JPH06100871A - 改良された水素化転化法 - Google Patents

改良された水素化転化法

Info

Publication number: JPH06100871A
Authority: JP; Japan
Prior art keywords: oil; metal; catalyst; molybdenum; boiling
Prior art date: 1992-07-02
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Pending

Application number

JP5151949A

Other languages

English (en)

Japanese (ja)

Inventor

Michael K Porter

マイケル・ケビン・ポーター

Glenn A Clausen

グレン・アレン・クローゼン

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Texaco Development Corp

Original Assignee

Texaco Development Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-07-02

Filing date

1993-06-23

Publication date

1994-04-12

1993-06-23 Application filed by Texaco Development Corp filed Critical Texaco Development Corp

1994-04-12 Publication of JPH06100871A publication Critical patent/JPH06100871A/ja

Status Pending legal-status Critical Current

Links

238000000034 method Methods 0.000 title claims abstract description 25
239000003921 oil Substances 0.000 claims abstract description 68
229910052751 metal Inorganic materials 0.000 claims abstract description 66
239000002184 metal Substances 0.000 claims abstract description 66
229930195733 hydrocarbon Natural products 0.000 claims abstract description 42
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 42
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 39
150000001875 compounds Chemical class 0.000 claims abstract description 39
238000009835 boiling Methods 0.000 claims abstract description 26
238000006243 chemical reaction Methods 0.000 claims abstract description 24
239000011148 porous material Substances 0.000 claims abstract description 22
239000007787 solid Substances 0.000 claims abstract description 20
239000002638 heterogeneous catalyst Substances 0.000 claims abstract description 19
RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 17
239000001257 hydrogen Substances 0.000 claims description 26
229910052739 hydrogen Inorganic materials 0.000 claims description 26
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 25
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 20
229910052799 carbon Inorganic materials 0.000 claims description 19
230000001965 increasing effect Effects 0.000 claims description 13
150000002736 metal compounds Chemical class 0.000 claims description 13
238000011065 in-situ storage Methods 0.000 claims description 7
230000003197 catalytic effect Effects 0.000 claims description 2
239000003054 catalyst Substances 0.000 abstract description 44
229910052750 molybdenum Inorganic materials 0.000 abstract description 38
229910052717 sulfur Inorganic materials 0.000 abstract description 14
239000000295 fuel oil Substances 0.000 abstract description 6
229910052759 nickel Inorganic materials 0.000 abstract description 6
150000002739 metals Chemical class 0.000 abstract description 5
229910052757 nitrogen Inorganic materials 0.000 abstract description 4
239000000126 substance Substances 0.000 abstract description 4
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
ZAMXQXCSMBMVRG-UHFFFAOYSA-J molybdenum(4+) naphthalene-1-carboxylate Chemical compound C1(=CC=CC2=CC=CC=C12)C(=O)[O-].[Mo+4].C1(=CC=CC2=CC=CC=C12)C(=O)[O-].C1(=CC=CC2=CC=CC=C12)C(=O)[O-].C1(=CC=CC2=CC=CC=C12)C(=O)[O-] ZAMXQXCSMBMVRG-UHFFFAOYSA-J 0.000 abstract 1
239000011733 molybdenum Substances 0.000 description 37
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 23
239000000203 mixture Substances 0.000 description 14
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 13
XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 13
239000011593 sulfur Substances 0.000 description 13
PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
238000001994 activation Methods 0.000 description 11
150000003839 salts Chemical class 0.000 description 11
230000004913 activation Effects 0.000 description 10
230000008569 process Effects 0.000 description 10
230000001186 cumulative effect Effects 0.000 description 7
239000007789 gas Substances 0.000 description 7
229910052742 iron Inorganic materials 0.000 description 7
239000010936 titanium Substances 0.000 description 7
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
239000010779 crude oil Substances 0.000 description 6
230000000694 effects Effects 0.000 description 6
238000005984 hydrogenation reaction Methods 0.000 description 6
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
-1 asphaltene Substances 0.000 description 5
239000011651 chromium Substances 0.000 description 5
239000000571 coke Substances 0.000 description 5
239000007788 liquid Substances 0.000 description 5
230000003134 recirculating effect Effects 0.000 description 5
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
239000003426 co-catalyst Substances 0.000 description 4
229910017052 cobalt Inorganic materials 0.000 description 4
239000010941 cobalt Substances 0.000 description 4
WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 description 4
238000002474 experimental method Methods 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
239000011572 manganese Substances 0.000 description 4
239000010955 niobium Substances 0.000 description 4
229910000510 noble metal Inorganic materials 0.000 description 4
239000010948 rhodium Substances 0.000 description 4
229910052719 titanium Inorganic materials 0.000 description 4
229910052720 vanadium Inorganic materials 0.000 description 4
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 3
239000002253 acid Substances 0.000 description 3
229910052804 chromium Inorganic materials 0.000 description 3
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
239000010949 copper Substances 0.000 description 3
238000004821 distillation Methods 0.000 description 3
239000011777 magnesium Substances 0.000 description 3
VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 3
238000012360 testing method Methods 0.000 description 3
GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 3
VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 2
KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 2
150000007513 acids Chemical class 0.000 description 2
239000008186 active pharmaceutical agent Substances 0.000 description 2
239000010692 aromatic oil Substances 0.000 description 2
229910052797 bismuth Inorganic materials 0.000 description 2
JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 2
238000001354 calcination Methods 0.000 description 2
239000011575 calcium Substances 0.000 description 2
150000001735 carboxylic acids Chemical class 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
238000001035 drying Methods 0.000 description 2
229910052735 hafnium Inorganic materials 0.000 description 2
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
229910052741 iridium Inorganic materials 0.000 description 2
GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
229910052749 magnesium Inorganic materials 0.000 description 2
229910052748 manganese Inorganic materials 0.000 description 2
239000000463 material Substances 0.000 description 2
238000002156 mixing Methods 0.000 description 2
GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 2
229910052758 niobium Inorganic materials 0.000 description 2
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
229910052762 osmium Inorganic materials 0.000 description 2
SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 2
229910052763 palladium Inorganic materials 0.000 description 2
229910052697 platinum Inorganic materials 0.000 description 2
229910052702 rhenium Inorganic materials 0.000 description 2
WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 2
229910052703 rhodium Inorganic materials 0.000 description 2
MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 2
229910052707 ruthenium Inorganic materials 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011734 sodium Substances 0.000 description 2
229910052715 tantalum Inorganic materials 0.000 description 2
GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 2
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
229910052721 tungsten Inorganic materials 0.000 description 2
239000010937 tungsten Substances 0.000 description 2
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
229910052726 zirconium Inorganic materials 0.000 description 2
DKIJBUAXSIPIKK-UHFFFAOYSA-J C(CCCCC)(=O)[O-].[Mo+4].C(CCCCC)(=O)[O-].C(CCCCC)(=O)[O-].C(CCCCC)(=O)[O-] Chemical compound C(CCCCC)(=O)[O-].[Mo+4].C(CCCCC)(=O)[O-].C(CCCCC)(=O)[O-].C(CCCCC)(=O)[O-] DKIJBUAXSIPIKK-UHFFFAOYSA-J 0.000 description 1
CLLMBHCKCCOJQC-UHFFFAOYSA-J C(CCCCCCCCCCCCC)(=O)[O-].[Mo+4].C(CCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCC)(=O)[O-] Chemical compound C(CCCCCCCCCCCCC)(=O)[O-].[Mo+4].C(CCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCC)(=O)[O-] CLLMBHCKCCOJQC-UHFFFAOYSA-J 0.000 description 1
OOEZIAXUILASOW-UHFFFAOYSA-J C1(=CC=CC=C1)S(=O)(=O)[O-].[Mo+4].C1(=CC=CC=C1)S(=O)(=O)[O-].C1(=CC=CC=C1)S(=O)(=O)[O-].C1(=CC=CC=C1)S(=O)(=O)[O-] Chemical compound C1(=CC=CC=C1)S(=O)(=O)[O-].[Mo+4].C1(=CC=CC=C1)S(=O)(=O)[O-].C1(=CC=CC=C1)S(=O)(=O)[O-].C1(=CC=CC=C1)S(=O)(=O)[O-] OOEZIAXUILASOW-UHFFFAOYSA-J 0.000 description 1
RIDXAPCAYFXSEU-UHFFFAOYSA-L C1(=CC=CC=C1)S(=O)[O-].[Fe+2].C1(=CC=CC=C1)S(=O)[O-] Chemical compound C1(=CC=CC=C1)S(=O)[O-].[Fe+2].C1(=CC=CC=C1)S(=O)[O-] RIDXAPCAYFXSEU-UHFFFAOYSA-L 0.000 description 1
ZLRMHTMPNNYIIU-UHFFFAOYSA-J C1(=CC=CC=C1)S(=O)[O-].[Mo+4].C1(=CC=CC=C1)S(=O)[O-].C1(=CC=CC=C1)S(=O)[O-].C1(=CC=CC=C1)S(=O)[O-] Chemical compound C1(=CC=CC=C1)S(=O)[O-].[Mo+4].C1(=CC=CC=C1)S(=O)[O-].C1(=CC=CC=C1)S(=O)[O-].C1(=CC=CC=C1)S(=O)[O-] ZLRMHTMPNNYIIU-UHFFFAOYSA-J 0.000 description 1
PWQNJLVWZHFJBL-UHFFFAOYSA-J CC1=CC=C(C(=O)[O-])C=C1.[Mo+4].CC1=CC=C(C(=O)[O-])C=C1.CC1=CC=C(C(=O)[O-])C=C1.CC1=CC=C(C(=O)[O-])C=C1 Chemical compound CC1=CC=C(C(=O)[O-])C=C1.[Mo+4].CC1=CC=C(C(=O)[O-])C=C1.CC1=CC=C(C(=O)[O-])C=C1.CC1=CC=C(C(=O)[O-])C=C1 PWQNJLVWZHFJBL-UHFFFAOYSA-J 0.000 description 1
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
IBXOEKXWTOFALE-UHFFFAOYSA-J [Fe+2].[Fe+2].C(CN(C(=O)[O-])C(=O)[O-])N(C(=O)[O-])C(=O)[O-] Chemical compound [Fe+2].[Fe+2].C(CN(C(=O)[O-])C(=O)[O-])N(C(=O)[O-])C(=O)[O-] IBXOEKXWTOFALE-UHFFFAOYSA-J 0.000 description 1
RYZGGGMGTVKVLI-UHFFFAOYSA-N [Mo].[CH]1C=CC=C1 Chemical compound [Mo].[CH]1C=CC=C1 RYZGGGMGTVKVLI-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
230000032683 aging Effects 0.000 description 1
125000002723 alicyclic group Chemical group 0.000 description 1
150000007933 aliphatic carboxylic acids Chemical class 0.000 description 1
229910052782 aluminium Inorganic materials 0.000 description 1
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 1
229910052787 antimony Inorganic materials 0.000 description 1
WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
229910052785 arsenic Inorganic materials 0.000 description 1
RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical group [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
125000003118 aryl group Chemical group 0.000 description 1
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
229910052788 barium Inorganic materials 0.000 description 1
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
229910052790 beryllium Inorganic materials 0.000 description 1
ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical group [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 1
229910052793 cadmium Inorganic materials 0.000 description 1
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
229910002090 carbon oxide Inorganic materials 0.000 description 1
239000003245 coal Substances 0.000 description 1
150000001868 cobalt Chemical class 0.000 description 1
HAHWEWIEZYKVQO-UHFFFAOYSA-L cobalt(2+);2-methylbenzoate Chemical compound [Co+2].CC1=CC=CC=C1C([O-])=O.CC1=CC=CC=C1C([O-])=O HAHWEWIEZYKVQO-UHFFFAOYSA-L 0.000 description 1
NESZSZYIXNIWCV-UHFFFAOYSA-L cobalt(2+);4-methylbenzenesulfonate Chemical compound [Co+2].CC1=CC=C(S([O-])(=O)=O)C=C1.CC1=CC=C(S([O-])(=O)=O)C=C1 NESZSZYIXNIWCV-UHFFFAOYSA-L 0.000 description 1
GAYAMOAYBXKUII-UHFFFAOYSA-L cobalt(2+);dibenzoate Chemical compound [Co+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 GAYAMOAYBXKUII-UHFFFAOYSA-L 0.000 description 1
OHJGFUZYZGIONC-UHFFFAOYSA-L cobalt(2+);diphenoxide Chemical compound [Co+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 OHJGFUZYZGIONC-UHFFFAOYSA-L 0.000 description 1
DXZRXGASEKGJJE-UHFFFAOYSA-N cobalt;phthalic acid Chemical compound [Co].OC(=O)C1=CC=CC=C1C(O)=O DXZRXGASEKGJJE-UHFFFAOYSA-N 0.000 description 1
238000004939 coking Methods 0.000 description 1
239000000470 constituent Substances 0.000 description 1
MWKGQBHHUJMIPW-UHFFFAOYSA-N cyclohexanecarboxylic acid;molybdenum Chemical compound [Mo].OC(=O)C1CCCCC1 MWKGQBHHUJMIPW-UHFFFAOYSA-N 0.000 description 1
WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
230000005484 gravity Effects 0.000 description 1
125000005842 heteroatom Chemical group 0.000 description 1
HWPOPTGELZAGNY-UHFFFAOYSA-J hexadecanoate molybdenum(4+) Chemical compound C(CCCCCCCCCCCCCCC)(=O)[O-].[Mo+4].C(CCCCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCCCC)(=O)[O-] HWPOPTGELZAGNY-UHFFFAOYSA-J 0.000 description 1
RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
229910010272 inorganic material Inorganic materials 0.000 description 1
239000011147 inorganic material Substances 0.000 description 1
NGXHXXMELBDZNB-UHFFFAOYSA-N iron;phenol Chemical compound [Fe].OC1=CC=CC=C1.OC1=CC=CC=C1 NGXHXXMELBDZNB-UHFFFAOYSA-N 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
GPSDUZXPYCFOSQ-UHFFFAOYSA-M m-toluate Chemical compound CC1=CC=CC(C([O-])=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-M 0.000 description 1
238000005259 measurement Methods 0.000 description 1
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
229910052753 mercury Inorganic materials 0.000 description 1
229910044991 metal oxide Inorganic materials 0.000 description 1
150000004706 metal oxides Chemical class 0.000 description 1
229910052976 metal sulfide Inorganic materials 0.000 description 1
239000005078 molybdenum compound Substances 0.000 description 1
150000002752 molybdenum compounds Chemical class 0.000 description 1
KMYNOLMHFFIADC-UHFFFAOYSA-J molybdenum(4+) octadecanoate Chemical compound C(CCCCCCCCCCCCCCCCC)(=O)[O-].[Mo+4].C(CCCCCCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCCCCCC)(=O)[O-].C(CCCCCCCCCCCCCCCCC)(=O)[O-] KMYNOLMHFFIADC-UHFFFAOYSA-J 0.000 description 1
WMHRKEPRXRKOGP-UHFFFAOYSA-J molybdenum(4+);phenyl phosphate Chemical compound [Mo+4].[O-]P([O-])(=O)OC1=CC=CC=C1.[O-]P([O-])(=O)OC1=CC=CC=C1 WMHRKEPRXRKOGP-UHFFFAOYSA-J 0.000 description 1
238000003541 multi-stage reaction Methods 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
230000000737 periodic effect Effects 0.000 description 1
239000003209 petroleum derivative Substances 0.000 description 1
238000005504 petroleum refining Methods 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000011591 potassium Substances 0.000 description 1
229910052700 potassium Inorganic materials 0.000 description 1
238000012545 processing Methods 0.000 description 1
229910052705 radium Inorganic materials 0.000 description 1
HCWPIIXVSYCSAN-UHFFFAOYSA-N radium atom Chemical compound [Ra] HCWPIIXVSYCSAN-UHFFFAOYSA-N 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000009467 reduction Effects 0.000 description 1
102200118166 rs16951438 Human genes 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
238000002791 soaking Methods 0.000 description 1
239000011949 solid catalyst Substances 0.000 description 1
229910052712 strontium Inorganic materials 0.000 description 1
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
239000000758 substrate Substances 0.000 description 1
150000004763 sulfides Chemical class 0.000 description 1
150000003464 sulfur compounds Chemical class 0.000 description 1
JBQYATWDVHIOAR-UHFFFAOYSA-N tellanylidenegermanium Chemical compound [Te]=[Ge] JBQYATWDVHIOAR-UHFFFAOYSA-N 0.000 description 1
239000008096 xylene Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
- C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Catalysts (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

JP5151949A 1992-07-02 1993-06-23 改良された水素化転化法 Pending JPH06100871A (ja)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US90788092A	1992-07-02	1992-07-02
US907880		1992-07-02

Publications (1)

Publication Number	Publication Date
JPH06100871A true JPH06100871A (ja)	1994-04-12

Family

ID=25424796

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
JP5151949A Pending JPH06100871A (ja)	1992-07-02	1993-06-23	改良された水素化転化法

Country Status (3)

Country	Link
EP (1)	EP0577413A1 (fr)
JP (1)	JPH06100871A (fr)
CA (1)	CA2095664A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2002204959A (ja) *	2001-01-05	2002-07-23	Nippon Kecchen Kk	水素化処理用触媒並びに水素化処理方法
KR100506699B1 (ko) *	2001-08-17	2005-08-09	인테베프, 에스.에이.	나프타의 수소전환을 위한 촉매 시스템
JP2023550824A (ja) *	2020-11-27	2023-12-05	イエフペエネルジヌヴェル	黒鉛質材料を含有し、かつ黒鉛質材料は、そのｈ／ｃ比によって特徴付けられる触媒を用いる石油フラクションの水素化脱硫方法

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
RU2181751C2 (ru) *	1996-02-14	2002-04-27	Тексако Дивелопмент Корпорейшн	Способ гидроконверсии тяжелых углеводородов при низком давлении (варианты)
RU2219220C2 (ru) *	1996-04-01	2003-12-20	Закрытое акционерное общество "Грозненский нефтяной научно-исследовательский институт"	Способ гидрогенизационной переработки остаточных нефтепродуктов
RU2146274C1 (ru) *	1998-12-18	2000-03-10	Скибицкая Наталья Александровна	Способ переработки высокомолекулярного углеводородного сырья
RU2309974C1 (ru) *	2006-07-25	2007-11-10	Открытое акционерное общество "Всероссийский научно-исследовательский институт по переработке нефти"	Способ переработки нефтяных остатков

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2503733B1 (fr) *	1981-04-09	1985-09-06	Inst Francais Du Petrole	Procede d'hydrotraitement d'une charge hydrocarbonee en presence d'un catalyseur soumis a une presulfuration
NL8203780A (nl) *	1981-10-16	1983-05-16	Chevron Res	Werkwijze voor de hydroverwerking van zware koolwaterstofhoudende olien.
DE69206314T2 (de) *	1991-05-02	1996-04-18	Texaco Development Corp	Hydroumwandlungsverfahren.
CA2073417C (fr) *	1991-11-22	2004-04-20	Michael K. Porter	Procede ameliore d'hydroconversion

1993
- 1993-05-06 CA CA 2095664 patent/CA2095664A1/fr not_active Abandoned
- 1993-06-23 JP JP5151949A patent/JPH06100871A/ja active Pending
- 1993-06-30 EP EP93305127A patent/EP0577413A1/fr not_active Withdrawn

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2002204959A (ja) *	2001-01-05	2002-07-23	Nippon Kecchen Kk	水素化処理用触媒並びに水素化処理方法
KR100506699B1 (ko) *	2001-08-17	2005-08-09	인테베프, 에스.에이.	나프타의 수소전환을 위한 촉매 시스템
JP2023550824A (ja) *	2020-11-27	2023-12-05	イエフペエネルジヌヴェル	黒鉛質材料を含有し、かつ黒鉛質材料は、そのｈ／ｃ比によって特徴付けられる触媒を用いる石油フラクションの水素化脱硫方法

Also Published As

Publication number	Publication date
CA2095664A1 (fr)	1994-01-03
EP0577413A1 (fr)	1994-01-05

Publication	Publication Date	Title
US5622616A (en)	1997-04-22	Hydroconversion process and catalyst
US5372705A (en)	1994-12-13	Hydroprocessing of heavy hydrocarbonaceous feeds
JPH06240265A (ja)	1994-08-30	改定された水素化転化法
US4313818A (en)	1982-02-02	Hydrocracking process utilizing high surface area catalysts
US4244839A (en)	1981-01-13	High surface area catalysts
US5288681A (en)	1994-02-22	Catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks
US5868923A (en)	1999-02-09	Hydroconversion process
US5474977A (en)	1995-12-12	Catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks
US4134825A (en)	1979-01-16	Hydroconversion of heavy hydrocarbons
US3696027A (en)	1972-10-03	Multi-stage desulfurization
US4626340A (en)	1986-12-02	Process for the conversion of heavy hydrocarbon feedstocks characterized by high molecular weight, low reactivity and high metal contents
US4357229A (en)	1982-11-02	Catalysts and hydrocarbon treating processes utilizing the same
Ancheyta et al.	2002	Hydroprocessing of Maya heavy crude oil in two reaction stages
CN103097026B (zh)	2015-07-15	低品质烃类原料的加氢转化方法
EP3104968B1 (fr)	2019-04-24	Procédé d'hydrocraquage d'huile lourde et de résidus d'huile
EP3104969A1 (fr)	2016-12-21	Procédé d'hydrocraquage pour pétrole lourd et résidu pétrolier à l'aide d'un additif carboné
US4435277A (en)	1984-03-06	Process for the hydrotreatment of heavy hydrocarbons in the presence of reduced metals
US20170260463A1 (en)	2017-09-14	Process for hydrocracking heavy oil and oil residue with a non-metallised carbonaceous additive
US4954473A (en)	1990-09-04	Method of preparing a catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks
US4430198A (en)	1984-02-07	Hydrotreating hydrocarbon feedstocks
KR100362299B1 (ko)	2003-03-15	접촉분해 가솔린의 탈황방법
JPH06100871A (ja)	1994-04-12	改良された水素化転化法
US4295995A (en)	1981-10-20	Catalysts hydrocarbon treating processes
JP3051566B2 (ja)	2000-06-12	新規な水素化転化法
EP0028667B1 (fr)	1986-05-28	Catalyseurs à grande surface, leur préparation et procédés de traitement d'hydrocarbures les utilisant

JPH06100871A - 改良された水素化転化法 - Google Patents

Info

Links

Classifications

Landscapes

Applications Claiming Priority (2)

Publications (1)

Family

ID=25424796

Family Applications (1)

Country Status (3)

Cited By (3)

Families Citing this family (4)

Family Cites Families (4)

Cited By (3)

Also Published As

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