JPH0565232B2 - - Google Patents

Info

Publication number
JPH0565232B2
JPH0565232B2 JP25279688A JP25279688A JPH0565232B2 JP H0565232 B2 JPH0565232 B2 JP H0565232B2 JP 25279688 A JP25279688 A JP 25279688A JP 25279688 A JP25279688 A JP 25279688A JP H0565232 B2 JPH0565232 B2 JP H0565232B2
Authority
JP
Japan
Prior art keywords
coating material
coating
repair
paint
laser
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP25279688A
Other languages
Japanese (ja)
Other versions
JPH0299171A (en
Inventor
Toyoichi Shimizu
Masuo Oshima
Asahisa Fujisawa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kansai Paint Co Ltd
Original Assignee
Kansai Paint Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kansai Paint Co Ltd filed Critical Kansai Paint Co Ltd
Priority to JP25279688A priority Critical patent/JPH0299171A/en
Publication of JPH0299171A publication Critical patent/JPH0299171A/en
Publication of JPH0565232B2 publication Critical patent/JPH0565232B2/ja
Granted legal-status Critical Current

Links

Landscapes

  • Application Of Or Painting With Fluid Materials (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

産業上の利用分野 本発明は、粉塵、油滴等の付着に起因する微小
塗膜欠陥部を補修するための塗膜面の補修塗装方
法に関する。 従来の技術及びその問題点 例えば、自動車の車体塗装工程においては、組
立てられた車体は、脱脂、除錆等の塗装前処理の
後、プライマ電着及び焼付け、中塗り及び焼付
け、研摩、上塗り及び焼付け等の工程へ順次移行
され、その後の外観検査において問題がなければ
次の総組立てラインへ送られる。従来、塗膜欠陥
を有し外観検査に不合格となつた車体は、別途設
けられた補修処理ラインへ送られ、塗膜欠陥の補
修処理後、再び外観検査工程へ送られる。前記塗
膜欠陥のほとんどは、浮遊シリコン油滴等の付着
により塗料や弾かれてできた凹所、及び粉塵が塗
膜中に包含されれてできた凸部などの微小欠陥部
が点在することである。 凸状欠陥の場合の補修塗装処理方法の例を第1
4図に示す。 第14図aは、車体の鋼板52上に電着プライ
マ層53、中塗り層54及び上塗り層55が塗装
焼付けされ、上塗り層55に粉塵56が包含され
て直径Xの範囲で外方へ突出した塗膜欠陥部57
が生じた状態を拡大して示す。従来の補修方法に
おいては、まず、塗膜欠陥部57及びその周辺部
を、第14図bに示すように、グラインダ58、
紙やすり等を用いて研削除去し、粉塵56を完全
に取り除く。塗膜欠陥部がシリコン油等の付着に
よる凹所であるときは、同様にして該シリコン油
等の付着物を完全に取り除く。つぎに、スプレー
ガン59を用いて塗料研削部60に補修用塗料6
4を吹付け塗布し(第14図c参照)、乾燥又は
熱源62を用いて焼付けを行い(第14図d参
照)、回転式バフ63等を使用して補修塗膜部6
1を磨き(第14図e参照)、第14図fに示す
ように平滑に仕上げる。 上記従来補修方法は、つぎの問題点を有してい
る。 () 微小な塗膜欠陥部に比べ極めて大きいデイ
スクを備えるグラインダ、又は大きな面積を有
する紙やすり等を用いて塗膜欠陥部及びその周
辺部を研削除去するため、研削部は広範囲に及
び、また場合によりプライマ層や鋼板(被塗
物)にまで達する結果、その上に形成された塗
膜補修部の面積が大きくなり、全体としての塗
膜性能が低下する。 () スプレーガンを用いた補修用塗料の吹付け
塗装は、前記研削部より更に広範な面に施され
るため、多量の補修用塗料を要し、また乾燥焼
付けに用いる熱源を広い範囲に配設しなければ
ならないので多量のエネルギを消費する。 () 上記のような広範囲の研削、塗装、乾燥、
研磨等を要するため、作業時間が例えば全体で
30分以上かかり、従つて補修塗装ラインを別途
に設けなければならず、作業及び設備の双方が
コスト高となる。 () 補修用塗料塗布面積が大きいため、均質な
補修塗装のための熟練者を要する。 これらの問題は、自動車の車体塗装のみなら
ず、広く一般の塗装にも生ずることである。 本発明の目的は、上記問題点を解決し、手間及
び時間を要することなく簡便に塗膜欠陥部の補修
をすることができ、しかも補修部の塗膜性能の低
下をほとんど生じない塗膜面の補修塗装方法を提
供することにある。 問題点を解決するための手段 本発明の上記目的は、粉塵、油滴等の付着に起
因する微小塗膜欠陥部の該粉塵、油滴等及び塗膜
部を除去して塗膜面に微小凹所を形成し、その後
10dyn/cm以上60dyn/cm以下の表面張力を有す
るシートの片面に、塊状に且つ剥離可能に固着さ
れた塗膜形成可能な固体状塗材を前記微小凹所に
押圧転写し、更に該転写塗材を硬化させることを
特徴とする塗膜面の補修塗装方法により達成され
る。 本発明において、上記微小塗膜欠陥部を除去す
るには、レーザ照射又は切削加工機を用いて行う
のが有効であるが、微小凹所を形成し得るのであ
れば、これに限定されない。該微小凹所の大きさ
及び深さをできるだけ小さくするのが、塗膜保護
のため、及び該塗膜の補修塗装を簡便なものとす
るために好ましい。上記の“塗膜形成可能”と
は、塗材中の樹脂が硬化して周囲面の既存塗膜と
一体となつた塗膜を形成し得ることをいう。 実施例 以下に、本発明の実施例を、添付図面を参照し
つつ説明する。 先ず、微小塗膜欠陥部の除去を、レーザ照射に
基づき塗膜面に微小凹所を形成して行う例につき
説明する。第1図aは、第14図aに示したと同
様に、車体の鋼板1上の電着プライマ層2、中塗
り層3及び上塗り層4からなる塗膜の上塗り層4
に、粉塵5が包含されて凸状の微小塗膜欠陥部6
が生じた状態を拡大して示す。まず、第1図bに
示すように、欠陥部6に略対応する光束断面の加
工用レーザ7を、該欠陥部6に垂直に照射し、粉
塵5を含む欠陥部6を昇華させ、該欠陥部6を除
去して微小凹所8を塗膜面に形成する。レーザ7
を放射するためのレーザ加工機の1例を第2図に
示す。 レーザ加工機41は、He−Neレーザ等の位置
合わせ用可視レーザ及び炭酸ガスレーザ、YAG
レーザ等の加工用レーザ7を発振するレーザ発振
器42と、電源43に接続されてレーザ7の出力
及び発振時間を制御する制御部44と、該制御部
44を操作するための操作部45とを備えてい
る。このように構成されたレーザ加工機41を、
まず可視レーザで塗膜欠陥部6に対応し得るよう
に位置決めし、つぎに加工用レーザを出力調整下
に照射する。これにより、補修を要する塗膜欠陥
部6を必要な深さ、例えば上塗り層4深さ、中塗
り層3までの深さ、又は上塗り層4が着色塗膜と
該着色塗膜上の透明性塗膜とで形成されている場
合の透明性塗膜深さまでなど、任意の深さまで昇
華除去させることができ、必要最小限の微小凹所
8を形成することができる。 該微小凹所8を形成するにあたり、第3図に示
すレーザ発振器42′を用いることもできる。該
レーザ発振器42′は、上述のレーザ発振器42
と同様に、可視レーザ7′を発振する可視レーザ
発振器46と、加工用レーザ7を発振する加工用
レーザ発振器47と、筒状の放出部51を有し両
発振器46,47を収容するハウジング50とを
備えている。発振器46から発せられた位置合わ
せ用の可視レーザ7′は、プリズム48によりそ
の照射角度に対し直角方向へ反射され、更にジン
クセレンコーテイングミラー49により反射され
て筒状放出部51を通過し、位置合わせを要する
部位に照射される。加工用レーザ7は、ジンクセ
レンコーテイングミラー49を透過し、可視レー
ザ7′と同じ経路で筒状放出部51を通過して上
記部位に照射される。このレーザ発振器42′は、
そのハウジング50内に、窒素ガス等の不活性ガ
スNが送り込まれるようになつている。該ハウジ
ング50内に充満した不活性ガスNは、筒状放出
部51を通つて上記位置合わせを要する部位、即
ち上述の塗膜欠陥部6とその周辺部とに吹き付け
られ、該欠陥部6及びその周辺を不活性ガスN雰
囲気下におく。これにより、加工用レーザ7の熱
によつて発生する塗膜欠陥部6周辺塗膜面の変色
(樹脂の炭化等の変質による)が抑制される。ま
た、不活性ガスNは、ハウジング50内で循環
し、可視レーザ及び加工用レーザの発振器46,
47を冷却しつつ吐出される。このため、該両発
振器46,47の使用時間にかかわりなく、両発
振器46,47からは安定した出力のレーザ7,
7′を得ることができるという利点もある。 次に、切削加工機を用いた微小塗膜欠陥部の除
去方法の1例を説明する。ここで、“切削加工機”
なる語は、前記微小凹所を形成させ得る穴明け加
工機及び切削工程を含む広義の意味で使用してお
り、例えば小径の回転式ドリル、回転式ヤスリ、
超音波加工機等を用いることができる。 第4図aは、第1図aに示したと同様に、車体
の鋼板1上の電着プライマ層2、中塗り層3及び
上塗り層4からなる塗膜の上塗り層4に、粉塵5
が包含されて凸状の微小塗膜欠陥部6が生じた状
態を拡大して示す。第4図bにおいて、該欠陥部
6の粉塵5及び該粉塵5を覆う塗膜部を切削加工
機を用いて除去するにあたり、本実施例において
は、前記切削加工機として回転式ドリル9を使用
するが、これに限定されるものではない。切削除
去せしめる塗膜の深さは、塗膜欠陥部の状態に基
づき任意に選択でき、例えば上塗り層4深さ、中
塗り層3までの深さ、又は上塗り層4が着色塗膜
と該塗膜上の透明性塗膜とで形成されている場合
の透明性塗膜深さまでなど、任意の深さとするこ
とができ、目的に応じた大きさ及び深さの塗膜部
除去が可能であり、上述の微小凹所8を形成する
ことができる。 次に、形成した微小凹所に押圧転写する塗材に
ついて説明する。第5図は、該塗材の1例を示
し、10dyn/cm以上60dyn/cm以下の表面張力、
好ましくは20dyn/cm以上40dyn/cm以下の表面
張力を有するシート15の片面に、塊状に且つ剥
離可能に固着された塗膜形成可能な固体状塗材1
6である。このような表面張力を有するシート1
5である場合、該シート15に塗材16が固着し
易くなり、該塗材16を微小でありながら肉厚な
点状のものとすることができる。しかも、該塗材
16は、製造時、輪送時及び貯蔵時等において受
ける程度の衝撃では剥離することがなく、それで
いて微小凹所8に当てがわれてシート15裏面か
ら押圧された場合には、該シート15から容易に
剥離され得る。従つて、該塗材16を、微小凹所
8に容易に転写させることができ、該微小凹所8
の補修を簡便なものとし得る。 シート15の表面張力が上記範囲を越えると、
該シート面の塗材16は必要時に剥離し難くな
り、また上記範囲未満である場合には、塗材16
が該シート面から脱落し易くなるばかりでなく、
該塗材16を塊状のものとし得ない。 上記シート15は、平滑性に富むものが好まし
いが、網状若しくは布状であつてもよく、その厚
さは、好ましくは20μm〜1mm、より好ましくは
20μm〜100μmである。また、上記シート15の
組成としては、上述の範囲内にある表面張力を有
する成分であればよく、例えばフツ素樹脂、ポリ
エチレン、ポリプロピレン、ポリエステル、塩化
ビニル樹脂等から選ばれた合成樹脂製シート、
網、布、又はこれら以外の合成樹脂製シート網、
布、紙等に上記合成樹脂やシリコン樹脂等が含
浸、塗装若しくは積層されてなるシートを挙げる
ことができる。シートが網状である場合、その網
目の大きさ、形状等は、塗材が塊状に固着でき、
且つ容易に脱離しない程度であればよい。しかし
ながら、取り扱いを簡便とする上で、これらシー
トは、透明又は半透明であるのが好ましい。 上述の塗膜形成可能な固体状塗材16は、シー
ト15の表面に点状に固着されたものであり、常
温において流動性を殆ど若しくは全く有しておら
ず、しかも硬化塗膜を形成していないことが必要
である。ここで、常温とは、室温から100℃の範
囲内の温度をいう。また、該塗材16は、粘着性
又は被粘着性のいずれの性質を有していてもよ
く、有機溶剤若しくは水又はこれらの混合からな
る溶剤を適量含む湿潤状態若しくはこれらの溶剤
を殆んど含まない乾燥状態のいずれであつてもよ
い。しかし、補修作業の容易性、並びに仕上がり
塗膜面の優れた平滑性を得る上で、上記塗材16
は、非粘着性を有し且つ乾燥状態であるのが好ま
しい。 この塗材16は、微小凹所8に転写(充填)さ
れた後、そのままの状態、或いはその一部若しく
は全部が上記溶剤で湿潤、軟化又は溶解された状
態で、常温放置、加熱又は活性エネルギ線の照射
などにより硬化され、塗膜を形成する。以下に、
上記固体状塗材の主成分となる塗料について詳細
に説明する。 (1) 常温放置により硬化し、塗膜を形成する固体
塗材; (a) 2液型塗料……例えば、ポリオール樹脂/
ポリイソシアネート化合物系、エポキシ樹
脂/アミン類系、不飽和ポリエステル樹脂/
重合性単量体/重合開始剤系などを挙げるこ
とができる。 (b) 触媒硬化型塗料……例えば、硬化触媒とし
て酸性有機化合物を配合してなるアミノ・ア
ルキド樹脂系塗料等を採用できる。 (c) 溶剤揮発型塗料……溶剤が揮発するだけで
固化する塗料であり、例えば熱可塑性アクリ
ル樹脂を主成分とするラツカー、ニトロセル
ロースラツカー、油性系塗料、乾性油変性樹
脂系塗料等を挙げることができる。 これら常温放置により硬化する固体状塗材の
うち溶剤揮発性塗料を主成分とする塗材にあつ
ては、これら塗材を充填前に塗膜面の微小凹所
内に予め溶剤を入れておくか、又は該塗材充填
後に溶剤を用いて湿潤、軟化若しくは溶解させ
ることが好ましい。また、上記2液型塗料又は
触媒軟化型塗料を主成分とする塗材において
は、凹所内で塗膜を形成するのに必ずしも溶剤
を要しなが、該両塗料は、架橋反応により常温
で硬化するので、上記シート表面上で硬化が進
行し過ぎないうちに、前記塗膜面の微小凹所に
充填することが好ましい。 (2) 加熱により硬化し、塗膜を形成する固体状塗
材; (a) 熱硬化型塗料……例えば、基体樹脂及び架
橋剤からなり、加熱によりこれら両成分が反
応して架橋硬化する塗料を挙げることができ
る。上記基体樹脂としては、アルキド樹脂、
ポリエステル樹脂、アルキル樹脂、フツ素樹
脂、シリコン樹脂等を採用でき、上記架橋剤
としては、アミノ樹脂ブロツクポリイソシア
ネート化合物、多価カルボン酸化合物等を採
用できる。また、基体樹脂単独で架橋硬化す
る自己架橋型樹脂を使用できる。 (b) 熱可塑性塗料……例えば、ビニル樹脂、ア
クリル樹脂等の熱可塑性樹脂を主成分とする
塗料を挙げることができる。 (c) 上記(1)において例示した塗料も、加熱によ
り硬化させ得る。 これら加熱により硬化する固体状塗材のう
ち、熱硬化型塗料を主成分とする塗材として
は、溶剤を殆ど若しくは全く含まず、充填後加
熱により溶融した後架橋硬化する塗材、例えば
粉体塗料を主成分とする塗材、及び充填前若し
くは後で溶剤の存在下に軟化し、次いで加熱に
より架橋反応を起こして硬化する塗料などを挙
げることができる。また、熱可塑性塗料は、充
填後、主成分たる熱可塑性樹脂が加熱により溶
融した後硬化するか、又は溶剤の存在下で軟
化、溶解し、加熱により該溶剤を揮発すること
により塗膜を形成する。 上記塗膜面の微小凹所に充填した上記塗材を
加熱する方法として、赤外線、レーザ及び電子
線の照射、熱風の供給、電磁誘導等を採用で
き、特に微小凹所のみを加熱し得るレーザ照射
が有効である。 (3) 紫外線や電子線などの活性エネルギ線照射に
より硬化し、塗膜を形成する塗材; 重合性不飽和結合を有する樹脂(例えば、ア
クリル樹脂、ポリエステル樹脂等)を主成分と
し、必要に応じて重合性不飽和モノマーが配合
された塗料を採用できる。この塗料を凹所に充
填するにあたり、該塗材に予め粘着性を付与し
ておくか、又は溶剤を存在させておくことが好
ましい。 上記(1)〜(3)で例示した塗料を主成分とする塗材
には、必要に応じて着色顔料、メタリツク顔料、
体質顔料、パール顔料、タレ止め剤、可塑剤等を
配合できる。尚、(3)における活性エネルギ照射を
紫外線照射とする場合、該(3)に例示した塗料に光
増感剤を添加するのが好ましく、上記着色顔料等
の着色剤を添加しないのがよい。これにより、該
塗料を主成分とする塗材の硬化を速めることがで
きる。 次に、シート15の片面に塗材16を塊状に且
つ剥離可能に固着させる方法を、第6図を参照し
つつ説明する。 先ず、固体状塗材を構成する成分を、必要に応
じ溶剤中に溶解又は分散させて液状物とする。こ
の液状物(以下、「液状塗料」と記す)の粘度及
び不揮発分等は、シート片面に固着させる大き
さ、形状により任意に選択できる。次に、液状塗
料10のシート15の片面に滴下し、溶剤を揮散
させて固体状の塗材16とする(第5図参照)。
なお、架橋反応により常温で硬化する2液型塗料
及び触媒硬化型塗料等を主成分とする液状塗料に
あつては、原則として上記溶剤の揮散を要しな
い。 図に示すように、該シート15は、支持板14
により保持されていてもよい。これにより、塗材
の取扱いが容易となる。液状塗料10のシート1
5片面への滴下は、例えば注射器、デイスペン
サ、スポイド等の器材13を使用し、該液状塗材
10をこれら器材13から押し出すことにより行
うことができ、針、棒等を用いて流し滴下するこ
ともできる。滴下した塗材中に含まれ得る気泡
は、該塗材が固体化する前に除去しておくことが
望ましい。 シート15に滴下した塗材の溶剤揮散に基づく
固体化は、該シート15が熱により軟化せず且つ
該塗材が完全に硬化しない程度、例えば熱硬化型
塗料が固体状とはなるが架橋硬化しない程度に加
熱し、塗材中に含有されている溶剤の殆ど若しく
は全てを揮散させるか、又は室温で放置して該溶
剤を上記と同様に揮散させることにより行われ
る。 シート15の片面に固着される塗材16の大き
さ、形状は、補修を要する塗膜面の微小凹所8の
大きさに応じた任意のものとすることができる。
例えば、該塗材16を、直径0.1mm〜20mm、高さ
0.3mm〜10mmの範囲内のものとすることができ、
更にその形状を、例えば半球体、直方体、その他
の多面体、円錐体若しくは角錐体又はこれらの組
合わせからなる形状などとすることができる。 上記支持板14の厚さは、シート15に固着し
た塗材の高さと同じ又は該高さ以上であるのが好
ましく、また該支持板の材質としては、例えば塩
化ビニル樹脂、テフロン、ポリエチレン、ポリプ
ロピレン、ポリエステル、紙等を採用できる。該
支持板14とシート15との貼着は、粘着剤又は
接着剤の使用により、或いは熱融着により行われ
る。 このように構成された塊状の固体状塗材16を
微小凹所8に転写し充填する方法を、第7図を参
照しつつ説明する。 先ず、第7図aに示すように、塗膜に存してい
た微小塗膜欠陥部6を上記方法により除去して微
小凹所8を形成し、次いで該微小凹所8内に溶剤
21を滴下して該微小凹所8の壁面を湿潤させて
おく。これにより、塗材16と微小凹所8壁面
(塗膜)との親和性及び付着性を良好なものとす
ることができる。溶剤21としては、塗膜及び塗
材16との親和性に富むものを用いることが好ま
しく、例えば炭化水素系、アルコール系、エステ
ル系、ケトン系、エーテル系等の有機溶剤や水、
又はこれらの混合液を使用することができる。も
つとも、補修用塗材が既存塗膜との親和性、付着
性に富む場合、上記溶剤の滴下を省略することが
できる。次に、シート15の片面に固着された塊
状の固体状塗材16を微小凹所8に当てがい、シ
ート15の裏面から該塗材16を微小凹所8に向
けて押圧する(第7図b及びc参照)。これによ
り、塗材16がシート15から剥離されて微小凹
所8内に転写充填されると共に、該微小凹所8内
の溶剤21の一部か外部に押出され、この溢れ出
る溶剤21により、微小凹所8内への気泡の侵入
が防止される。更に、該溶剤により、塗材16の
表面が溶解、膨潤若しくは軟化して既存塗膜との
親和性及び付着性が良好になる。塗材16の大き
さ、形状は、微小凹所8のそれ同一若しくはやや
大きいことが望ましい。なお、これらの溶剤は、
塗材充填後に付加されてもよい。 微小凹所8に充填した塗材16の硬化方法に
は、常温放置、加熱処理、活性エネルギー照射等
がある。本実施例においては、上記充填塗材16
に更にレーザ7を照射して充填塗材16を加熱
し、硬化させる(第7図d参照)。 該充填部塗材16を硬化させる場合において
も、第3図に例示したレーザ発振器42′を用い
た不活性ガスN雰囲気の下で行なうのが、上述の
如き周辺塗膜面及び充填塗料の変色を防止する上
で好ましい。更にまた、充填塗材16を硬化させ
るにあたり、第3図に示すように、レーザ発振器
42′のハウジング50に取り付けられた筒状放
出部51内にコイル状ヒータ51′を配置し、該
放出部51を通過する不活性ガスNを加熱するの
が好ましい。これにより、高温硬化型塗料(高出
力のレーザ照射で硬化させ得るもの)のみなら
ず、低温硬化型塗料(低出力のレーザ照射により
硬化するもの)も短時間で硬化させ得る。低温硬
化型塗料は、低出力レーザの照射を要するので、
不活性ガスNを加熱しない場合においては、熱伝
導性の高い車体鋼板1の放熱作用の影響が大とな
り、よつて該低温硬化型塗料を硬化させるのに特
に長時間を要していた。しかしながら、加熱され
た不活性ガスN雰囲気下においては、上述の放熱
作用を補うことができ、短時間で硬化させること
が可能となる。なお、上記放熱作用を補う加熱
は、上記の如き不活性ガスの加熱に限られるもの
ではなく、例えば温風の供給による加熱、誘導加
熱、赤外線又は遠赤外線照射による加熱等、種々
の加熱手段を採用できる。 塗材硬化後、充填部塗材16を砥石、回転式小
型バフ29等を用いて平滑化し、仕上げる(第7
図e参照)。 このように、本発明の塗膜欠陥部の補修塗装方
法においては、レーザ照射や切削加工機を用いて
必要最小限の欠陥部を除去し、該欠陥部除去後の
凹所内に必要なだけの補修用塗材を充填し、該充
填部塗材だけを硬化させるので、補修用塗料及び
エネルギの消費量が少なくて済み、また作業に手
間及び時間を要せず、塗装熟練者も要しない。本
発明方法による補修作業時間を従来方法による補
修作業時間と対比させて第1表に示す。
INDUSTRIAL APPLICATION FIELD The present invention relates to a repair coating method for a coating surface for repairing minute coating defects caused by adhesion of dust, oil droplets, etc. Conventional techniques and their problems For example, in the car body painting process of an automobile, the assembled car body is subjected to pre-painting treatments such as degreasing and rust removal, followed by primer electrodeposition and baking, intermediate coating and baking, polishing, top coating and They are sequentially transferred to processes such as baking, and if there are no problems in the subsequent visual inspection, they are sent to the next general assembly line. Conventionally, a vehicle body that has paint film defects and fails a visual inspection is sent to a separately provided repair processing line, and after the paint film defects are repaired, the vehicle body is sent to the visual inspection process again. Most of the paint film defects mentioned above are scattered minute defects such as recesses caused by paint and repelling due to adhesion of floating silicone oil droplets, etc., and convexities caused by dust trapped in the paint film. That's true. An example of the repair painting method for convex defects is shown in the first example.
Shown in Figure 4. FIG. 14a shows that an electrodeposited primer layer 53, an intermediate coat layer 54, and a top coat layer 55 are painted and baked on a steel plate 52 of a car body, and dust 56 is included in the top coat layer 55 and protrudes outward within a diameter X range. Paint film defect area 57
This figure shows an enlarged view of the situation where this occurs. In the conventional repair method, first, the coating film defect 57 and its surrounding area are removed using a grinder 58, as shown in FIG. 14b.
The dust 56 is completely removed by sanding using sandpaper or the like. If the defective part of the coating film is a recess caused by adhesion of silicone oil, etc., the adhesion of silicone oil, etc. is completely removed in the same manner. Next, the repair paint 6 is applied to the paint grinding part 60 using the spray gun 59.
4 is applied by spraying (see Fig. 14 c), dried or baked using a heat source 62 (see Fig. 14 d), and the repair coating part 6 is applied using a rotary buff 63 or the like.
1 (see Fig. 14e) and finished smooth as shown in Fig. 14f. The conventional repair method described above has the following problems. () Since the paint film defects and their surrounding areas are ground away using a grinder with a disk that is extremely large compared to the minute paint film defects, or sandpaper with a large area, the grinding area covers a wide area, and In some cases, the paint reaches the primer layer or the steel plate (subject to be coated), resulting in an increase in the area of the repaired paint film formed thereon, and the overall performance of the paint film deteriorates. () Spraying of repair paint using a spray gun requires a large amount of repair paint because it is applied to a wider area than the ground area, and the heat source used for dry baking must be distributed over a wide area. This consumes a large amount of energy. () Extensive grinding, painting, drying,
Because polishing, etc. is required, the total work time is, for example,
It takes more than 30 minutes, and therefore a separate repair painting line must be installed, resulting in high costs for both work and equipment. () Since the area to be coated with repair paint is large, skilled workers are required to apply uniform repair paint. These problems occur not only in car body painting, but also in general painting. The purpose of the present invention is to solve the above-mentioned problems, and to provide a coating surface that can easily repair defective coating parts without requiring much effort and time, and that causes almost no deterioration in the coating performance of the repaired area. The purpose of the present invention is to provide a repair painting method. Means for Solving the Problems The above-mentioned object of the present invention is to remove dust, oil droplets, etc. and paint film parts from minute paint film defects caused by adhesion of dust, oil droplets, etc. form a recess and then
On one side of a sheet having a surface tension of 10 dyn/cm or more and 60 dyn/cm or less, a solid coating material capable of forming a coating film, which is adhered in a lump and removable manner, is transferred by pressure to the minute depressions, and the transfer coating is further applied. This is achieved by a method of refinishing a painted surface, which is characterized by curing the material. In the present invention, it is effective to remove the minute coating film defects by using a laser irradiation or a cutting machine, but the present invention is not limited to this as long as minute recesses can be formed. It is preferable to make the size and depth of the minute recesses as small as possible in order to protect the paint film and to facilitate repair painting of the paint film. The above-mentioned "capable of forming a coating film" means that the resin in the coating material can be cured to form a coating film that is integrated with the existing coating film on the surrounding surface. Embodiments Hereinafter, embodiments of the present invention will be described with reference to the accompanying drawings. First, an example will be described in which the removal of minute coating film defects is performed by forming minute depressions on the coating surface based on laser irradiation. FIG. 1a shows a top coat layer 4 of a coating film consisting of an electrodeposited primer layer 2, an intermediate coat layer 3 and a top coat layer 4 on a steel plate 1 of a car body, similar to that shown in FIG. 14a.
The dust 5 is included in the convex minute coating film defects 6.
This figure shows an enlarged view of the situation where this occurs. First, as shown in FIG. 1b, a processing laser 7 whose beam cross section approximately corresponds to the defective part 6 is irradiated perpendicularly to the defective part 6, and the defective part 6 containing the dust 5 is sublimated. The portion 6 is removed to form a minute recess 8 on the coating surface. laser 7
An example of a laser beam processing machine for emitting light is shown in FIG. The laser processing machine 41 uses a visible laser for positioning such as a He-Ne laser, a carbon dioxide laser, and a YAG laser.
A laser oscillator 42 that oscillates a processing laser 7 such as a laser, a control section 44 that is connected to a power source 43 and controls the output and oscillation time of the laser 7, and an operation section 45 that operates the control section 44. We are prepared. The laser processing machine 41 configured in this way is
First, a visible laser is used to position the coating film defect 6, and then a processing laser is irradiated with the output adjusted. As a result, the paint film defect 6 that requires repair can be adjusted to a required depth, for example, the depth of the top coat layer 4, the depth up to the intermediate coat layer 3, or the top coat layer 4 is a colored paint film and the transparency on the colored paint film is Sublimation and removal can be performed to any desired depth, such as the depth of a transparent paint film when it is formed with a paint film, and the minimum necessary micro-recesses 8 can be formed. In forming the minute recesses 8, a laser oscillator 42' shown in FIG. 3 can also be used. The laser oscillator 42' is the laser oscillator 42 described above.
Similarly, a visible laser oscillator 46 that oscillates a visible laser 7', a processing laser oscillator 47 that oscillates a processing laser 7, and a housing 50 that has a cylindrical emission part 51 and accommodates both oscillators 46 and 47. It is equipped with The visible laser 7' for positioning emitted from the oscillator 46 is reflected by the prism 48 in a direction perpendicular to its irradiation angle, further reflected by the zinc selenium coating mirror 49, passes through the cylindrical emission part 51, and is reflected by the prism 48 in a direction perpendicular to the irradiation angle. Irradiation is applied to areas that require alignment. The processing laser 7 passes through the zinc selenium coating mirror 49, passes through the cylindrical emission part 51 along the same path as the visible laser 7', and is irradiated onto the above-mentioned region. This laser oscillator 42' is
Inert gas N such as nitrogen gas is fed into the housing 50. The inert gas N filling the housing 50 is blown through the cylindrical discharge part 51 to the area requiring the above-mentioned alignment, that is, the above-mentioned coating film defect part 6 and its surrounding area, and is blown to the defect part 6 and the surrounding area thereof. The surrounding area is placed under an inert gas N atmosphere. This suppresses discoloration (due to deterioration such as carbonization of the resin) of the coating surface around the coating film defect portion 6 caused by the heat of the processing laser 7. Further, the inert gas N circulates within the housing 50, and the visible laser and processing laser oscillators 46,
47 is discharged while being cooled. Therefore, regardless of the usage time of both oscillators 46, 47, the laser 7, which outputs stable output from both oscillators 46, 47,
There is also the advantage that 7' can be obtained. Next, an example of a method for removing minute coating film defects using a cutting machine will be described. Here, “cutting machine”
The term is used in a broad sense to include drilling machines and cutting processes that can form the minute recesses, such as small-diameter rotary drills, rotary files,
An ultrasonic processing machine or the like can be used. FIG. 4a shows that, similarly to the case shown in FIG.
This is an enlarged view of a state in which a convex minute coating film defect 6 is generated by being included. In FIG. 4b, when removing the dust 5 of the defective part 6 and the coating film covering the dust 5 using a cutting machine, in this embodiment, a rotary drill 9 is used as the cutting machine. However, it is not limited to this. The depth of the paint film to be cut and removed can be arbitrarily selected based on the state of the paint film defect. For example, the depth of the top coat layer 4, the depth up to the intermediate coat layer 3, or the depth of the top coat layer 4 between the colored paint film and the paint film. The depth can be set to any desired depth, such as the depth of the transparent coating when it is formed with a transparent coating on the membrane, and it is possible to remove the coating to a size and depth according to the purpose. , the above-mentioned minute recess 8 can be formed. Next, the coating material to be press-transferred to the formed minute recesses will be explained. Figure 5 shows an example of the coating material, which has a surface tension of 10 dyn/cm or more and 60 dyn/cm or less,
A solid coating material 1 capable of forming a coating film, which is adhered in a lump-like and removable manner to one side of a sheet 15, preferably having a surface tension of 20 dyn/cm or more and 40 dyn/cm or less.
It is 6. Sheet 1 having such surface tension
5, the coating material 16 is likely to adhere to the sheet 15, and the coating material 16 can be shaped into small but thick dots. Moreover, the coating material 16 does not peel off even when subjected to impacts such as during manufacturing, transport, storage, etc., and when applied to the minute depressions 8 and pressed from the back surface of the sheet 15. , can be easily peeled off from the sheet 15. Therefore, the coating material 16 can be easily transferred to the minute depressions 8, and the coating material 16 can be easily transferred to the minute depressions 8.
can be easily repaired. If the surface tension of the sheet 15 exceeds the above range,
The coating material 16 on the sheet surface becomes difficult to peel off when necessary, and if it is less than the above range, the coating material 16
Not only does it become easier to fall off the sheet surface,
The coating material 16 cannot be made into lumps. The sheet 15 is preferably highly smooth, but may be mesh-like or cloth-like, and its thickness is preferably 20 μm to 1 mm, more preferably
It is 20 μm to 100 μm. The composition of the sheet 15 may be any component having a surface tension within the above-mentioned range, such as a synthetic resin sheet selected from fluorine resin, polyethylene, polypropylene, polyester, vinyl chloride resin, etc.
Nets, cloth, or other synthetic resin sheet nets,
Examples include sheets formed by impregnating, painting, or laminating cloth, paper, or the like with the synthetic resin, silicone resin, or the like. If the sheet is mesh-like, the size, shape, etc. of the mesh may be such that the coating material can stick in lumps.
It is sufficient that the amount is not easily desorbed. However, for ease of handling, these sheets are preferably transparent or translucent. The solid coating material 16 capable of forming a coating film is fixed in dots on the surface of the sheet 15, has little or no fluidity at room temperature, and does not form a cured coating film. It is necessary that you do not. Here, normal temperature refers to a temperature within the range of room temperature to 100°C. Further, the coating material 16 may have either adhesive or adhesive properties, and may be in a wet state containing an appropriate amount of an organic solvent, water, or a mixture thereof, or in a wet state containing almost no amount of these solvents. It may be in any dry state without containing it. However, in order to facilitate repair work and obtain excellent smoothness of the finished coating surface, the above coating material 16
is preferably non-tacky and dry. After being transferred (filled) into the minute recesses 8, the coating material 16 is left at room temperature, heated, or exposed to active energy, either as it is, or in a state where a part or all of it is moistened, softened, or dissolved with the above-mentioned solvent. It is cured by irradiation with a wire and forms a coating film. less than,
The coating material that is the main component of the above-mentioned solid coating material will be explained in detail. (1) Solid coating materials that harden and form a coating film when left at room temperature; (a) Two-component coatings...for example, polyol resin/
Polyisocyanate compound type, epoxy resin/amine type, unsaturated polyester resin/
Examples include a polymerizable monomer/polymerization initiator system. (b) Catalyst-curing paint...For example, an amino alkyd resin paint containing an acidic organic compound as a curing catalyst can be used. (c) Solvent-volatile paints: Paints that solidify simply by volatilizing the solvent, such as lacquers whose main component is thermoplastic acrylic resin, nitrocellulose lacquers, oil-based paints, dry oil-modified resin-based paints, etc. can be mentioned. Among these solid coating materials that harden when left at room temperature, for coating materials whose main component is solvent-volatile paint, it is necessary to put a solvent in advance into the minute depressions on the coating surface before filling these coating materials. , or after filling the coating material, it is preferable to use a solvent to moisten, soften, or dissolve the coating material. Furthermore, in the case of coating materials whose main components are the above-mentioned two-component paints or catalytically softened paints, a solvent is not necessarily required to form a coating film in the recesses, but these two paints can be used at room temperature due to crosslinking reactions. Since it hardens, it is preferable to fill the minute recesses on the surface of the coating film before curing progresses too much on the surface of the sheet. (2) Solid coating material that hardens by heating to form a coating film; (a) Thermosetting paint...For example, a paint that consists of a base resin and a crosslinking agent, and which crosslinks and hardens by reacting with both components when heated. can be mentioned. As the above-mentioned base resin, alkyd resin,
Polyester resins, alkyl resins, fluororesins, silicone resins, etc. can be used, and as the crosslinking agent, amino resin block polyisocyanate compounds, polyhydric carboxylic acid compounds, etc. can be used. Furthermore, a self-crosslinking resin that is crosslinked and cured by the base resin alone can be used. (b) Thermoplastic paint... Examples include paints whose main component is a thermoplastic resin such as vinyl resin or acrylic resin. (c) The paints exemplified in (1) above can also be cured by heating. Among these solid coating materials that cure by heating, coating materials whose main component is thermosetting coatings include coating materials that contain little or no solvent and are crosslinked and cured after being melted by heating after being filled, such as powder. Examples include coating materials whose main component is paint, and paints that are softened in the presence of a solvent before or after filling, and then cured by causing a crosslinking reaction by heating. In addition, after filling, thermoplastic paints form a coating film by either heating the thermoplastic resin, which is the main component, and then curing it, or softening and dissolving it in the presence of a solvent, and then vaporizing the solvent by heating. do. As a method of heating the coating material filled in the minute depressions on the coating surface, infrared rays, laser and electron beam irradiation, supply of hot air, electromagnetic induction, etc. can be employed, and in particular, laser which can heat only the minute depressions can be used. Irradiation is effective. (3) Coating materials that are cured by irradiation with active energy rays such as ultraviolet rays or electron beams to form a coating film; The main component is a resin containing polymerizable unsaturated bonds (e.g., acrylic resin, polyester resin, etc.) and Depending on the situation, a paint containing a polymerizable unsaturated monomer can be used. When filling the recesses with this paint, it is preferable to impart adhesiveness to the paint material in advance or to make a solvent present therein. Coating materials whose main components are the coatings exemplified in (1) to (3) above may include colored pigments, metallic pigments,
Extender pigments, pearl pigments, anti-sagging agents, plasticizers, etc. can be added. In addition, when the active energy irradiation in (3) is ultraviolet irradiation, it is preferable to add a photosensitizer to the coating material exemplified in (3), and it is preferable not to add a coloring agent such as the above-mentioned colored pigment. Thereby, the curing of the coating material containing the coating material as a main component can be accelerated. Next, a method for releasably adhering the coating material 16 in bulk to one side of the sheet 15 will be explained with reference to FIG. First, the components constituting the solid coating material are dissolved or dispersed in a solvent as necessary to form a liquid. The viscosity, nonvolatile content, etc. of this liquid material (hereinafter referred to as "liquid paint") can be arbitrarily selected depending on the size and shape of the material to be fixed to one side of the sheet. Next, the liquid coating material 10 is dropped onto one side of the sheet 15, and the solvent is evaporated to form a solid coating material 16 (see FIG. 5).
In addition, in the case of liquid paints whose main components are two-component paints and catalyst-curing paints that harden at room temperature through a crosslinking reaction, volatilization of the above-mentioned solvent is not required in principle. As shown in the figure, the sheet 15 is attached to the support plate 14.
It may be held by This makes handling of the coating material easier. 1 sheet of liquid paint 10
5 Dripping onto one side can be performed by using equipment 13 such as a syringe, dispenser, dropper, etc., and pushing out the liquid coating material 10 from these equipment 13, or by pouring and dropping using a needle, stick, etc. You can also do it. It is desirable to remove air bubbles that may be contained in the dropped coating material before the coating material solidifies. The solidification of the coating material dropped onto the sheet 15 due to solvent volatilization occurs to the extent that the sheet 15 is not softened by heat and the coating material is not completely cured, for example, a thermosetting coating material becomes solid but crosslinked and cured. This is carried out by heating to such an extent that most or all of the solvent contained in the coating material is volatilized, or by leaving it at room temperature and volatilizing the solvent in the same manner as above. The size and shape of the coating material 16 fixed to one side of the sheet 15 can be arbitrary depending on the size of the minute recesses 8 on the coating surface that require repair.
For example, the coating material 16 has a diameter of 0.1 mm to 20 mm and a height of 0.1 mm to 20 mm.
Can be within the range of 0.3mm to 10mm,
Furthermore, the shape can be, for example, a hemisphere, a rectangular parallelepiped, another polyhedron, a cone, a pyramid, or a combination thereof. The thickness of the support plate 14 is preferably the same as or greater than the height of the coating material fixed to the sheet 15, and the material of the support plate is, for example, vinyl chloride resin, Teflon, polyethylene, polypropylene. , polyester, paper, etc. can be used. The support plate 14 and the sheet 15 are attached by using an adhesive or an adhesive, or by heat fusion. A method for transferring and filling the lump-like solid coating material 16 configured in this way into the minute recesses 8 will be explained with reference to FIG. 7. First, as shown in FIG. 7a, microscopic coating film defects 6 existing in the coating film are removed by the above method to form microscopic depressions 8, and then a solvent 21 is poured into the microscopic depressions 8. The wall surface of the minute recess 8 is kept moist by dripping. Thereby, the affinity and adhesion between the coating material 16 and the wall surface (coating film) of the minute recess 8 can be improved. As the solvent 21, it is preferable to use a solvent having high affinity with the coating film and the coating material 16, such as hydrocarbon-based, alcohol-based, ester-based, ketone-based, ether-based organic solvents, water,
Or a mixture thereof can be used. However, if the repair coating material has high affinity and adhesion to the existing coating film, the above-mentioned dripping of the solvent can be omitted. Next, a block-like solid coating material 16 fixed to one side of the sheet 15 is applied to the micro-recess 8, and the coating material 16 is pressed from the back surface of the sheet 15 toward the micro-recess 8 (Fig. 7). b and c). As a result, the coating material 16 is peeled off from the sheet 15 and transferred and filled into the micro-recesses 8, and a part of the solvent 21 in the micro-recesses 8 is pushed out to the outside, and this overflowing solvent 21 causes Air bubbles are prevented from entering the micro-recesses 8. Furthermore, the surface of the coating material 16 is dissolved, swollen, or softened by the solvent, thereby improving the affinity and adhesion with the existing coating film. It is desirable that the size and shape of the coating material 16 be the same as or slightly larger than that of the minute recesses 8. In addition, these solvents are
It may be added after filling the coating material. Methods for curing the coating material 16 filled in the minute recesses 8 include leaving it at room temperature, heat treatment, irradiation with active energy, and the like. In this embodiment, the filling coating material 16
Further, the filling coating material 16 is heated and hardened by irradiating the laser 7 (see FIG. 7d). Even in the case of curing the filling part coating material 16, it is done under an inert gas N atmosphere using the laser oscillator 42' illustrated in FIG. This is preferable in terms of preventing. Furthermore, in curing the filler coating material 16, as shown in FIG. Preferably, the inert gas N passing through 51 is heated. As a result, not only high-temperature curing paints (those that can be cured by high-output laser irradiation) but also low-temperature curing paints (those that can be hardened by low-output laser irradiation) can be cured in a short time. Low-temperature curing paints require low-power laser irradiation, so
When the inert gas N is not heated, the influence of the heat dissipation effect of the highly thermally conductive car body steel plate 1 becomes large, and therefore it takes a particularly long time to cure the low temperature curing type paint. However, in a heated inert gas N atmosphere, the above-mentioned heat dissipation effect can be supplemented, and it becomes possible to harden in a short time. Note that the heating that supplements the heat dissipation effect is not limited to the heating of inert gas as described above, but various heating means such as heating by supplying hot air, induction heating, heating by infrared rays or far-infrared irradiation, etc. Can be adopted. After the coating material hardens, the filling portion coating material 16 is smoothed and finished using a grindstone, a small rotary buff 29, etc. (7th step)
(see figure e). In this way, in the repair coating method for defective parts of a paint film of the present invention, the minimum necessary number of defective parts is removed using laser irradiation or a cutting machine, and the necessary amount is filled in the recess after the defective part has been removed. Since the repair coating material is filled and only the filled part coating material is cured, the consumption of the repair coating material and energy is small, and the work does not require labor and time, and does not require a coating expert. Table 1 shows the repair work time by the method of the present invention in comparison with the repair work time by the conventional method.

【表】 第1表に示したように、本発明方法による補修
作業の所要時間は、従来方法による補修作業の所
要時間に比べ約1/9〜1/18と短く、これにより本
ライン内での塗膜欠陥部の補修が可能となり、別
途補修ラインをなくすることもできる。 なお、充填部塗材16を硬化させるにあたり、
上記レーザ7を照射するのに換えて、該充填部塗
材16に熱風を供給し、該熱風と充填部塗材との
接触により加熱し硬化させることもできる。前記
熱風を供給する装置として、第8図に示す熱風供
給装置121を用いることができる。該熱風供給
装置121は、両端に開口を有し一端速開口部が
先細にされた筒状体122内に、電源123に接
続されたコイル状電気ヒータ124と、該電気ヒ
ータ124に向けて空気を送る送風機125とが
配置され、電気ヒータ124により加熱された空
気を筒状体122の小径開口126から吐出する
ものである。このように構成された熱風供給装置
121を用いることにより、熱風を充填部塗材1
6に集中的に供給することができ、迅速に硬化さ
せることができる。第9図に示す熱風供給装置7
1は、両端に開口を有する小径の筒状体72と、
該筒状体72内に配置された電気ヒータ73とを
備え、筒状体72の一端開口から供給される不活
性ガス等の気体を加熱し、他端開口から該加熱気
体を吐出するものである。この熱風供給装置71
も、上記熱風供給装置61と同様の効果を得るこ
とができ、不活性ガスを使用した場合には、塗膜
の変色(樹脂の炭化等の変質による)を防止する
こともできる。 また、充填部塗材16を硬化させるにあたり、
赤外線又は遠赤外線を照射し硬化させることがで
きる。電子線を照射し硬化させることもできる。
赤外線又は遠赤外線(以下、「赤外線」と記す)
を照射する場合、第10図に示すように、例えば
赤外線照射ランプ82と、該ランプ82から照射
される赤外線を一定方向へ反射する半球面形状反
射板83とを備える赤外線照射装置81を使用す
ることができる。電子線を照射する場合には、第
11図に示すように、電子線加速器92と、該加
速器92に高電圧を供給する高電圧発生器93
と、該高電圧発生器93を制御するための制御部
94とを備える電子線照射装置91を採用でき
る。 更に、充填部塗材16を常温で乾燥、又は架橋
反応等の反応に基づき硬化させてもよく、周辺に
相当する車体鋼板1の部位を、電磁誘導により誘
導加熱し、これにより充填部塗材16を硬化させ
てもよい。誘導加熱装置としては、第12図に示
すように、塗膜面に門型に載置された誘導コイル
102に巻回されたコ字形状コア103と、電源
104に接続され誘導コイル102に電流を送る
制御部105とを備え、鋼板1に渦電流を発生さ
せ、該渦電流によるジユール熱によつて該鋼板1
を加熱する誘導加熱装置101を採用できる。こ
の誘導加熱装置101には、鋼板1の温度を検知
し、この検知信号を制御部105へ送る温度セン
サ(図示せず)が備えられていてもよい。これに
より、鋼板1の加熱温度が略一定に保持され得
る。 更に、紫外線硬化型の補修用塗料を用いた場合
には、例えば第13図に示す紫外線照射装置11
1を使用した紫外線照射により迅速に該補修用塗
料を硬化させることができる。紫外線照射装置1
11は、紫外線発生装置112に接続された小径
の光フアイバ113を備え、前記補修用塗材16
に集中して紫外線照射を行い得るものである。前
記紫外線硬化型の補修用塗材としては、紫外線を
透過させ得る透明性塗材を特に有利に採用でき
る。 なお、上記実施例では、粉塵が塗膜中に包含さ
れてできた凸状の塗膜欠陥部を補修方法に関し詳
述したが、浮遊シリコン油滴等の付着により塗料
が弾かれてできた凹状塗膜欠陥部の補修も同様の
方法で行なわれる。この場合、レーザ照射又は回
転式ドリル等の切削加工機で前記油滴等の付着物
を除去する。 また、上塗り層が、例えば着色塗膜及び該着色
塗膜上の透明性塗膜からなり、該上塗り層に粉塵
が包含され、微小塗膜欠陥部となつた場合の補修
用塗材として、着色及び透明性の2種の固体状塗
材を用いて補修塗装することもできる。これら固
体状の着色塗材及び透明性塗材を用いた補修塗材
充填工程及び該塗材を硬化させる工程を以下に説
明する。 先ず、切削加工機やレーザ照射等を用いて上記
着色塗膜までを除去し、微小凹所を形成する。そ
の後、該着色塗膜と同色の上記着色塗材を微小凹
所と同じ厚みとなるように該凹所の底部に押圧、
転写し、上述と同様の方法、即ちレーザ照射、熱
風の供給、赤外線又は電子線照射、常温硬化、誘
導加熱、紫外線照射のいずれかの方法で着色塗材
を硬化させる。つぎに、透明性塗材を、硬化した
着色塗材上に転写して微小凹所をこれら塗材で充
たし、更に凹所内透明性塗材を硬化させる。硬化
した透明性塗料の表面は、上記実施例と同様に、
研磨することにより平滑に仕上げられる。 本実施例においては、硬化させるべき着色塗材
を透明性塗材の分だけ減少させることができ、更
に着色塗料としてメタリツク塗料を用い、その上
に無色透明性塗料がコーテイングされたメタリツ
ク塗装等の補修に特に有利に採用できる。 尚、上記実施例においては、着色塗材を硬化さ
せてのち、透明性塗材を充填し硬化させていた
が、着色塗材を凹所内に入れてのち硬化させない
で透明性塗材を充填し、上述と同様の方法、即ち
レーザ照射、熱風の供給、赤外線又は電子線照
射、常温硬化、誘導加熱、赤外線照射のいずれか
の方法で、或いはこれらいずれかの方法を併用し
て前記両塗材を硬化させてもよい。 本発明方法は、上述の自動車の車体塗装のみな
らず、広く一般の塗装にも採用され得る。 発明の効果 以上から明らかなように、本発明方法によれ
ば、以下に述べる効果を得ることができる。即
ち、微小塗膜欠陥部を、切削加工機やレーザ照射
等を用いて極めて狭い範囲で除去し、これにより
塗膜面に微小凹所を形成するので該微小凹所内に
充填される補修用塗材の使用両は極めて小量でよ
く、該塗材を硬化させるためのエネルギ消費量も
少なくて済む。また、狭い範囲の補修であるた
め、塗膜全体の性能をほとんど低下させることな
く、しかも短時間で補修することができ、且つ仕
上げも簡便であり、補修塗装のための熟練者を特
に要しない。上記補修用塗材の微小凹所内への充
填及び該充填補修用塗材の硬化を不活性ガス雰囲
気下において行なえば、塗膜面の変色を防止する
ことができる。更に、前記塗材の硬化をレーザ照
射、熱風の供給、赤外線照射、電子線照射、誘導
加熱、常温硬化、紫外線照射等の諸方向で行なう
ことができるので、補修用塗材として低温硬化型
から高温硬化型に至る広い範囲の種々の塗材を用
いることができる。更にまた、上記の如く補修時
間が極めて短くなる結果、本ライン内で補修塗装
を行なうことができ、別個の補修ラインを省略す
ることも可能となる。
[Table] As shown in Table 1, the time required for repair work using the method of the present invention is approximately 1/9 to 1/18 shorter than the time required for repair work using the conventional method. It is now possible to repair defective parts of the paint film, and it is also possible to eliminate a separate repair line. In addition, in curing the filling part coating material 16,
Instead of irradiating with the laser 7, hot air may be supplied to the filling portion coating material 16, and the filling portion coating material may be heated and hardened by contact with the hot air. As the device for supplying the hot air, a hot air supply device 121 shown in FIG. 8 can be used. The hot air supply device 121 includes a coiled electric heater 124 connected to a power source 123, and a coiled electric heater 124 that is placed in a cylindrical body 122 having openings at both ends and a tapered opening at one end, and a coiled electric heater 124 that supplies air toward the electric heater 124. A blower 125 is disposed to discharge air heated by the electric heater 124 from the small diameter opening 126 of the cylindrical body 122. By using the hot air supply device 121 configured in this way, hot air can be supplied to the filling part coating material 1.
6 can be supplied intensively and can be rapidly cured. Hot air supply device 7 shown in FIG.
1 is a small diameter cylindrical body 72 having openings at both ends;
It is equipped with an electric heater 73 disposed inside the cylindrical body 72, and heats gas such as an inert gas supplied from an opening at one end of the cylindrical body 72, and discharges the heated gas from the opening at the other end. be. This hot air supply device 71
Also, the same effect as the hot air supply device 61 can be obtained, and when an inert gas is used, discoloration of the coating film (due to deterioration such as carbonization of the resin) can also be prevented. In addition, in curing the filling part coating material 16,
It can be cured by irradiating infrared rays or far infrared rays. It can also be cured by irradiating it with an electron beam.
Infrared rays or far infrared rays (hereinafter referred to as "infrared rays")
When irradiating, as shown in FIG. 10, for example, an infrared irradiation device 81 comprising an infrared irradiation lamp 82 and a hemispherical reflector 83 that reflects the infrared rays irradiated from the lamp 82 in a certain direction is used. be able to. In the case of electron beam irradiation, as shown in FIG.
An electron beam irradiation device 91 can be employed, which includes a controller 94 for controlling the high voltage generator 93. Furthermore, the filling portion coating material 16 may be dried at room temperature or cured based on a reaction such as a crosslinking reaction, and a portion of the car body steel plate 1 corresponding to the surrounding area may be induction heated by electromagnetic induction, thereby forming the filling portion coating material. 16 may be cured. As shown in FIG. 12, the induction heating device consists of a U-shaped core 103 wound around an induction coil 102 placed in a portal shape on the coating surface, and a U-shaped core 103 that is connected to a power source 104 and supplies current to the induction coil 102. The control unit 105 generates an eddy current in the steel plate 1, and the steel plate 1 is generated by the joule heat caused by the eddy current.
An induction heating device 101 for heating can be employed. This induction heating device 101 may be equipped with a temperature sensor (not shown) that detects the temperature of the steel plate 1 and sends a detection signal to the control unit 105. Thereby, the heating temperature of the steel plate 1 can be kept substantially constant. Furthermore, when using an ultraviolet curing type repair paint, for example, an ultraviolet irradiation device 11 shown in FIG.
The repair paint can be rapidly cured by ultraviolet irradiation using No. 1. Ultraviolet irradiation device 1
11 includes a small diameter optical fiber 113 connected to an ultraviolet generator 112, and the repair coating material 16
It is possible to perform ultraviolet irradiation in a concentrated manner. As the UV-curable repair coating material, a transparent coating material that can transmit ultraviolet light can be particularly advantageously employed. In the above example, a method for repairing convex paint film defects caused by dust trapped in the paint film was described in detail. Repair of paint film defects is also carried out in a similar manner. In this case, the deposits such as oil droplets are removed by laser irradiation or by a cutting machine such as a rotary drill. In addition, the top coat layer is composed of, for example, a colored paint film and a transparent paint film on top of the colored paint film, and the colored paint can be used as a repair coating material when dust is included in the top coat layer, resulting in minute paint film defects. Repair painting can also be performed using two types of solid coating materials: transparent and transparent. The repair coating material filling process using these solid colored coating materials and transparent coating materials and the process of curing the coating materials will be explained below. First, using a cutting machine, laser irradiation, etc., the colored coating film is removed to form minute recesses. After that, the colored coating material of the same color as the colored coating film is pressed onto the bottom of the microscopic depression so that it has the same thickness as the microscopic depression,
After transferring, the colored coating material is cured by the same method as described above, that is, by laser irradiation, hot air supply, infrared ray or electron beam irradiation, room temperature curing, induction heating, or ultraviolet irradiation. Next, the transparent coating material is transferred onto the cured colored coating material to fill the minute recesses with the coating material, and the transparent coating material in the recesses is further cured. The surface of the cured transparent paint is similar to the above example,
Polishing gives it a smooth finish. In this embodiment, the amount of colored coating material to be cured can be reduced by the amount of transparent coating material, and furthermore, metallic coating is used as the colored coating and a colorless transparent coating is coated on top of the metallic coating. It can be particularly advantageously used for repairs. In the above example, after the colored coating material was cured, the transparent coating material was filled and cured, but the colored coating material was put into the recess and then the transparent coating material was filled without curing. , by any of the methods described above, namely laser irradiation, supply of hot air, infrared ray or electron beam irradiation, room temperature curing, induction heating, infrared irradiation, or by using any of these methods in combination. may be cured. The method of the present invention can be applied not only to the above-mentioned car body painting, but also to a wide range of general painting. Effects of the Invention As is clear from the above, according to the method of the present invention, the following effects can be obtained. That is, microscopic coating film defects are removed in an extremely narrow range using a cutting machine, laser irradiation, etc., thereby forming microscopic depressions on the coating film surface, so that the repair coating that is filled into the microscopic depressions can be removed. Only a very small amount of material can be used, and the amount of energy consumed for curing the coating material can also be small. In addition, since the repair is a narrow area, there is almost no deterioration in the performance of the entire paint film, and it can be repaired in a short period of time.Furthermore, finishing is easy and does not require a particularly skilled person for repair painting. . If the above-mentioned repair coating material is filled into the micro-recesses and the filled repair coating material is cured in an inert gas atmosphere, discoloration of the coating surface can be prevented. Furthermore, since the coating material can be cured in various directions such as laser irradiation, hot air supply, infrared ray irradiation, electron beam irradiation, induction heating, room temperature curing, and ultraviolet irradiation, it can be used as a repair coating material from low temperature curing type to A wide variety of coating materials can be used, including high temperature curing types. Furthermore, as a result of the extremely short repair time as described above, repair painting can be performed within the main line, making it possible to omit a separate repair line.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図a及びbは本発明の1実施例にかかる塗
膜面の補修塗装方法における微小塗膜欠陥部の除
去工程の1例を示す説明図、第2図は本発明方法
に用いるレーザ加工機の1例を示す概略図、第3
図はレーザ発振器の1例を示す縦断正面図、第4
図a及びbは上記微小塗膜欠陥部の除去工程の他
の例を示す説明図、第5図は本発明で用いる塗膜
形成可能な固体状塗材の1例を示す縦断側面図、
第6図はその作製方法の1例を示す縦断側面図、
第7図a〜eは本発明の上記実施例にかかる塗膜
面の補修塗装方法を段階的に示す説明図、第8図
は熱風供給装置の1例を概略的に示す縦断正面
図、第9図は熱風供給装置の他の例を概略的に示
す縦断正面図、第10図は赤外線照射装置の1例
を概略的に示す縦断正面図、第11図は電子線照
射装置の1例を概略的に示す正面図、第12図は
誘導加熱装置の1例を概略的に示す正面図、第1
3図は紫外線照射装置の1例を概略的に示す正面
図、第14図a〜fは従来の塗膜面補修方法にか
かる補修工程を前記塗膜を用いて段階的に示す説
明図である。 1……車体の鋼板、4……上塗り層、5……粉
塵、6……微小塗膜欠陥部、7……加工用レー
ザ、8……微小凹所、9……回転式ドリル、15
……シート、16……固体状塗材、21……溶
剤。
Figures 1a and b are explanatory diagrams showing an example of the step of removing minute paint film defects in the method for repairing paint surfaces according to one embodiment of the present invention, and Figure 2 is a laser processing method used in the method of the present invention. Schematic diagram showing an example of the machine, Part 3
The figure is a longitudinal sectional front view showing an example of a laser oscillator.
Figures a and b are explanatory diagrams showing another example of the step of removing the minute coating film defects, and Figure 5 is a longitudinal side view showing one example of the solid coating material capable of forming a coating film used in the present invention.
FIG. 6 is a vertical side view showing an example of the manufacturing method;
7a to 7e are explanatory diagrams showing step-by-step the method for repairing a coating surface according to the above-described embodiment of the present invention; FIG. 8 is a longitudinal sectional front view schematically showing an example of a hot air supply device; FIG. 9 is a longitudinal front view schematically showing another example of a hot air supply device, FIG. 10 is a longitudinal front view schematically showing an example of an infrared irradiation device, and FIG. 11 is a longitudinal front view schematically showing an example of an electron beam irradiation device. FIG. 12 is a front view schematically showing an example of an induction heating device;
FIG. 3 is a front view schematically showing an example of an ultraviolet irradiation device, and FIGS. 14 a to 14 f are explanatory diagrams showing a repair process according to a conventional coating film surface repair method step by step using the coating film. . 1... Steel plate of car body, 4... Top coat layer, 5... Dust, 6... Minute coating film defect, 7... Laser for processing, 8... Minute recess, 9... Rotary drill, 15
... sheet, 16 ... solid coating material, 21 ... solvent.

Claims (1)

【特許請求の範囲】[Claims] 1 粉塵、油滴等の付着に起因する微小塗膜欠陥
部の該粉塵、油滴等及び塗膜部を除去して塗膜面
に微小凹所を形成し、その後10dyn/cm以上
60dyn/cm以下の表面張力を有するシートの片面
に、塊状に且つ剥離可能に固着された塗膜形成可
能な固体状塗材を前記微小凹所に押圧転写し、更
に該転写塗材を硬化させることを特徴とする塗膜
面の補修塗装方法。
1. Remove the dust, oil droplets, etc. and the coating film from the microscopic coating film defects caused by the adhesion of dust, oil droplets, etc. to form microscopic depressions on the coating film surface, and then apply 10 dyn/cm or more.
On one side of a sheet having a surface tension of 60 dyn/cm or less, a solid coating material capable of forming a film, which is adhered in a lump-like manner and releasable, is transferred by pressure to the minute depressions, and the transferred coating material is further cured. A repair coating method for a painted surface, which is characterized by:
JP25279688A 1988-10-05 1988-10-05 Coating method for repairing surface of film Granted JPH0299171A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP25279688A JPH0299171A (en) 1988-10-05 1988-10-05 Coating method for repairing surface of film

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP25279688A JPH0299171A (en) 1988-10-05 1988-10-05 Coating method for repairing surface of film

Publications (2)

Publication Number Publication Date
JPH0299171A JPH0299171A (en) 1990-04-11
JPH0565232B2 true JPH0565232B2 (en) 1993-09-17

Family

ID=17242364

Family Applications (1)

Application Number Title Priority Date Filing Date
JP25279688A Granted JPH0299171A (en) 1988-10-05 1988-10-05 Coating method for repairing surface of film

Country Status (1)

Country Link
JP (1) JPH0299171A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19727324C1 (en) * 1997-06-27 1999-04-01 Daimler Benz Ag Method and device for repairing small paint defects in paint layers
EP1268088B1 (en) * 2000-03-16 2007-01-24 Volkswagen Aktiengesellschaft Method for removing minor lacquer imperfections
DE10392212B4 (en) * 2002-01-21 2011-06-09 Kansai Paint Co., Ltd., Amagasaki A method of forming a coating film on a vehicle body
JP2013141651A (en) * 2012-01-11 2013-07-22 Lintec Corp Energy ray irradiation apparatus

Also Published As

Publication number Publication date
JPH0299171A (en) 1990-04-11

Similar Documents

Publication Publication Date Title
US4960611A (en) Method of remedying coating
US5919853A (en) Method and compositions for laser imprinting and articles imprinted using such methods and composition
KR101855604B1 (en) Powder material for three-dimensional object formation, hardening liquid and three-dimensional object formation kit, and formation method and formation apparatus of three-dimensional object
US5824373A (en) Radiation curing of powder coatings on wood
KR100249596B1 (en) Process for the reparir of small paint faults in paint layers
RU2003130275A (en) METHOD FOR PRODUCING DECORATIVE PANELS
EP0996549B1 (en) Method and compositions for laser imprinting, and articles imprinted using such methods and compositions
JPH0565232B2 (en)
US20100183820A1 (en) Methods for curing uv-curable coatings
MXPA04005568A (en) Process for repairing coated substrate surfaces.
JPH01315374A (en) Method for repairing coating film surface
JPH01315375A (en) Method for repairing coating film surface
JP2003501260A (en) How to refinish defects in baked enamel with powder coating
JPH0545312B2 (en)
US7273530B2 (en) Process for the production of decorative coatings on substrates
CN113457954B (en) System and method for processing super-hydrophobic surface by laser
KR930002047B1 (en) Method of remedying coating
JPH0689273B2 (en) Coating film repair material
JP2024042358A (en) Surface treatment method
JP2003200102A5 (en)
JP4984654B2 (en) Water-based paint film forming equipment
JPH10109064A (en) Repairing coating method
JPH06296926A (en) Production of coated body with porous base material powder paint
CN120362115A (en) Material coating system tuned for removal by laser ablation
JPS6031854A (en) Formation of thick film