JPH06275697A - 昇温脱離ガス分析装置 - Google Patents

昇温脱離ガス分析装置

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Publication number
JPH06275697A
JPH06275697A JP5064196A JP6419693A JPH06275697A JP H06275697 A JPH06275697 A JP H06275697A JP 5064196 A JP5064196 A JP 5064196A JP 6419693 A JP6419693 A JP 6419693A JP H06275697 A JPH06275697 A JP H06275697A
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Prior art keywords
sample
temperature
desorbed
mass
gas
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JP3298974B2 (ja
Inventor
Taizo Uchiyama
山 泰 三 内
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DENSHI KAGAKU KK
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DENSHI KAGAKU KK
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Priority to JP06419693A priority Critical patent/JP3298974B2/ja
Priority to US08/210,761 priority patent/US5528032A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J49/00Particle spectrometers or separator tubes
    • H01J49/02Details
    • H01J49/04Arrangements for introducing or extracting samples to be analysed, e.g. vacuum locks; Arrangements for external adjustment of electron- or ion-optical components
    • H01J49/0468Arrangements for introducing or extracting samples to be analysed, e.g. vacuum locks; Arrangements for external adjustment of electron- or ion-optical components with means for heating or cooling the sample
    • H01J49/049Arrangements for introducing or extracting samples to be analysed, e.g. vacuum locks; Arrangements for external adjustment of electron- or ion-optical components with means for heating or cooling the sample with means for applying heat to desorb the sample; Evaporation

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
  • Testing Or Measuring Of Semiconductors Or The Like (AREA)

Abstract

(57)【要約】 【目的】 測定結果に一つの基準を設定し、真空中に脱
離するガスの種類ごとの測定結果の絶対値を表示できる
ようにする。 【構成】 真空チャンバ内の試料ステージ上に載置した
試料に赤外線を照射して加熱し、質量分析計により脱離
するガスを検出して質量を分析する昇温脱離ガス分析装
置において、質量分析計の出力電気信号を取込む演算回
路を備え、試料の加熱開始からその試料からの脱離ガス
がきわめて小さくなる温度までの温度(または経過時
間)の関数として、検出物質の質量毎にその信号強度を
継続的に記録し、その質量毎にその信号強度の温度(ま
たは時間)について積分値を演算する。この積分値を標
準サンプルについての値と比較することにより、分子数
の絶対値を求めることができる。

Description

【発明の詳細な説明】
【0001】
【産業上の利用分野】本発明は、集積回路用半導体チッ
プその他小形かつ精密な部品の試験に利用する。本発明
は、被試験物となる試料を高真空中に配置し、その試料
を加熱するときに、この試料から放出されるきわめて微
量の脱離ガスを捕捉してその質量分析をすることによ
り、その試料の製造工程の経歴を評価して、その製造工
程を改良するために利用する。
【0002】
【従来の技術】半導体チップの製造工程では、薬品によ
る処理、洗浄、蒸着などが繰り返し実行される多数の工
程を経ることになるが、製造歩留りを向上するためには
その製造工程のどの部分をどのように改良すればよいか
を発見しなければならない。このために、半導体チップ
の半製品あるいは製品の脱離ガスを検出する技術が知ら
れている。これは、製造工程の途中あるいは終点で摘出
された半製品あるいは製品を試料として、これを極めて
高い真空中に置きこの試料を加熱する。そうすると、そ
の試料に残留している薬品などの微量成分がガス状で放
出される。このガスをその真空雰囲気中で捕捉し、その
質量分析をするとその組成を特定することができるか
ら、製造工程中のどの部分の処理がどのように影響して
いるかを評価することができる。
【0003】本願出願人は、このための装置を飛躍的に
改良する発明について先に特許出願した(特開平4−4
8254号公報参照)。この改良は、きわめて高い真空
を作るために金属円筒を外殻とする真空チャンバを鉛直
に用い、その中心付近に試料ステージを配置し、その試
料ステージを下方から赤外線により照射する構造であ
る。そして、試験期間を通じて高い真空度を維持するた
めに高性能の真空ポンプを用い、これを試験期間を通じ
て連続的に運転するとともに、真空チャンバ内の雰囲気
を真空ポンプに導入する排気通路に脱離ガスを検出する
ための質量分析計を配置したものである。
【0004】
【発明が解決しようとする課題】この装置は、これまで
測定不能であった低レベルのガスを計測することができ
る装置として内外からきわめて高い評価を得た。この装
置を用いて測定を繰り返すうちに発明者は次のことに気
付いた。すなわち、試料を室温からはじめてしだいに加
熱すると、試料温度が上昇するにしたがって試料から脱
離するガスの量が大きくなるが、さらに温度を上昇させ
ると脱離するガスの量はしだいに小さくなり脱離ガスが
ほとんどなくなる状態になる。これは、試料に付着した
そのガスの成分が全部脱離したものと考えられるから、
温度の上昇にしたがって測定されるそのガス信号強度を
温度を横軸にしたグラフに描くと、そのグラフにより囲
まれた面積が脱離したガスの全量に比例することにな
る。
【0005】一方、シリコン基板の表面をフッ酸により
処理すると、シリコン基板の表面には水素分子が一層だ
け配列することが知られている(文献:「水素終端Si
表面の評価」 高萩隆行 財団法人電気学会 電子材料
研究会資料 EFM−92−37)。これは水素分子の
数にして1cm2 当り 7×1014個である。シリコン
基板の表面をフッ酸により処理した試料について、この
脱離ガス分析装置を利用して繰り返し測定を行うと常に
その信号強度はほぼ均一に測定することができる。
【0006】本発明はこの現象を基にして、このような
装置による測定結果に一つの基準を設定し、測定結果の
絶対値を表示することができる脱離ガス分析装置を提供
することを目的とする。
【0007】
【課題を解決するための手段】本発明は、真空チャンバ
と、この真空チャンバを真空に維持する真空ポンプと、
この真空チャンバ内に配置された試料ステージと、この
試料ステージ上に置かれた試料をこの試料ステージの下
から赤外線を照射することにより加熱する加熱器と、前
記真空チャンバ内に配置され前記試料から脱離するガス
を検出する質量分析計とを備えた昇温脱離ガス分析装置
において、前記質量分析計の出力電気信号を取込む演算
回路を備え、この演算回路は、前記試料の加熱開始から
その試料からの脱離ガスがきわめて小さくなる温度まで
の温度(または経過時間)の関数として、検出物質の質
量毎にその信号強度を継続的に記録する手段と、その質
量毎にその信号強度の温度(または時間)についての積
分値を演算し、前記積分値を基準値に対する比により表
示する手段を備え、前記基準値は、フッ酸により表面処
理を施したシリコン基板から脱離する水素分子について
の前記積分値に相当するもので、その値は2×7×10
14 個/cm2 とすることができる。
【0008】
【作用】真空チャンバ内の試料ステージ上に試料を載置
し、真空ポンプにより真空チャンバ内を真空状態にし
て、試料ステージ上に置かれた試料を試料ステージの下
から加熱器により赤外線を照射して加熱する。この加熱
により試料から脱離するガスを質量分析計が検出し電気
信号として演算回路に出力する。演算回路はこの電気信
号を取込み、試料の加熱開始からその試料からの脱離ガ
スがきわめて小さくなる温度までの温度(または経過時
間)の関数として、検出物質の質量毎にその信号強度を
継続的に記録し、その質量毎にその信号強度の温度(ま
たは時間)についての積分値を演算する。
【0009】これにより、試料から脱離するガスがほぼ
なくなるまでの温度(または経過時間)を関数とした信
号強度を質量ごとに図形として表示しその積分値を演算
することができる。この積分値を用いて、標準サンプル
(この例ではフッ酸により処理されたSi基板)に対す
る比例関係から、脱離したガス分子の個数を求めること
ができる。
【0010】
【実施例】次に、本発明実施例を図面に基づいて説明す
る。図1は本発明実施例装置の要部の構成を示すブロッ
ク図、図2は本発明実施例装置全体の外観形状を示す正
面図、図3は本発明実施例装置要部の外観形状を示す斜
視図である。
【0011】本発明実施例は、真空チャンバ1と、この
真空チャンバ1を真空に維持する真空ポンプ1aと、真
空チャンバ1内に配置された試料ステージ2と、この試
料ステージ2上に置かれた試料3をこの試料ステージ2
の下から赤外線を照射することにより加熱する加熱器4
と、真空チャンバ1内に配置され試料3から脱離するガ
スを検出する質量分析計5とを備え、さらに、本発明の
特徴として、質量分析計5の出力電気信号を取込む演算
回路7を備える。この演算回路7には、試料3の加熱開
始からその試料3からの脱離ガスがきわめて小さくなる
温度までの温度(または経過時間)の関数として、検出
物質の質量毎にその信号強度を継続的に記録する手段
と、その質量毎にその信号強度の温度(または時間)に
ついての積分値を演算する手段と、その積分値を基準値
に対する比としてCRT表示装置8の画面に表示し、あ
るいはプリンタ9により印字表示する手段とを備える。
【0012】前記基準値は、フッ酸により表面処理を施
したシリコン基板から脱離する水素分子についての前記
積分値に相当する値であり、2×7×1014個/cm2
である。この説明は後でらさに詳しく述べる。
【0013】真空チャンバ1の外殻には、中心軸が鉛直
に配置された一つの金属円筒11と、この金属円筒11
の上端に被せられた蓋12とを含み、試料ステージ2の
試料載置面が前記中心軸上にその中心軸に垂直な平面に
なるように形成され、蓋12には、ほぼその中心にその
試料ステージ2を透過する赤外線をこの真空チャンバ1
の外部に放散させる赤外線透過窓12aが形成され、質
量分析計5が蓋12に赤外線透過窓12aに並んで配置
されたポート12bに取付けられる。
【0014】さらに、金属円筒11には、質量分析計5
を試料3に対し他の方向から取付けるためのポート12
cが取付けられる。この質量分析計5を取付けるポート
は必要に応じて複数設けられる。
【0015】なお、図1および図2中、15はロードロ
ックチャンバ、16は試料移載用マニュプレータ、17
は試料出入ポート、20は測温装置である。
【0016】試料分析の操作は、真空状態に保った真空
チャンバ1内の試料ステージ2の上に、ゲート弁を持つ
ロードロックチャンバ15から試料3を搬送載置し、十
分高い真空度が得られてから、加熱器4から赤外線を照
射し試料ステージ2上の試料3を加熱する。加熱された
試料3からは脱離ガスが放出される。このガス分子を直
接質量分析計5の取入口に導入して、この分子をイオン
化し、加速して電界および磁界、あるいはそのいずれか
を通過させることによりその質量数と質量数に対応する
イオン強度を測定する。この質量分析計5の動作につい
ては公知であるのでここでは詳しい説明を省略する。
【0017】ここで、演算回路7による試料3の分子数
計算について説明する。図4は本発明実施例装置による
分子数計算の流れを示す流れ図、図5は本発明実施例装
置による面積計算処理の流れを示す流れ図、図6は本発
明実施例装置により求められたH2 の面積強度の一例を
示す図、図7は本発明実施例装置により求められたH2
Oの面積強度の一例を示す図である。
【0018】まず、標準サンプルとして面積Acm2
シリコン基板を準備し、数パーセント濃度のフッ酸によ
りエッチング処理を施す。この処理の結果シリコン基板
にはその表裏それぞれに水素分子がきわめて安定に7×
1014個/cm2 存在することが知られている。これは
さまざまな測定結果から確かめられている(文献:「水
素終端Si表面の評価」 高萩隆行 財団法人電気学会
電子材料研究会資料EFM−92−37)。このエッ
チング処理により表面に配列されたNH2=2×7×10
14個×Aの水素分子が図6に示すような加熱によりすべ
て脱離したものとする。ここで2倍にしたのは表と裏が
あるからである。図6は横軸に温度上昇の経過をとり、
縦軸に質量分析計5に検出されたH2 の信号強度をと
る。図6に示す温度範囲R1 内の斜線部分の面積SH2
求めると、この面積SH2は脱離した全水素分子の数に比
例することになる。この温度範囲R1 の上限を越える領
域に記録された信号強度は標準サンプル以外の部分から
のものとして対象外とする。
【0019】ここで、いま測定した標準サンプルのサイ
ズAcm2 を入力し次式により比例定数Kを求める。
【0020】 K=NH2/SH2 =2×7×1014個×A/SH2 (1) 次に、被測定サンプルを真空チャンバ1内の試料ステー
ジ2上に載置し、真空ポンプ1aにより真空状態を維持
する。
【0021】いま被測定サンプルについて、室温から数
百℃までサンプル温度を上昇させながら、しかもそのサ
ンプル温度を熱電対温度計で測定しながら、H2 Oの脱
離ガス信号強度を測定する。この測定結果の一例として
図7に示すものが得られた。すなわち、サンプル温度9
00℃位まで有効な測定が行われ、図7に示す温度65
0℃を越えると信号強度がほとんどなくなることが見ら
れた。このことにより温度範囲R2 で、この被測定サン
プルの表面から全H2 O分子が脱離したものと推定され
る。
【0022】図7の斜線を付した部分の面積SH2O を求
めると、これはこの被測定サンプルの表面から脱離した
全H2 O分子の数に比例することになる。そしてその比
例定数は、上で求めたKである。
【0023】いま、わかりやすい一例として図7を示す
が、実際の測定時では、温度上昇はゆっくり行い、この
間に質量分析計5のチャンネルを切替えて、質量数
(M)の異なる複数の物質について並行的に測定を行う
ことができる。例えば、H2 (M=2)、H2 O(M=
18)、N2 (M=28)、CO2 (M=44)などが
図7のグラフと同様に求まる。そして、各物質毎に面積
H2、SH2O 、SN2、SCO2 などを計算する。次に各物
質の分子式を入力し、演算回路7に記憶されたテーブル
より、各物質固有の比例定数と、(1)式の比例定数と
から求める分子数を計算する。ちなみに図7で求めたS
H2O から求めた全脱離H2 Oの分子数は1.6×1017
個であった。
【0024】これを一般論として、質量Mの物質Xにつ
いて考えると次のようになる。四重極質量分析計におい
て真空チャンバ内のこの物質Xの分圧PPX の信号強度
XMは、 IXM=PPX ×(FFXM×XFX ×TFM )×KS (2) ここで、FFXM:フラグメンテーション・ファクタ XFX :イオン化難易度 TFM :質量数28に対する質量数Mの通過ファクタ KS :イオン・マルチプライヤの印加電圧に依存する
定数である。
【0025】また、サンプル表面の分子数Nに対して得
られたデータの面積Sは S=N×(FFXM×XFX ×TFM )×KN (3) ここで、 KN :比例定数である 水素H2 については、 SH2=NH2×(FFXM×XFX ×TFM H2×KN (4) 分子Xについては、 SX =NX ×(FFXM×XFX ×TFM X ×KN (5) となる。
【0026】したがって、(4)式および(5)式より NX =SX ×NH2/SH2×(FFXM×XFX ×TFM H2 /(FFXM×XFX ×TFM X (1)式の比例定数Kを用いて、 NX =K×SX ×(FFXM×XFX ×TFM H2 /(FFXM×XFX ×TFM X (6) となり、分子Xの分子数が計算される。
【0027】このようにして求められた値はプリンタ9
に出力される。
【0028】また、面積計算を行うには、図5に示すよ
うに、表示のT(温度)、Y(信号強度)範囲を入力す
ることにより、まずCRT表示装置8に信号強度の図形
を表示し、次いで面積計算の開始温度、終了温度を入力
することにより、開始温度と終了温度との間の信号強度
の和として面積を求める。
【0029】ここで、水素H2 の計算の実例をあげる
と、水素H2 について XF=0.44、FF=0.98、TF=28/2=1
4 水H2 Oについて XF=1.0、FF=0.75、TF=28/18=
1.55 であるので、 (FFXM×XFX ×TFM H2/(FFXM×XFX ×TFM H2O =0.44×0.98×14/1.0×0.75×1.55=5.19 図6に示す標準サンプルのフッ酸処理したSi基板(面
積:1cm2 )のデータはSH2が728であることから
(1)式を用いて、 K=NH2/SH2 =2×7×1014個/728 =1.92×1012個 また、水H2 Oについては、図7に示す実例では、面積
強度SH2O は16077であるので、水H2 Oの分子数
は(6)式から NH2O =1.92×1012個×16077×5.19 =1.60×1017個となる。
【0030】実用的な測定では、被測定サンプルを交換
するためにロードロックチャンバ15を使用しても、交
換のつど真空度が低下し、これを回復させるためには時
間がかかるから、質量分析計5の測定質量数(チャンネ
ル)を切替えながら測定を行い、図6のような結果を多
数いちどに得ることができる。図4に示すフローチャー
トに表れるループはこの異なる多数の物質についてすべ
て演算することを示す。これにより、脱離分子の数を多
数の物質についていちどに測定するとこができる。
【0031】本発明においては、フッ酸により表面処理
を施したシリコン基板を基準試料として用いているが、
表面に付着する分子数が既知である他の板を基準試料と
して用いることもできる。
【0032】
【発明の効果】以上説明したように本発明によれば、試
料から脱離するガスがほぼなくなるまでの温度(または
経過時間)を関数とした信号強度を種類ごとに図形とし
て表示しその積分値を演算することにより、脱離ガスの
種別毎に、その分子数を測定することができる効果があ
る。
【0033】この装置を半導体集積回路の製造工程評価
に利用すると、工程中で回路基板に付着した望まない物
質の量を知ることができ、製造歩留りを向上させること
ができる。
【図面の簡単な説明】
【図1】本発明実施例装置の要部の構成を示すブロック
図。
【図2】本発明実施例装置全体の外観形状を示す正面
図。
【図3】本発明実施例装置要部の外観形状を示す斜視
図。
【図4】本発明実施例装置による分子数計算処理の流れ
を示す流れ図。
【図5】本発明実施例装置による面積計算処理の流れを
示す流れ図。
【図6】本発明実施例装置により求められたH2 の面積
強度の一例を示す図。
【図7】本発明実施例装置により求められたH2 Oの面
積強度の一例を示す図。
【符号の説明】
1 真空チャンバ 1a 真空ポンプ 2 試料ステージ 3 試料 4 加熱器 5 質量分析計 7 演算回路 8 CRT表示装置 9 プリンタ 11 金属円筒 12 蓋 12a 赤外線透過窓 12b、12c ポート 15 ロードロックチャンバ 16 試料移載用マニュプレータ 17 試料出入ポート

Claims (2)

    【特許請求の範囲】
  1. 【請求項1】 真空チャンバと、この真空チャンバを真
    空に維持する真空ポンプと、この真空チャンバ内に配置
    された試料ステージと、この試料ステージ上に置かれた
    試料を加熱する加熱器と、前記真空チャンバ内に配置さ
    れ前記試料から脱離するガスを検出する質量分析計とを
    備えた昇温脱離ガス分析装置において、 前記質量分析計の出力電気信号を取込む演算回路を備
    え、 この演算回路は、前記試料の加熱開始からその試料から
    の脱離ガスがきわめて小さくなる温度までの温度(また
    は経過時間)の関数として、検出物質の質量毎にその信
    号強度を継続的に記録する手段と、その質量毎にその信
    号強度の温度(または時間)についての積分値を演算す
    るとともに、その積分値を基準値に対する比により前記
    試料の表面に付着した前記検出物質の分子数を表示する
    手段を備えたことを特徴とする昇温脱離ガス分析装置。
  2. 【請求項2】 前記基準値は、フッ酸により表面処理を
    施したシリコン基板から脱離する水素分子に比例する前
    記積分値に相当する値である請求項1記載の昇温脱離ガ
    ス分析装置。
JP06419693A 1993-03-23 1993-03-23 昇温脱離ガス分析装置 Expired - Lifetime JP3298974B2 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP06419693A JP3298974B2 (ja) 1993-03-23 1993-03-23 昇温脱離ガス分析装置
US08/210,761 US5528032A (en) 1993-03-23 1994-03-22 Thermal desorption gas spectrometer

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP06419693A JP3298974B2 (ja) 1993-03-23 1993-03-23 昇温脱離ガス分析装置

Publications (2)

Publication Number Publication Date
JPH06275697A true JPH06275697A (ja) 1994-09-30
JP3298974B2 JP3298974B2 (ja) 2002-07-08

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Country Status (2)

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