JPH0545604B2 - - Google Patents

Info

Publication number: JPH0545604B2
Authority: JP; Japan
Prior art keywords: particles; parts; resin particles; vinylidene chloride; particle size
Prior art date: 1988-12-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Lifetime

Application number

JP30681288A

Other languages

English (en)

Japanese (ja)

Other versions

JPH02153911A (ja

Inventor

Norio Onobusa

Ichiro Ibuki

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Asahi Chemical Industry Co Ltd

Original Assignee

Asahi Chemical Industry Co Ltd

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-12-06

Filing date

1988-12-06

Publication date

1993-07-09

1988-12-06 Application filed by Asahi Chemical Industry Co Ltd filed Critical Asahi Chemical Industry Co Ltd

1988-12-06 Priority to JP30681288A priority Critical patent/JPH02153911A/ja

1990-06-13 Publication of JPH02153911A publication Critical patent/JPH02153911A/ja

1993-07-09 Publication of JPH0545604B2 publication Critical patent/JPH0545604B2/ja

Status Granted legal-status Critical Current

Links

239000002245 particle Substances 0.000 claims description 165
229920005989 resin Polymers 0.000 claims description 80
239000011347 resin Substances 0.000 claims description 80
239000000178 monomer Substances 0.000 claims description 54
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 34
239000000725 suspension Substances 0.000 claims description 24
239000003381 stabilizer Substances 0.000 claims description 23
230000008961 swelling Effects 0.000 claims description 13
239000003431 cross linking reagent Substances 0.000 claims description 11
238000004519 manufacturing process Methods 0.000 claims description 9
238000010557 suspension polymerization reaction Methods 0.000 claims description 9
239000007870 radical polymerization initiator Substances 0.000 claims description 7
239000007900 aqueous suspension Substances 0.000 claims description 3
239000002075 main ingredient Substances 0.000 claims 1
239000000463 material Substances 0.000 claims 1
238000006116 polymerization reaction Methods 0.000 description 32
238000009826 distribution Methods 0.000 description 27
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 25
238000000034 method Methods 0.000 description 21
238000003756 stirring Methods 0.000 description 20
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
238000006243 chemical reaction Methods 0.000 description 17
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 12
239000000203 mixture Substances 0.000 description 12
238000005187 foaming Methods 0.000 description 11
239000000047 product Substances 0.000 description 11
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 10
239000011324 bead Substances 0.000 description 9
HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 7
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 7
238000001914 filtration Methods 0.000 description 7
LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 6
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
238000005470 impregnation Methods 0.000 description 6
229910052757 nitrogen Inorganic materials 0.000 description 6
239000004604 Blowing Agent Substances 0.000 description 5
230000000052 comparative effect Effects 0.000 description 5
238000010558 suspension polymerization method Methods 0.000 description 5
239000004372 Polyvinyl alcohol Substances 0.000 description 4
238000001035 drying Methods 0.000 description 4
238000010097 foam moulding Methods 0.000 description 4
229920002451 polyvinyl alcohol Polymers 0.000 description 4
239000000243 solution Substances 0.000 description 4
238000005406 washing Methods 0.000 description 4
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
-1 N-substituted maleimides Chemical class 0.000 description 3
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
239000007864 aqueous solution Substances 0.000 description 3
150000002148 esters Chemical class 0.000 description 3
239000006260 foam Substances 0.000 description 3
239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 3
229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 3
UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 3
235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 3
239000011259 mixed solution Substances 0.000 description 3
229920002959 polymer blend Polymers 0.000 description 3
238000007873 sieving Methods 0.000 description 3
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
229920001890 Novodur Polymers 0.000 description 2
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
238000004581 coalescence Methods 0.000 description 2
239000006185 dispersion Substances 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
239000004088 foaming agent Substances 0.000 description 2
238000009413 insulation Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
230000000704 physical effect Effects 0.000 description 2
238000010926 purge Methods 0.000 description 2
239000002994 raw material Substances 0.000 description 2
229940058015 1,3-butylene glycol Drugs 0.000 description 1
FBPVUBVZRPURIU-UHFFFAOYSA-N 1-hexylpyrrole-2,5-dione Chemical compound CCCCCCN1C(=O)C=CC1=O FBPVUBVZRPURIU-UHFFFAOYSA-N 0.000 description 1
ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
YIYWMWTZIFFMCO-UHFFFAOYSA-N 3-(2-chlorophenyl)pyrrole-2,5-dione Chemical compound ClC1=CC=CC=C1C1=CC(=O)NC1=O YIYWMWTZIFFMCO-UHFFFAOYSA-N 0.000 description 1
BXAAQNFGSQKPDZ-UHFFFAOYSA-N 3-[1,2,2-tris(prop-2-enoxy)ethoxy]prop-1-ene Chemical compound C=CCOC(OCC=C)C(OCC=C)OCC=C BXAAQNFGSQKPDZ-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
230000004888 barrier function Effects 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
235000019437 butane-1,3-diol Nutrition 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
230000007423 decrease Effects 0.000 description 1
125000004386 diacrylate group Chemical group 0.000 description 1
150000002009 diols Chemical class 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
230000008020 evaporation Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000011049 filling Methods 0.000 description 1
239000010419 fine particle Substances 0.000 description 1
230000004927 fusion Effects 0.000 description 1
239000007789 gas Substances 0.000 description 1
125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
238000007654 immersion Methods 0.000 description 1
239000003999 initiator Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
230000000379 polymerizing effect Effects 0.000 description 1
238000012805 post-processing Methods 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
238000002791 soaking Methods 0.000 description 1
238000005728 strengthening Methods 0.000 description 1
239000000126 substance Substances 0.000 description 1
238000009827 uniform distribution Methods 0.000 description 1

Landscapes

Polymerisation Methods In General (AREA)
Graft Or Block Polymers (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

JP30681288A 1988-12-06 1988-12-06 塩化ビニリデン系樹脂粒子の製造方法 Granted JPH02153911A (ja)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
JP30681288A JPH02153911A (ja)	1988-12-06	1988-12-06	塩化ビニリデン系樹脂粒子の製造方法

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
JP30681288A JPH02153911A (ja)	1988-12-06	1988-12-06	塩化ビニリデン系樹脂粒子の製造方法

Publications (2)

Publication Number	Publication Date
JPH02153911A JPH02153911A (ja)	1990-06-13
JPH0545604B2 true JPH0545604B2 (de)	1993-07-09

Family

ID=17961561

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP30681288A Granted JPH02153911A (ja)	1988-12-06	1988-12-06	塩化ビニリデン系樹脂粒子の製造方法

Country Status (1)

Country	Link
JP (1)	JPH02153911A (de)

1988
- 1988-12-06 JP JP30681288A patent/JPH02153911A/ja active Granted

Also Published As

Publication number	Publication date
JPH02153911A (ja)	1990-06-13

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