JPH056834A - Formation method of laminated magnetic film - Google Patents

Formation method of laminated magnetic film

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Publication number
JPH056834A
JPH056834A JP1887891A JP1887891A JPH056834A JP H056834 A JPH056834 A JP H056834A JP 1887891 A JP1887891 A JP 1887891A JP 1887891 A JP1887891 A JP 1887891A JP H056834 A JPH056834 A JP H056834A
Authority
JP
Japan
Prior art keywords
thin film
film
magnetic
laminated
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1887891A
Other languages
Japanese (ja)
Inventor
Takaharu Yonemoto
隆治 米本
Keiji Mashita
啓治 真下
Takashi Ebisawa
孝 海老沢
Junzo Takahashi
純三 高橋
Kenichi Sano
謙一 佐野
Tsugio Miyagawa
亜夫 宮川
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LIMES KK
Original Assignee
LIMES KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LIMES KK filed Critical LIMES KK
Priority to JP1887891A priority Critical patent/JPH056834A/en
Publication of JPH056834A publication Critical patent/JPH056834A/en
Pending legal-status Critical Current

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  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Physical Vapour Deposition (AREA)
  • Magnetic Heads (AREA)
  • Thin Magnetic Films (AREA)

Abstract

PURPOSE:To provide the formation method of a laminated magnetic film wherein it is provided with such characteristics as a high saturation flux density and a low coercive force and it is suitable for the core material or the like of a magnetic head. CONSTITUTION:The title formation method is featured by repeating a process wherein an Fe thin film or an alloy thin film composed mainly of Fe is formed to be in 100 to 500Angstrom , the surface layer of the thin film is then irradiated with the plasma of N2 or the ions of N2, the thin film is nitrided and a nitride film in 10 to 200Angstrom is formed.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、積層磁性体膜の形成方
法に関し、特に磁気ディスク装置、VTR等に用いられ
る磁気ヘッド、磁気ヘッドのコア材料に適した積層磁性
体膜の形成方法に係わる。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method of forming a laminated magnetic film, and more particularly to a method of forming a laminated magnetic film suitable for a magnetic head used in a magnetic disk device, a VTR or the like and a core material of the magnetic head. .

【0002】[0002]

【従来の技術および課題】磁気ヘッドは、その記録時に
おける磁気飽和を防止するために高飽和磁束密度を有す
る材料により形成することが必要である。また、ヘッド
の再生効率の面から、低保磁力、高透磁率の特性を有す
る材料から形成することがことも必要である。
2. Description of the Related Art A magnetic head must be formed of a material having a high saturation magnetic flux density in order to prevent magnetic saturation during recording. Further, from the viewpoint of reproducing efficiency of the head, it is also necessary to form it from a material having characteristics of low coercive force and high magnetic permeability.

【0003】高飽和磁束密度を有する磁性材料として
は、鉄が知られている。しかしながら、鉄はスパッタリ
ング、蒸着等の通常の成膜技術を用いて多結晶膜を形成
させた場合には、保磁力が大きく磁気ヘッド材料として
使用することが難しい。
Iron is known as a magnetic material having a high saturation magnetic flux density. However, iron has a large coercive force and is difficult to use as a magnetic head material when a polycrystalline film is formed by using a normal film forming technique such as sputtering or vapor deposition.

【0004】また、Feの軟磁気特性の改善のためにF
eを主成分とする合金の開発が進められている。しかし
ながら、これらの合金の中で飽和磁束密度が1.8T以
上の材料の多くは保磁力が大きく、磁気ヘッド材料とし
ては特性的に十分満足するものではない。
Further, in order to improve the soft magnetic properties of Fe, F
Development of alloys containing e as a main component is in progress. However, among these alloys, most of the materials having a saturation magnetic flux density of 1.8 T or more have a large coercive force, and are not sufficiently satisfactory in characteristics as magnetic head materials.

【0005】このようなことから、軟磁気特性を改善す
る方法としてFeと他の化合物、金属とを積層する方法
が試みられている。例えば、Fe薄膜と積層される薄膜
としてSiO2 、Al2 3 などの非磁性化合物、A
l、Ag、Cuなどの非磁性金属、Co、Ni、Fe−
Ni合金などの磁性金属が用いられている。
Under these circumstances, a method of laminating Fe with another compound or a metal has been attempted as a method of improving the soft magnetic characteristics. For example, as a thin film laminated with a Fe thin film, a non-magnetic compound such as SiO 2 or Al 2 O 3 , A
l, Ag, Cu and other non-magnetic metals, Co, Ni, Fe-
A magnetic metal such as a Ni alloy is used.

【0006】しかしながら、前記薄膜は飽和磁束密度が
磁性金属においてもFeの飽和磁束密度以下であるた
め、必然的に積層膜の飽和磁束密度がFeよりも低くな
り、保磁力を低下させることができるものの、磁気ヘッ
ド材料としては十分満足するものではない。
However, since the saturation magnetic flux density of the thin film is less than that of Fe even in a magnetic metal, the saturation magnetic flux density of the laminated film is inevitably lower than that of Fe and the coercive force can be lowered. However, it is not a satisfactory magnetic head material.

【0007】[0007]

【発明が解決しようとする課題】本発明は、前記従来の
問題点を解消するためになされたもので、低保磁力、高
透磁率および高飽和磁束密度の特性を有する積層磁性膜
の形成方法を提供しようとするものである。
SUMMARY OF THE INVENTION The present invention has been made to solve the above-mentioned conventional problems, and is a method for forming a laminated magnetic film having characteristics of low coercive force, high permeability and high saturation magnetic flux density. Is to provide.

【0008】[0008]

【課題を解決するための手段】本発明は、Fe薄膜また
はFeを主成分とする合金薄膜を成膜した後に前記薄膜
の表面層を窒化して窒化層を形成する工程とを繰り返す
ことを特徴とする積層磁性体膜の形成方法である。前記
Feを主成分とする合金としては、例えばFe−Co合
金、Fe−Ni合金等を挙げることができる。
The present invention is characterized in that the steps of forming an Fe thin film or an alloy thin film containing Fe as a main component and then nitriding the surface layer of the thin film to form a nitride layer are repeated. And a method of forming a laminated magnetic film. Examples of the alloy containing Fe as a main component include Fe—Co alloy and Fe—Ni alloy.

【0009】前記Fe薄膜またはFeを主成分とする合
金薄膜の厚さは、100〜500オングストローム
(A)とすることが望ましい。この理由は、前記薄膜の
厚さを100A未満にすると飽和磁束密度が低下する恐
れがあり、一方前記薄膜の厚さが500Aを越えるFe
薄膜等の結晶粒の粗大化などの原因によって保磁力が大
きくなる恐れがある。前記窒化処理としては、低温で窒
化層を形成することが可能なN2 プラズマまたはN2
オンを前記薄膜表面に照射する方法を用いることが望ま
しい。
The thickness of the Fe thin film or the alloy thin film containing Fe as a main component is preferably 100 to 500 angstrom (A). The reason for this is that if the thickness of the thin film is less than 100 A, the saturation magnetic flux density may decrease, while the thickness of the thin film exceeds 500 A Fe.
The coercive force may increase due to the coarsening of crystal grains of a thin film or the like. As the nitriding treatment, it is desirable to use a method of irradiating the surface of the thin film with N 2 plasma or N 2 ions capable of forming a nitride layer at a low temperature.

【0010】前記窒化層の厚さは、10〜200オング
ストローム(A)とすることが望ましい。この理由は、
前記窒化層の厚さを10A未満にすると保磁力を低くす
る作用を十分達成することが困難となり、一方前記窒化
層の厚さが200Aを越えると飽和磁束密度の低下が大
きくなる恐れがある。
The thickness of the nitride layer is preferably 10 to 200 Å (A). The reason for this is
If the thickness of the nitride layer is less than 10 A, it becomes difficult to sufficiently achieve the action of lowering the coercive force. On the other hand, if the thickness of the nitride layer exceeds 200 A, the saturation magnetic flux density may be greatly reduced.

【0011】[0011]

【作用】本発明によれば、Fe薄膜またはFeを主成分
とする合金薄膜を成膜した後に前記薄膜の表面層を窒化
して窒化層を形成する工程を繰り返すことによって、F
e単体の磁性体膜に比べて飽和磁束密度が高く、かつ低
保持力の軟磁気特性を有し、しかも内部応力が低減され
た積層磁性体膜を形成することができる。
According to the present invention, the steps of forming an Fe thin film or an alloy thin film containing Fe as a main component and then nitriding the surface layer of the thin film to form a nitride layer are repeated.
It is possible to form a laminated magnetic film having a high saturation magnetic flux density, a low coercive force, and a soft magnetic characteristic as compared with a magnetic film made of e alone, and having reduced internal stress.

【0012】すなわち、Fe窒化物層をFe薄膜または
Feを主成分とする合金薄膜と共に積層した場合、高飽
和磁束密度で低保磁力の積層磁性体膜を作製することが
可能である。しかしながら、前記Fe窒化物層をN2
スを使用した反応性スパッタリングや反応性蒸着などの
方法で前記Fe薄膜またはFeを主成分とする合金薄膜
と共に積層した場合、得られた積層磁性体膜の内部応力
が大きくなるため、期待したほどの保磁力の低下が見ら
れないという問題がある。これに対し、本発明のように
成膜したFe薄膜またはFeを主成分とする合金薄膜の
表面層を窒化して窒化層を形成することによって、窒化
層の形成に起因する内部応力の増大を防止できる。その
結果、前記薄膜の表面層を窒化して窒化層を形成する工
程を繰り返すことによって、Fe単体の磁性体膜に比べ
て飽和磁束密度が高く、かつ低保持力の軟磁気特性を有
し、内部応力を低減した積層磁性体膜を形成できる。
That is, when the Fe nitride layer is laminated with the Fe thin film or the alloy thin film containing Fe as a main component, it is possible to produce a laminated magnetic film having a high saturation magnetic flux density and a low coercive force. However, when the Fe nitride layer is laminated with the Fe thin film or the alloy thin film containing Fe as a main component by a method such as reactive sputtering or reactive vapor deposition using N 2 gas, the obtained laminated magnetic film is Since the internal stress increases, there is a problem that the expected decrease in coercive force is not observed. On the other hand, by nitriding the surface layer of the Fe thin film or the alloy thin film containing Fe as a main component formed as in the present invention to form a nitride layer, the internal stress due to the formation of the nitride layer is increased. It can be prevented. As a result, by repeating the step of nitriding the surface layer of the thin film to form a nitride layer, the saturation magnetic flux density is higher than that of the magnetic film made of only Fe, and the soft magnetic characteristics have low coercive force, A laminated magnetic film with reduced internal stress can be formed.

【0013】[0013]

【実施例】以下、本発明の実施例を詳細に説明する。 実施例1EXAMPLES Examples of the present invention will be described in detail below. Example 1

【0014】まず、コーニング社製7059のガラスか
らなる基板上に、Feターゲットを用い直流マグネトロ
ンスパッタリングによりFe薄膜を成膜した。この時、
Arガス圧は、3×10-3torr、成膜速度は3A/se
cとした。つづいて、前記Fe薄膜にECRN2 プラズ
マを照射してプラズマ窒化を行なった。この時、N2
力は0.5mtorr、マイクロ波圧力は400Wとした。
このような処理により厚さ200AのFe薄膜に50A
のFe窒化層が形成された。次いで、前記操作を繰り返
して全厚さが5000Aの積層膜を前記基板上に形成し
た。 比較例1
First, an Fe thin film was formed on a substrate made of Corning 7059 glass by DC magnetron sputtering using an Fe target. This time,
Ar gas pressure is 3 × 10 −3 torr, film formation rate is 3 A / se
c. Subsequently, the Fe thin film was irradiated with ECRN 2 plasma for plasma nitriding. At this time, the N 2 pressure was 0.5 mtorr and the microwave pressure was 400 W.
With such a treatment, a Fe thin film with a thickness of 200 A has a thickness of 50 A.
Fe nitride layer was formed. Then, the above operation was repeated to form a laminated film having a total thickness of 5000 A on the substrate. Comparative Example 1

【0015】実施例1と同様な基板上に、電子銃加熱方
式によりFeを真空蒸着した。この時のFeの成膜速度
は、3A/secとした。つづいて、電子銃加熱方式に
よりFeを真空蒸着すると共に、N2 ガスを導入する反
応性蒸着によりFe窒化膜を成膜した。この時、N2
ス圧力は2×10-5torr、成膜速度は0.5A/sec
とした。このような処理により厚さ200AのFe薄膜
と50AのFe窒化膜とが形成された。次いで、前記操
作を繰り返して全厚さが5000Aの積層膜を前記基板
上に形成した。 比較例2
Fe was vacuum-deposited on the same substrate as in Example 1 by the electron gun heating method. The Fe deposition rate at this time was 3 A / sec. Subsequently, Fe was vacuum-deposited by an electron gun heating method, and a Fe nitride film was formed by reactive vapor deposition in which N 2 gas was introduced. At this time, the N 2 gas pressure was 2 × 10 −5 torr and the film formation rate was 0.5 A / sec.
And By such a treatment, a 200 A thick Fe thin film and a 50 A Fe nitride film were formed. Then, the above operation was repeated to form a laminated film having a total thickness of 5000 A on the substrate. Comparative example 2

【0016】実施例1と同様な直流マグネトロンスパッ
タリングにより基板上に、Fe薄膜を成膜した。つづい
て、反応性スパッタリングにより前記Fe薄膜上にFe
窒化膜を成膜した。この時、Feターゲットを使用し、
2 流量/Ar流量の比が0.2のArとN2 の混合ガ
スを使用し、その全圧力を3×10-3torrとした。この
ような処理により厚さ200AのFe薄膜と50AのF
e窒化膜とが形成された。次いで、前記操作を繰り返し
て全厚さが5000Aの積層膜を前記基板上に形成し
た。
An Fe thin film was formed on the substrate by the same DC magnetron sputtering as in Example 1. Then, Fe is deposited on the Fe thin film by reactive sputtering.
A nitride film was formed. At this time, using a Fe target,
A mixed gas of Ar and N 2 having an N 2 flow rate / Ar flow rate ratio of 0.2 was used, and the total pressure thereof was set to 3 × 10 −3 torr. By such treatment, a Fe thin film with a thickness of 200 A and an F thin film with a thickness of 50 A
An e-nitride film was formed. Then, the above operation was repeated to form a laminated film having a total thickness of 5000 A on the substrate.

【0017】得られた各積層膜について、飽和磁束密
度、保磁力及び膜の応力を測定した。その結果を下記表
1に示す。なお、膜の応力は成膜前後の基板の反りを測
定することにより求めた。 前記表1から明らかなように実施例1により得られた
積層膜は、比較例1、2の積層膜に比べて低残留応力で
低保磁力であることがわかる。 実施例2
The saturation magnetic flux density, the coercive force, and the stress of the film were measured for each of the obtained laminated films. The results are shown in Table 1 below. The stress of the film was determined by measuring the warp of the substrate before and after film formation. As is clear from Table 1 above, the laminated film obtained in Example 1 has lower residual stress and lower coercive force than the laminated films of Comparative Examples 1 and 2. Example 2

【0018】実施例1と同様な方法により下記表2に示
すようにFe薄膜の厚さおよびFe窒化層の厚さを変化
させ、かつ全膜厚が約5000Aになるように積層数
(2種の膜を1層として計算)を変化させて12種の積
層膜を前記ガラス基板上に形成した。
By the same method as in Example 1, the thickness of the Fe thin film and the thickness of the Fe nitride layer were changed as shown in Table 2 below, and the number of layers (two types) was set so that the total film thickness was about 5000A. The film of (1) was calculated as one layer, and 12 kinds of laminated films were formed on the glass substrate by changing.

【0019】得られた各積層膜について、飽和磁束密度
および保磁力を測定した。その結果を下記表2に併記し
た。なお、下記表2のNo13は、Feのみからなる膜
である。
The saturation magnetic flux density and the coercive force of each obtained laminated film were measured. The results are also shown in Table 2 below. No. 13 in Table 2 below is a film made of only Fe.

【0020】前記表2に明らかなようにNo13のFe
単層膜の保磁力は、10Oe以上であるが、Fe薄膜と
Fe窒化層を所定の膜厚比で積層することによって、保
磁力は3Oe以下に低下し、しかも軟磁気特性もFe単
層膜より優れた積層膜を形成できることがわかる。
As is apparent from Table 2, No 13 Fe
The coercive force of the single layer film is 10 Oe or more, but the coercive force is reduced to 3 Oe or less by stacking the Fe thin film and the Fe nitride layer at a predetermined film thickness ratio, and the soft magnetic property is also the Fe single layer film. It can be seen that a more excellent laminated film can be formed.

【0021】しかしながら、Fe窒化層の厚さが10A
未満のNo1の積層膜では、飽和磁束密度の増加が見ら
れるが、保磁力の低下が少ない。また、Fe窒化層の厚
さが200Aを越えるNo6の積層膜、Fe薄膜の厚さ
が100A未満のNo7の積層膜では、飽和磁束密度の
低が著しく、保磁力の低かも少ない。更に、Fe薄膜の
厚さが500Aを越えるNo12の積層膜ではFe薄膜
が厚くなり過ぎて積層の効果が低下し、保磁力の低下が
ほとんど見られなくなる。
However, the thickness of the Fe nitride layer is 10 A
In the No. 1 laminated film of less than 1, the saturation magnetic flux density is increased, but the coercive force is not significantly decreased. Further, in the No. 6 laminated film in which the Fe nitride layer thickness exceeds 200 A and in the No. 7 laminated film in which the Fe thin film thickness is less than 100 A, the saturation magnetic flux density is remarkably low, and the coercive force is low. Further, in the No. 12 laminated film in which the thickness of the Fe thin film exceeds 500 A, the Fe thin film becomes too thick and the stacking effect is reduced, so that the coercive force is hardly reduced.

【0022】[0022]

【発明の効果】以上詳述した如く、本発明によれば高飽
和磁束密度、低保磁力の特性を有し、磁気ヘッドのコア
材等に適した積層磁性膜を形成することができる。した
がって、磁気ヘッドの主磁極膜として用いた場合、0.
2μm程度の薄膜にしても磁気飽和を起すことなく、磁
極の先端に強い磁束を発生することができ、超高密度磁
気記録を達成することができる。
As described above in detail, according to the present invention, it is possible to form a laminated magnetic film having characteristics of high saturation magnetic flux density and low coercive force and suitable for a core material of a magnetic head and the like. Therefore, when used as the main magnetic pole film of the magnetic head,
Even if the thin film has a thickness of about 2 μm, a strong magnetic flux can be generated at the tip of the magnetic pole without causing magnetic saturation, and super high density magnetic recording can be achieved.

───────────────────────────────────────────────────── フロントページの続き (72)発明者 海老沢 孝 東京都港区西新橋1丁目7番2号 株式会 社ライムズ内 (72)発明者 高橋 純三 東京都港区西新橋1丁目7番2号 株式会 社ライムズ内 (72)発明者 佐野 謙一 東京都港区西新橋1丁目7番2号 株式会 社ライムズ内 (72)発明者 宮川 亜夫 東京都港区西新橋1丁目7番2号 株式会 社ライムズ内   ─────────────────────────────────────────────────── ─── Continued front page    (72) Inventor Takashi Ebisawa             1-7-2 Nishi-Shimbashi, Minato-ku, Tokyo Stock market             Inside the company limes (72) Inventor Junzo Takahashi             1-7-2 Nishi-Shimbashi, Minato-ku, Tokyo Stock market             Inside the company limes (72) Inventor Kenichi Sano             1-7-2 Nishi-Shimbashi, Minato-ku, Tokyo Stock market             Inside the company limes (72) Inventor Ao Miyagawa             1-7-2 Nishi-Shimbashi, Minato-ku, Tokyo Stock market             Inside the company limes

Claims (4)

【特許請求の範囲】[Claims] 【請求項1】 Fe薄膜またはFeを主成分とする合金
薄膜を成膜した後に前記薄膜の表面層を窒化して窒化層
を形成する工程を繰り返すことを特徴とする積層磁性体
膜の形成方法。
1. A method of forming a laminated magnetic film, which comprises repeating a step of forming an Fe thin film or an alloy thin film containing Fe as a main component and then nitriding a surface layer of the thin film to form a nitride layer. .
【請求項2】 前記窒化処理はN2 プラズマまたはN2
イオンを前記薄膜表面に照射することによりなされるこ
とを特徴とする請求項1記載の積層磁性体膜の形成方
法。
2. The nitriding treatment is N 2 plasma or N 2
The method for forming a laminated magnetic film according to claim 1, wherein the method is performed by irradiating the surface of the thin film with ions.
【請求項3】 Fe薄膜またはFeを主成分とする合金
薄膜の厚さは、100〜500オングストローム(A)
であることを特徴とする請求項1記載の積層磁性体膜の
形成方法。
3. The thickness of the Fe thin film or the alloy thin film containing Fe as a main component is 100 to 500 angstrom (A).
2. The method for forming a laminated magnetic film according to claim 1, wherein
【請求項4】 前記窒化層の厚さは10〜200オング
ストローム(A)であることを特徴とする請求項1記載
の積層磁性体膜の形成方法。
4. The method for forming a laminated magnetic film according to claim 1, wherein the nitride layer has a thickness of 10 to 200 angstroms (A).
JP1887891A 1991-02-12 1991-02-12 Formation method of laminated magnetic film Pending JPH056834A (en)

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Application Number Priority Date Filing Date Title
JP1887891A JPH056834A (en) 1991-02-12 1991-02-12 Formation method of laminated magnetic film

Publications (1)

Publication Number Publication Date
JPH056834A true JPH056834A (en) 1993-01-14

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Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001052244A1 (en) * 2000-01-07 2001-07-19 Storage Technology Corporation Nitrided elements and method of making same
WO2004055784A1 (en) * 2002-12-18 2004-07-01 Fujitsu Limited Magnetic thin film and magnetic head using the same
US7485378B2 (en) * 2004-03-19 2009-02-03 Hitachi Global Storage Technologies Netherlands B.V. Magnetic thin film head

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61141114A (en) * 1984-12-14 1986-06-28 Hitachi Ltd Magnetic film manufacturing method
JPH02263416A (en) * 1988-12-15 1990-10-26 Matsushita Electric Ind Co Ltd Method for manufacturing soft magnetic alloy film

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61141114A (en) * 1984-12-14 1986-06-28 Hitachi Ltd Magnetic film manufacturing method
JPH02263416A (en) * 1988-12-15 1990-10-26 Matsushita Electric Ind Co Ltd Method for manufacturing soft magnetic alloy film

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001052244A1 (en) * 2000-01-07 2001-07-19 Storage Technology Corporation Nitrided elements and method of making same
US6473960B1 (en) 2000-01-07 2002-11-05 Storage Technology Corporation Method of making nitrided active elements
US6915559B1 (en) 2000-01-07 2005-07-12 Storage Technology Corporation Method of manufacturing a read head
WO2004055784A1 (en) * 2002-12-18 2004-07-01 Fujitsu Limited Magnetic thin film and magnetic head using the same
US7485378B2 (en) * 2004-03-19 2009-02-03 Hitachi Global Storage Technologies Netherlands B.V. Magnetic thin film head

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