JPH05509362A - ケミカルパルプの漂白方法 - Google Patents
ケミカルパルプの漂白方法Info
- Publication number
- JPH05509362A JPH05509362A JP3503752A JP50375291A JPH05509362A JP H05509362 A JPH05509362 A JP H05509362A JP 3503752 A JP3503752 A JP 3503752A JP 50375291 A JP50375291 A JP 50375291A JP H05509362 A JPH05509362 A JP H05509362A
- Authority
- JP
- Japan
- Prior art keywords
- treatment
- bleaching
- pulp
- bleaching method
- alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000000034 method Methods 0.000 title claims description 44
- 229920001131 Pulp (paper) Polymers 0.000 title claims description 3
- 238000004076 pulp bleaching Methods 0.000 title 1
- 238000011282 treatment Methods 0.000 claims description 47
- 108090000790 Enzymes Proteins 0.000 claims description 34
- 102000004190 Enzymes Human genes 0.000 claims description 34
- 238000004061 bleaching Methods 0.000 claims description 31
- 230000003647 oxidation Effects 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 claims description 10
- 230000002255 enzymatic effect Effects 0.000 claims description 10
- 239000007800 oxidant agent Substances 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 7
- 239000004155 Chlorine dioxide Substances 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 235000019398 chlorine dioxide Nutrition 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- 229940088598 enzyme Drugs 0.000 claims 11
- 108010059892 Cellulase Proteins 0.000 claims 1
- 108090000371 Esterases Proteins 0.000 claims 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 claims 1
- 235000011613 Pinus brutia Nutrition 0.000 claims 1
- 241000018646 Pinus brutia Species 0.000 claims 1
- 108010059820 Polygalacturonase Proteins 0.000 claims 1
- 102000003425 Tyrosinase Human genes 0.000 claims 1
- 108060008724 Tyrosinase Proteins 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 229940106157 cellulase Drugs 0.000 claims 1
- 108010093305 exopolygalacturonase Proteins 0.000 claims 1
- 229940059442 hemicellulase Drugs 0.000 claims 1
- 108010002430 hemicellulase Proteins 0.000 claims 1
- 108010062085 ligninase Proteins 0.000 claims 1
- 239000011122 softwood Substances 0.000 claims 1
- 238000002474 experimental method Methods 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 7
- 239000007844 bleaching agent Substances 0.000 description 7
- 239000000460 chlorine Substances 0.000 description 7
- 229910052801 chlorine Inorganic materials 0.000 description 6
- 229920005610 lignin Polymers 0.000 description 5
- 239000002699 waste material Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 231100000331 toxic Toxicity 0.000 description 3
- 230000002588 toxic effect Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000004045 organic chlorine compounds Chemical class 0.000 description 2
- 230000036284 oxygen consumption Effects 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 1
- 241000021559 Dicerandra Species 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 235000010654 Melissa officinalis Nutrition 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910001902 chlorine oxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000000865 liniment Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000021962 pH elevation Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/1057—Multistage, with compounds cited in more than one sub-group D21C9/10, D21C9/12, D21C9/16
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/12—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds
- D21C9/14—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites
- D21C9/142—Bleaching ; Apparatus therefor with halogens or halogen-containing compounds with ClO2 or chlorites with ClO2/Cl2 in a multistage process involving ClO2/Cl2 exclusively
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/147—Bleaching ; Apparatus therefor with oxygen or its allotropic modifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C9/00—After-treatment of cellulose pulp, e.g. of wood pulp, or cotton linters ; Treatment of dilute or dewatered pulp or process improvement taking place after obtaining the raw cellulosic material and not provided for elsewhere
- D21C9/10—Bleaching ; Apparatus therefor
- D21C9/16—Bleaching ; Apparatus therefor with per compounds
- D21C9/163—Bleaching ; Apparatus therefor with per compounds with peroxides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Paper (AREA)
- Hard Magnetic Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Investigating Or Analysing Biological Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FI900549 | 1990-02-02 | ||
| FI900549A FI89814C (fi) | 1990-02-02 | 1990-02-02 | Foerfarande foer blekning av cellulosamassa |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH05509362A true JPH05509362A (ja) | 1993-12-22 |
Family
ID=8529828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3503752A Pending JPH05509362A (ja) | 1990-02-02 | 1991-02-01 | ケミカルパルプの漂白方法 |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0513140B2 (de) |
| JP (1) | JPH05509362A (de) |
| AT (1) | ATE128498T1 (de) |
| CA (1) | CA2075187A1 (de) |
| DE (1) | DE69113444D1 (de) |
| ES (1) | ES2079062T5 (de) |
| FI (1) | FI89814C (de) |
| WO (1) | WO1991011553A1 (de) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI90670C (sv) * | 1991-05-02 | 1994-03-10 | Metsae Serla Oy | Behandling av alkalibehandlad massa för användning i pappersframställning |
| US7816129B2 (en) | 1994-07-29 | 2010-10-19 | Ab Enzymes Gmbh | Production and secretion of proteins of bacterial origin in filamentous fungi |
| EP0905306A1 (de) | 1997-09-26 | 1999-03-31 | Consortium für elektrochemische Industrie GmbH | Mehrkomponentensystem zum Verändern, Abbau oder Bleichen von Lignin, ligninhaltigen Materialien sowie Verfahren zu seiner Anwendung |
| US6602700B1 (en) | 1998-09-04 | 2003-08-05 | University Of Georgia Research Foundation, Inc. | Phenolic acid esterases, coding sequences and methods |
| EP1109912A1 (de) | 1998-09-04 | 2001-06-27 | University Of Georgia Research Foundation, Inc. | Phenolsäure esterasen, kodierende sequenzen und verfahren |
| WO2002052100A2 (en) | 2000-12-22 | 2002-07-04 | Iogen Bio-Products Corporation | Alkaline extraction stages comprising xylanase |
| US7320741B2 (en) | 2001-01-18 | 2008-01-22 | Iogen Bio-Products Corporation | Method of xylanase treatment in a chlorine dioxide bleaching sequence |
| FI20041152L (fi) * | 2002-03-06 | 2004-09-06 | Iogen Bio Products Corp | Kemiallisen massan ksylanaasikäsittely |
| CN1675365A (zh) | 2002-06-14 | 2005-09-28 | 戴弗萨公司 | 木聚糖酶、编码木聚糖酶的核酸以及制备和应用它们的方法 |
| BRPI0707784B1 (pt) | 2006-02-14 | 2018-05-22 | Verenium Corporation | Ácido nucléico isolado, sintético ou recombinante, cassete de expressão, vetor ou veículo de clonagem, célula hospedeira isolada transformada, e método para produção de um polipeptídeo recombinante |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI90888B (fi) * | 1989-02-14 | 1993-12-31 | Enso Gutzeit Oy | Menetelmä selluloosamassan valkaisemiseksi |
| ZA904441B (en) * | 1989-06-22 | 1991-03-27 | Int Paper Co | Enzymatic delignification of lignocellulosic material |
-
1990
- 1990-02-02 FI FI900549A patent/FI89814C/fi not_active IP Right Cessation
-
1991
- 1991-02-01 AT AT91903684T patent/ATE128498T1/de not_active IP Right Cessation
- 1991-02-01 EP EP91903684A patent/EP0513140B2/de not_active Expired - Lifetime
- 1991-02-01 ES ES91903684T patent/ES2079062T5/es not_active Expired - Lifetime
- 1991-02-01 CA CA002075187A patent/CA2075187A1/en not_active Abandoned
- 1991-02-01 JP JP3503752A patent/JPH05509362A/ja active Pending
- 1991-02-01 WO PCT/FI1991/000033 patent/WO1991011553A1/en not_active Ceased
- 1991-02-01 DE DE69113444T patent/DE69113444D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| FI89814C (fi) | 1993-11-25 |
| EP0513140B2 (de) | 1998-03-18 |
| CA2075187A1 (en) | 1991-08-03 |
| ES2079062T3 (es) | 1996-01-01 |
| FI900549L (fi) | 1991-08-03 |
| FI900549A0 (fi) | 1990-02-02 |
| DE69113444D1 (de) | 1995-11-02 |
| ATE128498T1 (de) | 1995-10-15 |
| ES2079062T5 (es) | 1998-07-16 |
| WO1991011553A1 (en) | 1991-08-08 |
| EP0513140A1 (de) | 1992-11-19 |
| FI89814B (fi) | 1993-08-13 |
| EP0513140B1 (de) | 1995-09-27 |
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