JPH05500650A - 低アルミニウムホウ素ベータゼオライト - Google Patents

低アルミニウムホウ素ベータゼオライト

Info

Publication number: JPH05500650A
Authority: JP; Japan
Prior art keywords: zeolite; oxide; catalyst; boron; metal
Prior art date: 1989-07-07
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP2510577A

Other languages

English (en)

Japanese (ja)

Inventor

ゾーンズ，ステイシー，アイ．

ホルターマン，デニス，エル．

ジョセンズ，ローレンス，ダブリュ．

サンティリ，ドナルド，エス．

レイニス，アンドリュー

ジーマー，ジェームス，エヌ．

Original Assignee

シェブロン　リサーチ　アンド　テクノロジー　カンパニー

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1989-07-07

Filing date

1990-07-03

Publication date

1993-02-12

1990-07-03 Application filed by シェブロン　リサーチ　アンド　テクノロジー　カンパニー filed Critical シェブロン　リサーチ　アンド　テクノロジー　カンパニー

1993-02-12 Publication of JPH05500650A publication Critical patent/JPH05500650A/ja

Status Pending legal-status Critical Current

Links

239000010457 zeolite Substances 0.000 claims description 126
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 119
239000003054 catalyst Substances 0.000 claims description 110
229910021536 Zeolite Inorganic materials 0.000 claims description 107
238000000034 method Methods 0.000 claims description 80
239000000203 mixture Substances 0.000 claims description 60
238000006243 chemical reaction Methods 0.000 claims description 56
229910052751 metal Inorganic materials 0.000 claims description 54
239000002184 metal Substances 0.000 claims description 54
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 50
229930195733 hydrocarbon Natural products 0.000 claims description 36
150000002430 hydrocarbons Chemical class 0.000 claims description 35
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 33
-1 alkali metal cation Chemical class 0.000 claims description 30
229910052796 boron Inorganic materials 0.000 claims description 29
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 28
239000004215 Carbon black (E152) Substances 0.000 claims description 28
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 27
150000002739 metals Chemical class 0.000 claims description 25
230000008569 process Effects 0.000 claims description 24
229910052782 aluminium Inorganic materials 0.000 claims description 23
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 23
239000001257 hydrogen Substances 0.000 claims description 22
229910052739 hydrogen Inorganic materials 0.000 claims description 22
150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 21
150000001875 compounds Chemical class 0.000 claims description 20
239000000377 silicon dioxide Substances 0.000 claims description 20
239000013078 crystal Substances 0.000 claims description 18
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 18
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 16
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
238000004517 catalytic hydrocracking Methods 0.000 claims description 16
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 15
150000001336 alkenes Chemical class 0.000 claims description 14
229910000323 aluminium silicate Inorganic materials 0.000 claims description 13
238000006317 isomerization reaction Methods 0.000 claims description 13
238000002441 X-ray diffraction Methods 0.000 claims description 11
125000003118 aryl group Chemical group 0.000 claims description 11
238000004519 manufacturing process Methods 0.000 claims description 11
150000003839 salts Chemical class 0.000 claims description 11
239000000126 substance Substances 0.000 claims description 11
229910052697 platinum Inorganic materials 0.000 claims description 10
239000002253 acid Substances 0.000 claims description 9
229910052783 alkali metal Inorganic materials 0.000 claims description 9
239000000758 substrate Substances 0.000 claims description 9
238000005336 cracking Methods 0.000 claims description 8
239000007791 liquid phase Substances 0.000 claims description 8
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
229910052710 silicon Inorganic materials 0.000 claims description 8
239000010703 silicon Substances 0.000 claims description 8
239000011701 zinc Substances 0.000 claims description 8
229910052810 boron oxide Inorganic materials 0.000 claims description 7
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 claims description 7
229910052732 germanium Inorganic materials 0.000 claims description 7
GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 7
239000011159 matrix material Substances 0.000 claims description 7
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 7
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 6
MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 6
230000029936 alkylation Effects 0.000 claims description 6
238000005804 alkylation reaction Methods 0.000 claims description 6
229910052809 inorganic oxide Inorganic materials 0.000 claims description 6
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
238000002407 reforming Methods 0.000 claims description 6
229910052814 silicon oxide Inorganic materials 0.000 claims description 6
238000010555 transalkylation reaction Methods 0.000 claims description 6
229910052725 zinc Inorganic materials 0.000 claims description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
150000002431 hydrogen Chemical class 0.000 claims description 5
150000002500 ions Chemical class 0.000 claims description 5
239000000395 magnesium oxide Substances 0.000 claims description 5
239000011148 porous material Substances 0.000 claims description 5
229910052761 rare earth metal Inorganic materials 0.000 claims description 5
239000005995 Aluminium silicate Substances 0.000 claims description 4
UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
235000012211 aluminium silicate Nutrition 0.000 claims description 4
238000004523 catalytic cracking Methods 0.000 claims description 4
YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 claims description 4
229910052901 montmorillonite Inorganic materials 0.000 claims description 4
PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 claims description 4
150000002910 rare earth metals Chemical class 0.000 claims description 4
239000008096 xylene Substances 0.000 claims description 4
GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 3
238000009835 boiling Methods 0.000 claims description 3
229910052733 gallium Inorganic materials 0.000 claims description 3
229910052742 iron Inorganic materials 0.000 claims description 3
238000006384 oligomerization reaction Methods 0.000 claims description 3
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
125000000217 alkyl group Chemical group 0.000 claims description 2
230000002152 alkylating effect Effects 0.000 claims description 2
HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 2
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 2
AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 claims description 2
229910001195 gallium oxide Inorganic materials 0.000 claims description 2
229910052621 halloysite Inorganic materials 0.000 claims description 2
230000003647 oxidation Effects 0.000 claims description 2
238000007254 oxidation reaction Methods 0.000 claims description 2
TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
235000019355 sepiolite Nutrition 0.000 claims description 2
229960000892 attapulgite Drugs 0.000 claims 1
238000001833 catalytic reforming Methods 0.000 claims 1
238000005470 impregnation Methods 0.000 claims 1
229910052625 palygorskite Inorganic materials 0.000 claims 1
239000006069 physical mixture Substances 0.000 claims 1
229910052723 transition metal Inorganic materials 0.000 claims 1
150000003624 transition metals Chemical class 0.000 claims 1
239000000047 product Substances 0.000 description 31
150000001768 cations Chemical class 0.000 description 19
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
238000005984 hydrogenation reaction Methods 0.000 description 16
230000003197 catalytic effect Effects 0.000 description 12
239000011541 reaction mixture Substances 0.000 description 12
239000007789 gas Substances 0.000 description 11
229910052757 nitrogen Inorganic materials 0.000 description 11
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 10
229910052799 carbon Inorganic materials 0.000 description 10
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
239000000243 solution Substances 0.000 description 9
239000004927 clay Substances 0.000 description 8
230000000694 effects Effects 0.000 description 8
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 8
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
239000011230 binding agent Substances 0.000 description 7
230000015572 biosynthetic process Effects 0.000 description 7
238000001354 calcination Methods 0.000 description 7
239000003921 oil Substances 0.000 description 7
RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 6
239000000463 material Substances 0.000 description 6
239000002245 particle Substances 0.000 description 6
239000000843 powder Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 5
239000000654 additive Substances 0.000 description 5
150000001340 alkali metals Chemical class 0.000 description 5
238000005899 aromatization reaction Methods 0.000 description 5
125000004432 carbon atom Chemical group C* 0.000 description 5
239000003795 chemical substances by application Substances 0.000 description 5
238000001035 drying Methods 0.000 description 5
238000005342 ion exchange Methods 0.000 description 5
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
229910052759 nickel Inorganic materials 0.000 description 5
229910052763 palladium Inorganic materials 0.000 description 5
238000012545 processing Methods 0.000 description 5
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 5
150000004760 silicates Chemical class 0.000 description 5
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
DJPURDPSZFLWGC-UHFFFAOYSA-N alumanylidyneborane Chemical compound [Al]#B DJPURDPSZFLWGC-UHFFFAOYSA-N 0.000 description 4
238000003763 carbonization Methods 0.000 description 4
238000002425 crystallisation Methods 0.000 description 4
230000008025 crystallization Effects 0.000 description 4
125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
239000012528 membrane Substances 0.000 description 4
239000002808 molecular sieve Substances 0.000 description 4
230000000737 periodic effect Effects 0.000 description 4
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 4
238000003756 stirring Methods 0.000 description 4
238000003786 synthesis reaction Methods 0.000 description 4
CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 4
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
230000000996 additive effect Effects 0.000 description 3
239000003513 alkali Substances 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
239000011651 chromium Substances 0.000 description 3
229910017052 cobalt Inorganic materials 0.000 description 3
239000010941 cobalt Substances 0.000 description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
239000000571 coke Substances 0.000 description 3
229910052675 erionite Inorganic materials 0.000 description 3
238000004231 fluid catalytic cracking Methods 0.000 description 3
150000004820 halides Chemical class 0.000 description 3
238000005216 hydrothermal crystallization Methods 0.000 description 3
239000012535 impurity Substances 0.000 description 3
229910052741 iridium Inorganic materials 0.000 description 3
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 3
239000007788 liquid Substances 0.000 description 3
150000002736 metal compounds Chemical class 0.000 description 3
229910044991 metal oxide Inorganic materials 0.000 description 3
150000004706 metal oxides Chemical class 0.000 description 3
229910052750 molybdenum Inorganic materials 0.000 description 3
239000011733 molybdenum Substances 0.000 description 3
229910052680 mordenite Inorganic materials 0.000 description 3
229910000510 noble metal Inorganic materials 0.000 description 3
238000002360 preparation method Methods 0.000 description 3
238000000926 separation method Methods 0.000 description 3
239000011734 sodium Substances 0.000 description 3
229910052717 sulfur Inorganic materials 0.000 description 3
239000011593 sulfur Substances 0.000 description 3
239000010936 titanium Substances 0.000 description 3
229910052719 titanium Inorganic materials 0.000 description 3
238000011282 treatment Methods 0.000 description 3
KVNYFPKFSJIPBJ-UHFFFAOYSA-N 1,2-diethylbenzene Chemical compound CCC1=CC=CC=C1CC KVNYFPKFSJIPBJ-UHFFFAOYSA-N 0.000 description 2
PFEOZHBOMNWTJB-UHFFFAOYSA-N 3-methylpentane Chemical compound CCC(C)CC PFEOZHBOMNWTJB-UHFFFAOYSA-N 0.000 description 2
PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
239000005977 Ethylene Substances 0.000 description 2
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 2
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
230000002378 acidificating effect Effects 0.000 description 2
239000003463 adsorbent Substances 0.000 description 2
229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
239000002585 base Substances 0.000 description 2
150000007514 bases Chemical class 0.000 description 2
239000000440 bentonite Substances 0.000 description 2
229910000278 bentonite Inorganic materials 0.000 description 2
239000005388 borosilicate glass Substances 0.000 description 2
238000005219 brazing Methods 0.000 description 2
OCKPCBLVNKHBMX-UHFFFAOYSA-N butylbenzene Chemical compound CCCCC1=CC=CC=C1 OCKPCBLVNKHBMX-UHFFFAOYSA-N 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000011575 calcium Substances 0.000 description 2
150000004649 carbonic acid derivatives Chemical class 0.000 description 2
230000008859 change Effects 0.000 description 2
239000002738 chelating agent Substances 0.000 description 2
229910052570 clay Inorganic materials 0.000 description 2
UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 2
230000000295 complement effect Effects 0.000 description 2
238000012937 correction Methods 0.000 description 2
238000006356 dehydrogenation reaction Methods 0.000 description 2
238000004821 distillation Methods 0.000 description 2
238000009826 distribution Methods 0.000 description 2
238000005516 engineering process Methods 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
238000009472 formulation Methods 0.000 description 2
239000000295 fuel oil Substances 0.000 description 2
239000003502 gasoline Substances 0.000 description 2
239000000499 gel Substances 0.000 description 2
PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
239000010931 gold Substances 0.000 description 2
229910052737 gold Inorganic materials 0.000 description 2
DCAYPVUWAIABOU-UHFFFAOYSA-N hexadecane Chemical compound CCCCCCCCCCCCCCCC DCAYPVUWAIABOU-UHFFFAOYSA-N 0.000 description 2
239000004615 ingredient Substances 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000011572 manganese Substances 0.000 description 2
238000005259 measurement Methods 0.000 description 2
229910000000 metal hydroxide Inorganic materials 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
239000003208 petroleum Substances 0.000 description 2
238000005504 petroleum refining Methods 0.000 description 2
231100000572 poisoning Toxicity 0.000 description 2
230000000607 poisoning effect Effects 0.000 description 2
238000006116 polymerization reaction Methods 0.000 description 2
238000000634 powder X-ray diffraction Methods 0.000 description 2
239000010970 precious metal Substances 0.000 description 2
150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
238000011160 research Methods 0.000 description 2
229910052702 rhenium Inorganic materials 0.000 description 2
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
239000010948 rhodium Substances 0.000 description 2
229910052703 rhodium Inorganic materials 0.000 description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
235000012239 silicon dioxide Nutrition 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000002594 sorbent Substances 0.000 description 2
238000010561 standard procedure Methods 0.000 description 2
239000004575 stone Substances 0.000 description 2
150000003568 thioethers Chemical class 0.000 description 2
238000013519 translation Methods 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
PBWHJRFXUPLZDS-UHFFFAOYSA-N (1-Ethylpropyl)benzene Chemical compound CCC(CC)C1=CC=CC=C1 PBWHJRFXUPLZDS-UHFFFAOYSA-N 0.000 description 1
NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
OKIRBHVFJGXOIS-UHFFFAOYSA-N 1,2-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=CC=C1C(C)C OKIRBHVFJGXOIS-UHFFFAOYSA-N 0.000 description 1
NMUWSGQKPAEPBA-UHFFFAOYSA-N 1,2-dibutylbenzene Chemical compound CCCCC1=CC=CC=C1CCCC NMUWSGQKPAEPBA-UHFFFAOYSA-N 0.000 description 1
LRJOXARIJKBUFE-UHFFFAOYSA-N 1,2-diethyl-3-methylbenzene Chemical compound CCC1=CC=CC(C)=C1CC LRJOXARIJKBUFE-UHFFFAOYSA-N 0.000 description 1
HYFLWBNQFMXCPA-UHFFFAOYSA-N 1-ethyl-2-methylbenzene Chemical compound CCC1=CC=CC=C1C HYFLWBNQFMXCPA-UHFFFAOYSA-N 0.000 description 1
MHTNEJUGSUVVPA-UHFFFAOYSA-M 2,2-dimethylpropyl(trimethyl)azanium;iodide Chemical compound [I-].CC(C)(C)C[N+](C)(C)C MHTNEJUGSUVVPA-UHFFFAOYSA-M 0.000 description 1
GKGTVJOYFGUPSA-UHFFFAOYSA-N 2,4-dimethylpentan-3-ylbenzene Chemical compound CC(C)C(C(C)C)C1=CC=CC=C1 GKGTVJOYFGUPSA-UHFFFAOYSA-N 0.000 description 1
VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
241000255925 Diptera Species 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
241000828585 Gari Species 0.000 description 1
VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
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229910052774 Proactinium Inorganic materials 0.000 description 1
239000004113 Sepiolite Substances 0.000 description 1
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241000689006 Syntrophorhabdaceae Species 0.000 description 1
229910052776 Thorium Inorganic materials 0.000 description 1
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
TVWHNULVHGKJHS-UHFFFAOYSA-N Uric acid Natural products N1C(=O)NC(=O)C2NC(=O)NC21 TVWHNULVHGKJHS-UHFFFAOYSA-N 0.000 description 1
150000000475 acetylene derivatives Chemical class 0.000 description 1
238000010306 acid treatment Methods 0.000 description 1
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230000009471 action Effects 0.000 description 1
239000011149 active material Substances 0.000 description 1
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125000001931 aliphatic group Chemical group 0.000 description 1
150000001339 alkali metal compounds Chemical class 0.000 description 1
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XSBJUSIOTXTIPN-UHFFFAOYSA-N aluminum platinum Chemical compound [Al].[Pt] XSBJUSIOTXTIPN-UHFFFAOYSA-N 0.000 description 1
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238000004458 analytical method Methods 0.000 description 1
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150000001491 aromatic compounds Chemical class 0.000 description 1
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229910052728 basic metal Inorganic materials 0.000 description 1
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230000009286 beneficial effect Effects 0.000 description 1
230000008901 benefit Effects 0.000 description 1
SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
210000000988 bone and bone Anatomy 0.000 description 1
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UNYSKUBLZGJSLV-UHFFFAOYSA-L calcium;1,3,5,2,4,6$l^{2}-trioxadisilaluminane 2,4-dioxide;dihydroxide;hexahydrate Chemical compound O.O.O.O.O.O.[OH-].[OH-].[Ca+2].O=[Si]1O[Al]O[Si](=O)O1.O=[Si]1O[Al]O[Si](=O)O1 UNYSKUBLZGJSLV-UHFFFAOYSA-L 0.000 description 1
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238000006555 catalytic reaction Methods 0.000 description 1
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238000007385 chemical modification Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000011208 chromatographic data Methods 0.000 description 1
238000004587 chromatography analysis Methods 0.000 description 1
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229910000428 cobalt oxide Inorganic materials 0.000 description 1
IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
239000008119 colloidal silica Substances 0.000 description 1
238000002485 combustion reaction Methods 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
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239000000356 contaminant Substances 0.000 description 1
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230000001351 cycling effect Effects 0.000 description 1
230000009849 deactivation Effects 0.000 description 1
238000006477 desulfuration reaction Methods 0.000 description 1
230000023556 desulfurization Effects 0.000 description 1
239000003599 detergent Substances 0.000 description 1
239000012973 diazabicyclooctane Substances 0.000 description 1
150000001993 dienes Chemical class 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000000945 filler Substances 0.000 description 1
238000001914 filtration Methods 0.000 description 1
238000010304 firing Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000000446 fuel Substances 0.000 description 1
239000003292 glue Substances 0.000 description 1
230000005484 gravity Effects 0.000 description 1
229910052736 halogen Inorganic materials 0.000 description 1
150000002367 halogens Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
229910000271 hectorite Inorganic materials 0.000 description 1
KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 description 1
239000001307 helium Substances 0.000 description 1
229910052734 helium Inorganic materials 0.000 description 1
SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
239000000017 hydrogel Substances 0.000 description 1
XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
238000007327 hydrogenolysis reaction Methods 0.000 description 1
GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical group [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
238000011065 in-situ storage Methods 0.000 description 1
230000002779 inactivation Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000011534 incubation Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000011081 inoculation Methods 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
229910052500 inorganic mineral Inorganic materials 0.000 description 1
239000003456 ion exchange resin Substances 0.000 description 1
229920003303 ion-exchange polymer Polymers 0.000 description 1
229910052622 kaolinite Inorganic materials 0.000 description 1
239000012263 liquid product Substances 0.000 description 1
238000011068 loading method Methods 0.000 description 1
229910052749 magnesium Inorganic materials 0.000 description 1
239000011777 magnesium Substances 0.000 description 1
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
150000004692 metal hydroxides Chemical class 0.000 description 1
229910021645 metal ion Inorganic materials 0.000 description 1
150000005172 methylbenzenes Chemical class 0.000 description 1
239000011707 mineral Substances 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
229910000476 molybdenum oxide Inorganic materials 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
229910000480 nickel oxide Inorganic materials 0.000 description 1
150000002823 nitrates Chemical class 0.000 description 1
229910017464 nitrogen compound Inorganic materials 0.000 description 1
150000002830 nitrogen compounds Chemical class 0.000 description 1
OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
210000000056 organ Anatomy 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
239000003973 paint Substances 0.000 description 1
239000000123 paper Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
239000011591 potassium Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
125000001453 quaternary ammonium group Chemical group 0.000 description 1
SBYHFKPVCBCYGV-UHFFFAOYSA-N quinuclidine Chemical class C1CC2CCN1CC2 SBYHFKPVCBCYGV-UHFFFAOYSA-N 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
238000004064 recycling Methods 0.000 description 1
230000008929 regeneration Effects 0.000 description 1
238000011069 regeneration method Methods 0.000 description 1
239000012266 salt solution Substances 0.000 description 1
229910052624 sepiolite Inorganic materials 0.000 description 1
238000007873 sieving Methods 0.000 description 1
HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
239000008279 sol Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000012265 solid product Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
241000894007 species Species 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
238000010025 steaming Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
238000010189 synthetic method Methods 0.000 description 1
229940034610 toothpaste Drugs 0.000 description 1
239000000606 toothpaste Substances 0.000 description 1
IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
238000011144 upstream manufacturing Methods 0.000 description 1
229940116269 uric acid Drugs 0.000 description 1
229910052720 vanadium Inorganic materials 0.000 description 1
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
238000005406 washing Methods 0.000 description 1
229910052649 zeolite group Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
- C10G47/10—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used with catalysts deposited on a carrier
- C10G47/12—Inorganic carriers
- C10G47/16—Crystalline alumino-silicate carriers
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/86—Borosilicates; Aluminoborosilicates
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/1009—Compounds containing boron and oxygen having molecular-sieve properties
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
- C01B39/12—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the replacing atoms being at least boron atoms
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
- C07C2/66—Catalytic processes
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G35/00—Reforming naphtha
- C10G35/04—Catalytic reforming
- C10G35/06—Catalytic reforming characterised by the catalyst used
- C10G35/065—Catalytic reforming characterised by the catalyst used containing crystalline zeolitic molecular sieves, other than aluminosilicates
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/86—Borosilicates; Aluminoborosilicates

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Chemical Kinetics & Catalysis (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Oil, Petroleum & Natural Gas (AREA)
Materials Engineering (AREA)
Life Sciences & Earth Sciences (AREA)
General Chemical & Material Sciences (AREA)
General Life Sciences & Earth Sciences (AREA)
Geology (AREA)
Inorganic Chemistry (AREA)
Catalysts (AREA)
Silicates, Zeolites, And Molecular Sieves (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

JP2510577A 1989-07-07 1990-07-03 低アルミニウムホウ素ベータゼオライト Pending JPH05500650A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US37735989A	1989-07-07	1989-07-07
US377,359		1989-07-07

Publications (1)

Publication Number	Publication Date
JPH05500650A true JPH05500650A (ja)	1993-02-12

Family

ID=23488797

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP2510577A Pending JPH05500650A (ja)	1989-07-07	1990-07-03	低アルミニウムホウ素ベータゼオライト

Country Status (9)

Country	Link
EP (1)	EP0592392A1 (de)
JP (1)	JPH05500650A (de)
KR (1)	KR920703201A (de)
AU (1)	AU6052190A (de)
BR (1)	BR9007515A (de)
CA (1)	CA2062947A1 (de)
NZ (1)	NZ234405A (de)
WO (1)	WO1991000777A1 (de)
ZA (1)	ZA905369B (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2004010537A (ja) *	2002-06-06	2004-01-15	Mitsubishi Chemicals Corp	水熱合成用テンプレート、ケイ素含有層状化合物の製造方法及びケイ素含有層状化合物
JP2013510226A (ja) *	2009-11-05	2013-03-21	シェブロンユー．エス．エー．インコーポレイテッド	ボロシリケートＺＳＭ−４８モレキュラーシーブを使用するｎ−パラフィン選択的水素化変換プロセス
JP2018536614A (ja) *	2015-12-08	2018-12-13	ビーエーエスエフソシエタス・ヨーロピアＢａｓｆＳｅ	Ｂｅａ骨格構造を有するスズ含有ゼオライト材料

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPH05503526A (ja) *	1990-01-24	1993-06-10	モービル・オイル・コーポレイション	脂肪族化合物の脱水素化／脱水素環化方法
DE4115263C2 (de) *	1991-05-10	1995-04-06	Taiwan Styrene Monomer Corp	Modifizierter Beta-Zeolith
US5227569A (en) *	1991-08-19	1993-07-13	Texaco Inc.	Skeletal isomerization of n-butylenes to isobutylene on boron-beta zeolites
IT1265041B1 (it) *	1993-07-23	1996-10-28	Eniricerche Spa	Catalizzatore bifunzionale efficace nella idroisomerizzazione di cere e procedimento per la sua preparazione
IT1270230B (it) *	1994-06-16	1997-04-29	Enichem Sintesi	Composizione catalitica e processo per l'alchilazione di composti aromatici
DE10256431A1 (de) *	2002-05-31	2004-01-15	SCHÜMANN SASOL GmbH	Mikrokristallines Paraffin, Verfahren zur Herstellung von mikrokristallinen Paraffine und Verwendung der mikrokristallinen Paraffine
ES2692818B2 (es)	2017-06-05	2019-11-28	Univ Valencia Politecnica	Sintesis de la zeolita beta en su forma nanocristalina, procedimiento de sintesis y su uso en aplicaciones cataliticas

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DE3167118D1 (en) *	1980-12-19	1984-12-13	Ici Plc	Zeolites
US4554145A (en) *	1984-04-16	1985-11-19	Mobil Oil Corporation	Preparation of crystalline silicate zeolite Beta
US4683214A (en) *	1984-09-06	1987-07-28	Mobil Oil Corporation	Noble metal-containing catalysts
NZ220463A (en) *	1986-06-26	1988-11-29	Mobil Oil Corp	Two-phase synthesis of crystalline binary oxides
US4717466A (en) *	1986-09-03	1988-01-05	Mobil Oil Corporation	Multiple riser fluidized catalytic cracking process utilizing hydrogen and carbon-hydrogen contributing fragments
US4788169A (en) *	1987-10-26	1988-11-29	Mobil Oil Corporation	Low acidity alumina-bound zeolites containing tetrahedral boron, gallium, indium and/or thallium

1990
- 1990-07-03 BR BR909007515A patent/BR9007515A/pt not_active Application Discontinuation
- 1990-07-03 EP EP90911359A patent/EP0592392A1/de not_active Withdrawn
- 1990-07-03 AU AU60521/90A patent/AU6052190A/en not_active Abandoned
- 1990-07-03 CA CA002062947A patent/CA2062947A1/en not_active Abandoned
- 1990-07-03 KR KR1019920700024A patent/KR920703201A/ko not_active Withdrawn
- 1990-07-03 WO PCT/US1990/003764 patent/WO1991000777A1/en not_active Ceased
- 1990-07-03 JP JP2510577A patent/JPH05500650A/ja active Pending
- 1990-07-06 NZ NZ234405A patent/NZ234405A/en unknown
- 1990-07-09 ZA ZA905369A patent/ZA905369B/xx unknown

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2004010537A (ja) *	2002-06-06	2004-01-15	Mitsubishi Chemicals Corp	水熱合成用テンプレート、ケイ素含有層状化合物の製造方法及びケイ素含有層状化合物
JP2013510226A (ja) *	2009-11-05	2013-03-21	シェブロンユー．エス．エー．インコーポレイテッド	ボロシリケートＺＳＭ−４８モレキュラーシーブを使用するｎ−パラフィン選択的水素化変換プロセス
JP2018536614A (ja) *	2015-12-08	2018-12-13	ビーエーエスエフソシエタス・ヨーロピアＢａｓｆＳｅ	Ｂｅａ骨格構造を有するスズ含有ゼオライト材料

Also Published As

Publication number	Publication date
WO1991000777A1 (en)	1991-01-24
NZ234405A (en)	1992-05-26
KR920703201A (ko)	1992-12-17
EP0592392A1 (de)	1994-04-20
BR9007515A (pt)	1992-06-23
CA2062947A1 (en)	1991-01-08
ZA905369B (en)	1991-06-26
EP0592392A4 (de)	1992-10-05
AU6052190A (en)	1991-02-06

Publication	Publication Date	Title
US4963337A (en)	1990-10-16	Zeolite SSZ-33
US5106801A (en)	1992-04-21	Zeolite SSZ-31
JP2500256B2 (ja)	1996-05-29	化合物
US5603821A (en)	1997-02-18	Low-aluminum boron beta zeolite
US5316753A (en)	1994-05-31	Zeolite SSZ-35
US5215648A (en)	1993-06-01	Hydrocarbon conversion processes using SSZ-31
US4826667A (en)	1989-05-02	Zeolite SSZ-25
US5202014A (en)	1993-04-13	Zeolite SSZ-25
US5200377A (en)	1993-04-06	Zeolite SSZ-28
US5254514A (en)	1993-10-19	Zeolite SSZ-37
US4610854A (en)	1986-09-09	Zeolite SSZ-15 and process for preparing the same
US5007997A (en)	1991-04-16	Zeolite SSZ-26
US5120425A (en)	1992-06-09	Use of zeolite SSZ-33 in hydrocarbon conversion processes
JPH05500650A (ja)	1993-02-12	低アルミニウムホウ素ベータゼオライト
US5421992A (en)	1995-06-06	Hydrocarbon conversion process using zeolite SSZ-25
EP0394434B1 (de)	1997-05-28	Neues zeolith ssz-31
EP0522196B1 (de)	1996-12-27	Zeolith SSZ-32
US6005154A (en)	1999-12-21	Isomerization process using zeolite SSZ-25
CA2062799A1 (en)	1991-01-08	Zeolite
CA1335600C (en)	1995-05-16	Zeolite ssz-26

JPH05500650A - 低アルミニウムホウ素ベータゼオライト - Google Patents

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Cited By (3)

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Cited By (3)

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