JPH06207262A - Far infrared ray radiation member and manufacture thereof - Google Patents

Far infrared ray radiation member and manufacture thereof

Info

Publication number
JPH06207262A
JPH06207262A JP1672593A JP1672593A JPH06207262A JP H06207262 A JPH06207262 A JP H06207262A JP 1672593 A JP1672593 A JP 1672593A JP 1672593 A JP1672593 A JP 1672593A JP H06207262 A JPH06207262 A JP H06207262A
Authority
JP
Japan
Prior art keywords
hot
far
infrared radiation
alloy
heating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1672593A
Other languages
Japanese (ja)
Inventor
Mamoru Matsuo
守 松尾
Seiju Maejima
正受 前嶋
Koichi Saruwatari
光一 猿渡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujikura Ltd
Sky Aluminium Co Ltd
Original Assignee
Fujikura Ltd
Sky Aluminium Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujikura Ltd, Sky Aluminium Co Ltd filed Critical Fujikura Ltd
Priority to JP1672593A priority Critical patent/JPH06207262A/en
Publication of JPH06207262A publication Critical patent/JPH06207262A/en
Pending legal-status Critical Current

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  • Other Surface Treatments For Metallic Materials (AREA)
  • Resistance Heating (AREA)

Abstract

(57)【要約】 【目的】 電子誘導加熱もしくは通電加熱により発熱さ
せて遠赤外線を放射させる部材として、遠赤外線放射特
性が優れ、かつ耐ヒートクラック性、耐食性、成形性、
コスト等を満足し得る遠赤外線放射部材を提供する。 【構成】 請求項1:電磁誘導加熱もしくは通電加熱可
能な鉄系材料からなる基材表面に、Si1〜15%を含
有するAl−Si系合金からなる溶融メッキ層が形成さ
れ、その溶融メッキ層の表面に陽極酸化皮膜が形成され
ている遠赤外線放射部材。 請求項2:溶融メッキ層の
合金として、Si1〜15%のほか、Fe,Mg,C
u,Mn,Ni,Cr,V,Ti,Zr,P,Na,S
b,Srのうちの1種以上を含有するAl−Si系合金
を用いる。 請求項3:製造方法として、鉄系材料基材
にAl−Si系合金の溶融メッキした後に200〜55
0℃×0.5〜24時間の析出処理を行ない、その後陽
極酸化処理を施す。
(57) [Abstract] [Purpose] As a member that emits far infrared rays by generating heat by electron induction heating or electric heating, it has excellent far infrared radiation characteristics, and also has heat crack resistance, corrosion resistance, formability,
Provided is a far-infrared radiation member that can satisfy cost and the like. [Claim 1] A hot-dip plated layer made of an Al-Si alloy containing 1 to 15% of Si is formed on the surface of a base material made of an iron-based material that can be heated by electromagnetic induction or electric current. Far-infrared radiation member with an anodized film formed on the surface of. Claim 2: As an alloy of the hot dip plated layer, in addition to Si 1 to 15%, Fe, Mg, C
u, Mn, Ni, Cr, V, Ti, Zr, P, Na, S
An Al-Si alloy containing at least one of b and Sr is used. Claim 3: As a manufacturing method, after the hot dipping of an Al-Si alloy on an iron-based material substrate, 200 to 55 is applied.
A precipitation treatment is performed at 0 ° C. for 0.5 to 24 hours, and then an anodic oxidation treatment is performed.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【産業上の利用分野】この発明は、暖房、調理、乾燥、
材料の加熱等の輻射加熱、そのほか遠赤外線を利用する
際に、遠赤外線放射のために用いられる遠赤外線放射部
材に関するものであり、特に電磁誘導加熱もしくは通電
加熱により発熱させて遠赤外線を放射する部材に関する
ものである。
This invention relates to heating, cooking, drying,
The present invention relates to a far-infrared radiation member used for far-infrared radiation when radiant heating such as heating of materials and other far-infrared radiation is used, and particularly far-infrared radiation is generated by heating by electromagnetic induction heating or electric heating. It relates to members.

【0002】[0002]

【従来の技術】一般に遠赤外線放射を行なうにあたって
は、遠赤外線を放射可能な材料を100℃〜数百℃に加
熱する必要がある。一方、電気的な加熱手段として代表
的なものとしては、材料に交番磁界を加えて誘導電流を
生ぜしめ、その誘導電流によりジュール発熱させるいわ
ゆる電磁誘導加熱や、材料に直接通電してその通電電流
によりジュール発熱させるいわゆる通電加熱がある。そ
こでこのような電磁誘導加熱もしくは通電加熱によって
材料を発熱させて、その材料自体から遠赤外線を放射さ
せることが考えられるが、従来の一般的な電磁誘導加熱
もしくは通電加熱可能な材料は、そのままでは遠赤外線
放射が不可能かまたは可能であっても遠赤外線放射性能
が低く、実用に供することは困難であった。
2. Description of the Related Art Generally, in emitting far infrared rays, it is necessary to heat a material capable of emitting far infrared rays to 100 ° C. to several hundreds of ° C. On the other hand, as a typical electrical heating means, so-called electromagnetic induction heating in which an alternating current magnetic field is applied to a material to generate an induced current and Joule heat is generated by the induced current, or a current flowing directly to the material There is so-called electric heating that causes Joule heat generation. Therefore, it is conceivable to heat the material by such electromagnetic induction heating or electric current heating and radiate far infrared rays from the material itself, but conventional general electromagnetic induction heating or electric current heatable material is as it is. Far-infrared radiation is impossible, or even if far-infrared radiation is possible, the far-infrared radiation performance is low and it was difficult to put it to practical use.

【0003】すなわち、電磁誘導加熱、通電加熱のいず
れの場合も材料が導電体であってしかもある程度の電気
抵抗を有することが必要であるが、特に電磁誘導加熱の
場合は、強磁性体材料であることが望まれ、また量産規
模で適用するためには材料コストが低いことも要求され
る。そこで一般にはこれらの電磁誘導加熱、通電加熱に
おける発熱材料としては、鋼板や鉄板、あるいはステン
レス鋼(但しオーステナイト系ステンレス鋼を除く)な
どの主として鉄系材料を用いることが多いが、これらの
鉄系材料は、そのままでは遠赤外線を放射することがで
きない。
That is, in both cases of electromagnetic induction heating and electric heating, it is necessary that the material is a conductor and has a certain degree of electric resistance. Especially, in the case of electromagnetic induction heating, a ferromagnetic material is used. It is also desirable that the material cost be low for mass-scale application. Therefore, in general, mainly iron-based materials such as steel plate, iron plate, and stainless steel (excluding austenitic stainless steel) are mainly used as the heat-generating materials in these electromagnetic induction heating and electric heating. The material cannot emit far infrared rays as it is.

【0004】そこで電磁誘導加熱もしくは通電加熱によ
り発熱させて遠赤外線を放射させる部材としては、前述
のような鉄系材料の表面に、遠赤外線放射可能なセラミ
ックを溶射したものが考えられている。しかしながらこ
の場合には高コスト化を招くとともに、耐食性も劣り、
さらには大きな寸法の部材を得ることが困難であり、さ
らにはセラミック溶射後の成形加工が困難となってその
形状も限られてしまう等の問題がある。
Therefore, as a member that emits far infrared rays by generating heat by electromagnetic induction heating or electric heating, it is considered that the surface of the above iron material is sprayed with ceramics capable of emitting far infrared rays. However, in this case, the cost is increased, and the corrosion resistance is poor,
Further, it is difficult to obtain a member having a large size, and further, there is a problem that the molding process after ceramic spraying becomes difficult and the shape thereof is limited.

【0005】一方、遠赤外線放射性能の点からは、各種
セラミック材料のうちでもアルミナが優れていることが
知られており、そこで最近では、高純度のアルミニウム
の表面に陽極酸化処理を施してアルミナからなるアルマ
イト層(陽極酸化皮膜)を形成した遠赤外線放射部材
が、熱伝導性と遠赤外線放射性能に優れた放射部材とし
て注目されるようになっている。但し、アルミニウム材
料の場合、強磁性を有していないに加え、電気抵抗も小
さいところから、電磁誘導加熱や通電加熱には不適当で
あった。
On the other hand, from the viewpoint of far-infrared radiation performance, alumina is known to be excellent among various ceramic materials. Therefore, recently, the surface of high-purity aluminum has been anodized to form alumina. A far-infrared radiating member having an alumite layer (anodized film) made of is attracting attention as a radiating member excellent in thermal conductivity and far-infrared radiating performance. However, the aluminum material is not suitable for electromagnetic induction heating or electric heating because it has no ferromagnetism and has a small electric resistance.

【0006】[0006]

【発明が解決しようとする課題】前述のように、従来
は、電磁誘導加熱もしくは通電加熱によって発熱させて
遠赤外線を放射させる部材としては、コストや耐食性、
あるいは成形性や大寸法のものを得る点、そのほか優れ
た遠赤外線放射特性を有することなど、全ての点におい
て充分に満足し得るものは存在しなかったのが実情であ
る。
As described above, conventionally, as a member that emits far infrared rays by generating heat by electromagnetic induction heating or electric heating, cost, corrosion resistance,
In reality, none of them are sufficiently satisfactory in all respects, such as moldability, obtaining a large size, and having excellent far-infrared radiation characteristics.

【0007】この発明は以上の事情を背景としてなされ
たもので、電磁誘導加熱もしくは通電加熱によって遠赤
外線を放射する部材として、遠赤外線放射特性が優れる
ばかりでなく、耐食性や成形性が良好でかつ低コストで
しかも大寸法のものも容易に得られるようにした遠赤外
線放射部材を提供することを目的とするものである。
The present invention has been made in view of the above circumstances. As a member that radiates far infrared rays by electromagnetic induction heating or electric heating, not only the far infrared radiation characteristics are excellent, but also corrosion resistance and moldability are excellent. It is an object of the present invention to provide a far-infrared radiation member that can be easily obtained at a low cost and has a large size.

【0008】[0008]

【課題を解決するための手段】本発明者等は、前述のよ
うな課題を解決するべく、鋭意実験・検討を重ねた結
果、基本的には、電磁誘導加熱もしくは通電加熱可能な
鉄系材料を基材とし、一方陽極酸化皮膜の形成によって
遠赤外線放射可能なアルミニウム合金、特に遠赤外線放
射特性の優れたAl−Si系のアルミニウム合金からな
る溶融メッキ層を基材表面に形成することによって、前
述の課題を同時に解決し得ることを見出し、この発明を
なすに至ったのである。
Means for Solving the Problems The inventors of the present invention have conducted earnest experiments and studies to solve the above problems, and as a result, basically, an iron-based material capable of electromagnetic induction heating or electric current heating. On the other hand, by forming a hot-dip coating layer on the surface of the base material, on the other hand, an aluminum alloy capable of emitting far infrared rays by forming an anodized film, particularly an Al-Si-based aluminum alloy having excellent far infrared emission characteristics. The inventors have found that the aforementioned problems can be solved at the same time, and have completed the present invention.

【0009】すなわち、請求項1の発明の電磁誘導加熱
もしくは通電加熱可能な遠赤外線放射部材は、電磁誘導
加熱もしくは通電加熱可能な鉄系材料からなる基材の片
面もしくは両面に、Si1〜15wt%を含有するAl−
Si系合金からなる溶融メッキ層が形成され、さらにそ
の溶融メッキ層表面に陽極酸化皮膜が形成されたことを
特徴とするものである。
That is, the far infrared ray radiating member capable of electromagnetic induction heating or electric current heating according to the invention of claim 1 has Si of 1 to 15 wt% on one or both sides of a base material made of an iron-based material capable of electromagnetic induction heating or electric current heating. Containing Al-
It is characterized in that a hot-dip plated layer made of a Si-based alloy is formed, and an anodized film is further formed on the surface of the hot-dip plated layer.

【0010】また請求項2の発明の電磁誘導加熱もしく
は通電加熱可能な遠赤外線放射部材は、請求項1に記載
の遠赤外線放射部材において、前記溶融メッキ層のAl
−Si系合金が、Si1〜15wt%を含有し、かつF
0.05〜2.0wt%、Mg0.05〜2.0wt%、C
u0.05〜6.0wt%、Mn0.05〜2.0wt%、
Ni0.05〜3.0wt%、Cr0.05〜0.5wt
%、V0.05〜0.5wt%、Ti0.005〜0.2
wt%、Zr0.05〜0.5wt%、P0.005〜0.
1wt%、Na0.005〜0.1wt%、Sb0.005
〜0.3wt%、Sr0.005〜0.1wt%のうちの1
種または2種以上を含有し、残部がAlおよび不可避的
不純物よりなることを特徴とするものである。
Further, the far infrared radiation member capable of electromagnetic induction heating or electric heating according to the invention of claim 2 is the far infrared radiation member according to claim 1, wherein the Al of the hot-dip plated layer is
-Si-based alloy contains 1 to 15 wt% of Si, and F
0.05-2.0 wt%, Mg 0.05-2.0 wt%, C
u 0.05-6.0 wt%, Mn 0.05-2.0 wt%,
Ni0.05-3.0wt%, Cr0.05-0.5wt
%, V0.05-0.5 wt%, Ti0.005-0.2
wt%, Zr 0.05 to 0.5 wt%, P 0.005 to 0.
1 wt%, Na 0.005-0.1 wt%, Sb 0.005
~ 0.3wt%, 1 of Sr 0.005-0.1wt%
One kind or two or more kinds are contained, and the balance is made of Al and unavoidable impurities.

【0011】さらに請求項3の発明の電磁誘導加熱もし
くは通電加熱可能な遠赤外線放射部材の製造方法は、電
磁誘導加熱もしくは通電加熱可能な鉄系材料からなる基
材の片面もしくは両面に、Si1〜15wt%を含有する
Al−Si系合金を溶融メッキした後、その溶融メッキ
層を200〜550℃で0.5〜24時間加熱し、その
後溶融メッキ層表面に陽極酸化処理を施すことを特徴と
するものである。
According to the third aspect of the present invention, there is provided a method for producing a far infrared ray radiating member capable of electromagnetic induction heating or electric current heating, wherein Si1 to An Al-Si alloy containing 15 wt% is hot-dipped, the hot-dip layer is heated at 200 to 550 ° C. for 0.5 to 24 hours, and then the hot-dip layer surface is anodized. To do.

【0012】[0012]

【作用】この発明の遠赤外線放射部材においては、基材
の鉄系材料が電磁誘導加熱もしくは通電加熱によって発
熱して、その熱がAl−Si系合金からなる溶融メッキ
層の非陽極酸化部分によって陽極酸化皮膜に伝えられ、
その陽極酸化皮膜から遠赤外線が放射される。
In the far infrared ray radiating member of the present invention, the iron-based material of the base material generates heat by electromagnetic induction heating or electric heating, and the heat is generated by the non-anodized portion of the hot-dip plated layer made of Al-Si alloy. Transmitted to the anodized film,
Far infrared rays are emitted from the anodized film.

【0013】ここで、基材の鉄系材料としては、要は電
磁誘導加熱もしくは通電加熱が可能なものであれば良
く、炭素鋼板、鉄板、ステンレス鋼板、合金鋼板などを
用いることができる。但しステンレス鋼のうちでもオー
ステナイト系ステンレス鋼は強磁性を有していないから
電磁誘導加熱には不適当である。
Here, the iron-based material of the base material may be any material capable of electromagnetic induction heating or electric heating, and carbon steel plate, iron plate, stainless steel plate, alloy steel plate and the like can be used. However, among the stainless steels, austenitic stainless steels are not suitable for electromagnetic induction heating because they do not have ferromagnetism.

【0014】溶融メッキ層には純Alも使用できないこ
とはないが、純Alに陽極酸化皮膜を形成した場合、全
般的に遠赤外線放射特性が低いばかりでなく、特に3〜
7μmの波長域での遠赤外線放射特性が急激に低くなる
欠点があるほか、200℃以上の高温での使用に際し
て、熱衝撃によりクラックが生じて、耐久性を損なうと
ともに、遠赤外線放射性能も不安定となる。そこでこの
発明では、溶融メッキ層として、これらの問題を解決し
たAl−Si系合金を用いることとした。以下にこの溶
融メッキ層のAl−Si系合金について説明する。
Pure Al cannot be used in the hot-dip plated layer, but when an anodic oxide film is formed on pure Al, not only the far-infrared radiation characteristics are generally low, but especially 3 to
In addition to the drawback that the far-infrared radiation characteristics in the wavelength range of 7 μm sharply deteriorate, when used at high temperatures of 200 ° C or higher, thermal shock causes cracking, which impairs durability and impairs far-infrared radiation performance. Be stable. Therefore, in the present invention, as the hot-dip plated layer, an Al-Si alloy that solves these problems is used. The Al-Si alloy of this hot dip plated layer will be described below.

【0015】Al−Si系合金においては、Si含有量
に応じて、また必要に応じて施される熱処理条件に応じ
て、初晶Si、共晶Si、あるいは析出Siとして、金
属Si粒子が組織中に分散し、一部は固溶Siとしてマ
トリックスに存在する。初晶Si、共晶Si、析出Si
は、そのAl−Si系合金の表面を陽極酸化処理させた
後も、金属Si粒子として陽極酸化皮膜中に残り、した
がってこの金属Si粒子の分散状態が適切であれば、そ
の金属Si粒子が、遠赤外線放射特性に寄与するととも
に、耐ヒートクラック性の向上に寄与する。すなわち、
金属Si粒子がが分散しているアルミニウム合金メッキ
層の表面に陽極酸化処理を施せば、陽極酸化皮膜中にそ
の金属Si粒子が残存する。このような陽極酸化皮膜中
の分散粒子によって入射光が散乱吸収されて、遠赤外線
の放射特性が向上する。さらに、陽極酸化処理時におい
て陽極酸化皮膜(多孔質層)が成長する過程で、ポアは
枝分かれした構造となり、このような枝分かれポア構造
によって入射光に対する陽極酸化皮膜内での散乱吸収が
助長され、遠赤外線放射特性が一層向上する。
In the Al--Si alloy, metal Si particles are structured as primary crystal Si, eutectic Si, or precipitated Si depending on the Si content and, if necessary, the heat treatment conditions. Dispersed in the matrix, and part of it is present as solid solution Si in the matrix. Primary Si, Eutectic Si, Precipitated Si
Is, even after anodizing the surface of the Al-Si-based alloy, remains in the anodized film as metal Si particles, therefore, if the dispersion state of the metal Si particles is appropriate, the metal Si particles, It contributes to the far-infrared radiation characteristics and also improves the heat crack resistance. That is,
When the surface of the aluminum alloy plating layer in which the metallic Si particles are dispersed is subjected to anodizing treatment, the metallic Si particles remain in the anodized film. Incident light is scattered and absorbed by such dispersed particles in the anodic oxide film, and the radiation characteristics of far infrared rays are improved. Furthermore, the pores have a branched structure in the process of growing the anodized film (porous layer) during the anodizing treatment, and such branched pore structure promotes scattering absorption in the anodized film for incident light, Far-infrared radiation characteristics are further improved.

【0016】さらに、陽極酸化皮膜中に分散して存在す
る金属Si粒子は応力の緩和点としても機能し、また前
述のようなポアの枝分かれ構造は歪の吸収能力が高く、
そのためクラックが生じにくいとともに、仮にクラック
が発生してもその伝播が阻止され、耐ヒートクラック性
が良好となる。
Further, the metallic Si particles dispersedly present in the anodized film also function as a stress relaxation point, and the branched structure of the pores as described above has a high strain absorbing ability,
Therefore, cracks are unlikely to occur, and even if cracks occur, their propagation is prevented and heat crack resistance is improved.

【0017】このような溶融メッキ層のAl−Si系合
金における成分組成の限定理由を以下に説明する。
The reasons for limiting the component composition of the Al-Si alloy of the hot-dip plated layer will be described below.

【0018】Si:Siは、溶融メッキ時における凝固
時に、その添加量に応じて初晶Si、共晶Siとして晶
出し、一部は固溶Siとして存在する。また必要に応じ
て熱処理が行なわれた場合、Alマトリックス中の固溶
Siも金属Siとして析出する。これらの初晶Si、共
晶Si、析出Siは、前述のように陽極酸化処理時に金
属Si粒子として陽極酸化皮膜中に取込まれ、入射光に
対する散乱、吸収を通じて遠赤外線放射特性の向上に寄
与するとともに、クラックの発生防止に寄与する。さら
に金属Si粒子は、前述のように皮膜内のポアを枝分か
れ構造とすることに寄与し、これによっても遠赤外線放
射特性の向上とクラック発生防止に寄与する。アルミニ
ウム合金のSi量が1wt%未満では、金属Si粒子の数
が少なく、遠赤外線の放射が不充分となる。一方Si量
が15wt%を越えれれば、陽極酸化皮膜中の金属Si粒
子の体積率が大き過ぎて陽極酸化皮膜の強度、耐食性が
低下してしまう。したがってSi量は1〜15wt%の範
囲内とした。
Si: Si is crystallized as primary crystal Si and eutectic Si depending on the amount of addition during solidification during hot dipping, and part thereof exists as solid solution Si. Further, when heat treatment is performed as necessary, solid solution Si in the Al matrix also precipitates as metallic Si. As described above, these primary crystal Si, eutectic Si, and precipitated Si are incorporated into the anodized film as metallic Si particles during the anodization process, and contribute to the improvement of far infrared radiation characteristics through scattering and absorption of incident light. It also contributes to the prevention of cracks. Furthermore, the metal Si particles contribute to the pores in the coating having a branched structure as described above, which also contributes to the improvement of far infrared radiation characteristics and the prevention of cracks. When the amount of Si in the aluminum alloy is less than 1 wt%, the number of metallic Si particles is small and the far infrared radiation becomes insufficient. On the other hand, if the Si amount exceeds 15 wt%, the volume ratio of the metal Si particles in the anodized film is too large, and the strength and corrosion resistance of the anodized film are reduced. Therefore, the Si amount is set within the range of 1 to 15 wt%.

【0019】溶融メッキ層に使用されるAl−Si系合
金は、上記のSiのほかは、基本的にはAlおよび不可
避的不純物とすれば良いが、必要に応じて、Fe 0.
05〜2.0wt%、Mg 0.05〜2.0wt%、Cu
0.05〜6.0wt%、Mn 0.05〜2.0wt
%、Ni 0.05〜3.0wt%、Cr 0.05〜
0.5wt%、Zr 0.05〜0.5wt%、V 0.
05〜0.5wt%、Ti 0.005〜0.2wt%、P
0.005〜0.1wt%、Na 0.005〜0.
1wt%、Sb 0.005〜0.3wt%、Sr 0.0
05〜0.1wt%のうちの1種または2種以上を添加し
ても良い。これらの元素の添加理由は次の通りである。
The Al-Si based alloy used for the hot-dip plated layer may basically be Al and inevitable impurities in addition to the above Si, but if necessary, Fe 0.
05-2.0 wt%, Mg 0.05-2.0 wt%, Cu
0.05-6.0 wt%, Mn 0.05-2.0 wt
%, Ni 0.05 to 3.0 wt%, Cr 0.05 to
0.5 wt%, Zr 0.05 to 0.5 wt%, V 0.
05-0.5 wt%, Ti 0.005-0.2 wt%, P
0.005-0.1 wt%, Na 0.005-0.
1 wt%, Sb 0.005-0.3 wt%, Sr 0.0
You may add 1 type (s) or 2 or more types among 05-0.1 wt%. The reasons for adding these elements are as follows.

【0020】Fe:Feは強度向上および結晶粒微細化
のために有効である。Fe量が0.05wt%未満ではそ
の効果が得られず、2.0wt%を越えれば陽極酸化皮膜
の強度と耐食性が低下する。またFe量が2.0wt%を
越えれば、SiがFeと化合してAl−Fe−Si系の
金属間化合物の量が増加し、遠赤外線放射特性が低下す
る。したがってFeを添加する場合のFe量は0.05
〜2.0wt%の範囲とする。
Fe: Fe is effective for improving strength and refining crystal grains. If the Fe content is less than 0.05 wt%, the effect cannot be obtained, and if it exceeds 2.0 wt%, the strength and corrosion resistance of the anodic oxide film are deteriorated. On the other hand, if the amount of Fe exceeds 2.0 wt%, Si combines with Fe to increase the amount of Al-Fe-Si based intermetallic compounds, which deteriorates the far infrared radiation characteristics. Therefore, the amount of Fe when adding Fe is 0.05
˜2.0 wt%.

【0021】Mg:Mgも強度向上に寄与する。Mg量
が0.05wt%未満ではその効果が得られず、一方2.
0wt%を越えればMgとSiとが結合してMg2 Siの
生成量が増加し、遠赤外線放射特性が低下する。またM
g量が2.0wt%を越えれば溶融メッキ層の付着性も低
下する。したがってMgを添加する場合のMg量は0.
05〜2.0wt%の範囲内とする。
Mg: Mg also contributes to the improvement of strength. If the amount of Mg is less than 0.05 wt%, the effect cannot be obtained, while 2.
If it exceeds 0 wt%, Mg and Si are combined with each other to increase the amount of Mg 2 Si produced and the far infrared radiation characteristics deteriorate. Also M
If the g amount exceeds 2.0 wt%, the adhesion of the hot-dip plated layer will also decrease. Therefore, when Mg is added, the amount of Mg is 0.
It is within the range of 05 to 2.0 wt%.

【0022】Cu:Cuの添加も強度向上に寄与する。
Cu量が0.05wt%未満ではその効果が得られず、一
方6.0wt%を越えれば溶融メッキ層の付着性が低下す
る。したがってCuを添加する場合のCu量は0.05
〜6.0wt%の範囲内とした。
Cu: The addition of Cu also contributes to the strength improvement.
If the Cu content is less than 0.05 wt%, the effect cannot be obtained, while if it exceeds 6.0 wt%, the adhesion of the hot-dip layer is deteriorated. Therefore, the amount of Cu when adding Cu is 0.05
Within the range of up to 6.0 wt%.

【0023】Mn:Mnは強度向上に寄与するととも
に、結晶粒微細化、耐熱性向上に寄与する。Mn量が
0.05wt%未満ではこれらの効果が得られず、一方
2.0wt%を越えればMnがSiと結合してAl−Mn
−Si系の金属間化合物の生成量が増加し、遠赤外線放
射特性が低下する。またMn量が2.0wt%を越えれば
溶融メッキ層の付着性が低下する。したがってMnを添
加する場合のMn量は0.05〜2.0wt%の範囲内と
した。
Mn: Mn contributes to the improvement of strength, refinement of crystal grains and improvement of heat resistance. If the amount of Mn is less than 0.05 wt%, these effects cannot be obtained. On the other hand, if the amount of Mn exceeds 2.0 wt%, Mn is combined with Si to form Al-Mn.
The amount of -Si-based intermetallic compound produced increases, and the far-infrared radiation characteristics deteriorate. On the other hand, if the Mn content exceeds 2.0 wt%, the adhesion of the hot-dip layer will deteriorate. Therefore, when Mn is added, the amount of Mn is set in the range of 0.05 to 2.0 wt%.

【0024】Ni:Niも強度向上に寄与するととも
に、耐熱性向上に寄与する。Ni量が0.05wt%未満
ではこれらの効果が得られず、一方2.0wt%を越えれ
ば溶融メッキ層の付着性が低下する。したがってNiを
添加する場合のNi量は0.05〜2.0wt%の範囲内
とした。
Ni: Ni also contributes to the improvement of strength and heat resistance. If the amount of Ni is less than 0.05 wt%, these effects cannot be obtained, while if it exceeds 2.0 wt%, the adhesion of the hot-dip layer is reduced. Therefore, when Ni is added, the amount of Ni is set within the range of 0.05 to 2.0 wt%.

【0025】Cr,Zr,V:これらの元素は、強度向
上に寄与するとともに、結晶粒微細化に寄与する。いず
れも0.05wt%未満ではその効果が得られず、一方
0.5wt%を越えれば粗大な金属間化合物が生成され
て。溶融メッキ層の付着性が低下する。したがってC
r,Zr,Vの1種または2種以上を添加する場合の添
加量は、いずれも単独量で0.05〜0.5wt%の範囲
内とする。
Cr, Zr, V: These elements contribute to the improvement of strength and the refinement of crystal grains. In either case, the effect cannot be obtained if it is less than 0.05 wt%, while if it exceeds 0.5 wt%, a coarse intermetallic compound is formed. The adhesion of the hot-dip layer is reduced. Therefore C
When one or more of r, Zr, and V are added, the addition amount of each is within the range of 0.05 to 0.5 wt% as a single amount.

【0026】Ti:Tiは鋳塊結晶粒の微細化を通じて
組織の微細化に寄与する。Ti量が0.005wt%未満
ではその効果が得られず、一方0.2wt%を越えれば粗
大な金属間化合物が生成されて好ましくない。したがっ
てTiを添加する場合のTi量は0.005〜0.2wt
%の範囲内とした。なお鋳塊結晶粒微細化のためには、
TiとともにBを共存させることが効果的である。この
場合B量が1ppm 未満ではその効果が得られず、一方1
00ppm を越えればその効果が飽和するから、Tiと併
せてBを添加する場合のB量は1〜100ppm の範囲内
とすることが好ましい。
Ti: Ti contributes to the refinement of the structure through refinement of the ingot crystal grains. If the Ti content is less than 0.005 wt%, the effect cannot be obtained, while if it exceeds 0.2 wt%, a coarse intermetallic compound is formed, which is not preferable. Therefore, the amount of Ti when adding Ti is 0.005-0.2 wt.
Within the range of%. In addition, in order to refine the ingot crystal grains,
It is effective to make B coexist with Ti. In this case, if the amount of B is less than 1 ppm, the effect cannot be obtained.
Since the effect is saturated if it exceeds 00 ppm, the amount of B when B is added together with Ti is preferably in the range of 1 to 100 ppm.

【0027】P:Pは初晶Siの微細化に寄与する。し
たがってPの添加は初晶Siが晶出するような約10wt
%以上のSiを含有する合金の場合に効果的である。P
量が0.005wt%未満では初晶Siの微細化の効果が
得られず、一方P量が0.1wt%を越えればその効果が
飽和する。したがってPを添加する場合のP量は0.0
05〜0.1wt%の範囲内とした。
P: P contributes to the refinement of primary crystal Si. Therefore, the addition of P is about 10 wt% to crystallize the primary crystal Si.
This is effective in the case of an alloy containing Si in an amount of not less than%. P
If the amount is less than 0.005 wt%, the effect of refining the primary crystal Si cannot be obtained, while if the amount of P exceeds 0.1 wt%, the effect is saturated. Therefore, when adding P, the amount of P is 0.0
It was set within the range of 05 to 0.1 wt%.

【0028】Na,Sb,Sr:これらの元素は共晶S
iの微細化に寄与する。いずれも0.005wt%未満で
はその効果が得られず、一方Na,Srは0.1wt%を
越えればその効果が飽和し、またSbは0.3wt%を越
えればその効果が飽和する。したがってNaを添加する
場合のNa量は0.005〜0.1wt%、Sbを添加す
る場合のSb量は0.005〜0.3wt%、Srを添加
する場合のSr量は0.005〜0.1wt%の範囲内と
した。なおNb,Sb,SrがPと共存した場合には、
Pによる初晶Siの微細化効果が失われてしまうから、
Pとは共存させないことが望ましい。
Na, Sb, Sr: These elements are eutectic S
It contributes to miniaturization of i. If the content is less than 0.005 wt%, the effect cannot be obtained, while if Na and Sr exceed 0.1 wt%, the effect is saturated, and if Sb exceeds 0.3 wt%, the effect is saturated. Therefore, when Na is added, the amount of Na is 0.005 to 0.1 wt%, when Sb is added, the amount of Sb is 0.005 to 0.3 wt%, and when Sr is added, the amount of Sr is 0.005 to 0.1 wt%. It was set within the range of 0.1 wt%. When Nb, Sb and Sr coexist with P,
Since the effect of refining the primary crystal Si by P is lost,
It is desirable not to coexist with P.

【0029】以上の各元素のほか、通常のアルミニウム
合金においては、溶解原料としてスクラップを使用した
場合には、Znが必然的に混入する。Znを特に積極的
に添加することは少ないが、1.0wt%程度までは不可
避的不純物として混入しても特に遠赤外線放射特性等に
悪影響を及ぼすことはない。但し場合によっては強度向
上のためにZnを1.0wt%を越え7.0wt%まで添加
しても良い。Znの添加量が7.0wt%を越えれば溶融
メッキ層の付着性が悪化する。
In addition to the above-mentioned elements, Zn is inevitably mixed in ordinary aluminum alloys when scrap is used as a melting raw material. Zn is rarely added particularly positively, but far-infrared radiation characteristics and the like are not adversely affected even if it is mixed as an unavoidable impurity up to about 1.0 wt%. However, in some cases, Zn may be added in an amount of more than 1.0 wt% and 7.0 wt% to improve the strength. If the amount of Zn added exceeds 7.0% by weight, the adhesion of the hot-dip layer deteriorates.

【0030】そのほかの元素も、1.0wt%以下であれ
ば特に遠赤外線放射特性等に悪影響を及ぼすことはな
い。
Other elements as long as they are 1.0 wt% or less do not particularly affect far infrared radiation characteristics.

【0031】以上のような成分組成のAl−Si系合金
からなる溶融メッキ層が陽極酸化処理後に優れた遠赤外
線放射特性を発揮しかつ良好な耐ヒートクラック性を示
すためには、組織状態、特に金属Si粒子の分散状態が
重要である。すなわち、既に述べたように、Al−Si
系のアルミニウム合金では、凝固時にその添加量に応じ
て初晶Si、共晶Siとして晶出し、一部は固溶Siと
してマトリックス中に存在する。そして凝固後に熱処理
された場合には、Alマトリックス中から金属Siが析
出する。これらの晶出Si(初晶Si、共晶Si)や析
出Siは、陽極酸化処理後においてもそのまま金属Si
粒子として皮膜中に残存し、この陽極酸化皮膜中の金属
Si粒子は、赤外線放射特性や陽極酸化皮膜の耐ヒート
クラック性に大きな影響を与えるが、良好な遠赤外線の
放射特性を得るために有効な金属Si粒子は、0.05
μm以上のサイズ(粒径)のものである。すなわち、金
属Si粒子の径が0.05μm未満の場合には、遠赤外
線の散乱吸収が不充分であって、良好な放射特性が得ら
ない。そしてこのような0.05μm以上のサイズの金
属Si粒子が均一かつ緻密に分散していることが重要で
ある。
In order for the hot dip plated layer made of the Al--Si alloy having the above-mentioned composition to exhibit excellent far infrared radiation characteristics after anodizing treatment and to exhibit good heat crack resistance, the structure state, Particularly, the dispersed state of the metal Si particles is important. That is, as already mentioned, Al--Si
In a system aluminum alloy, when solidified, it is crystallized as primary crystal Si and eutectic Si depending on the amount added, and a part thereof exists in the matrix as solid solution Si. When heat-treated after solidification, metallic Si precipitates from the Al matrix. These crystallized Si (primary crystal Si, eutectic Si) and precipitated Si remain as metallic Si even after anodizing treatment.
The metal Si particles that remain as particles in the anodic oxide coating have a great influence on the infrared radiation characteristics and heat crack resistance of the anodic oxide coating, but are effective for obtaining good far infrared radiation characteristics. 0.05% of metallic Si particles
It has a size (particle diameter) of not less than μm. That is, when the diameter of the metal Si particles is less than 0.05 μm, the far-infrared rays are not sufficiently scattered and absorbed, and good radiation characteristics cannot be obtained. It is important that such metal Si particles having a size of 0.05 μm or more are uniformly and densely dispersed.

【0032】前述のような成分組成のAl−Si系合金
を溶融メッキすれば、溶融Al−Si系合金は鉄系材料
からなる基材上で凝固することになり、この場合凝固時
には、一般に初晶Si、共晶Siが初晶のAl−αデン
ドライトとともに晶出する。ここのデンドライトの幹や
枝の部分は、凝固のままでは固溶体(α相)となってお
り、この部分には金属Siは生じていない。基板上での
溶融メッキ層の凝固速度が速い場合にはデンドライトの
幹や枝の部分が狭くなり、またSi含有量が多い場合に
は、初晶Si、共晶Siの晶出量が多くなるため、この
ように凝固速度が速くかつSi量が多い場合(3wt%程
度以上)の場合には、凝固のままでも全体として比較的
均一かつ緻密に0.05μm以上の金属Si粒子が分散
した組織が得られるが、凝固のままでは金属Si粒子が
不足する場合には、凝固後に改めて析出処理を行なっ
て、固溶体の部分から金属Siを析出させることが望ま
しい。
When an Al--Si alloy having the above-described composition is hot-plated, the molten Al--Si alloy is solidified on a base material made of an iron-based material. Crystalline Si and eutectic Si are crystallized together with primary Al-α dendrite. The trunk and branch portions of the dendrites here are solid solutions (α phase) in the solidified state, and no metallic Si is generated in this portion. When the solidification rate of the hot-dip layer on the substrate is fast, the trunk and branch parts of the dendrite become narrow, and when the Si content is high, the amount of primary crystallites and eutectic crystallites increases. Therefore, in the case where the solidification rate is high and the Si content is large (about 3 wt% or more), a structure in which metallic Si particles of 0.05 μm or more are relatively uniformly and densely dispersed as a whole even in the solidified state. However, if the metal Si particles are insufficient in the solidified state, it is desirable to perform another precipitation treatment after the solidification to precipitate the metal Si from the solid solution portion.

【0033】析出処理の条件は、溶融メッキ層のAl−
Si系合金の成分組成によっても異なるが、通常は20
0〜550℃にて0.5〜24時間の加熱を施すことが
望ましい。温度が200℃未満では析出Si粒子のサイ
ズが小さく、0.05μm未満となり易い。一方550
℃を越えれば局部溶融が生じたり、析出量が少なくなっ
たりする。また加熱時間が0.5時間未満ではSiを析
出させる効果が得られず、24時間以上の加熱は経済的
に無駄となるだけである。
The conditions for the precipitation treatment are Al- of the hot-dip coating layer.
Although it depends on the composition of the Si-based alloy, it is usually 20
It is desirable to perform heating at 0 to 550 ° C. for 0.5 to 24 hours. If the temperature is lower than 200 ° C., the size of the precipitated Si particles is small, and it tends to be less than 0.05 μm. Meanwhile 550
If the temperature exceeds ℃, local melting may occur or the amount of precipitation may decrease. If the heating time is less than 0.5 hours, the effect of precipitating Si is not obtained, and heating for 24 hours or more is economically wasted.

【0034】ここで、溶融メッキ層の厚みは特に限定し
ないが、通常は10〜500μmの範囲内とすることが
望ましい。溶融メッキ層の厚みが10μm未満では、陽
極酸化処理時にピンホールが生じ、健全な陽極酸化皮膜
を形成することが困難となるおそれがあり、一方500
μmを越える厚みの溶融メッキ層では、均一なメッキ層
を形成することが困難となる。
Here, the thickness of the hot-dip plated layer is not particularly limited, but it is usually desirable to set it within the range of 10 to 500 μm. If the thickness of the hot-dip layer is less than 10 μm, pinholes may be generated during the anodizing process, which may make it difficult to form a sound anodized film.
With a hot-dip layer having a thickness of more than μm, it becomes difficult to form a uniform plated layer.

【0035】さらにこの発明の遠赤外線放射部材におい
ては、Al−Si系合金からなる溶融メッキ層の表面に
陽極酸化皮膜が形成される。このようにAl−Si系合
金からなる溶融メッキ層の表面に形成した陽極酸化皮膜
は、優れた遠赤外線放射特性を示すとともに、良好な耐
ヒートクラック性を示す。すなわち、陽極酸化処理時に
は、溶融メッキ層の表面の金属Si粒子が皮膜中にその
まま残存した状態で陽極酸化皮膜が成長し、そのため、
皮膜中のポアの成長が金属Si粒子により妨げられ、枝
分かれした微細なポアを有する多孔質の皮膜が生成され
る。さらに、陽極酸化皮膜中にそのまま残存して分散し
ている金属Si粒子と前述の枝分かれした微細なポアが
入射光を散乱吸収し、その結果遠赤外線の放射特性が良
好となる。そしてまた前述の枝分かれした微細なポア構
造と皮膜中に分散した金属Si粒子が熱応力の緩和点と
して機能し、そのため皮膜にクラックが生じにくくな
り、500℃程度の高温に至るまでクラックが生じるこ
となく使用可能となる。
Further, in the far infrared ray radiating member of the present invention, an anodic oxide film is formed on the surface of the hot dip plated layer made of Al-Si alloy. The anodic oxide film formed on the surface of the hot-dip coating layer made of an Al-Si alloy in this way exhibits excellent far infrared radiation characteristics and good heat crack resistance. That is, during the anodizing treatment, the anodized film grows in a state where the metal Si particles on the surface of the hot-dip plated layer remain in the film as they are.
The growth of pores in the film is hindered by the metallic Si particles, and a porous film having branched fine pores is formed. Further, the metallic Si particles remaining in the anodic oxide film as they are and dispersed and the above-mentioned branched fine pores scatter and absorb the incident light, and as a result, the far infrared radiation characteristics are improved. Further, the branched fine pore structure and the metal Si particles dispersed in the coating function as a relaxation point for thermal stress, so that the coating is less likely to crack and cracks occur up to a high temperature of about 500 ° C. It can be used without.

【0036】なお陽極酸化処理の条件は特に限定される
ものではなく、硫酸、シュウ酸などの無機酸、あるいは
有機酸、さらにはこれらの混合酸などの電解浴を用い、
直流、交流、あるいは交直併用、交直重畳波形など、任
意の波形を用いて陽極酸化処理を行なえば良い。但し、
経済性や作業効率の観点からは、硫酸浴で直流電流を用
いることが好ましい。また陽極酸化処理の前には脱脂、
苛性エッチング等の前処理を行なうのが一般的であり、
苛性エッチングを行なった場合には引続いて硝酸等の酸
でデスマット処理を施すのが一般的である。そのほか必
要に応じて、切削加工、酸洗浄、化学研磨処理、ヘアラ
イン加工、シヨットブラスト等の機械的前処理などを実
施しても良いことはもちろんである。
The conditions of the anodizing treatment are not particularly limited, and an inorganic acid such as sulfuric acid or oxalic acid, or an organic acid, or an electrolytic bath of a mixed acid thereof is used.
The anodic oxidation treatment may be performed using an arbitrary waveform such as direct current, alternating current, alternating-current / direct-current combination, alternating-current / direct current superimposed waveform, or the like. However,
From the viewpoint of economy and work efficiency, it is preferable to use a direct current in a sulfuric acid bath. Also, degreasing before anodizing,
It is common to perform pretreatment such as caustic etching,
When caustic etching is performed, it is common to subsequently perform desmutting treatment with an acid such as nitric acid. In addition, it is needless to say that mechanical pretreatment such as cutting, acid cleaning, chemical polishing, hairline processing, and sailboat blasting may be carried out if necessary.

【0037】ここで、陽極酸化皮膜は、3μm以上の厚
みで形成することが望ましい。皮膜厚が3μm未満では
充分な遠赤外線放射特性が得られないおそれがある。な
お陽極酸化皮膜の目視の色調は、膜厚が10μm程度以
上で充分な濃色の黒色となり、遠赤外線放射特性が極め
て良好となる。一方10μm未満では灰色の色調とな
り、遠赤外線放射特性も若干低くなるが、用途によって
は灰色の色調が好まれる場合もあり、このような場合に
は陽極酸化皮膜厚は3〜10μm程度とすれば良く、そ
の場合でも実用上支障ない程度の遠赤外線放射特性は得
られる。
Here, it is desirable that the anodized film is formed with a thickness of 3 μm or more. If the coating thickness is less than 3 μm, sufficient far infrared radiation characteristics may not be obtained. The visual color tone of the anodized film is sufficiently dark black when the film thickness is about 10 μm or more, and the far-infrared radiation characteristics are extremely good. On the other hand, when the thickness is less than 10 μm, the color tone is gray and the far infrared radiation characteristics are slightly deteriorated, but the gray color tone may be preferred depending on the application. In such a case, if the thickness of the anodic oxide film is about 3 to 10 μm. It is good, and even in that case, far-infrared radiation characteristics that do not hinder practical use can be obtained.

【0038】[0038]

【実施例】板厚0.7μmの炭素鋼板を基材とし、その
基材表面に表1の合金番号1,2に示すAl−Si系合
金をメッキ厚200μmで溶融メッキした。
EXAMPLE A carbon steel plate having a plate thickness of 0.7 μm was used as a base material, and the surface of the base material was hot-dipped with an Al—Si alloy shown in alloy numbers 1 and 2 of Table 1 with a plating thickness of 200 μm.

【0039】合金番号1の溶融メッキ層の凝固時の表面
組織を調べたところ、共晶Siが比較的均一に分散して
いた。すなわち、晶出Siのサイズが3〜20μmで、
分布密度が5000〜50000個/m2 であった。そ
こで合金番号1の溶融メッキ層については特に析出処理
を行なわないこととした。
When the surface structure of the alloy No. 1 hot-dip layer during solidification was examined, eutectic Si was dispersed relatively uniformly. That is, when the size of crystallized Si is 3 to 20 μm,
The distribution density was 5000 to 50000 pieces / m 2 . Therefore, it was decided not to perform a precipitation treatment on the hot-dip layer of Alloy No. 1.

【0040】また合金番号2の溶融メッキ層の凝固後の
表面を調べたところ、晶出Siの分布密度が500個/
2 と低いことが判明した。そこで凝固のままの材料と
は別に、溶融メッキ後に改めて300℃×5時間の析出
処理を施した材料も用意した。析出処理後の表面を調べ
たところ、0.05〜2μmの金属Siが50000個
/m2 以上の分布密度で分散していることが確認され
た。
When the surface of the hot-dip plated layer of alloy No. 2 after solidification was examined, the distribution density of crystallized Si was 500 /
It was found to be as low as m 2 . Therefore, in addition to the as-solidified material, a material subjected to a deposition treatment at 300 ° C. for 5 hours after hot dipping was also prepared. When the surface after the precipitation treatment was examined, it was confirmed that metal Si of 0.05 to 2 μm was dispersed at a distribution density of 50,000 pieces / m 2 or more.

【0041】上述のように溶融メッキのままの合金番号
1、合金番号2の溶融メッキ層および析出処理後の合金
番号2の溶融メッキ層について、10%NaOH水溶液
にて60℃×1分間エッチングし、水洗後、30%硝酸
によりデスマット処理を施してから、次の条件で陽極酸
化処理を施した。 処理浴:15%硫酸 電解温度:20℃ 電流密度:1.5A/dm2 なお陽極酸化皮膜厚は目標15μmとした。
As described above, the hot-dip galvanized alloy No. 1 and alloy No. 2 hot-dip layers and the alloy No. 2 hot-dip plated layer after the precipitation treatment were etched with a 10% NaOH aqueous solution at 60 ° C. for 1 minute. After washing with water, desmutting treatment was performed with 30% nitric acid, and then anodizing treatment was performed under the following conditions. Treatment bath: 15% sulfuric acid Electrolysis temperature: 20 ° C. Current density: 1.5 A / dm 2 The target anodic oxide film thickness was 15 μm.

【0042】各材料について、陽極酸化処理後の表面
(陽極酸化皮膜の表面)の分光放射率を調べたので、そ
の結果を金属組織の調査結果とともに表2に示す。なお
分光放射率に関しては、従来の一般的な純Al系のアル
ミニウム陽極酸化皮膜においては3〜7μmの波長域で
の分光放射率が低いことが問題とされており、そこでこ
こではその波長域内の代表的な6μmの波長での分光放
射率を300℃において調べた。一般には、この分光放
射率が0.6以上の場合に良好な遠赤外線放射特性を有
していると言うことができる。
For each material, the spectral emissivity of the surface after anodizing (the surface of the anodized film) was examined, and the results are shown in Table 2 together with the results of the metallographic examination. Regarding the spectral emissivity, it has been a problem that the conventional general pure Al-based aluminum anodic oxide film has a low spectral emissivity in the wavelength range of 3 to 7 μm. Spectral emissivity at a typical 6 μm wavelength was examined at 300 ° C. Generally, it can be said that when the spectral emissivity is 0.6 or more, it has good far infrared radiation characteristics.

【0043】[0043]

【表1】 [Table 1]

【0044】[0044]

【表2】 [Table 2]

【0045】表2から明らかなように、金属Siのサイ
ズ、分散状態が適切な場合には、優れた遠赤外線放射特
性を得ることができた。またこれらの場合、陽極酸化処
理後に500℃に加熱してもヒートクラックの発生は認
められなかった。
As is clear from Table 2, excellent far-infrared radiation characteristics could be obtained when the size and dispersion state of metallic Si were appropriate. Further, in these cases, no heat crack was observed even when heated to 500 ° C. after the anodizing treatment.

【0046】[0046]

【発明の効果】この発明の遠赤外線放射部材は、電磁誘
導加熱もしくは通電加熱可能な鉄系材料からなる基材表
面に、Al−Si系合金からなる溶融メッキ層が形成さ
れ、かつその溶融メッキ層表面に陽極酸化皮膜が形成さ
れたものであって、溶融メッキ層のAl−Si系合金は
陽極酸化皮膜を形成した状態での遠赤外線放射特性およ
び耐ヒートクラック性が優れており、したがって基板部
分を電磁誘導加熱もしくは通電加熱によって直接的に加
熱することによって、溶融メッキ層表面の陽極酸化皮膜
から高い放射効率で遠赤外線を放射させることができる
とともに、高温でも陽極酸化皮膜にヒートクラックが生
じるおそれが少ないため、耐久性が高いとともに、遠赤
外線放射特性も安定している。また鉄系材料からなる基
材にAl−Si系アルミニウム合金を溶融メッキしたも
のであるため、耐食性が高く、また成形性も良好であっ
て、複雑な形状の放射部材や大寸法の放射部材にも容易
に適用することができ、さらにはコスト的にもさほど高
コストとはならない等、各種の長所を有する。
According to the far-infrared radiation member of the present invention, a hot-dip coating layer made of an Al-Si alloy is formed on the surface of a base material made of an iron-based material capable of electromagnetic induction heating or electric heating, and the hot-dip plating is performed. An anodized film is formed on the surface of the layer, and the Al-Si alloy of the hot-dip plated layer is excellent in far-infrared radiation characteristics and heat crack resistance in the state where the anodized film is formed. By directly heating the part by electromagnetic induction heating or electric heating, far infrared rays can be radiated with high radiation efficiency from the anodized film on the surface of the hot-dip plated layer, and heat cracks occur in the anodized film even at high temperatures. Since there is little fear, it has high durability and stable far infrared radiation characteristics. In addition, since the base material made of an iron-based material is hot-plated with an Al-Si-based aluminum alloy, it has high corrosion resistance and good formability, and is suitable for radiating members with complicated shapes and large-sized radiating members. Can be easily applied, and has various advantages such that the cost is not so high.

フロントページの続き (72)発明者 猿渡 光一 東京都江東区木場1丁目5番1号 株式会 社フジクラ内Front page continuation (72) Inventor Koichi Saruwatari Fujikura, 1-5-1 Kiba, Koto-ku, Tokyo

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】 電磁誘導加熱もしくは通電加熱可能な鉄
系材料からなる基材の片面もしくは両面に、Si1〜1
5wt%を含有するAl−Si系合金からなる溶融メッキ
層が形成され、さらにその溶融メッキ層表面に陽極酸化
皮膜が形成されたことを特徴とする、電磁誘導加熱もし
くは通電加熱可能な遠赤外線放射部材。
1. Si 1 to 1 on one or both sides of a base material made of an iron-based material capable of electromagnetic induction heating or electric current heating.
Far-infrared radiation capable of electromagnetic induction heating or electric current heating, characterized in that a hot-dip layer made of an Al-Si alloy containing 5 wt% is formed and an anodic oxide film is further formed on the surface of the hot-dip layer. Element.
【請求項2】 請求項1に記載の遠赤外線放射部材にお
いて、前記溶融メッキ層のAl−Si系合金が、Si1
〜15wt%を含有し、かつF0.05〜2.0wt%、M
g0.05〜2.0wt%、Cu0.05〜6.0wt%、
Mn0.05〜2.0wt%、Ni0.05〜3.0wt
%、Cr0.05〜0.5wt%、V0.05〜0.5wt
%、Ti0.005〜0.2wt%、Zr0.05〜0.
5wt%、P0.005〜0.1wt%、Na0.005〜
0.1wt%、Sb0.005〜0.3wt%、Sr0.0
05〜0.1wt%のうちの1種または2種以上を含有
し、残部がAlおよび不可避的不純物よりなることを特
徴とする、電磁誘導加熱もしくは通電加熱可能な遠赤外
線放射部材。
2. The far-infrared radiation member according to claim 1, wherein the Al—Si alloy of the hot-dip plated layer is Si1.
˜15 wt% and F0.05-2.0 wt%, M
g 0.05 to 2.0 wt%, Cu 0.05 to 6.0 wt%,
Mn 0.05-2.0 wt%, Ni 0.05-3.0 wt
%, Cr 0.05 to 0.5 wt%, V 0.05 to 0.5 wt%
%, Ti 0.005 to 0.2 wt%, Zr 0.05 to 0.
5 wt%, P 0.005-0.1 wt%, Na 0.005-
0.1 wt%, Sb 0.005-0.3 wt%, Sr0.0
A far-infrared radiation member capable of electromagnetic induction heating or electric heating, containing one or more of 0.05 to 0.1 wt% and the balance being Al and unavoidable impurities.
【請求項3】 電磁誘導加熱もしくは通電加熱可能な鉄
系材料からなる基材の片面もしくは両面に、Si1〜1
5wt%を含有するAl−Si系合金を溶融メッキした
後、その溶融メッキ層を200〜550℃で0.5〜2
4時間加熱し、その後溶融メッキ層表面に陽極酸化処理
を施すことを特徴とする、電磁誘導加熱もしくは通電加
熱可能な遠赤外線放射部材の製造方法。
3. Si 1 to 1 on one or both sides of a base material made of an iron-based material capable of electromagnetic induction heating or electric current heating.
After hot-plating an Al-Si alloy containing 5 wt%, the hot-dip coating layer is applied at 200-550 ° C for 0.5-2.
A method for producing a far-infrared emitting member capable of electromagnetic induction heating or electric current heating, which comprises heating for 4 hours and then subjecting the surface of the hot-dip plated layer to anodization.
JP1672593A 1993-01-06 1993-01-06 Far infrared ray radiation member and manufacture thereof Pending JPH06207262A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1672593A JPH06207262A (en) 1993-01-06 1993-01-06 Far infrared ray radiation member and manufacture thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1672593A JPH06207262A (en) 1993-01-06 1993-01-06 Far infrared ray radiation member and manufacture thereof

Publications (1)

Publication Number Publication Date
JPH06207262A true JPH06207262A (en) 1994-07-26

Family

ID=11924242

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1672593A Pending JPH06207262A (en) 1993-01-06 1993-01-06 Far infrared ray radiation member and manufacture thereof

Country Status (1)

Country Link
JP (1) JPH06207262A (en)

Cited By (15)

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WO1997047159A1 (en) * 1996-06-03 1997-12-11 Kanagawa Prefectural Government Process for producing infrared emitting device and infrared emitting device produced by the process
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Publication number Priority date Publication date Assignee Title
WO1997047159A1 (en) * 1996-06-03 1997-12-11 Kanagawa Prefectural Government Process for producing infrared emitting device and infrared emitting device produced by the process
US6204083B1 (en) 1996-06-03 2001-03-20 Anritsu Corporation Process for producing infrared emitting device and infrared emitting device produced by the process
JP2000328216A (en) * 1999-03-15 2000-11-28 Nippon Steel Corp High corrosion resistant plated steel sheet
JP2001073108A (en) * 1999-06-29 2001-03-21 Nippon Steel Corp Hot-dip aluminized steel sheet with excellent corrosion resistance and appearance and its manufacturing method
JP2001214249A (en) * 2000-01-31 2001-08-07 Nisshin Steel Co Ltd Aluminum plated steel sheet excellent in corrosion resistance
JP2004107730A (en) * 2002-09-19 2004-04-08 Jfe Steel Kk Hot-dip Al-Zn coated steel sheet with excellent bending workability and peeling resistance
KR100835499B1 (en) * 2006-12-28 2008-06-04 김인달 Steel-aluminum alloy body coated with aluminum or aluminum alloy on steel material and manufacturing method thereof
JP2010281537A (en) * 2009-06-08 2010-12-16 Oki Kogei:Kk Ingredient drying device
JP2013166977A (en) * 2012-02-14 2013-08-29 Nisshin Steel Co Ltd MOLTEN Al-BASED PLATED STEEL SHEET FOR ANODIC OXIDATION INSULATION PROCESS AND METHOD FOR PRODUCING THE SAME
JP2013166978A (en) * 2012-02-14 2013-08-29 Nisshin Steel Co Ltd Surface treated steel sheet having good insulation property and method for producing the same
JP2013171876A (en) * 2012-02-17 2013-09-02 Nisshin Steel Co Ltd Cis solar battery and manufacturing method therefor
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JP2020007585A (en) * 2018-07-04 2020-01-16 Jfeスチール株式会社 Hot-dip Al-Si plated steel sheet and method for producing the same
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