乏しいばかりでなく、滑り角度を大幅に低下させる傾
向がある。これに対して、本発明の変性シリコ−ンオイ
ルは、滑り角度を低下させず、種類によっては滑り角度
を増大させるものもある。しかも、汚れ防止能力は無変
性のシリコ−ンオイルより高い。その理由は定かではな
いが、本発明の変性シリコ−ンオイルは親水基と疎水基
とのバランスにより、界面活性剤と同様な作用を発揮し
て帯電防止効果が汚れ防止に寄与しているものと推定さ
れる。また、無変性シリコ−ンオイルが液体状に浮出し
て表面を滑り易くするのに対し、変性シリコ−ンオイル
は防滑塗装面と紙との結合に寄与して表面で流動するこ
とがなく、そのために優れた防滑性が実現されるものと
考えられる。The unmodified silicone oil has the effect of reducing the tackiness of the anti-slip coating surface, but it is not only poor in the ability to prevent stains, but also tends to significantly reduce the sliding angle. On the other hand, the modified silicone oil of the present invention does not decrease the sliding angle, but increases the sliding angle depending on the type. Moreover, the stain-proofing ability is higher than that of unmodified silicone oil. Although the reason is not clear, the modified silicone oil of the present invention exhibits the same action as a surfactant due to the balance between the hydrophilic group and the hydrophobic group, and the antistatic effect contributes to stain prevention. Presumed. Further, the unmodified silicone oil floats in a liquid state and makes the surface slippery, whereas the modified silicone oil does not flow on the surface by contributing to the binding between the anti-slip coating surface and the paper, and It is considered that excellent anti-slip properties are realized.
【００１４】[0014]
実施例１ スチレン４３重量％とアクリル酸２−エチルヘキシル５
７重量％とからなる共重合体エマルジョン（固形分５０
％、Ｔｇ＝−２０℃）１００重量部に、シリカ４５重量
部と、水５５重量部と、東レ・ダウコ−ニング・シリコ
−ン（株）社製のポリエ−テル変性シリコ−ンオイル
０．２５重量部（樹脂固形分に対して 0.5重量％に相
当）を加えて充分に攪拌し、実施例１の塗料組成物を得
た。Example 1 43% by weight of styrene and 2-ethylhexyl acrylate 5
Copolymer emulsion consisting of 7% by weight (solid content 50
%, Tg = −20 ° C.), 100 parts by weight of silica, 45 parts by weight of silica, 55 parts by weight of water, and 0.25% of polyether-modified silicone oil manufactured by Toray Dow Corning Silicone Co., Ltd. Parts by weight (corresponding to 0.5% by weight with respect to the resin solid content) were added and sufficiently stirred to obtain the coating composition of Example 1.
【００１５】実施例２ スチレン１４重量％、メタクリル酸メチル１４重量％及
びアクリル酸２−エチルヘキシル７２重量％からなる共
重合体エマルジョン（固形分５０％、Ｔｇ＝−４０℃）
１００重量部に、シリカ４５重量部と、水５５重量部
と、東レ・ダウコ−ニング・シリコ−ン（株）社製のポ
リエ−テル変性シリコ−ンオイル０．５重量部（樹脂固
形分に対して１．０重量％に相当）を加えて充分に攪拌
し、実施例２の塗料組成物を得た。Example 2 Copolymer emulsion consisting of 14% by weight of styrene, 14% by weight of methyl methacrylate and 72% by weight of 2-ethylhexyl acrylate (solid content 50%, Tg = -40 ° C.)
To 100 parts by weight, 45 parts by weight of silica, 55 parts by weight of water, and 0.5 part by weight of polyether modified silicone oil manufactured by Toray Dow Corning Silicone Co., Ltd. (Corresponding to 1.0% by weight) and sufficiently stirred to obtain the coating composition of Example 2.
【００１６】実施例３ スチレン５６重量％とアクリル酸２−エチルヘキシル４
４重量％からなる共重合体エマルジョン（固形分５０
％、Ｔｇ＝０℃）１００重量部に、シリカ４５重量部
と、水５５重量部と、東レ・ダウコ−ニング・シリコ−
ン（株）社製のポリエ−テル変性シリコ−ンオイル０．
１重量部（樹脂固形分に対して０．２重量％に相当）を
加えて充分に攪拌し、実施例３の塗料組成物を得た。Example 3 56% by weight of styrene and 4-ethylhexyl acrylate 4
Copolymer emulsion consisting of 4% by weight (solid content 50
%, Tg = 0 ° C.) 100 parts by weight, silica 45 parts by weight, water 55 parts by weight, Toray Dow Corning Silicone
Polyether-modified silicone oil manufactured by Co., Ltd.
1 part by weight (corresponding to 0.2% by weight based on the resin solid content) was added and sufficiently stirred to obtain a coating composition of Example 3.
【００１７】実施例４ スチレン４３重量％とアクリル酸２−エチルヘキシル５
７重量％からなる共重合体エマルジョン（固形分５０
％、Ｔｇ＝−２０℃）１００重量部に対して、シリカ４
５重量部と、水５５重量部と、東レ・ダウコ−ニング・
シリコ−ン（株）社製エポキシポリエ−テル変性シリコ
−ンオイル０．２５重量部（樹脂固形分に対して０．５
重量％に相当）を加えて充分に攪拌し、実施例４の塗料
組成物を得た。Example 4 43% by weight of styrene and 5-ethylhexyl acrylate 5
Copolymer emulsion consisting of 7% by weight (solid content 50
%, Tg = −20 ° C.) 100 parts by weight of silica 4
5 parts by weight, 55 parts by weight of water, Toray Dow Corning
0.25 part by weight of epoxy polyester-modified silicone oil manufactured by Silicone Co., Ltd. (0.5 based on resin solid content)
(Corresponding to wt%) was added and sufficiently stirred to obtain the coating composition of Example 4.
【００１８】比較例２ スチレン４３重量％とアクリル酸２−エチルヘキシル５
７重量％からなる共重合体エマルジョン（固形分５０
％、Ｔｇ＝−２０℃）１００重量部に対して、シリカ４
５重量部と、水５５重量部と、信越シリコ−ン（株）社
製ジメチルシリコ−ンオイルのエマルジョン（固形分３
０％）０．８３重量部（樹脂固形分に対して０．５重量
％に相当）を加えて充分に攪拌し、比較例２の塗料組成
物を得た。Comparative Example 2 43% by weight of styrene and 5-ethylhexyl acrylate 5
Copolymer emulsion consisting of 7% by weight (solid content 50
%, Tg = −20 ° C.) 100 parts by weight of silica 4
5 parts by weight, 55 parts by weight of water, and an emulsion of dimethyl silicone oil manufactured by Shin-Etsu Silicone Co., Ltd. (solid content 3
0%) 0.83 parts by weight (corresponding to 0.5% by weight based on the resin solid content) was added and sufficiently stirred to obtain a coating composition of Comparative Example 2.
【００１９】比較例１ スチレン４３重量％とアクリル酸２−エチルヘキシル５
７重量％からなる共重合体エマルジョン（固形分５０
％、Ｔｇ＝−２０℃）１００重量部に対して、シリカ４
５重量部と水５５重量部を加えて充分に攪拌し、比較例
１の塗料組成物を得た。Comparative Example 1 43% by weight of styrene and 5-ethylhexyl acrylate 5
Copolymer emulsion consisting of 7% by weight (solid content 50
%, Tg = −20 ° C.) 100 parts by weight of silica 4
5 parts by weight and 55 parts by weight of water were added and sufficiently stirred to obtain a coating composition of Comparative Example 1.
【００２０】上記の実施例及び比較例で得た各塗料組成
物を、それぞれ段ボ−ル用ラインシ−ト（本州製紙
（株）社製ＲＫ２８０）に、固形分塗布量が２ｇ／ｍ2
になるように塗布して乾燥し、テストシ−トを得た。こ
のテストシ−トを用いて次の方法により、防滑性、耐ブ
ロッキング性及び耐汚れ適性を評価した。結果を表１に
示す。Each coating composition obtained in the above Examples and Comparative Examples was applied to a line sheet for corrugated ball (RK280, manufactured by Honshu Paper Co., Ltd.) at a solid coating amount of 2 g / m 2.
To obtain a test sheet. Using this test sheet, the slip resistance, blocking resistance and stain resistance were evaluated by the following methods. The results are shown in Table 1.
【００２１】防滑性 温度及び湿度が設定条件（２０℃で６０％、０℃で６
０％）になるように設定された恒温恒湿室内で、ＪＩＳ
Ｐ８１４７の方法により滑り角度を測定した。 耐ブロッキング性 シ−トを５ｃｍ角に切り、その２枚を塗布面同志が対
向するように重ね合わせ、これを２ｋｇ／ｃｍ2 の圧力
で２４時間圧縮後、２枚のシ−トを手で剥がしてブロッ
キング状態を判定した。優を◎印で、良を○印で示す。耐汚れ適性 ２５℃、６５ＲＨの条件に設定された室内で、テスト
シ−トの塗布面をゼロックス用トナ−で充分にまぶして
から余分なトナ−を叩き落してトナ−の付着状態を判定
した。判定は直読測色色差計でトナ−付着前後の色度を
測定して行い、色差ΔＥが４０以上の場合を×、３０〜
３９の場合を△、３０未満の場合を○とした。×は商品
として適さない程度の汚れ易さである。[0021]Anti-slip property Temperature and humidity are set conditions (60% at 20 ° C, 6% at 0 ° C)
0%) in a constant temperature and humidity room set to JIS
The sliding angle was measured by the method of P8147. Blocking resistance Cut the sheet into 5 cm squares, and put two of them on the coated surface.
Stack so that they face each other, and add this to 2kg / cm2Pressure of
After compressing for 24 hours, peel off the two sheets by hand and block.
The king state was judged. Excellent is indicated by ◎, and good is indicated by ○.Suitable for stain resistance Tested in a room set to 25 ℃ and 65RH
Spread the coated surface of the sheet thoroughly with a Xerox toner.
The excess toner is knocked off from and the adhesion state of the toner is determined.
did. Judgment is made with a direct reading colorimetric color difference meter,
When the color difference ΔE is 40 or more, the measurement is performed as ×, 30 to
The case of 39 was evaluated as Δ, and the case of less than 30 was evaluated as ◯. × is a product
It's easy to get dirty.
【００２２】[0022]
【表１】試 料 共重合体 シリカ 変性シリコ−ン 滑り角度 ブロッ 耐汚れ Ｔｇ 重量％ 種類 オイル量 20℃ ０℃ キング 適性 実施例１ −２０℃ ４５ ＰＥ 0.5wt% ５８ ５４ ◎ 〇 実施例２ −４０℃ ４５ ＰＥ 1.0wt% ５８ ５６ 〇 〇 実施例３ ０℃ ４５ ＰＥ 0.2wt% ５４ ４５ ◎ 〇 実施例４ −２０℃ ４５ EP/PE 0.5wt% ５７ ５３ ◎ △ 比較例１ −２０℃ ４５ −− ０wt% ５７ ５２ 〇 × 比較例２ −２０℃ ４５ ＤＭ 0.5wt% ５２ ４６ 〇 × 注）ＰＥ＝ポリエ−テル変性シリコ−ンオイル ＤＭ＝ジメチルシリコ−ンオイル EP/PE ＝エポキシポリエ−テル変性シリコ−ンオイル[Table 1]Sample Copolymer Silica Modified silicone Sliding angle Block Antifouling Tg weight% Type Oil amount 20 ℃ 0 ℃ King Aptitude Example 1-20 ° C 45 PE 0.5wt% 58 54 ◎ 〇 Example 2 -40 ° C 45 PE 1.0wt% 58 56 〇 〇 Example 3 0 ° C 45 PE 0.2wt% 54 45 ◎ 〇 Example 4-20 ° C 45 EP / PE 0.5 wt% 57 53 ◎ △ Comparative Example 1 -20 ° C 45 --0 wt% 57 52 〇 × Comparative Example 2 -20 ° C. 45 DM 0.5 wt% 52 46 〇 × Note) PE = polyether modified silicone -Oil oil DM = Dimethyl silicone oil EP / PE = Epoxy polyether modified silicone oil
Claims (1)
らなる防滑性塗料組成物に於いて、重合体のガラス転移
温度が０℃以下であり、かつ、ポリエ−テル変性シリコ
−ンオイルを重合体の０．１〜２重量％含有することを
特徴とする防滑性塗料組成物。Claims: 1. An anti-slip coating composition comprising a mixture of an aqueous polymer dispersion and inorganic particles, wherein the glass transition temperature of the polymer is 0 ° C or lower, and An anti-slip coating composition comprising 0.1 to 2% by weight of a polymer of tellurium modified silicone oil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20226291A JPH0533295A (en) | 1991-07-18 | 1991-07-18 | Non-slip coating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP20226291A JPH0533295A (en) | 1991-07-18 | 1991-07-18 | Non-slip coating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0533295A true JPH0533295A (en) | 1993-02-09 |
Family
ID=16454631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP20226291A Pending JPH0533295A (en) | 1991-07-18 | 1991-07-18 | Non-slip coating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0533295A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1178152A1 (en) * | 2000-08-03 | 2002-02-06 | National Starch and Chemical Investment Holding Corporation | Process for providing an anti-slip treatment |
| US6383656B1 (en) | 1999-06-11 | 2002-05-07 | Nichias Corporation | Perform for metal matrix composite material and cylinder block made of the same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55107597A (en) * | 1979-02-13 | 1980-08-18 | Tokai Pulp Kk | Antiislip paper |
| JPS5976996A (en) * | 1982-10-22 | 1984-05-02 | デイツク・ハ−キユレス株式会社 | Slip preventing agent of paper and paperboard |
| JPS61123635A (en) * | 1984-11-09 | 1986-06-11 | ダウ・コーニング・リミテツド | Organosiloxane-oxyalkylene copolymer |
| JPS61127733A (en) * | 1984-11-27 | 1986-06-16 | Toray Silicone Co Ltd | Novel organopolysiloxane compound |
-
1991
- 1991-07-18 JP JP20226291A patent/JPH0533295A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55107597A (en) * | 1979-02-13 | 1980-08-18 | Tokai Pulp Kk | Antiislip paper |
| JPS5976996A (en) * | 1982-10-22 | 1984-05-02 | デイツク・ハ−キユレス株式会社 | Slip preventing agent of paper and paperboard |
| JPS61123635A (en) * | 1984-11-09 | 1986-06-11 | ダウ・コーニング・リミテツド | Organosiloxane-oxyalkylene copolymer |
| JPS61127733A (en) * | 1984-11-27 | 1986-06-16 | Toray Silicone Co Ltd | Novel organopolysiloxane compound |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6383656B1 (en) | 1999-06-11 | 2002-05-07 | Nichias Corporation | Perform for metal matrix composite material and cylinder block made of the same |
| EP1178152A1 (en) * | 2000-08-03 | 2002-02-06 | National Starch and Chemical Investment Holding Corporation | Process for providing an anti-slip treatment |
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