JPH0629400B2 - Curing agent for putty composition - Google Patents
Curing agent for putty compositionInfo
- Publication number
- JPH0629400B2 JPH0629400B2 JP63134356A JP13435688A JPH0629400B2 JP H0629400 B2 JPH0629400 B2 JP H0629400B2 JP 63134356 A JP63134356 A JP 63134356A JP 13435688 A JP13435688 A JP 13435688A JP H0629400 B2 JPH0629400 B2 JP H0629400B2
- Authority
- JP
- Japan
- Prior art keywords
- curing agent
- peroxide
- putty composition
- container
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000002978 peroxides Chemical class 0.000 claims description 15
- 229920006305 unsaturated polyester Polymers 0.000 claims description 10
- 125000002252 acyl group Chemical group 0.000 claims description 8
- 150000002576 ketones Chemical class 0.000 claims description 7
- 238000005192 partition Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 description 18
- -1 methyl isobutyl ketone peroxide Chemical class 0.000 description 11
- 238000000034 method Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 235000019400 benzoyl peroxide Nutrition 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
Landscapes
- Sealing Material Composition (AREA)
- Polymerization Catalysts (AREA)
- Paints Or Removers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Description
【発明の詳細な説明】 （発明の属する分野） 本発明は自動車補修用不飽和ポリエステルパテ組成物を
実際に使用する場合に極めて作業性の良好な硬化剤を提
供するものである。Description: FIELD OF THE INVENTION The present invention provides a curing agent having excellent workability when an unsaturated polyester putty composition for automobile repair is actually used.
（従来技術の説明） 従来パテ組成物は、不飽和ポリエステルに充てん剤を混
合した主剤と過酸化物をペースト化した硬化剤とから構
成されている。過酸化物として、メチルエチルケトンパ
ーオキサイド、メチルイソブチルケトンパーオキサイ
ド、シクロヘキサノンパーオキサイド、メチルシクロヘ
キサノンパーオキサイドなどのケトン系パーオキサイド
と、ベンゾイルパーオキサイドのようなアシル系パーオ
キサイドが汎用である。レドックス触媒を用いて常温硬
化させるため、ケトン系パーオキサイドは、ナフテン酸
コバルトなどコバルト塩を触媒とし、アシル系パーオキ
サイドは、ジメチルアニリンなどアミン系化合物を触媒
としている。この組合せから自動車補修用不飽和ポリエ
ステルパテ組成物としての特性が表われ、ベンゾイルパ
ーオキサイドを用いると被着体に対する接着性が良いが
触媒のアミンによる塗装面の汚染が現われる。また、パ
テの硬化時、空気との接着面に粘着性が残りなかなかタ
ックフリーにならない。ケトン系パーオキサイドを用い
ると被着体に対する接着性は、アシル系に比べてやゝ劣
るが塗装面の汚染は、ほとんどない。また、硬化後のパ
ラ表面のタックフリーはアシル系に比較して速いが、反
応は緩慢であるため硬度の立上りは遅い。本発明はこの
ような従来の問題点を解消し、併せて著しく作業性を改
善した良好な硬化剤を提供するものである。(Explanation of Prior Art) A conventional putty composition is composed of a main agent obtained by mixing an unsaturated polyester with a filler and a curing agent obtained by converting a peroxide into a paste. Commonly used peroxides are ketone-based peroxides such as methyl ethyl ketone peroxide, methyl isobutyl ketone peroxide, cyclohexanone peroxide, and methylcyclohexanone peroxide, and acyl-based peroxides such as benzoyl peroxide. Since the redox catalyst is used to cure at room temperature, the ketone peroxide uses a cobalt salt such as cobalt naphthenate as a catalyst, and the acyl peroxide uses an amine compound such as dimethylaniline as a catalyst. From this combination, the characteristics as an unsaturated polyester putty composition for automobile repair are exhibited. When benzoyl peroxide is used, the adhesion to the adherend is good, but the coated surface is contaminated by the amine of the catalyst. Also, when the putty is cured, tackiness does not easily become tack-free on the adhesive surface to the air. When a ketone-based peroxide is used, the adhesion to the adherend is slightly inferior to the acyl-based one, but there is almost no stain on the coated surface. Further, the tack-free property of the para surface after curing is faster than that of the acyl system, but the reaction is slow and the rise of hardness is slow. The present invention solves these conventional problems and provides a good curing agent with significantly improved workability.
（発明の構成） 本発明は一つの容器に隔壁を界してケトン系パーオキサ
イドとアシル系パーオキサイドを充てんさせ、使用の際
に当該二液を当該容器から吐出し混合してなることを特
徴とする自動車補修用不飽和ポリエステルパテ組成物用
硬化剤に関する。(Structure of the Invention) The present invention is characterized in that one container is filled with a ketone-based peroxide and an acyl-based peroxide by interposing a partition wall, and the two liquids are discharged from the container and mixed when used. And a curing agent for an unsaturated polyester putty composition for automobile repair.
前述した通りケトン系パーオキサイドとアシル系パーオ
キサイドはそれぞれ硬化剤としての欠点を有している
が、これを同時に使用する方法を追求したところ、両者
の長所だけが現われ、従来の自動車補修パテの特性が大
幅に改善されることを見い出した。ところがケトン系パ
ーオキサイドとアシル系パーオキサイドを混合すると硬
化剤のライフサイクルが短くなり、商品化するには冷暗
所保管が必要となる。As mentioned above, ketone-based peroxides and acyl-based peroxides each have drawbacks as curing agents, but when we pursued a method of using both at the same time, only the advantages of both appeared and the conventional car repair putty It has been found that the characteristics are greatly improved. However, when a ketone-based peroxide and an acyl-based peroxide are mixed, the life cycle of the curing agent is shortened, and storage in a cool and dark place is required for commercialization.
又、硬化剤を別々の容器に入れて使えば従来１回で済む
作業が２回となり作業が増加するだけでなく硬化剤量の
計量も従来の半分となるため計量精度の低下で自動車補
修用不飽和ポリエステルパテ組成物の品質にも問題が発
生する。In addition, if the curing agent is put in separate containers and used, the work required only once will be performed twice, and the work will be increased, and the amount of the curing agent will be halved as compared with the conventional method. Problems also occur in the quality of the unsaturated polyester putty composition.
本発明はこのような問題に対して隔壁を有する容器を使
用することにより解決し、極めて作業性の高い良好な硬
化剤を作ることに成功した。The present invention has solved such problems by using a container having a partition wall, and succeeded in producing a good curing agent having extremely high workability.
隔壁のある容器から同時にそれぞれを取出す方法として
ピストン方式と絞出方式が考えられる。A piston method and a squeezing method are conceivable as methods of simultaneously taking out each from a container having a partition.
ピストン方式としては、容器には変形しにくい材質でポ
リエチレンやポリプロピレンの成形品がある。また絞出
方式としては容器は変形し易い材質でポリエチレンやポ
リプロピレンのフィルム状のものがある。As the piston method, there are molded articles made of polyethylene or polypropylene that are not easily deformed in the container. As for the squeezing method, the container may be a deformable material such as polyethylene or polypropylene film.
実施例について説明すれば、１は容器本体（ネジ付キャ
ップ付）である。押出棒５をプランジャー４に押し当て
ることにより１の反対側の先端から隔壁３を界して硬化
剤２，２′が出てくる。又、フィルム状容器の場合、使
用時に、フィルムヒートシール部６の切り込み７で容器
の口を開き、プラスチック治具８、９でシールされた端
部より巻き取りハンドル１０を回転させてフィルムを絞
りながら押出口より硬化剤を吐出し混合して自動車補修
用不飽和ポリエステルパテ組成物の硬化剤として使用す
る。Explaining an example, 1 is a container body (with a cap with a screw). By pressing the push rod 5 against the plunger 4, the hardeners 2 and 2 ′ come out from the tip on the side opposite to 1 through the partition wall 3. Further, in the case of a film-like container, at the time of use, the mouth of the container is opened by the notch 7 of the film heat-sealing portion 6, and the winding handle 10 is rotated from the end portion sealed by the plastic jigs 8 and 9 to squeeze the film. Meanwhile, the curing agent is discharged from the extrusion port and mixed to be used as a curing agent for the unsaturated polyester putty composition for automobile repair.
（実施例および比較例の説明） 次に実施例および比較例を挙げて本発明を具体的に説明
する。(Description of Examples and Comparative Examples) Next, the present invention will be specifically described with reference to Examples and Comparative Examples.
実施例１． 不飽和ポリエステル樹脂ポリセット１７１
４Ｂ（日立化成工業ＫＫ製）４０重量パーセントに輸入
タルク ＴＡＬＣＳＰ（日本タルクＫＫ製）３０重量パ
ーセント超微粒子炭酸カルシウムＮＳ−１００（日東粉
化工業ＫＫ製）３０重量パーセント及び硬化促進剤ＣＴ
−１３（日立化成工業ＫＫ製）５重量パーセントを均一
になるまで混合し、主剤とした。この自動車補修用不飽
和ポリエステルパテ組成物の主剤１００重量パーセント
に対して図１に示す容器を用いて、ベンゾルパーオキサ
イド ナイパーＢＯ（日本油脂ＫＫ製）とケトンパーオ
キサイド パーヘキサＤ（日本油脂ＫＫ製）とを各１重
量パーセント混合し、特性を調べた。その結果を表１に
示す。Example 1. Unsaturated polyester resin polyset 171
4B (manufactured by Hitachi Chemical Co., Ltd. KK) 40% by weight imported talc TALCSP (manufactured by Nippon Talc KK) 30% by weight Ultrafine calcium carbonate NS-100 (manufactured by Nitto Koka Kogyo KK) 30% by weight and curing accelerator CT
-13 (manufactured by Hitachi Chemical Co., Ltd. KK) was mixed in an amount of 5% by weight until it became uniform to prepare a main agent. Using 100% by weight of the main ingredient of the unsaturated polyester putty composition for automobile repair, using the container shown in FIG. 1, benzol peroxide niper BO (manufactured by NOF Corporation KK) and ketone peroxide perhexa D (manufactured by NOF Corporation KK). And 1% by weight of each were mixed and the characteristics were examined. The results are shown in Table 1.
比較例１． 実施例１で作成した主剤１００重量パーセ
ントに対してナイパーＢＯを２重量パーセント混合し、
特性を調べた。その結果を表１に示す。Comparative Example 1. 2% by weight of Niper BO was mixed with 100% by weight of the main agent prepared in Example 1,
The characteristics were investigated. The results are shown in Table 1.
比較例２． 実施例１で作成した主剤１００重量パーセ
ントに対してパーヘキサＤを２重量パーセント混合し、
特性を調べた。その結果を表１に示す。Comparative example 2. 2% by weight of Perhexa D was mixed with 100% by weight of the main agent prepared in Example 1,
The characteristics were investigated. The results are shown in Table 1.
比較例３． 実施例１で作成した主剤１００重要パーセ
ントに対してナイパーＢＯとパーヘキサＤとを等量混合
したポリエチレンチューブ入り硬化剤２重量パーセント
を混合し、特性を調べた。その結果を表１に示す。Comparative Example 3. 2% by weight of a curing agent contained in a polyethylene tube, in which equal amounts of Niper BO and Perhexa D were mixed, was mixed with 100% by weight of the main agent prepared in Example 1, and the characteristics were examined. The results are shown in Table 1.
（本発明の効果） 以上のように、本発明の自動車補修用不飽和ポリエステ
ルパテ組成物用硬化剤により本件に関する従来技術の問
題点が解決され、極めて良好な自動車補修用不飽和ポリ
エステルパテ組成物が提供されることになる。 (Effect of the present invention) As described above, the curing agent for unsaturated polyester putty composition for automobile repair of the present invention solves the problems of the prior art relating to the present matter, and is an excellent unsaturated polyester putty composition for automobile repair. Will be provided.
第１図は本発明の断面図であり第２図は本発明の平面図
であり第３図は本発明の正面図である。 １……容器本体（ネジ付キャップ付） ２……ケトン系パーオキサイド又はアシル系パーオキサ
イド ２′…… 〃 ３……隔壁 ４……プランジャー ５……押出棒 ６……フィルムヒートシール部 ７……切り込み ８……フィルム端部を閉じるプラスチック治具（雄型） ９……フィルム端部を閉じるプラスチック治具（雌型） １０……巻き取りハンドル1 is a sectional view of the present invention, FIG. 2 is a plan view of the present invention, and FIG. 3 is a front view of the present invention. 1 ... Container body (with screw cap) 2 ... Ketone-based peroxide or acyl-based peroxide 2 '... 〃 3 ...... Partition wall 4 ...... Plunger 5 ...... Extrusion rod 6 ...... Film heat seal part 7 …… Incision 8 …… Plastic jig for closing the film edge (male type) 9 …… Plastic jig for closing the film edge (female type) 10 …… Winding handle
───────────────────────────────────────────────────── フロントページの続き (56)参考文献 特開 昭57−40507（ＪＰ，Ａ) 特開 昭50−22893（ＪＰ，Ａ) 特開 昭51−134741（ＪＰ，Ａ) ─────────────────────────────────────────────────── ─── Continuation of the front page (56) References JP-A-57-40507 (JP, A) JP-A-50-22893 (JP, A) JP-A-51-134741 (JP, A)
Claims (1)
キサイドとアシル系パーオキサイドを充てんさせ、使用
の際に当該二液を当該容器から吐出し混合してなること
を特徴とする自動車補修用不飽和ポリエステルパテ組成
物用硬化剤1. An automobile characterized in that one container is filled with a ketone-based peroxide and an acyl-based peroxide with a partition wall and the two liquids are discharged from the container and mixed when used. Curing agent for unsaturated polyester putty composition for repair
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63134356A JPH0629400B2 (en) | 1988-06-02 | 1988-06-02 | Curing agent for putty composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63134356A JPH0629400B2 (en) | 1988-06-02 | 1988-06-02 | Curing agent for putty composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01304106A JPH01304106A (en) | 1989-12-07 |
| JPH0629400B2 true JPH0629400B2 (en) | 1994-04-20 |
Family
ID=15126455
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63134356A Expired - Fee Related JPH0629400B2 (en) | 1988-06-02 | 1988-06-02 | Curing agent for putty composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0629400B2 (en) |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS524315B2 (en) * | 1973-06-28 | 1977-02-02 | ||
| JPS51134741A (en) * | 1975-05-06 | 1976-11-22 | Syntex Inc | Method of producing betaastage unsaturated polyester resin |
| JPS5740507A (en) * | 1980-08-25 | 1982-03-06 | Kayaku Nuurii Kk | Peroxide mixture composition |
-
1988
- 1988-06-02 JP JP63134356A patent/JPH0629400B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01304106A (en) | 1989-12-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |