JPH0631408B2 - Liquid cleanser composition - Google Patents
Liquid cleanser compositionInfo
- Publication number
- JPH0631408B2 JPH0631408B2 JP62305078A JP30507887A JPH0631408B2 JP H0631408 B2 JPH0631408 B2 JP H0631408B2 JP 62305078 A JP62305078 A JP 62305078A JP 30507887 A JP30507887 A JP 30507887A JP H0631408 B2 JPH0631408 B2 JP H0631408B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- point
- component
- stains
- cleanser composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Landscapes
- Detergent Compositions (AREA)
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、優れた洗浄力、研磨力を有し、しかも洗浄対
象面を傷つけることのない液体クレンザー組成物に関す
る。TECHNICAL FIELD The present invention relates to a liquid cleanser composition which has excellent cleaning power and polishing power, and which does not damage the surface to be cleaned.
クレンザーが対象とする汚れは、あまり熱変性していな
い油汚れ（弱変性油汚れ）や流し台の水アカ、ヌルヌル
汚れ等の柔らかい汚れから油や食物の焦げつき汚れの様
な固い汚れまである。この様に一般に見られる汚れの性
質は多種多様であるために、これらの汚れに対して十分
な洗浄力を得るべく特開昭62−95400号公報には特定の
粒径と硬度を有する研磨剤を２種混合することが開示さ
れている。しかしながら、弱変性汚れ研磨力については
満足できるレベルではなく、より大きな弱変性研磨力を
有するクレンザーが求められていた。The stains targeted by the cleanser include oil stains that have not been heat-denatured (weakly modified oil stains), soft stains such as water stains on the sink and slimy stains, and hard stains such as burnt stains of oil and food. Since the properties of stains generally seen in this way are diverse, in order to obtain sufficient cleaning power against these stains, JP-A-62-95400 discloses an abrasive having a specific particle size and hardness. It is disclosed to mix two kinds. However, the polishing power of weakly modified soil is not at a satisfactory level, and a cleanser having a larger polishing power of weakly modified soil has been demanded.
本発明者等は上記の如き一般にみられる広範囲の汚れに
対して十分な洗浄力と、又油が軽く変性したような柔ら
かめの焦げつき汚れに特に優れた洗浄力を有するクレン
ザーを得るべく鋭意検討した結果、特定の粒度を有する
３種の研磨剤を特定の比率で併用すればよいことを見出
し、本発明を完成した。The present inventors have earnestly studied to obtain a cleanser having a sufficient cleaning power for a wide range of stains generally seen as described above, and a particularly excellent cleaning power for soft, charred stains such as lightly modified oil. As a result, they have found that three kinds of abrasives having a specific particle size should be used together in a specific ratio, and completed the present invention.
即ち、本発明は、 (a)平均粒子径が５〜40μの炭酸カルシウム (b)平均粒子径が５〜40μの二酸化珪素 (c)平均粒子径が２〜15μの結晶性アルミノ珪酸塩 (d)陰イオン性界面活性剤 (e)非イオン性界面活性剤 を必須成分として含有し、(a)成分、(b)成分及び(c)成
分の合計が20重量％〜60重量％、かつ(a)成分、(b)成分
及び(c)成分の比率が三角座標の点Ｆ〔(a)80：(b)５：
(c)15〕、点Ｂ〔(a)70：(b)５：(c)25〕、点Ｇ〔(a)6
5：(b)8.5：(c)26.5〕、点Ｅ〔(a)65：(b)30：(c)
５〕、点Ｈ〔(a)80：(b)15：(c)５〕で囲まれた範囲内
にあり、(d)成分を0.5〜５重量％、(e)成分を１〜10重
量％含有することを特徴とする液体クレンザー組成物を
提供するものである。That is, the present invention includes: (a) calcium carbonate having an average particle size of 5 to 40μ (b) silicon dioxide having an average particle size of 5 to 40μ (c) crystalline aluminosilicate having an average particle size of 2 to 15μ (d ) Anionic surfactant (e) Nonionic surfactant is contained as an essential component, and the total of the components (a), (b) and (c) is 20% by weight to 60% by weight, and ( The point F [(a) 80: (b) 5: where the ratio of a), (b) and (c) is triangular coordinates
(c) 15], point B [(a) 70: (b) 5: (c) 25], point G [(a) 6]
5: (b) 8.5: (c) 26.5], point E [(a) 65: (b) 30: (c)
5], within the range surrounded by point H [(a) 80: (b) 15: (c) 5], the component (d) is 0.5 to 5% by weight, and the component (e) is 1 to 10% by weight. % Of the liquid cleanser composition.
(a)成分、(b)成分は平均粒径５〜40μの範囲にあるもの
が使用できるが、60μ以上の粒子含有率が40重量％以
下、５μ以下の粒子含有率が20重量％以下であることが
望ましい。又、(c)成分は平均粒径２〜15μの範囲にあ
るものが使用できるが、30μ以上の粒子含有率が40重量
％以下、0.5μ以下の粒子含有率が20重量％以下である
ことが望ましい。(a)成分、(b)成分及び(c)成分の合計
量は20〜60重量％、好ましくは40〜55重量％である。As the component (a) and the component (b), those having an average particle size in the range of 5 to 40μ can be used, but the particle content of 60μ or more is 40% by weight or less and the particle content of 5μ or less is 20% by weight or less. Is desirable. Further, as the component (c), those having an average particle size in the range of 2 to 15μ can be used, but the particle content of 30μ or more is 40% by weight or less, and the particle content of 0.5μ or less is 20% by weight or less. Is desirable. The total amount of the components (a), (b) and (c) is 20 to 60% by weight, preferably 40 to 55% by weight.
本発明において、(a)、(b)、(c)成分の比率は添付図面
第１図に示す三角座標の点Ａ〔(a)90：(b)５：(c)
５〕、点Ｂ〔(a)70：(b)５：(c)25〕、点Ｃ〔(a)10：
(b)50：(c)40〕、点Ｄ〔(a)10：(b)70：(c)20〕、点Ｅ
〔(a)65：(b)30：(c)５〕で囲まれた四辺形の範囲内に
ある組成物は特開昭62−95400号公報に記載のクレンザ
ー組成物よりも充分に大きな弱変性汚れ研磨力を有する
が、更にこの範囲内に於ても特に三角座標の点Ｆ〔(a)8
0：(b)５：(c)15〕、点Ｂ〔(a)70：(b)５：(c)25〕、点
Ｇ〔(a)65：(b)8.5：(c)26.5〕、点Ｅ〔(a)65：(b)30：
(c)５〕、点Ｈ〔(a)80：(b)15：(c)５〕に囲まれた範囲
内のクレンザー組成物が弱変性汚れ研磨力に於て優れて
いるのみならず、強変性汚れに対してもより優れた研磨
力を発揮する。In the present invention, the ratio of the components (a), (b) and (c) is the point A [(a) 90: (b) 5: (c) of the triangular coordinates shown in FIG. 1 of the accompanying drawings.
5], point B [(a) 70: (b) 5: (c) 25], point C [(a) 10:
(b) 50: (c) 40], point D [(a) 10: (b) 70: (c) 20], point E
The composition within the range of the quadrangle surrounded by [(a) 65: (b) 30: (c) 5] is sufficiently weaker than the cleanser composition described in JP-A-62-95400. It has the ability to polish denatured dirt, but even within this range, it is especially the point F [(a) 8 of the triangular coordinates.
0: (b) 5: (c) 15], point B [(a) 70: (b) 5: (c) 25], point G [(a) 65: (b) 8.5: (c) 26.5] , Point E [(a) 65: (b) 30:
(c) 5], the cleanser composition within the range surrounded by the point H [(a) 80: (b) 15: (c) 5] is not only excellent in weakly modified soil polishing power, Exhibits more excellent polishing power against strongly modified dirt.
本発明に使用される(d)成分陰イオン性界面活性剤とし
ては、直鎖又は分岐鎖アルキル（C8〜C22）ベンゼンス
ルホン酸塩、長鎖アルキル（C8〜C22）スルホン酸塩、
長鎖オレフィンスルホン酸塩、ポリオキシエチレン（１
〜６モル）長鎖アルキル（C8〜C22）エーテル硫酸エス
テル塩、ポリオキシエチレン（１〜６モル）長鎖アルキ
ル（C8〜C22）フェニルエーテル硫酸エステル塩等があ
り、組成物に0.5〜５重量％配合される。これら陰イオ
ン性界面活性剤の対イオンとしての陽イオンは、ナトリ
ウム、カリウム等のアルカリ金属イオン、モノエタノー
ルアミン、ジエタノールアミン、トリエタノールアミン
等のアルカノールアミンイオン等である。The component (d) anionic surfactant used in the present invention, straight-chain or branched-chain alkyl (C 8 ~C 22) benzenesulfonate, long chain alkyl (C 8 ~C 22) sulfonate ,
Long-chain olefin sulfonate, polyoxyethylene (1
6 mol) long-chain alkyl (C 8 -C 22) ether sulfate, polyoxyethylene (1-6 moles) long chain alkyl (C 8 -C 22) There are phenyl ether sulfate, etc., in the composition 0.5 to 5% by weight is compounded. The cations as counterions of these anionic surfactants are alkali metal ions such as sodium and potassium, alkanolamine ions such as monoethanolamine, diethanolamine and triethanolamine.
(e)成分の非イオン性界面活性剤としては、ポリオキシ
エチレン（１〜20モル）長鎖アルキル（第１級又は第２
級C8〜C22）エーテル、ポリオキシエチレン（１〜20モ
ル）長鎖アルキル（C8〜C18）フェニルエーテル、炭素
数10〜16の高級脂肪酸アルカノールアミド、炭素数10〜
16の高級脂肪酸アルカノールアミドエチレンオキサイド
付加物（ｐ＝１〜６）等が使用され、組成物に対して１
〜10重量％配合される。As the nonionic surfactant as the component (e), polyoxyethylene (1 to 20 mol) long-chain alkyl (primary or secondary)
Grade C 8 -C 22) ethers, polyoxyethylene (1-20 moles) long chain alkyl (C 8 -C 18) phenyl ethers, higher fatty acid alkanolamides having 10 to 16 carbon atoms, 10 carbon atoms
16 higher fatty acid alkanolamide ethylene oxide adducts (p = 1 to 6) etc. are used, and 1 for the composition
~ 10 wt% is compounded.
さらに、本発明では、珪酸ソーダ等の珪酸塩及び炭素数
３〜８のジ又はトリカルボン酸又はそれらの塩を配合す
ることにより、洗浄後のすすぎ時に非常に艶の有る仕上
がり感を付与することが出来る。Further, in the present invention, by adding a silicate such as sodium silicate and a di- or tricarboxylic acid having a carbon number of 3 to 8 or a salt thereof, it is possible to give a very glossy finish at the time of rinsing after washing. I can.
本発明組成物で使用される炭素数３〜８のジあるいはト
リカルボン酸又はその塩の具体例を例示すれば、マロン
酸、リンゴ酸、酒石酸、クエン酸、Ｌ−アスパラギン酸
又はその塩である。Specific examples of the di- or tricarboxylic acid having 3 to 8 carbon atoms or a salt thereof used in the composition of the present invention include malonic acid, malic acid, tartaric acid, citric acid, L-aspartic acid or a salt thereof.
ジあるいはトリカルボン酸又はその塩の配合量は0.1〜
５重量％が好ましく、さらに好ましくは0.5〜３重量
％、珪酸ソーダの配合量は0.1〜８重量％が好ましく、
さらに好ましくは0.3〜５重量％である。The amount of di- or tricarboxylic acid or salt thereof is 0.1-
5% by weight is preferable, 0.5 to 3% by weight is more preferable, and the content of sodium silicate is 0.1 to 8% by weight,
More preferably, it is 0.3 to 5% by weight.
本発明の実施にあたって、必要に応じて少量の香料、顔
料、染料、殺菌剤、可溶化剤を添加することもできる。In carrying out the present invention, a small amount of a fragrance, a pigment, a dye, a bactericide, or a solubilizer may be added if necessary.
液のpHは、台所で用いられるため、油汚れに対して優れ
た洗浄力を発揮する様に中性からアルカリ性に調整され
るものである。Since the pH of the liquid is used in the kitchen, it is adjusted from neutral to alkaline so as to exert an excellent cleaning power against oil stains.
本発明の液体クレンザー組成物は、被洗浄面を傷つける
ことなく、又柔らかい汚れから固い汚れまで多種多様の
汚れに対して優れた洗浄力、研磨力を有する。さらに、
洗浄すすぎ後の被洗浄面に非常に艶のある仕上がり感を
付与する。The liquid cleanser composition of the present invention does not damage the surface to be cleaned and has excellent cleaning power and polishing power against a wide variety of stains from soft stains to hard stains. further,
Gives the surface to be cleaned after washing and rinsing a very glossy finish.
以下に実施例により本発明を具体的に説明するが、本発
明はこれら実施例により限定されるものではない。The present invention will be specifically described below with reference to examples, but the present invention is not limited to these examples.
実施例１ 表−１に示す組成物を調製し、各組成物の洗浄力、傷つ
け性について以下の様に評価を行った。尚、表中の組成
は重量％で表わした。Example 1 The compositions shown in Table 1 were prepared, and the cleaning power and scratchability of each composition were evaluated as follows. The composition in the table is expressed by weight%.
〈試験法〉 洗浄力 １．モデル汚れ作製 柔らかい汚れ（弱変性汚れ）は３×８（cm2）の鉄のテ
ストピースに、ナタネ油／カーボンブラック（重量比：
５／１）を1.0ｇ塗布したものを150℃で130分変性した
（鉛筆硬度５Ｂ）。又、固い汚れ（強変性汚れ）は上記
のものを195℃で115分変性させたものを使用した（鉛筆
硬度３Ｈ）。<Test method> Detergency 1. Model dirt preparation Soft dirt (weakly modified dirt) was applied to a 3 x 8 (cm 2 ) iron test piece and rapeseed oil / carbon black (weight ratio:
What was coated with 1.0 g of 5/1) was denatured at 150 ° C. for 130 minutes (pencil hardness 5B). For hard stains (strongly modified stains), those obtained by modifying the above at 115 ° C. for 115 minutes were used (pencil hardness 3H).
２．洗浄力評価 試料１ｇを採取し、ウレタンスポンジを用いて、１kg／
30cm2の荷重により30回洗浄した後の重量減少率より相
対研磨力を求め、下記のとおり６段階評価を行った。2. Detergency evaluation 1g sample was taken and urethane sponge was used for 1kg /
Relative polishing power was obtained from the weight reduction rate after washing 30 times with a load of 30 cm 2 , and the following 6-grade evaluation was performed.
相対研磨力（％） ６ 101〜 ５ 81〜100 ４ 61〜80 ３ 41〜60 ２ 21〜40 １ ０〜20 （相対研磨力（％）；液体クレンザー市販品Ａの研磨洗
浄力を50とした。） 傷つけ性 試料１ｇを採取し、ウレタンスポンジにてステンレスを
30回洗浄後、傷の有無を肉眼観察し、評価を行った。Relative polishing power (%) 6 101 to 5 81 to 100 4 61 to 80 3 41 to 60 2 21 to 40 10 to 20 (relative polishing power (%); polishing power of liquid cleanser commercial product A was set to 50) Scratchability Take 1g of sample and use stainless steel with urethane sponge.
After washing 30 times, the presence or absence of scratches was visually observed and evaluated.
実施例２ 表−２に示す組成物を調整し、各組成物の仕上がり感に
ついて以下の様に評価を行った。 Example 2 The compositions shown in Table 2 were prepared, and the finished feeling of each composition was evaluated as follows.
すすいだ後の艶、仕上がり感 各組成物について主婦30人に流し台を洗って貰い、すす
いだ後の艶、仕上がり感について５段階評価を行いその
平均値を求めた。Gloss and Rinse Feeling after Rinsing For each composition, 30 housewives wash the sink, and the luster after rinsing and the feel of finishing are evaluated on a scale of 5 and the average value is calculated.
５ 仕上がり感がよい（艶がでる） ４ やや仕上がり感がよい（やや艶がでる ３ どちらともいえない ２ あまり仕上がり感がよくない（あまり艶がでな
い） １ 仕上がり感がよくない（艶がでない） 5 Good finish (glossy) 4 Slightly finish (somewhat glossy 3 Not very good 2 Not very good finish (not very glossy) 1 Not good finish (no gloss)
第１図は本発明の組成物の(a)成分、(b)成分、(c)成分
の比率を示す図である。FIG. 1 is a diagram showing the ratio of the components (a), (b) and (c) of the composition of the present invention.
フロントページの続き (72)発明者 出口 勝彦 栃木県宇都宮市泉が丘２―４―12―507 (56)参考文献 特開 昭62−95400（ＪＰ，Ａ) 特開 昭60−188496（ＪＰ，Ａ)(72) Inventor Katsuhiko Deguchi 2-14-12-507 Izumigaoka, Utsunomiya City, Tochigi Prefecture (56) References JP 62-95400 (JP, A) JP 60-188496 (JP, A)
Claims (3)
ム (b)平均粒子径が５〜40μの二酸化珪素 (c)平均粒子径が２〜15μの結晶性アルミノ珪酸塩 (d)陰イオン性界面活性剤 (e)非イオン性界面活性剤 を必須成分として含有し、(a)成分、(b)成分及び(c)成
分の合計が20重量％〜60重量％、かつ(a)成分、(b)成分
及び(c)成分の比率が三角座標の点Ｆ〔(a)80：(b)５：
(c)15〕、点Ｂ〔(a)70：(b)５：(c)25〕、点Ｇ〔(a)6
5：(b)8.5：(c)26.5〕、点Ｅ〔(a)65：(b)30：(c)
５〕、点Ｈ〔(a)80：(b)15：(c)５〕で囲まれた範囲内
にあり、(d)成分を0.5〜５重量％、(e)成分を１〜10重
量％含有することを特徴とする液体クレンザー組成物。1. (a) Calcium carbonate having an average particle size of 5 to 40 μ (b) Silicon dioxide having an average particle size of 5 to 40 μ (c) Crystalline aluminosilicate (d) having an average particle size of 2 to 15 μ Anionic surfactant (e) contains a nonionic surfactant as an essential component, and the total of the components (a), (b) and (c) is 20% by weight to 60% by weight, and (a) ) Component, (b) component and (c) component ratio in triangular coordinates F [(a) 80: (b) 5:
(c) 15], point B [(a) 70: (b) 5: (c) 25], point G [(a) 6]
5: (b) 8.5: (c) 26.5], point E [(a) 65: (b) 30: (c)
5], within the range surrounded by point H [(a) 80: (b) 15: (c) 5], the component (d) is 0.5 to 5% by weight, and the component (e) is 1 to 10% by weight. % Of a liquid cleanser composition.
の範囲第１項記載の液体クレンザー組成物。2. The liquid cleanser composition according to claim 1, which contains 0.1 to 8% by weight of a silicate.
それらの塩を0.1〜５重量％含有する特許請求の範囲第
１項記載の液体クレンザー組成物。3. A liquid cleanser composition according to claim 1, containing 0.1 to 5% by weight of a di- or tricarboxylic acid having 3 to 8 carbon atoms or a salt thereof.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62305078A JPH0631408B2 (en) | 1987-12-02 | 1987-12-02 | Liquid cleanser composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62305078A JPH0631408B2 (en) | 1987-12-02 | 1987-12-02 | Liquid cleanser composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01146993A JPH01146993A (en) | 1989-06-08 |
| JPH0631408B2 true JPH0631408B2 (en) | 1994-04-27 |
Family
ID=17940847
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP62305078A Expired - Lifetime JPH0631408B2 (en) | 1987-12-02 | 1987-12-02 | Liquid cleanser composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0631408B2 (en) |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60188496A (en) * | 1984-03-09 | 1985-09-25 | ライオン株式会社 | Cleaning abrasive base material |
| JPS6295400A (en) * | 1985-10-21 | 1987-05-01 | 花王株式会社 | Liquid cleanser composition |
-
1987
- 1987-12-02 JP JP62305078A patent/JPH0631408B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH01146993A (en) | 1989-06-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US6812194B2 (en) | Alkaline metal cleaner comprising sulfonated-hydrophobically modified polyacrylate | |
| EP0232092A2 (en) | Compositions and methods for removing tarnish from household articles | |
| JPS60112898A (en) | Liquid cleanser composition | |
| WO2006041704A1 (en) | Light duty liquid detergent composition | |
| US4158553A (en) | Non-scratching liquid scouring cleanser using abrasives with a Mohs hardness of greater than 3 | |
| JPH09183996A (en) | Detergent composition | |
| JPS6114296A (en) | Abrasive-containing liquid cleaning composition | |
| JPH1025494A (en) | Liquid detergent composition for tableware | |
| US2708157A (en) | Abrasive cleanser and method of scouring surfaces | |
| JPS606797A (en) | Abrasive-containing liquid detergent composition | |
| JPH0631408B2 (en) | Liquid cleanser composition | |
| GB2125428A (en) | Liquid scouring cleanser compositions | |
| JPS597760B2 (en) | Bathroom cleaning composition | |
| JPH02151692A (en) | Liquid cleanser composition | |
| JP3208223B2 (en) | Cleaning composition for hard surfaces | |
| JPH0472880B2 (en) | ||
| RU2089587C1 (en) | Composition for production of paste for cleaning articles of precious metals | |
| CN115572644B (en) | Liquid composition for improving glossiness of hard surface and hard surface detergent | |
| JP3299039B2 (en) | Hard surface cleaning composition | |
| JPS60184599A (en) | Abrasive-containing liquid cleaning composition | |
| JPH0572958B2 (en) | ||
| JPS6072997A (en) | Abrasive-containing cleaning composition | |
| JPS63234094A (en) | Liquid cleanser composition | |
| JPS61243899A (en) | Multipurpose detergent for hard surface | |
| JPH02215898A (en) | Liquid cleanser composition |