JPH0618068A - Thermal storage cooling or heating method - Google Patents

Thermal storage cooling or heating method

Info

Publication number
JPH0618068A
JPH0618068A JP24014791A JP24014791A JPH0618068A JP H0618068 A JPH0618068 A JP H0618068A JP 24014791 A JP24014791 A JP 24014791A JP 24014791 A JP24014791 A JP 24014791A JP H0618068 A JPH0618068 A JP H0618068A
Authority
JP
Japan
Prior art keywords
heat
heat storage
heating method
storage agent
medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP24014791A
Other languages
Japanese (ja)
Inventor
Yukihiko Akamatsu
幸彦 赤松
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Paper Mills Ltd
Original Assignee
Mitsubishi Paper Mills Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Paper Mills Ltd filed Critical Mitsubishi Paper Mills Ltd
Priority to JP24014791A priority Critical patent/JPH0618068A/en
Publication of JPH0618068A publication Critical patent/JPH0618068A/en
Pending legal-status Critical Current

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  • Other Air-Conditioning Systems (AREA)

Abstract

(57)【要約】 【目的】 蓄熱式冷却または加熱方法において、蓄熱剤
を熱媒として使用することにより熱搬送能力を高め、熱
効率のよい蓄熱式冷却または加熱方法を提供すること。 【構成】 蓄熱式冷却または加熱方法において、熱媒
を、水和塩、共融物、有機化合物等から成る蓄熱剤を封
入した多数の徴小樹脂カプセルと水またはブラインとの
混合物としたこと。 【効果】 顕熱のみならず潜熱も搬送することができる
ため、熱搬送能力が高まり、熱媒の搬送管、帰還管の管
径を小さくすることかでき、熱搬送動力の軽減が図れ
る。
(57) [Abstract] [PROBLEMS] To provide a heat storage type cooling or heating method with high heat efficiency by enhancing heat transfer ability by using a heat storage agent as a heat medium in the heat storage type cooling or heating method. In the heat storage type cooling or heating method, the heat medium is a mixture of a large number of small resin capsules enclosing a heat storage agent composed of a hydrated salt, a eutectic, an organic compound or the like, and water or brine. [Effect] Since not only sensible heat but also latent heat can be transferred, the heat transfer capability is enhanced, the transfer medium transfer tube and return tube diameter can be reduced, and heat transfer power can be reduced.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】本発明は、蓄熱槽内で予め冷却ま
たは加熱しておいた熱媒を熱交換器に供給し、熱交換が
済んだ熱媒を蓄熱槽に回収する循環方式を採用して熱交
換器を冷却または加熱させることにより目的物を冷却ま
たは加熱するようにした蓄熱式冷却または加熱方法に関
するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention employs a circulation system in which a heat medium that has been cooled or heated in advance in a heat storage tank is supplied to a heat exchanger, and the heat medium that has undergone heat exchange is recovered in the heat storage tank. The present invention relates to a heat storage type cooling or heating method for cooling or heating an object by cooling or heating a heat exchanger.

【0002】[0002]

【従来技術及びその問題点】一般に、この種蓄熱式冷却
または加熱方法は、低廉な深夜電力を利用することを目
的として考えられた方法で、深夜電力を使用して冷凍機
またはヒータで蓄熱槽内蓄熱剤を冷却または加熱してお
き、この蓄熱剤との熱交換によって冷却または加熱され
た水またはブライン(例えばエチレングリコール)を必
要時に熱交換器に送って目的物を冷却または加熱するよ
うにした方法である。しかしながら、この方法にあって
は蓄熱剤に蓄えられた熱を熱交換器に搬送する媒体つま
り熱媒は水またはブラインであったため、熱交換器との
間では顕熱交換しか出来なかった。そこで、蓄熱剤自体
を熱媒として搬送管中を流すことができれば、蓄熱剤の
蓄熱原理である潜熱(融解または凝固熱)も利用して熱
交換することができることによって一定熱量を送るのに
搬送管の径も小径にでき、熱搬送動力も小さくすること
ができるのではないかとの観点から、水またはブライン
に溶解しない蓄熱剤を選択してこれをクラッシャーによ
って微粒子化し、この微粒子化した蓄熱剤を水またはブ
ラインと混合して搬送管中を流してみたが、一旦粒子化
した蓄熱剤同士が搬送管中で大きな固まりとなって管路
を閉塞することがあるだけでなく、蓄熱剤自体も水また
ブラインに溶解せず、かつ、金属を腐食しないものに限
られ、蓄熱剤の種類が限定される等の問題があって実施
不能であるとの結論に達した。
2. Description of the Related Art Generally, this kind of heat storage type cooling or heating method is a method conceived for the purpose of utilizing low-priced late-night power. The internal heat storage agent is cooled or heated, and water or brine (eg ethylene glycol) cooled or heated by heat exchange with this heat storage agent is sent to a heat exchanger when necessary to cool or heat the target object. It is the method. However, in this method, since the medium for transferring the heat stored in the heat storage agent to the heat exchanger, that is, the heat medium was water or brine, only sensible heat could be exchanged with the heat exchanger. Therefore, if the heat storage agent itself can be used as the heat medium to flow through the transfer pipe, the latent heat (heat of melting or solidification), which is the principle of heat storage of the heat storage agent, can also be used for heat exchange, so that a certain amount of heat can be transferred. From the viewpoint that the diameter of the pipe can be made small and the heat transfer power can be made small, a heat storage agent that does not dissolve in water or brine is selected and finely divided by a crusher. I mixed it with water or brine and let it flow through the carrier pipe, but not only the heat storage agents that have once become particles may become large solids in the transfer tube and block the pipeline, but also the heat storage agent itself. It was concluded that it could not be carried out due to problems such as being insoluble in water or brine and not corroding metals, and having limited types of heat storage agents.

【0003】[0003]

【発明の目的】本発明は、上記問題点である蓄熱剤同士
の結合を防止し、かつ、蓄熱剤の種類が限定されること
がないように蓄熱剤を樹脂でコーティングしたものつま
り蓄熱剤を樹脂成の微小カプセル内に封入したものを製
造し、これを水またはブライン中に混合し、この混合物
を熱媒として使用することにより熱搬送能力を高め、熱
効率のよい蓄熱式冷却または加熱方法を提供することを
目的とするものである。
An object of the present invention is to provide a heat storage agent coated with a resin, that is, a heat storage agent, which prevents the above-mentioned problems from binding the heat storage agents to each other and does not limit the type of the heat storage agent. A resin-encapsulated microcapsule is manufactured, and this is mixed in water or brine, and the heat transfer capacity is enhanced by using this mixture as a heat transfer medium. It is intended to be provided.

【0004】[0004]

【発明の開示】本発明は、蓄熱槽と熱交換器との間で閉
回路を構成し、該蓄熱槽内の冷却または加熱された熱媒
をこの閉回路内で循環させて熱交換器を冷却または加熱
させることにより目的物を冷却または加熱させるように
した蓄熱式冷却または加熱方法において、前記熱媒を、
水和塩、共融物、有機化合物等から成る蓄熱剤を封入し
た多数の微小樹脂カプセルと水またはブラインとの混合
物としたことを特徴とするものである。
DISCLOSURE OF THE INVENTION According to the present invention, a closed circuit is formed between a heat storage tank and a heat exchanger, and a heat medium cooled or heated in the heat storage tank is circulated in the closed circuit to form a heat exchanger. In a heat storage type cooling or heating method for cooling or heating an object by cooling or heating, the heat medium,
It is characterized in that it is a mixture of a large number of fine resin capsules enclosing a heat storage agent composed of a hydrated salt, a eutectic, an organic compound and the like, and water or brine.

【0005】[0005]

【実施例】本発明方法を、目的物を冷却する場合につい
て具体的に説明する。即ち、1は、圧縮機11、凝縮器
12及び冷却部13から成る冷却装置で、蓄熱槽2内の
熱媒(冷媒)をポンプ3によって前記冷却装置13との
間で循環させることによって冷却させる。この熱媒は、
直径数十μ乃至数百μのポリエチレン製等の多数の樹脂
製球形カプセル中に水和塩、共融物、有機化合物等から
成る公知の蓄熱剤を封入したものと、水またはブライン
の混合物より成るもので、蓄熱剤としては、0℃以上5
℃以下の温度で相変化つまり凝固するものが最適で、蓄
熱剤の総量と水またはブラインの量との比は、約4/6
程度のときが好ましい。前記冷却装置1の駆動により冷
却された熱媒は、ポンプ4により搬送管5を介して熱交
換器6に送られ、熱交換器通過後、帰還管7を介して再
び蓄熱槽2に帰還し、ポンプ4の駆動中この循環が行わ
れる。上記熱媒の循環により熱交換器6が冷却され、目
的物が空気つまり空気調和機の場合は空気との間で熱交
換が行われ冷風が被空調域に供給される。
EXAMPLES The method of the present invention will be specifically described in the case of cooling an object. That is, 1 is a cooling device composed of a compressor 11, a condenser 12 and a cooling unit 13, which cools the heat medium (refrigerant) in the heat storage tank 2 by circulating it with the cooling device 13 by means of a pump 3. . This heat medium is
From a mixture of a large number of resin spherical capsules made of polyethylene or the like with a diameter of several tens of μm to several hundred μm, in which a known heat storage agent composed of a hydrate salt, a eutectic, an organic compound, etc., is enclosed, and water or brine. As a heat storage agent, it should be 0 ° C or higher and 5
A material that undergoes a phase change, that is, solidification at a temperature of ℃ or less, is optimal, and the ratio of the total amount of heat storage agent to the amount of water or brine is about 4/6.
It is preferably about the same. The heat medium cooled by the drive of the cooling device 1 is sent by the pump 4 to the heat exchanger 6 via the carrier pipe 5, and after passing through the heat exchanger, is returned to the heat storage tank 2 again via the return pipe 7. This circulation is performed while the pump 4 is being driven. The heat exchanger 6 is cooled by the circulation of the heat medium, and when the object is air, that is, in the case of an air conditioner, heat is exchanged with the air and cold air is supplied to the air-conditioned area.

【0006】[0006]

【発明の作用】深夜電力による冷却装置の駆動によって
冷却された蓄熱槽2内の熱媒中の全カプセル内の蓄熱剤
は凝固して固体となって潜熱を保有しているため、熱交
換器6に至る搬送管5中での熱損失が少なく、熱交換器
6における空気等との熱交換の際も主に蓄熱剤の融解熱
が利用され、また、顕熱交換も含め空気側との交換熱量
も非常に大きくなるとともに、蓄熱槽2に帰還した熱媒
中のカプセル内の蓄熱剤もきわめて微小であることと相
まって効率よく直ちに凝固するため冷却効率がよいもの
である。また、加熱方法の場合は、図1の冷却装置1に
代えて加熱装置を使用し、カプセル内の蓄熱剤として5
0℃以下40℃以上の温度で相変化つまり融解するもの
を選択しておけば、冷却方法の場合と同じく潜熱たる凝
固熱が利用され、搬送管中での熱損失が少なく、顕熱交
換も含め空気側との交換熱量も非常に大きくなるととも
に、カプセル内の蓄熱剤もきわめて微小であることと相
まって効率よく直ちに融解するため、加熱効率がよいも
のである。
The heat storage agent in all the capsules in the heat medium in the heat storage tank 2 cooled by the drive of the cooling device by the late-night power is solidified to become a solid and retains latent heat. The heat loss in the transfer pipe 5 up to 6 is small, and the heat of fusion of the heat storage agent is mainly used during the heat exchange with the air in the heat exchanger 6, and the sensible heat exchange with the air side is also used. The amount of heat exchanged also becomes very large, and the heat storage agent in the capsule in the heat medium returned to the heat storage tank 2 is also extremely small, so that the heat is efficiently solidified immediately and the cooling efficiency is good. In the case of the heating method, a heating device is used instead of the cooling device 1 of FIG.
If you select a material that undergoes a phase change, that is, melts at a temperature of 0 ° C or lower and 40 ° C or higher, the solidification heat, which is latent heat, is used as in the case of the cooling method, and the heat loss in the carrier pipe is small and sensible heat exchange is also possible. In addition to the very large amount of heat exchanged with the air side, the heat storage agent in the capsule also melts efficiently and immediately due to the fact that the heat storage agent in the capsule is extremely small, so that the heating efficiency is good.

【発明の効果】本発明に係る蓄熱式冷却または加熱方法
によれば、熱媒として蓄熱剤を封入した多数の微小樹脂
カプセルと水またはブラインの混合物を使用したもので
あるから、潜熱を含めた熱搬送が可能となり、蓄熱剤自
体も樹脂製皮膜で保護されているため、粒子化された蓄
熱剤同士が結合して搬送管路を閉塞するようなことがな
く、また、水またはブラインに溶解する性質の蓄熱剤で
あっても使用することができ、用途に応じて蓄熱剤の種
類を自由に選択することができるものである。更に、本
発明方法によれば、潜熱を含めた熱搬送が可能となった
ため、従来の水またはブラインによる顕熱のみの搬送に
比べて蓄熱剤の蓄熱能力の違いによって多少の差はある
が、10倍以上の熱搬送能力を有することになり、配管
断面積を1/10以下と小さくしても冷却または加熱能
力の低下を来さないため、搬送管、帰還管の管径を小さ
くすることができ、これによって外部からの熱の吸収量
または外部への熱の放出量を少なくすることができるた
め、蓄熱効果を長時間に亘って維持することができると
ともに施工性の向上が図れ、熱搬送動力の軽減による運
転費その他コストの低減が図れるものである。また、0
℃以上の温度で凝固する蓄熱剤を使用すれば、冷却装置
も小さなものでよく、消費電力の少ない小型の冷却装置
を使用することができて経済的であり、蓄熱剤の潜熱を
主に交換させる方法で運転したときは、搬送管と帰還管
中の熱媒の温度差を小さくすることができるため、両管
を二重管式あるいは接合式とすることができ、配管工事
並びに断熱処理が簡単に行え、断熱効果を高めることが
できるものである。
According to the heat storage type cooling or heating method of the present invention, since a mixture of a large number of fine resin capsules enclosing a heat storage agent and water or brine is used as a heat medium, latent heat is included. Since heat transfer is possible and the heat storage agent itself is protected by the resin coating, there is no possibility that particleified heat storage agents will bind to each other and block the transfer pipeline, and will also dissolve in water or brine. Even a heat storage agent having a property to be used can be used, and the type of the heat storage agent can be freely selected according to the application. Further, according to the method of the present invention, since it is possible to transfer heat including latent heat, there is a slight difference due to the difference in the heat storage capacity of the heat storage agent compared to the conventional transfer of only sensible heat by water or brine, Since it has a heat transfer capacity of 10 times or more, and the cooling or heating capacity does not decrease even if the piping cross-sectional area is reduced to 1/10 or less, the transfer and return pipes must have a small diameter. As a result, the amount of heat absorbed from the outside or the amount of heat released to the outside can be reduced, so that the heat storage effect can be maintained for a long time and the workability can be improved. The operating power and other costs can be reduced by reducing the transportation power. Also, 0
If a heat storage agent that solidifies at a temperature of ℃ or higher is used, a small cooling device can be used, and it is economical to use a small cooling device with low power consumption, and the latent heat of the heat storage agent is mainly exchanged. When operated by the method described above, the temperature difference between the heat transfer medium in the transfer pipe and the return pipe can be reduced, so both pipes can be made into a double pipe type or a joint type, and piping work and heat insulation treatment can be performed. It can be easily done and the heat insulation effect can be enhanced.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明に係る蓄熱式冷却または加熱方法の概略
構成図である。
FIG. 1 is a schematic configuration diagram of a heat storage type cooling or heating method according to the present invention.

【符号の説明】[Explanation of symbols]

1 冷却装置 2 蓄熱槽 3 ポンプ 4 ポンプ 5 搬送管 6 熱交換器 7 帰還管 1 Cooling device 2 Heat storage tank 3 Pump 4 Pump 5 Conveyor pipe 6 Heat exchanger 7 Return pipe

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 蓄熱槽と熱交換器との間で閉回路を構成
し、該蓄熱槽内の冷却または加熱された熱媒をこの閉回
路内で循環させて熱交換器を冷却または加熱させること
により、目的物を冷却または加熱させるようにした蓄熱
式冷却または加熱方法において、前記熱媒を、水和塩、
共融物、有機化合物等から成る蓄熱剤を封入した多数の
微小樹脂カプセルと水またはブラインの混合物としたこ
とを特徴とする蓄熱式冷却または加熱方法。
1. A closed circuit is formed between a heat storage tank and a heat exchanger, and a heat medium cooled or heated in the heat storage tank is circulated in the closed circuit to cool or heat the heat exchanger. Thereby, in the heat storage type cooling or heating method for cooling or heating the object, the heat medium is a hydrated salt,
A heat storage type cooling or heating method, characterized in that a mixture of a large number of fine resin capsules enclosing a heat storage agent composed of a eutectic, an organic compound or the like and water or brine is used.
【請求項2】 請求項1の熱媒を、0℃以上5℃以下の
温度で相変化する水和塩、共融物、有機化合物等から成
る蓄熱剤を封入した多数の微小樹脂カプセルと水または
ブラインとの混合物としたことを特徴とする請求項1の
蓄熱式冷却方法。
2. A large number of fine resin capsules in which the heat medium of claim 1 is filled with a heat storage agent composed of a hydrated salt, a eutectic, an organic compound, or the like that undergoes a phase change at a temperature of 0 ° C. or higher and 5 ° C. or lower, and water. Alternatively, the heat storage type cooling method according to claim 1, wherein the method is a mixture with brine.
【請求項3】 請求項1の熱媒を、50℃以下40℃以
上の温度で相変化する水和塩、共融物、有機化合物等か
ら成る蓄熱剤を封入した多数の微小樹脂カプセルと水ま
たはブラインとの混合物としたことを特徴とする請求項
1の蓄熱式加熱方法。
3. A large number of fine resin capsules containing the heat medium of claim 1 in which a heat storage agent composed of a hydrated salt, a eutectic, an organic compound or the like that changes in phase at a temperature of 50 ° C. or higher and 40 ° C. or higher, and water. Alternatively, the heat storage type heating method according to claim 1, wherein the method is a mixture with brine.
JP24014791A 1991-05-27 1991-05-27 Thermal storage cooling or heating method Pending JPH0618068A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24014791A JPH0618068A (en) 1991-05-27 1991-05-27 Thermal storage cooling or heating method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24014791A JPH0618068A (en) 1991-05-27 1991-05-27 Thermal storage cooling or heating method

Publications (1)

Publication Number Publication Date
JPH0618068A true JPH0618068A (en) 1994-01-25

Family

ID=17055196

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24014791A Pending JPH0618068A (en) 1991-05-27 1991-05-27 Thermal storage cooling or heating method

Country Status (1)

Country Link
JP (1) JPH0618068A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62263230A (en) * 1986-05-08 1987-11-16 Ube Ind Ltd Rough-surfaced polyimide film and its production

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62263230A (en) * 1986-05-08 1987-11-16 Ube Ind Ltd Rough-surfaced polyimide film and its production

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